Organic Nitrogen Compound Contains A Nitrogen Atom Bonded To Three Atoms Or Carbon Patents (Class 528/53)
  • Patent number: 11746265
    Abstract: A solvent-based two-component adhesive composition is disclosed. The adhesive composition comprises an isocyanate component and a polyol component. One or both of the isocyanate component and polyol component comprises at least one butylene oxide-based polyol. The at least one butylene oxide-based polyol can be selected from the group consisting of a polybutylene oxide polyols, polybutylene oxide-propylene oxide copolymer polyols, polybutylene oxide-polyethylene oxide copolymer polyols, and combinations of two or more thereof. A method for forming a laminate is also disclosed. The method comprises forming an adhesive composition, the composition comprising at least one polyol comprising at least one butylene oxide-based polyol, applying a layer of the adhesive composition to a surface of a film, bringing the layer into contact with a surface of another film to form a laminate, and curing the adhesive composition. A laminate formed by this method is also disclosed.
    Type: Grant
    Filed: May 22, 2017
    Date of Patent: September 5, 2023
    Assignee: The Dow Chemical Company
    Inventors: Mikhail Y. Gelfer, Rui Xie, Jonathan Barrus
  • Patent number: 11708456
    Abstract: The present invention relates to novel (per)fluoropolyether polymers characterized by high molecular weight and high functionality, to a process for their manufacture and to their use as intermediate compounds in the preparation of further polymers.
    Type: Grant
    Filed: February 6, 2020
    Date of Patent: July 25, 2023
    Assignee: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.
    Inventors: Pier Antonio Guarda, Giovanni Simeone, Rosaldo Picozzi, Marco Galimberti
  • Patent number: 11680131
    Abstract: A two-component polyurethane composition including a polyol component and a polyisocyanate component, wherein the polyol component comprises at least one polyester polyol A1 based on dimer fatty acids and/or dimer fatty alcohols having an OH number of 65-350 mg KOH/g, at least one polybutadiene polyol A2 and at least one alkoxylated alkylenediamine A3. The polyurethane composition has high strength and only a minor dependence of the mechanical properties, especially strength, on temperature, especially in the range from ?40° C. to +100° C.
    Type: Grant
    Filed: March 16, 2020
    Date of Patent: June 20, 2023
    Assignee: SIKA TECHNOLOGY AG
    Inventor: Steffen Kelch
  • Patent number: 11673998
    Abstract: A triazine ring-containing polymer, having a structural unit represented by the following formula (1), in which a peak top molecular weight obtained by gel permeation chromatography is 19,000 or less.
    Type: Grant
    Filed: May 12, 2021
    Date of Patent: June 13, 2023
    Assignee: IDEMITSU KOSAN CO., LTD.
    Inventor: Hirotoshi Ishii
  • Patent number: 11597795
    Abstract: The present invention relates to the use of tertiary amines as catalysts for the cross-linking of isocyanate groups which are aliphatically and/or cyclo-aliphatically bonded. The catalysts according to the invention have the particular advantage that they are thermally latent.
    Type: Grant
    Filed: April 12, 2019
    Date of Patent: March 7, 2023
    Assignee: Covestro Intellectual Property GmbH & Co. KG
    Inventors: Richard Meisenheimer, Paul Heinz, Dirk Achten, Frank-Stefan Stern
  • Patent number: 11311467
    Abstract: Polyurea capsules that encapsulate active materials in polymeric walls resulting from the polymerization of an aromatic or aliphatic polyisocyanate and a cross-linking agent are provided as are consumer products containing said polyurea capsules and for methods for producing such capsules.
    Type: Grant
    Filed: August 15, 2013
    Date of Patent: April 26, 2022
    Assignee: INTERNATIONAL FLAVORS & FRAGRANCES INC.
    Inventors: Yabin Lei, Li Xu, Carol Joyce, Lewis Michael Popplewell
  • Patent number: 10815330
    Abstract: The invention relates to a two-component system containing a component A) comprising at least one NCO-reactive connection, and a component B) comprising at least one polyisocyanate, characterised in that the component A) contains ?400 to ?9500 wt. ppm water, in relation to the total weight of the component A), and the component A) and/or the component B) contains at least one thermolatent, inorganic, tin-containing catalyst. The invention also relates to a method for producing a coating on a substrate, coatings that can be obtained with the method, the use of the component A) or B) in the two-component system, and substrates coated with the coating, in particular coated vehicle bodies or vehicle parts.
