Abstract: The disclosure shows a cleaning blade for electrophotographic equipment, the cleaning blade through which both high hardness and low warping are obtained and excellent toner scraping properties are realized. The cleaning blade (10) includes a blade part (12) comprising a cured material of a urethane composition containing a polyol, an isocyanate, and a crosslinker or a chain extender. The content of the isocyanate is 28.0 mass % or more with respect to the entire composition. The crosslinker or the chain extender comprises a triol having a molecular weight of 150 or less. The content of the crosslinker or the chain extender is 4.0 mass % or less with respect to the entire composition. The content of the triol having a molecular weight of 150 or less is 0.8 mass % or more with respect to the entire composition.

Abstract: A resin composition which is capable of forming a film that has excellent heat resistance and slidability/bendability; a protective film for circuits, which uses the resin composition; and a dry film or the like which comprises the protective film are provided. Other aspects are a circuit board and a multilayer circuit board, each of which has excellent heat resistance and slidability/bendability. Furthermore, a protective film for circuit boards is provided, which is arranged in contact with a circuit of a printed wiring board, and contains a polyoxazolidone resin that has a weight average molecular weight of 3×104 or more.

Abstract: Polymer-modified polyol, for use as a starting material for polyurethane foam, is made by reacting an olamine, such as triethanolamine, with an isocyanate in the presence of a metal organic catalyst. The catalyst is a metal salt of an organic acid and the viscosity of the polymer-modified polyol is at least 2250 mPa·s. In one embodiment the catalyst is of the formulat M(O.CO.R.CH3)2 where M is a metal and R is a carbon chain of 6 to 20 carbons. A metal salt of a monohydroxy fatty acid, particularly ricinoleic acid may be used.

Abstract: The invention relates to a coating composition comprising: A) at least one thiol-functional compound having at least one thiol group, B) at least one polyisocyanate cross-linking agent with at least one free isocyanate group and C) at least one catalyst compound, said catalyst compound comprising at least one catalyst for the curing reaction between the thiol groups of component A and the free isocyanate groups of component B, and at least one cyclodextrine.

Abstract: The invention relates to a process for preparing binders which contain 1) allophanate groups, 2) groups that react with ethylenically unsaturated compounds with polymerization on exposure to actinic radiation (radiation-curing groups) and 3) optionally NCO-reactive groups, by reacting at temperatures ?130° C. A) one or more NCO-functional compounds containing uretdione groups with B) one or more compounds that contain isocyanate-reactive groups and groups that react with ethylenically unsaturated compounds with polymerization on exposure to actinic radiation (radiation-curing groups), and then C) with one or more saturated, hydroxyl-containing compounds other than B), at least one of these compounds having an OH functionality of ?2, in the presence of D) a catalyst containing one or more zinc compounds, the reaction with compounds C) taking place at least proportionally with the formation of allophanate groups. The present invention also relates to the binders obtained by the process of the invention.

Abstract: A method of reducing odors in lipid-based polyol. At least one lipid-based polyol is provided, and mixed with ricinoleic acid and/or a metal salt of ricinoleic acid. Isocyanate may be added, preferably toluene diisocyanate (TDI). The polyol, and the isocyanate when present, are reacted in the presence of the ricinoleic acid and/or a metal salt of ricinoleic acid which reduces or removes odors in the lipid-based polyol. When isocyanate is used, low, limiting levels are preferred, well below the level required to fully react with all of the polyol. Tin, zinc, sodium, and calcium ricinoleic acid metal salts are particularly preferred. Preferably the reaction takes place without added heat, at room temperature. The reaction may be performed in a chamber which is under at least a partial vacuum.

Abstract: The present invention relates to a single-stage process for preparing polyurethanes which comprise at least three hydrophilic sections, at least four hydrophobic sections, optionally allophanate segments and optionally isocyanurate segments, in the presence of alkali(ne earth) metal carboxylates or zinc carboxylates. Furthermore, the present invention relates to the polyurethanes themselves obtainable in this way, to the use thereof as thickeners for aqueous preparations, and to aqueous preparations comprising polyurethanes of this type.

