Abstract: A coated granule obtained by coating a bioactive substance-containing granule with a urethane resin obtained by reaction of an aromatic polyisocyanate with a polyol having an average molecular weight of 300 to 5000, wherein the polyol contains a polycaprolactonepolyol and a hydroxy fatty acid ester of the formula (I): (wherein, X represents —CH2-CH2- or —CH?CH—, n represents 1, 2 or 3, m represents 0, 1 or 2, and n+m is 2 or 3. In the case of n+m=2, A represents a C2 to C8 alkanediyl group, and in the case of n+m=3, A represents a C3 to C8 alkanetriyl group.) as the coat film, is capable of controlling elution of the bioactive substance appropriately, and, the urethane resin forming the coat film shows degradability in soil.

Abstract: This invention provides chain extender compositions. These compositions comprise (i) an aliphatic secondary diamine, and (ii) a component selected from the group consisting of: (a) a cycloaliphatic primary diamine; (b) an aliphatic secondary diamine; (c) an aliphatic secondary diamine and an aliphatic primary diamine; (d) an aliphatic diimine; and (e) a combination of any two or more of (a) through (d), with the proviso that when (ii) is (a), (i) is a noncyclic aliphatic secondary diamine. Processes for producing polyurethanes, polyureas, and polyurea-urethanes are also provided.

Abstract: Compositions for golf balls that include polyurethane linkages and that are crosslinked in the soft segments of the polymer backbone. In particular, the compositions of the invention, which are based on a polyurethane have improved crosslink density from the crosslinking between the soft, unsaturated segments of the polymer backbone. The curative blend includes at least one isocyanate-reactive component and a free radical initiator.

Abstract: A cross-linked thermoplastic polyurea is formed by heating a mixture containing a thermoplastic urethane base material, a monomeric and/or polymeric di-isocyanate comprising between 1 to 10% of the total weight of the mixture, and a diamine comprising between 1 to 10% of the total weight of the mixture. A thermoplastic polyurethane may be formed by substituting hydroquinone for the diamine. The mixture is heated to a temperature within the range of 250° F. to 550° F. The heated mixture, which is flowable, is then injected into at least one injection molding device. The mixture is then cured at a temperature between 150° F. to 250° F. for a period of time between 2 and 36 hours. The cross-linked thermoplastic polyurethane/polyurea retains the excellent flowability characteristics of a thermoplastic urethane while the same time exhibits good abrasion, tensile strength, rebound, and compression set characteristics which are similar to those found in thermoset urethanes.

Abstract: A golf ball having a layer composed of a polyurethane/polyurea material formed from reaction injection molding a polyol component and an isocyanate component. The polyol component preferably comprises a polytetramethylene ether glycol having a molecular weight of approximately 1000 and a 3,5-diethyl-2,4 toluenediamine. The layer is preferably a cover layer having a thickness ranging from 0.010 inch to 0.025 inch.

Abstract: Compositions for golf balls that include polyurea linkages and that are crosslinked in the soft segments of the polymer backbone. In particular, the compositions of the invention, which are based on a polyurea have improved crosslink density from the crosslinking between the soft, unsaturated segments of the polymer backbone. The curative blend includes at least one isocyanate-reactive component and a free radical initiator.

Abstract: Block poly(trimethylene-ethylene ether) glycols are disclosed. The block poly(trimethylene-ethylene ether) glycols can be prepared by the polycondensation of 1,3-propanediol reactant and polyethylene glycol reactant. The block poly(trimethylene-ethylene ether) glycols can be used in breathable membranes, synthetic lubricants, hydraulic fluids, cutting oils, motor oils, surfactants, spin-finishes, water-borne coatings, laminates, adhesives, packaging, films and foams, fibers and fabrics.

Abstract: A polyurethane elastomer is provided. The elastomer is the reaction product of at least a prepolymer and a chain extender, where the prepolymer is the reaction product of at least one polyol and at least one aliphatic diisocyanate. The chain extender is an aromatic diamine.

Abstract: The present invention concerns reduced-yellowing thermoplastic or thermoset polymer compositions derived from the reaction of a diisocyanate, a polyol or polyamine, and a dicyandiamide. The present invention also concerns golf balls comprising the reduced-yellowing thermoplastic or thermoset polymer compositions derived from the reaction of a diisocyanate, a polyol or polyamine, and a dicyandiamide. The present invention also relates to a method for making a golf ball which includes using reduced yellowing compositions derived from the reaction of a diisocyanate, a polyol or polyamine, and a dicyandiamide. The resulting golf balls have similar processability and physical properties (such as resiliency and shear resistance) as golf balls made from conventional polyurethane or polyurea formulations, while exhibiting substantially improved resistance to yellowing.