    Type: Grant
    Filed: April 18, 2017
    Date of Patent: October 27, 2020
    Assignee: Covestro Deutschland AG
    Inventors: Michael Grahl, Uwe Klippert, Frank Richter, Sven Siegemund, Jan Weikard
  • Patent number: 10730997
    Abstract: The invention relates to a polyisocyanate mixture comprising at least one polyisocyanurate which is based on tolylene diisocyanate and has isocyanate groups and at least one polyurethane which is based on tolylene diisocyanate and has isocyanate groups, wherein the polyisocyanate mixture has a) a solids content of from ?51 to ?90% by weight, based on the total weight of the polyisocyanate mixture and b) a content of monomeric tolylene diisocyanate of ?0.9% by weight, based on the total weight of the polyisocyanate mixture, and the polyisocyanurate which is based on tolylene diisocyanate and has isocyanate groups has a polydispersity D of from ?1 to ?1.
    Type: Grant
    Filed: October 18, 2017
    Date of Patent: August 4, 2020
    Assignee: Covestro Deutschland AG
    Inventors: Christoph Irle, Stefan Groth, Ruiwen Wu, Antonio Midolo, Robert Maleika, Hongchao Li, Hao Liu
  • Patent number: 10731052
    Abstract: A system for forming an elastomeric composition for application to a substrate includes an isocyanate component and an isocyanate-reactive component. The isocyanate component includes a polymeric polyisocyanate and optionally an isocyanate-terminated prepolymer. The isocyanate-reactive component is reactive with the isocyanate component and includes a polyol component and a polyetheramine. The polyol component is a mixture of (a) a hydrophobic polyol; (b) a polyether polyol different than the hydrophobic polyol and having a weight average molecular weight greater than 500 g/mol; and (c) a polyaminopolyol. The elastomeric composition is formed as the reaction product of the isocyanate component and the isocyanate-reactive component and may be applied as an elastomeric coating layer on a substrate such as a steel pipe. The steel pipe having the applied elastomeric coating layer satisfies the standard for use in the water supply industry as set forth in AWWA C222.
    Type: Grant
    Filed: February 10, 2016
    Date of Patent: August 4, 2020
    Assignee: BASF SE
    Inventors: Lyle Caillouette, David R. Phelps, Stephen Smith, Karl Gust
  • Patent number: 10584213
    Abstract: An elastomer, a process for forming an elastomer, and an article of manufacture are disclosed. The elastomer comprises a phosphazene backbone and at least one polyhexahydrotriazine component. The process for forming the elastomer includes obtaining an amine-terminated cyclotriphosphazene, reacting it with a diamine to form a phosphazene-containing PHT polymer, and then reacting the phosphazene-containing PHT polymer with a side-chain modified cyclic phosphazene to form a PCPHT elastomer with halogen ligands. The PCPHT elastomer with halogen ligands is then reacted with an alkoxide to form a PCPHT elastomer with at least one ether-linked side chain. The article of manufacture comprises a material comprising an elastomer having a phosphazene backbone and at least one PHT component.
    Type: Grant
    Filed: August 10, 2018
    Date of Patent: March 10, 2020
    Assignee: International Business Machines Corporation
    Inventors: Jason T. Wertz, Brandon M. Kobilka, Joseph Kuczynski, Jacob T. Porter
  • Patent number: 10457769
    Abstract: The present invention relates to the use of nitrogenous compounds of formula (I) and/or corresponding quaternized and/or protonated compounds for production of polyurethanes, to compositions comprising said compounds and also to polyurethane systems, in particular polyurethane foams, obtained using said compounds.
    Type: Grant
    Filed: July 10, 2015
    Date of Patent: October 29, 2019
    Assignee: Evonik Degussa GmbH
    Inventors: Thomas Günther, Michael Fiedel, Martin Glos, Roland Hubel
  • Patent number: 10428171
    Abstract: The present invention relates to a one-component processing method and system for preparing polyurea materials. This method and system involves a polymerization process using cyclic oligomeric polyurea precursors. These cyclic oligomeric precursors have dynamic urea bonds such as hindered urea bonds (HUBs). These cyclic oligomeric precursors exhibit dynamic properties to reversibly dissociate in situ yielding isocyanate and amine components which polymerize to yield the polyureas, such as linear, branched or cross-linked polyureas. This method and system has advantages over conventional methods that utilize two-component systems. Such two-component systems require the segregation of the isocyanate and amine components to prevent premature or too rapid polymerization. The resulting polyureas are useful for a variety of applications including coatings.
    Type: Grant
    Filed: February 3, 2016
    Date of Patent: October 1, 2019
    Assignee: THE BOARD OF TRUSTEES OF THE UNIVERSITY OF ILLINOIS
    Inventors: Jianjun Cheng, Hanze Ying
  • Patent number: 9884940
    Abstract: Compounds include boronate ester polythioaminals with substituents that include hydrogen, fluorine or substituted or unsubstituted alkyls. The boronate ester polythioaminals have number average molecular weight or weight average molecular weight between about 2,000 to about 160,000.