Abstract: The invention relates to a coating agent composition comprising an isocyanate-group-containing prepolymer obtained by reacting a polyol comprising a polyoxyalkylene polyol having 2-4 hydroxyl groups on average, an oxyethylene group content of 85-100% by mass based on all oxyalkylene groups (100% by mass), and an arithmetic-average molecular weight of 800-2,500 with an alicyclic isocyanate and/or an aliphatic isocyanate in the presence of an organic acid bismuth salt catalyst, the isocyanate(s) being used in such an amount as to result in an isocyanate index of 150-300. The invention can provide a coating agent composition which forms a coating film or film having moisture permeability, excellent in mechanical properties and yellowing resistance, having laundering durability and resistance to sweat deterioration, and containing no organotin compounds.

Abstract: The present invention provides high solids, two-component polyurethane compositions comprising, as one component, polyisocyanate compositions having one or more isocyanurate made from bis(isocyanatomethyl)-cyclohexane, as a second component, one or more high solids polyol, and in either component, one or more tertiary amine catalyst. Optionally, the compositions further comprise one or more zinc amine catalyst. The compositions provide coatings, which exhibit an excellent balance of pot life and dry to touch or tack free time, as well as early rain resistance and hardness, while enabling a lower volatile organic content (VOC) of the compositions for comparable performance.

Abstract: A method of manufacturing a polyurethane compound comprises mixing together a polyol, a polyisocyanate compound and a catalyst and allowing the mixture to cure to form a polyurethane, and is characterized in that the catalyst is a neutral complex of a metal selected from Ti, Zr, Hf, Al, Fe, Bi or Sn and a multidentate organic ligand having: a) a number of anionic donor sites=x; b) a number of neutral donor sites, capable of forming a co-ordinate bond with the metal, =y; c) where x+y=from 5 to 8; d) x is from 2 to 4; e) the ligand molecule is of a size and conformation to enable each of the anionic donor sites and neutral donor sites to form a bond with the same metal atom.

Abstract: Catalysts, which are free of tin, are described which are useful in the reaction between an isocyanate and an alcohol, which is a key step for preparing polyurethane polymers. The catalyst is a metal complex or salt of formula (1): [Zn(L1)l1(L2)l2(Y)x]??(1) in which: l1?1 and l2=0 or 1; with l1+l2=2, x=1 or 2, the symbol L1 represents a ligand which is a ?-dicarbonylato anion or the enolate anion of a ?-dicarbonyl compound or an acetylacetato anion derived from a ?-ketoester, when l1=2, the symbols L1 are identical or different, the symbol L2 represents an anionic ligand which is different from L1, and the symbol Y represents a neutral ligand; where the metal complex or salt C of formula (1) is not zinc diacetylacetonate.

Abstract: Disclosed are flexible polyamines, flexible amine-terminated polyformal adducts, flexible-amine-terminated polythioether adducts, compositions comprising flexible polyamines and isocyanate-terminated prepolymers, and compositions comprising flexible amine-terminated adducts and isocyanate-terminated prepolymers. Uses of the compositions as sealants, and particularly as aerospace sealants, are also disclosed.

Abstract: A method to form a urethane material, the method comprises blending and reacting at least one isocyanate, at least one isocyanate reactive compound and a metallized polyhedral oligomeric silsesquioxane to provide said urethane material, the metallized polyhedral oligomeric silsesquioxane is a dimeric structure with general formula wherein M represents a metal providing a 6-coordinated metal center, x and y being 1, R1O and R2O represent an alkoxide bridging the 6-coordinated metal centers, R3OH and R4OH represent an alcohol ligand and each of R5, to R18 is selected from the group consisting of alkyl-, polyether- and polyester ligands.

Abstract: A hybrid resin composition is described, the composition comprising: A. An A part composition comprising an aliphatic polyfunctional isocyanate compound and a free radical polymerization initiator; and B. A B part composition comprising an ethylenically unsaturated, substantially water-free polyester polyol and a polyurethane catalyst. The A part composition can contain a non-interfering solvent, e.g., styrene, and the B part composition typically has an acid value of 5 or less (based on solids). For outdoor use, the B part composition is preferably free of tertiary hydrogens, ether glycols and terephthalic acid residues.

Abstract: A method for curing a macromolecular cyanurate network. The method of curing includes suspending a plurality of functionalized silica-coated magnetic nanoparticles in a resin mixture, which includes cyanate ester monomers, cyanate ester oligomers, or both. After a static magnetic field is applied to the plurality of functionalized silica-coated magnetic nanoparticles in the resin mixture, an alternating electromagnetic field (having frequency ranging from about 1 kHz to about 10 MHz) is imposed for a cure time.

Abstract: The present invention relates to a novel composite for preventing ice adhesion. A superhydrophobic or superhydrophilic surface with a hydrophobic, low freezing point liquid adsorbed onto surface asperities results in a durable, renewable anti-icing surface. The preparation method for novel icing and rain protecting surface is disclosed.

Abstract: A process for the preparation of an allophanate of one or more identical or different isocyanates, compositions obtained by the process, and uses of the compositions are disclosed. The process comprises reacting an isocyanate with at least one monoalcohol comprising an ether or polyether functional group in the presence of a bismuth-comprising catalyst and a metal compound as co-catalyst.

Abstract: The invention concerns novel weather-resistant polyurethane casting compounds, a process for preparation thereof and use thereof in the building sector.

Abstract: The present invention relates to an obtainment process of biodegradable polymers from a citric residue resulting from the processing of orange juice. The polymers obtained are polyesters classified as polyhydroxyalkanoates including, among them the poly(3-hydroxybutyrate) and poly(3-hydroxybutyrate-co-3-hydroxyvalerate). The biodegradable polymer is obtained from the batch culture process or fed batch culture process with or without recirculation of the cells, using as a carbon source the pre-treated pressing liquor and/or the citric molasses. The polyhydroxyalkanoates, herein described, can be used as substitutes of the synthetic polyesters in different areas, including the food, pharmaceutical, medical, agricultural and other areas.

Abstract: The present invention relates to a process for preparing radiation-curing binders containing allophanate groups by reacting, at temperatures of ?130° C., A) one or more compounds containing uretdione groups with B) one or more OH-functional compounds which contain groups which react, with polymerization, with ethylenically unsaturated compounds on exposure to actinic radiation (radiation-curing groups), C) optionally NCO-reactive compounds other than B), in the presence of D) a catalyst containing at least one zinc compound, to form allophanate groups by opening the uretdione ring. The present invention also relates to the binders obtained by the process of the invention and to coating compositions containing these binders.

Abstract: The invention comprises a catalyst compound of formula Zr(L)(A1)(A2)(A3) where L represents a ketoamide ligand, A1, A2 & A3 may be the same or different and each represent a ligand derived from a compound selected from the group consisting of:—an alcohol, a polyol, an alkyl acetoacetate, a diketone, a ketoamide, a carboxylic acid or ester thereof, an alkanolamine, a phosphoric acid ester and a sulphonic acid or ester thereof. The compound may be made by the reaction of a zirconium alkoxide or haloalkoxide with a ketoamide. The compound is useful as a catalyst for the reaction of a polyisocyanate with a hydroxyl-containing compound, e.g. for the manufacture of polyurethanes or composite cellulosic materials such as fibre-boards.

Abstract: A building material composite that includes a building substrate at least partially lined with a urethane material. The urethane material of the present invention is typically the reaction product of an A-side that includes an isocyanate and a B-side that typically includes: a blown vegetable oil, a cross-linking agent, and a catalyst; a blown vegetable oil and a multifunctional alcohol; or an esterified polyol and a catalyst where the esterified polyol is typically the reaction product of a first polyol and a blown vegetable oil.

Abstract: There is provided a novel dicyanatophenyl-based difunctional cyanate ester which is in a liquid form at ordinary temperature and can obtain a cured product having an excellent low thermal expansion rate. There is disclosed a cyanate ester compound represented by the following formula (I): (wherein R1 represents a hydrocarbon group having 2 to 20 carbon atoms).

Abstract: A composition capable of radiation activated catalysis is provided. The composition comprises a metal compound, a mercapto compound and an olefinic compound. Radiation curable urethane compositions comprising the disclosed composition are also provided. The radiation curable urethane compositions comprise the disclosed composition, a hydroxyl compound and an isocyanate compound. Activation of the composition by radiation in a urethane formulation provides for an efficient method of curing the urethane composition. Coating and adhesive compositions comprising the radiation curable urethane compositions are also provided. In addition, methods for coating and bonding substrates are disclosed.