    Type: Grant
    Filed: May 12, 2016
    Date of Patent: February 6, 2018
    Assignee: INTERNATIONAL BUSINESS MACHINES CORPORATION
    Inventors: Dylan J. Boday, Jeannette M. Garcia, James L. Hedrick, Rudy J. Wojtecki
  • Patent number: 9809673
    Abstract: Methods and materials for preparing a covalent 3D nano-object are provided. A diamine or triamine monomer and a monoamine terminated precursor may be reacted to form a star polymer material. A cross-linking polymerization process may in a nanogel core with the monoamine terminated precursor covalently linked to the nanogel core. The covalent 3D nano-object may comprise HT, PHT, HA, and/or PHA materials.
    Type: Grant
    Filed: February 2, 2017
    Date of Patent: November 7, 2017
    Assignee: INTERNATIONAL BUSINESS MACHINES CORPORATION
    Inventors: Dylan J. Boday, Jeannette M. Garcia, James L. Hedrick, Rudy J. Wojtecki
  • Patent number: 9687424
    Abstract: Polyurea capsules that encapsulate active materials in polymeric walls resulting from the polymerization of an aliphatic polyisocyanate and a cross-linking agent such as a diamine, amphoteric amine or guanidine amine/salt are provided as are consumer products containing said polyurea capsules and for methods for producing such capsules.
    Type: Grant
    Filed: August 16, 2013
    Date of Patent: June 27, 2017
    Assignee: INTERNATIONAL FLAVORS & FRAGRANCES
    Inventors: Yabin Lei, Li Xu, Carol Joyce, Lewis Michael Popplewell
  • Patent number: 9562137
    Abstract: Monomer embodiments that can be used to make polymers, such as homopolymers, heteropolymers, and that can be used in particular embodiments to make sequence-defined polymers are described. Also described are methods of making polymers using such monomer embodiments. Methods of using the polymers also are described.
    Type: Grant
    Filed: May 13, 2016
    Date of Patent: February 7, 2017
    Assignee: Battelle Memorial Institute
    Inventors: Jay W. Grate, Kai-For Mo, Michael D. Daily
  • Patent number: 9416215
    Abstract: The present invention relates to new catalysts and production thereof as well as the preferred use thereof in the production of polyisocyanate polyaddition products. The described catalysts are tetravalent tin compounds with at least one ligand bonded via at least one oxygen atom or sulfur atom and containing at least one nitrogen atom.
    Type: Grant
    Filed: April 18, 2009
    Date of Patent: August 16, 2016
    Assignee: Covestro Deutschland AG
    Inventors: Jens Krause, Stephan Reiter, Stefan Lindner, Axel Schmidt, Klaus Jurkschat, Markus Schürmann, Gerrit Bradtmöller
  • Patent number: 9045672
    Abstract: The present invention is a composition comprising: a) one or more isocyanate functional prepolymers; b) one or more compounds containing a cycloaliphatic tertiary amine; c) one or more compounds containing a peroxide group; and d) one or more acrylate containing components. The system can be used in the form of a two part adhesive or in the form of a one part adhesive and an activator adapted to be applied to the surface of one or more of the substrates to which the adhesive is to be bonded.
    Type: Grant
    Filed: April 25, 2012
    Date of Patent: June 2, 2015
    Assignee: Dow GlobalTechnologies LLC
    Inventors: Gary L. Jialanella, Lirong Zhou
  • Patent number: 8987404
    Abstract: The invention relates to a coating composition comprising: A) at least one thiol-functional compound having at least one thiol group, B) at least one polyisocyanate cross-linking agent with at least one free isocyanate group and C) at least one catalyst compound, said catalyst compound comprising at least one catalyst for the curing reaction between the thiol groups of component A and the free isocyanate groups of component B, and at least one cyclodextrine.
    Type: Grant
    Filed: April 29, 2010
    Date of Patent: March 24, 2015
    Assignee: Axalta Coating Systems IP Co., LLC
    Inventors: Carmen Flosbach, Stefanie Matten, Katharina Dreger
  • Publication number: 20150065675
    Abstract: Polyisocyanate-based polymers are formed by curing a reaction mixture containing at least one polyisocyanate and at least one isocyanate-reactive compound having at least two isocyanate-reactive groups in the presence of a bismuth mono- or dithiocarbamate or mono- or dithiocarbonate salt.