Abstract: The present invention relates to a process for preparing hydrophobically modified alkylene oxide polyurethanes by polymerizing, in the presence of a catalyst, a solvent-free melt of a polyisocyanate branching agent; a water-soluble polyalkylene glycol having an Mw of from 2000 to 11,000 Daltons; and a diisocyanate; wherein the solvent-free melt further includes a hydrophobic capping agent, or a hydrophobic capping agent is added to the melt after the addition of catalyst. Hydrophobically modified alkylene oxide polyurethanes prepared by the process of the present invention show excellent ICI/KU properties and are useful as thickeners for coatings formulations.

Abstract: The invention relates to a process for preparing a thermoplastic polyisocyanate polyaddition product based on polyisocyanate (i) and compounds which are reactive toward polyisocyanate, with or without the use of chain extenders, a first catalyst (iv) and/or auxiliaries and/or additives (v), wherein a second catalyst is initially vaporized and then applied to the polyisocyanate polyaddition product by condensation, and to the products prepared therefrom.

Abstract: The present invention relates to polyurethane polymers comprising as part of its polymer backbone biobased ?-hydroxyfatty acids or derivatives thereof, processes for the preparation thereof, and compositions thereof having improved properties. The polyurethanes of the present invention are prepared from copolyester prepolymers comprising the biobased ?-hydroxyfatty acids that may also contain additional components that can be selected from aliphatic or aromatic diacids, diols and hydroxyacids obtained from synthetic and natural sources. The biobased ?-hydroxyfatty acids that comprise the polyurethanes and copolyester prepolymers of the present invention are made using a fermentation process from pure fatty acids, fatty acid mixtures, pure fatty acid ester, mixtures of fatty acid esters, and triglycerides from various sources.

Abstract: Disclosed are sulfur-containing polyurea compositions and methods of using the compositions as sealants, particularly as low specific-gravity aerospace sealants.

Abstract: The invention provides polyester polyol compositions and resin blends, useful as components of polyurethane and polyisocyanurate polymers, produced from cyclohexane oxidation reaction byproducts, such as water extracts and non-volatile distillation residues from the reaction. Such byproducts of industrial processes for preparation of adipic acid and caprolactam, important intermediates in the production of various types of nylon, have hitherto largely been used only as fuels. The present invention provides value-added products, methods for making, and methods for using the byproduct-derived polyester polyol compositions. For example, the invention provides polyurethane (PU) and/or polyisocyanurate (PIR) polymers made using the polyol compositions and polyfunctional isocyanates. The PU and PIR polymers can be used as adhesives, binders (e.g., for wood fibers), coatings (e.g., for controlled release fertilizers), and foams.

Abstract: The present invention relates to new high-functionality, highly branched or hyperbranched polylysines, to processes for preparing them, and to their use.

Abstract: A composition capable of radiation activated catalysis is provided. The composition comprises a metal compound, a mercapto compound and an olefinic compound. Radiation curable urethane compositions comprising the disclosed composition are also provided. The radiation curable urethane compositions comprise the disclosed composition, a hydroxyl compound and an isocyanate compound. Activation of the composition by radiation in a urethane formulation provides for an efficient method of curing the urethane composition. Coating and adhesive compositions comprising the radiation curable urethane compositions are also provided. In addition, methods for coating and bonding substrates are disclosed.

Abstract: A formulation for the production of a polyurethane system, in particular a polyurethane foam, containing or consisting of tin and/or zinc ricinoleate(s), optionally tin carboxylate(s), a mixture containing or consisting of urea, sugar alcohol and polyethylene glycol, optionally organic solvent, one or more organic isocyanates having two or more isocyanate functions, one or more polyols having two or more groups which are reactive towards isocyanate, optionally further catalysts for the isocyanate-polyol and/or isocyanate-water reactions and/or isocyanate trimerization, water, optionally physical blowing agents, optionally flame retardants and optionally further additives, a process for the production of polyurethane systems, these polyurethane systems and their use.