    Type: Application
    Filed: March 26, 2013
    Publication date: March 5, 2015
    Inventors: Richard J. Keaton, Peter M. Margl, Rajat Duggal, Scott D. Boelter, Duane R. Romer, Nathan Wilmot
  • Patent number: 8962784
    Abstract: A novel macromer or mixture thereof is described herein, comprising isocyanatophenyl ether terminal moieties and at least two residues of a water-soluble polymer having a molecular weight ranging from 80 to 10,000 adjacent to the ether group of the isocyanatophenyl ether terminal isocyanate moieties, thereby forming at least two ether linkages in the macromer or mixture thereof. A method for making a polyisocyanate macromer is also described herein.
    Type: Grant
    Filed: December 19, 2008
    Date of Patent: February 24, 2015
    Assignee: Ethicon, Inc.
    Inventors: Chetan Anirudh Khatri, Benjamin D. Fitz, Joseph Zavatsky
  • Patent number: 8961879
    Abstract: The invention relates to curable compositions which are prepared from polyol components containing one or more polyols and isocyanate components containing one or more isocyanates, which compositions contain at least one indicator having at least one quinonoid group, which indicator signifies the degree of curing by a change of color. The invention also relates to a method for indicating the progress of curing in such curable compositions.
    Type: Grant
    Filed: March 19, 2009
    Date of Patent: February 24, 2015
    Assignee: Mankiewicz Gebr. & Co. GmbH & Co. KG
    Inventors: Guenther John, Stefanie Ehmke (nee Behrens Brammertz)
  • Patent number: 8946372
    Abstract: The present invention relates to the use of specific inorganic Sn(IV) for the production of polyisocyanate polyaddition products from a) at least one aliphatic, cycloaliphatic, araliphatic and/or aromatic polyisocyanate, b) at least one NCO-reactive compound, c) at least one thermolatent inorganic tin-containing catalyst, d) optionally further catalysts and/or activators other than c), e) optionally fillers, pigments, additives, thickeners, antifoams and/or other auxiliary substances and additives, wherein the ratio of the weight of the tin from component c) and the weight of component a) is less than 3000 ppm when component a) is an aliphatic polyisocyanate and less than 95 ppm when component a) is an aromatic polyisocyanate, wherein as thermolatent catalysts cyclic tin compounds of formula I, II or III: wherein n>1, are used.
    Type: Grant
    Filed: October 26, 2010
    Date of Patent: February 3, 2015
    Assignee: Bayer Intellectual Property GmbH
    Inventors: Frank Richter, Raul Pires, Stephan Reiter, Jens Krause, Klaus Jurkschat, Ljuba Iovkova, Markus Schürmann, Gerrit Bradtmöller
  • Patent number: 8912113
    Abstract: Described herein are metal amidine complexes in combination with a second compound useful as catalysts in a number of polymerization reactions, including polyurethane and epoxy polymerization reactions. Also described herein are various coating compositions and methods of using same for coating substrates using the metal amidine complexes in combination with a second compound.
    Type: Grant
    Filed: March 5, 2012
    Date of Patent: December 16, 2014
    Assignee: King Industries, Inc.
    Inventors: Ramanathan Ravichandran, Robert Coughlin, Bing Hsieh, Farouk Abi-Karam, John Florio
  • Publication number: 20140343226
    Abstract: Invention relates to bismuth-containing catalysts, obtainable by reacting at least one bismuth(III) salt or bismuth(III) complex with at least one 1,3-ketoamide with the formula (I). Such complex compounds are suited in particular as catalysts for one- and two-component polyurethane compositions. The invention further relates to two-component polyurethane compositions, including at least one polyisocyanate as the first component, at least one polyol as the second component, and at least one such bismuth-containing catalyst. The invention further relates one-component polyurethane compositions, including at least one polyurethane prepolymer having isocyanate groups, produced from at least one polyisocyanate with at least one polyol, and one such bismuth-containing catalyst. The invention also relates to various uses of the aforementioned polyurethane compositions.
    Type: Application
    Filed: December 12, 2012
    Publication date: November 20, 2014
    Inventors: Urs Burckhardt, Rita Cannas
  • Patent number: 8889814
    Abstract: The object of the invention are compounds of the formula (2) wherein R1 is H, methyl or ethyl, R2 is C1- to C4 alkyl, A is a C2- to C4 alkylene group, m is number from 10 to 400, n is 1, 2, 3, 4, or 5, a method for their production and their use in the production of polyurethane prepolymers.
    Type: Grant
    Filed: August 27, 2013
    Date of Patent: November 18, 2014
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Klaus Poellmann, Juergen Muenter
  • Patent number: 8889813
    Abstract: An aspect of the present invention relates to a mixture of a sulfonate group-containing compound denoted by general formula (1) with a protonic acid: wherein, in general formula (1), X denotes a divalent linking group; each of R1 and R2 independently denotes an alkyl group comprising at least one hydroxyl group and equal to or more than three carbon atoms or an aralkyl group comprising at least one hydroxyl group and equal to or more than eight carbon atoms; and M denotes a cation.
    Type: Grant
    Filed: March 5, 2013
    Date of Patent: November 18, 2014
    Assignee: FUJIFILM Corporation
    Inventors: Kazufumi Omura, Katsumi Araki
  • Patent number: 8859675
    Abstract: The present invention provides a non-aqueous composition containing a particulate solid, an organic medium and a polyurethane dispersant having laterally attached pendant groups with tertiary amine group(s), an essentially linear backbone and laterally attached solvent-solubilising side chains of a polyester or polyether including mixtures of such side chains.
    Type: Grant
    Filed: December 3, 2007
    Date of Patent: October 14, 2014
    Assignee: Lubrizol Advanced Materials, Inc.
    Inventors: Stuart N. Richards, Andrew J. Shooter
  • Patent number: 8841380
    Abstract: The present invention provides high solids, two-component polyurethane compositions comprising, as one component, polyisocyanate compositions having one or more isocyanurate made from bis(isocyanatomethyl)-cyclohexane, as a second component, one or more high solids polyol, and in either component, one or more tertiary amine catalyst. Optionally, the compositions further comprise one or more zinc amine catalyst. The compositions provide coatings, which exhibit an excellent balance of pot life and dry to touch or tack free time, as well as early rain resistance and hardness, while enabling a lower volatile organic content (VOC) of the compositions for comparable performance.
    Type: Grant
    Filed: November 16, 2011
    Date of Patent: September 23, 2014
    Assignee: Rohm and Haas Company
    Inventors: Donald C. Schall, Jia Tang
  • Patent number: 8822594
    Abstract: Coating compositions comprising a polyurea formed from a reaction mixture comprising: (a) a first component comprising an isocyanate, the first component having a viscosity of ?2000 centipoise at a temperature ?7° C.; and (b) a second component comprising an amine. Substrates coated at least in part with such a composition are also disclosed. Footwear coated at least in part with polyurea are also disclosed.
    Type: Grant
    Filed: April 20, 2009
    Date of Patent: September 2, 2014
    Assignee: PPG Industries Ohio, Inc.
    Inventors: George Yakulis, Calum H. Munro, Edward R. Millero, Jr., John Furar, Barry A. Russell, Howard L. Senkfor, Debra L. Singer, Steven V. Barancyk, Thomas R. Hockswender
  • Patent number: 8802770
    Abstract: The present invention discloses a semicrystalline, thermoplastic polyurethane which is comprised of the reaction product of (1) a hydrophobic polyol, (2) a polyisocyanate, and (3) a linear chain extender containing 5 carbon atoms or 7 to 12 carbon atoms; wherein the hydrophobic polyol has a number average molecular weight which is within the range of about 1,000 to about 4,000; wherein the semicrystalline, thermoplastic polyurethane has a weight average molecular weight which is within the range of 50,000 to 1,000,000; and wherein the semicrystalline, thermoplastic polyurethane has a melting point which is within the range of 80° C. to 150° C. This hydrophobic thermoplastic polyurethane offers a unique array of characteristics that are highly desirable for utilization in manufacturing a variety of products. For instance, it can be used in overmolding soft grips onto consumer products, in adhesives, and in protective coatings.
    Type: Grant
    Filed: January 21, 2009
    Date of Patent: August 12, 2014
    Assignee: Lubrizol Advanced Materials, Inc.
    Inventors: Donald A. Meltzer, Jacques P. E. J. Horrion
  • Patent number: 8759469
    Abstract: The present invention relates to a process for preparing a compound comprising at least a urethane group —HN—C(?O)—O, said process comprising a step (E) in which a compound (I) comprising at least an isocyanate functional group —N?C?O is reacted with an organic compound (II) carrying at least a hydroxyl group —OH, said reaction being carried out in a presence of a carbene (III) used as a catalyst.
    Type: Grant
    Filed: July 25, 2008
    Date of Patent: June 24, 2014
    Assignees: Vencorex Frence, Centre National de la Recherche Scientifique (C.N.R.S)
    Inventors: Gerard Mignani, Mathias Destarac, Daniel Taton, Yves Gnanou, Antoine Baceiredo, Tsuyoshi Kato, Fabien Bonnette, Gopakumar Sivasankarapillai
  • Patent number: 8747602
    Abstract: A polyurethane adhesive which is useful in bonding porous and non-porous surfaces is provided. The adhesive is especially useful in bonding windshield glass into automotive frames under a variety of environmental conditions, particularly in after market windshield replacement applications. The polyurethane includes at least one urethane prepolymer which is based on at least one thermoplastic polyol. In one embodiment, the urethane prepolymer may be formed from one or more polyisocyanates, one or more polyetherpolyols and one or more thermoplastic polyesterpolyols, wherein the prepolymer has a free isocyanate content of from about 0.6 to about 3.5% by weight, based on the weight of the polyurethane. In another embodiment, a one-part adhesive composition is provided which includes an isocyanate-functional and thermoplastic polyurethane prepolymer having a free isocyanate content of from about 0.6 to about 3.