Abstract: The invention relates to liquid polyisocyanate mixtures, to a process for their preparation and to their use in single- and two-component polyurethane coating compositions.

Abstract: A one-component polyurethane composition includes at least one polyurethane prepolymer having terminal isocyanate groups which is prepared from at least one polyisocyanate and at least one polyol, and to at least one catalyst system which is obtainable from at least one bismuth compound and at least one aromatic nitrogen compound. The polyurethane composition may be used as an adhesive, sealant, coating or lining. Finally, catalysts for polyurethane compositions are disclosed which represent coordination compounds between bismuth and at least one aromatic nitrogen compound.

Abstract: A fast curable non-isocyanate-based polyurethane- and polyurethane-epoxy network nanocomposite polymeric compositions are derived upon crosslinking a mixture comprising of natural or modified nano-clay [ionic phyllosilicate] with platelet thickness in the scale of ? (˜1 nm) and aspect ratio (length/thickness) higher than 10 (nm)] preferably natural or modified montmorillonite with either a monomer(s) or oligomer(s) bearing at least one cyclocarbonate group or a mixture of the latter with an epoxy resin, with a hardener, which is a monomer or oligomer or mixtures therefrom, bearing primary and/or secondary amino groups. The use of the nanoclays reduces the gel time and increases the adhesion of the cured polyurethane and polyurethane/epoxy hybrid and also reduces its water absorption.

Abstract: The present invention relates to a process for preparing polyurethanes, which comprise at least three hydrophilic sections, at least four hydrophobic sections, optionally allophanate segments and/or isocyanurate segments and which are prepared in the presence of alkali(ne earth) metal carboxylates. The process may comprise using at least one carboxylic acid salt of at least one metal selected from the group consisting of the alkali metals, the alkaline earth metals and mixtures thereof. Furthermore, the present invention relates to the polyurethanes per se obtainable in this way, to the use thereof as thickeners for aqueous preparations, and to preparations comprising polyurethanes of this type.

Abstract: The present invention relates to a single-stage process for preparing polyurethanes which comprise at least three hydrophilic sections, at least four hydrophobic sections, optionally allophanate segments and optionally isocyanurate segments, in the presence of alkali(ne earth) metal carboxylates or zinc carboxylates. Furthermore, the present invention relates to the polyurethanes themselves obtainable in this way, to the use thereof as thickeners for aqueous preparations, and to aqueous preparations comprising polyurethanes of this type.

Abstract: A liquid rheological aid comprising at least one urea derivative preparable which is the reaction product of at least one compound having at least one isocyanate group and at least one co-reactant selected horn primary and secondary monoamines and polyamines and water reacted in the presence of organobismuth catalyst, process for the preparation thereof and its use.

Abstract: An adhesive composition for use in adhering insulation panels to roofing substrates and roofing membranes to the insulation panels include two components that are mixed prior to application on the roofing substrate. The first component may include a renewable polyol and catalyst. The renewable polyol is selected from any non-petroleum based polyol that is derived from a renewable source. The second component includes isocyanate, and may also include a polyol and a catalyst. The isocyanate and the polyol may each be any non-petroleum based isocyanate or polyol that is derived from a renewable source.

Abstract: High-opacity polyurethane resins are produced by polymerization of polyisocyanates with polymeric polyols and subsequent chain extension with polyamines. The resins provide high-opacity inks when formulated with white pigments, which maintain good extrusion and adhesive lamination bonding strength properties. The inks are useful in flexographic and/or gravure printing processes, particularly as back-up for laminated packaging.

Abstract: A process for preparing polyurethane carpet backings uses a filled polyurethane-forming composition that contains a mixture of certain metal acetylacetonate and sulfur-containing organotin catalysts. The mixture of catalysts is particularly beneficial in instances where the composition is processed at temperatures of above 30 to about 500 C, as long pot life is provided together with a rapid thermally-induced cure.