    Type: Grant
    Filed: November 22, 2010
    Date of Patent: June 10, 2014
    Assignee: Sika Technology AG
    Inventors: Steven Rosenberg, Hong Yao, Thomas Bove, Adrian Van Maurik, Hans Peter Tschan, Norman Blank
  • Publication number: 20140127516
    Abstract: The present invention relates to a novel composite for preventing ice adhesion. A superhydrophobic or superhydrophilic surface with a hydrophobic, low freezing point liquid adsorbed onto surface asperities results in a durable, renewable anti-icing surface. The preparation method for novel icing and rain protecting surface is disclosed.
    Type: Application
    Filed: November 5, 2012
    Publication date: May 8, 2014
    Inventors: LIANG WANG, VIKTORIA REN WANG
  • Patent number: 8648124
    Abstract: The invention concerns novel weather-resistant polyurethane casting compounds, a process for preparation thereof and use thereof in the building sector.
    Type: Grant
    Filed: February 25, 2011
    Date of Patent: February 11, 2014
    Assignee: Rhein Chemie Rheinau GmbH
    Inventors: Robert Eiben, Peter Schuster
  • Publication number: 20140018461
    Abstract: A titanium-oxo-chelate catalyst formulation, comprising: (i) at least one compound of the formula (I), wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, R11 and R12 independently of each other are for example hydrogen, halogen, C1-C20alkyl, C6-C14aryl which is unsubstituted or substituted; or R1, R2 and R3 and/or R4, R5 and R6 and/or R7, R8 and R9 and/or R10, R11 and R12 together with the C-atom to which they are attached each form a C6-C14aryl group which is unsubstituted or substituted; or R1 and R2 and/or R4 and R5 and/or R7 and R8 and/or R10 and R11 together with the C-atom to which they are attached form a 5- to 7-membered carbocyclic ring; at least one chelate ligand compound of the formula (IIa), (IIb) or (IIc), wherein R1, R2, R3, R4, R5 and R6 are defined as above for formula (I), is suitable as photolatent catalyst formulation for polymerizing compounds, which are capable to crosslink in the presence of a Lewis acid.
    Type: Application
    Filed: April 2, 2012
    Publication date: January 16, 2014
    Applicant: BASF SE
    Inventors: Tobias Hintermann, Antoine Carroy, Caroline Lordelot, Didier Bauer, Rachel Kohli Steck, Marc Faller
  • Patent number: 8563676
    Abstract: Polyurethanes made using compounds of formula A: Q-(R6)-M-(R7)-NR3R4 where Q is OH or NR1R2; M is O or NR5 where R5 is R1 or H; R1 is alkyl or an alkylene alcohol of from 1 to 6 carbons, especially CH3, CH2CH3, or CH2CH2OH; R2 is alkyl or an alkylene alcohol of from 1 to 6 carbons, especially CH3, CH2CH3, or —CH2CH2OH; R3 is hydrogen or alkyl of from 1 to 6 carbons, especially H, CH3 or CH2CH3; R4 is hydrogen; where R6 is an alkylene group of from 2 to 5 carbons; and wherein R7 is an alkylene group of from 2 to 5 carbons. Illustrative catalysts of this invention include but are not limited to N,N,N?-trimethylbis(aminoethyl)ether, dimethylaminoethoxypropylamine, and (3-aminopropyl)(2-hydroxyethyl)methylamine.
    Type: Grant
    Filed: June 11, 2008
    Date of Patent: October 22, 2013
    Assignee: Huntsman Petrochemical LLC
    Inventors: Jennifer Koch Pratt, Robert A. Grigsby, Jr., Gene Wiltz, Ernest L. Rister, Don Ridgway, Gabor Felber
  • Patent number: 8552078
    Abstract: A composition for making a polyurethane foam includes a non-fugitive tertiary amine urethane catalyst and an alkylated polyamine crosslinking additives. Foams prepared from the reaction of a polyol and an organic isocyanate in the presence of these ingredients show improved resistance to deterioration of physical properties upon humid ageing.
    Type: Grant
    Filed: October 17, 2006
    Date of Patent: October 8, 2013
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Gamini Ananda Vedage, Juan Jesus Burdeniuc, Allen Robert Arnold, Jr., James Douglas Tobias
  • Patent number: 8530544
    Abstract: The present invention relates to a method for preparing macromolecular species with a modified surface, comprising a step (e) in which macromolecular species (M), initially carrying —OH and/or —SH functions, are brought into contact with: a catalyst (C) carrying at least one conjugated guanidine function; and reactive species (E), comprising reactive groups including: (i) at least one group including an a,b-unsaturated carbonyl group C?C—C?O and/or an a,b-unsaturated thiocarbonyl group C?C—C?S; and/or (ii) at least one heterocyclic group comprising from 3 to 5 ring members, said group being selected from cyclic ethers, cyclic thioethers and aziridine rings; and/or (iii) at least one group selected from isocyanate —N?C?O or thioisocyanate —N?C?S groups, and trivalent groups of formula >C?CZ—, where Z is an electron-withdrawing group. The invention also relates to the macromolecular species with a modified surface that are obtained in this context.
    Type: Grant
    Filed: March 27, 2009
    Date of Patent: September 10, 2013
    Assignee: Polyrise
    Inventors: Vincent Gaud, Fabien Rouge
  • Publication number: 20130225781
    Abstract: Polyisocyanate-based polymers are formed by curing a reaction mixture containing at least one polyisocyanate and at least one isocyanate-reactive compound having at least two isocyanate-reactive groups in the presence of a zinc catalyst that contains at least one zinc atom associated with a polydentate ligand that contains at least one nitrogen-containing complexing site.
    Type: Application
    Filed: July 5, 2011
    Publication date: August 29, 2013
    Inventors: Richard J. Keaton, Peter M. Margl, Duane R. Romer, Nathan Wilmot, Rajat Duggal, Rashmi Chamsarkar
  • Patent number: 8512506
    Abstract: An automotive windshield replacement method which includes: a) applying an adhesive to an automotive windshield and/or an automobile body substrate, said adhesive including at least one urethane prepolymer formed from reaction materials including: i) isophorone diisocyanate and/or 4,4?-diphenylmethanediisocyanate; ii) an ethylene oxide-end-capped triol having a weight average molecular weight of about 4500 to about 5000; and iii) hexanediol adipate; b) contacting the substrates together, within the working time of the adhesive, along at least a portion of the substrate(s) to which the adhesive has been applied; and c) allowing the adhesive to bond the substrates together.
    Type: Grant
    Filed: December 21, 2010
    Date of Patent: August 20, 2013
    Assignee: Sika Technology AG
    Inventors: Steven A. Rosenberg, Hong Yao, Thomas Bove, Adrian Van Maurik, Hans Peter Tschan, Norman Blank
  • Patent number: 8492499
    Abstract: The invention relates to addition compounds which are obtainable by reacting a) one or more polyisocyanates containing uretdione groups with b) one or more compounds of the formula (I) Y—(XH)n??(I) with the proviso that at least 50% of the free isocyanate groups of component a) are reacted with the compounds of the formula (I) to give an intermediate which contains uretdione groups, and subsequently the intermediate is reacted with c) one or more compounds of the general formula (II) Z—NHRm??(II) with the proviso that all free NCO groups optionally still present and at least 20% of uretdione groups originally used are reacted with Z—(NHR)m. The invention further relates to the use of the addition compounds as dispersants and dispersion stabilizers, and to a process for preparing them.
    Type: Grant
    Filed: March 20, 2007
    Date of Patent: July 23, 2013
    Assignee: BYK-Chemie GmbH
    Inventors: Karlheinz Haubennestel, Stefan Moessmer, Wolfgang Pritschins, Thomas Launag
  • Patent number: 8470954
    Abstract: A novel macromer or mixture thereof is described herein, comprising benzoyl isocyanate terminal moieties and at least two residues of a water-soluble polymer having a molecular weight ranging from 80 to 10,000 adjacent to the carbonyl group of the benzoyl isocyanate moieties, thereby forming at least two ester linkages in the macromer or mixture thereof. A method for making a polyisocyanate macromer is also described herein.
    Type: Grant
    Filed: July 2, 2007
    Date of Patent: June 25, 2013
    Assignee: Ethicon, Inc.
    Inventors: Christopher M. Westergom, Benjamin D. Fitz
  • Patent number: 8455608
    Abstract: The invention relates to a process for preparing a thermoplastic polyisocyanate polyaddition product based on polyisocyanate (i) and compounds which are reactive toward polyisocyanate, with or without the use of chain extenders, a first catalyst (iv) and/or auxiliaries and/or additives (v), wherein a second catalyst is initially vaporized and then applied to the polyisocyanate polyaddition product by condensation, and to the products prepared therefrom.