Abstract: The present invention provides a urethane-forming reaction catalyst which is useful for catalyzing a reaction between an isocyanate compound, in particular, an aliphatic isocyanate and a hydroxyl group-containing compound to form a urethane material, which does not affect the performance of the urethane material, and which can be easily removed from the resulting urethane material, and a method for producing a metal compound-free urethane material using the urethane-forming reaction catalyst. The catalyst of the present invention is a urethane-forming reaction catalyst for producing a urethane material by allowing a hydroxyl group-containing compound to react with an isocyanate compound, the catalyst being at least one solid acid catalyst selected from the group consisting of a (A) composite metal oxide in which a metal oxide (A-2) or a non-metal compound (A-3) is carried on a surface of a metal oxide carrier (A-1), (B) zeolite, and a (C) heteropoly acid.

Abstract: The present invention provides a curable composition including: an organic polymer (A) which has on average 1.1 to 50 groups per one molecule thereof each represented by the general formula (1) and has one or more silicon-containing functional groups capable of cross-linking by forming siloxane bonds: —NR1—C(?O)—??(1) wherein R1 is a hydrogen atom, or a substituted or unsubstituted monovalent organic group; and a metal carboxylate and/or a carboxylic acid (B), the curable composition giving a cured article excellent in curability and also excellent in heat resistance although a non-organotin catalyst is used.

Abstract: The present invention relates to moisture curable reactive adhesive compositions containing a visual indicator and methods for using these compositions. Specifically, the invention relates to a two part moisture curable reactive adhesive system, where one part consists of a prepolymer with moisture reactive groups and the second part consists of catalyst, a visual indicator and water. The presence of the indicator allows the combination of the two part system to be visible to the naked eye. The visible indicator ensures that the two part system is combined uniformly and completely to a desired substrate, but it does not interfere with the crosslinking reaction.

Abstract: Disclosed is a method for preparing polyoxazolidones wherein an ether of a bisanhydrohexitol is reacted with a diisocyanate under conditions which form polyoxazolidones. Preferred bisanhydrohexitols include isoidide, isomannide and isosorbide. The polyoxazolidones are highly crosslinked, rigid, and have high solvent resistance.

Abstract: The present invention relates to a process for preparing radiation-curing binders containing allophanate groups by reacting at temperatures of ?130° C. A) one or more compounds containing uretdione groups with B) one or more OH-functional compounds which contain groups which react, with polymerization, with ethylenically unsaturated compounds on exposure to actinic radiation (radiation-curing groups), C) optionally NCO-reactive compounds other than B), in the presence of D) a catalyst containing at least one zinc compound, to form allophanate groups by opening the uretdione ring.

Abstract: Disclosed is a method for preparing polyoxazolidones wherein an ether of a bisanhydrohexitol is reacted with a diisocyanate under conditions which form polyoxazolidones. Preferred bisanhydrohexitols include isoidide, isomannide and isosorbide. The polyoxazolidones are highly crosslinked, rigid, and have high solvent resistance.

Abstract: The invention relates to the use of compositions containing a polyaldimine ALD of formula (I) as primers for adhesives or sealants. It turned out that said primers accelerate adhesion especially in winter weather without reducing the open time of the primer. Said accelerated adhesion is particularly important for fast-curing polyurethane adhesives or sealants.

Abstract: The present invention relates to aromatic aldimines, which are based on primary aromatic polyamines, which are solid at room temperature and liquid at room temperature and which have the lowest possible viscosity, hydrolyze with little odor, and can be used as blocked amines in curable compositions, in particular in compositions having one-component and two-component isocyanate groups. Said compositions have a relatively long open time, but cure surprisingly rapidly, said curing occurring without strong odor formation and without bubbling. In addition, the compositions have outstanding mechanical properties after curing, in particular high strength with high ductility, and good resistance to heat and moisture.

Abstract: A method of manufacturing a polyurethane compound comprises mixing together a polyol, a polyisocyanate compound and a catalyst and allowing the mixture to cure to form a polyurethane, and is characterised in that the catalyst is a neutral complex of a metal selected from Ti, Zr, Hf, Al, Fe, Bi or Sn and a multidentate organic ligand having: a) a number of anionic donor sites=x; b) a number of neutral donor sites, capable of forming a co-ordinate bond with the metal, =y; c) where x+y=from 5 to 8; d) x is from 2 to 4; e) the ligand molecule is of a size and conformation to enable each of the anionic donor sites and neutral donor sites to form a bond with the same metal atom.