    Type: Grant
    Filed: February 25, 2011
    Date of Patent: June 4, 2013
    Assignee: BASF SE
    Inventors: Torben Kaminsky, Dirk Kempfert
  • Publication number: 20130085193
    Abstract: A composition and method for producing a tertiary amine is disclosed. The tertiary amine is contacted with an inert gas. The inert gas is nitrogen or more preferably argon. The amine composition is useful in producing polyurethane foam with lower levels of chemical emissions particularly lower emissions of toxic chemicals.
    Type: Application
    Filed: October 2, 2012
    Publication date: April 4, 2013
    Applicant: AIR PRODUCTS AND CHEMICALS, INC.
    Inventors: Juan Jesus Burdeniuc, Jennifer Elizabeth Antoline Al-Rashid, Andrew Wilson Wang, Diana Sue Dunn, You-Moon Jeon, Jane Garrett Kniss, Stephan Hermann Wendel
  • Patent number: 8349987
    Abstract: The disclosure relates to biocompatible components useful for forming compositions for use as medical/surgical synthetic adhesives and sealants. Biocompatible components of the present disclosure may include a polymeric polyol core, which may be treated with a nitroaryl compound to form a nitro ester. The resulting nitro ester groups may be reduced to form amino groups which, in turn, may be treated to form isocyanate groups. The resulting isocyanate may then be reacted with a second component to form adhesive and/or sealant compositions.
    Type: Grant
    Filed: February 2, 2010
    Date of Patent: January 8, 2013
    Assignee: Covidien LP
    Inventors: Mbiya Kapiamba, Jack Kennedy, Roland Ostapoff
  • Publication number: 20120316290
    Abstract: The present invention relates to a melt processable polyurea and/or copolyurea elastomers made by reacting a lactam-terminated diisocyanate, and an alkylene diol of the general formula HO—R—OH where in is an alkylene group containing from 1 to 20 carbon atoms. The invention further provides for methods of making said polyurea and/or copolyurea elastomers, including a continuous extruder method of production.
    Type: Application
    Filed: February 24, 2011
    Publication date: December 13, 2012
    Applicant: LUBRIZOL ADVANCED MATERIALS, INC.
    Inventors: Bryce W. Steinmetz, Umit G. Makal
  • Publication number: 20120316256
    Abstract: The present invention relates to a polyurethane polymer composition comprising polyethyleneglycol dialkyl ether. There is also provided a process for preparing a polyurethane. The invention also relates to a process for preparing a polyurethane xerogel in the form of a molded article, said process comprising the steps of: i. preparing a mixture of a. at least one polyethylene glycol or at least one polyol of formula (I), wherein at least three Of X1, X2, X3, X4 and X5 are each independently an OH-terminated group, and the remainder of X1, X2, X3, X4 and X5 are each independently H or absent, and Z is a central linking unit, a. at least one di- or poly-isocyanate, b. optionally at least one OH-terminated chain extender, and c. at least one polyethyleneglycol dialkyl ether; ii. dispensing the reaction mixture formed in step i) into a mold; iii. allowing the reaction mixture to react and cure; iv. removing the molded article from the mold; and v. hydrating the molded article.
    Type: Application
    Filed: November 2, 2010
    Publication date: December 13, 2012
    Inventors: Abdul Rashid, Roderick William Jonathan Bowers, Wade Tipton, Neil Bonnette Graham
  • Patent number: 8318889
    Abstract: An organic polyurethane shape memory material includes a C10 chain or C18 chain and consists of hard segment and soft segment. The material is produced by reacting the single-chain type dendrimer with diethylenetriamine to produce dendrimer. Then dendrimer reacts with N-(3-aminopropyl)diethanolamine to produce dendritic diols. Next, polymer HO(C6H10O2)xC2H4OC2H4(C6H10O2)yOH, where x+y=25˜26, reacts with methylenedi-p-phenyl diisocyanate, and at least one type of dendritic diols is added to produce the organic polyurethane shape memory material.
    Type: Grant
    Filed: August 17, 2007
    Date of Patent: November 27, 2012
    Assignee: Chung Shan Institute of Science and Technology, Armaments Bureau, M.N.D.
    Inventors: Wen-Chiung Su, Cheng-Che Tsai, Ching-Shiang Yu, Shenghong A Dai, Ru-Jong Jeng
  • Publication number: 20120225982
    Abstract: Described herein are metal amidine complexes in combination with a second compound useful as catalysts in a number of polymerization reactions, including polyurethane and epoxy polymerization reactions. Also described herein are various coating compositions and methods of using same for coating substrates using the metal amidine complexes in combination with a second compound.
    Type: Application
    Filed: March 5, 2012
    Publication date: September 6, 2012
    Inventors: Ramanathan Ravichandran, Robert Coughlin, Bing Hsieh, Farouk Abi-Karam, John Florio