Abstract: The present invention is directed to a method of forming a golf ball that contains an interpenetrating polymer network, or IPN, which includes at least two polymeric systems, in one or more of the layers. The first polymeric system may include a polyurethane-based or polyurea-based system having blocked isocyanate groups and the second polymeric system may include an epoxy-based or acrylic-based system, wherein the two systems are polymerized or cured simultaneously or sequentially to form an IPN.

Abstract: A polyol compound denoted by general formula (I). A transparent molded article obtained by polymerizing monomer components comprising the aforementioned polyol compound. A transparent molded article obtained by polymerizing monomer components comprising components (C) and (D). A method of manufacturing a transparent molded article, comprising casting a mixture of component (C) and component (D) into a casting mold and then polymerizing component (C) and component (D) to obtain a molded article.

Abstract: A prepolymer having an NCO content of less than 10%, based on the reaction of (a) diisocyanate with (b) polyether alcohol, the (b) polyether alcohol comprising (b1) and (b2) and/or (b3) with the following meanings for (b1), (b2) and (b3): (b1) polytetrahydrofuran having a molecular weight of from 1800 to 2100 g/mol and (b2) polyether alcohol having a molecular weight of from 500 to 7000 g/mol, based on ethylene oxide and/or propylene oxide, and/or (b3) polytetrahydrofuran having a molecular weight of from 800 to 1200 g/mol.

Abstract: Golf equipment having improved cut and shear resistance that includes a polyurea composition, preferably saturated and/or water resistant, formed of a polyurea prepolymer and a curing agent, wherein the polyurea prepolymer includes an isocyanate and an amine-terminated compound, and wherein the curing agent includes a hydroxy-terminated curing agent, amine-terminated curing agent, or a mixture thereof.

Abstract: Polyurethane and polyurea compositions for golf balls with improved stability of the curative blend, wherein the curative blend includes a pigment, a curing agent, and a compatible freezing point depressing agent so that the curative blend has a lower freezing point than the curing agent by itself and the blend does not lose pigment dispersion upon solidification and subsequent thawing.

Abstract: Disclosed herein is a composition comprising an aromatic diamine that is a solid at room temperature and a stabilizing quantity of a hindered amine light stabilizer and its use as a polyurethane curing agent.

Abstract: Polyurethane-based and polyurea-based compositions including modified amine curing agents for use in golf ball layers where modified amine curing agent of the invention allows control of the reaction rate by providing a composition with both primary and secondary amine linkages.

Abstract: A transparent, non elastomeric, high index, impact resistant polythiourethane/urea material comprising the reaction product of: a) at least one (?, ?)-diiso(thio)cyanate cycloaliphatic or aromatic prepolymer having a number average molecular weight ranging from 100 to 3000 gmol?1, and b) at least one primary diamine, in an equivalent molar ratio amine function/iso(thio)cyanate function from 0.5 to 2, preferably from 0.90 to 1.10, wherein, said prepolymer and diamine are free from disulfide (—S—S—) linkage and at least one of the prepolymer or the diamine contains one or more S atoms in its chain.

Abstract: A golf ball comprising a core, an inner cover layer, and an outer cover layer, the outer cover layer being formed from a polyurea including a prepolymer and an amine curative. The prepolymer is formed from an aliphatic isocyanate and a secondary polyamine polyether having a formula: where x=1-70; R1 and R2 each independently=a C1-20 alkyl group, phenyl, or a mixture thereof; and R3=H, CH3, or a mixture thereof.

Abstract: Provided is a composition including a reaction product of: (A) a reactive compound that includes a material having functional groups that are reactive with active hydrogens; (B) a thioether-functional, oligomeric polythiol prepared by reacting together: (1) a compound having at least two thiol functional groups; (2) a compound having triple bond functionality; and optionally (3) a compound having at least two double bonds; and, optionally, (C) a compound different from (B) containing active hydrogens. Coating compositions, articles of manufacture and related processes also are provided.

Abstract: A polyurethaneurea system that includes in some embodiments Parts A and B reaction components for a polyurethaneurea, wherein an exemplary embodiment provides a Part A that comprises between 55 and 75 wt. % of an oligomeric polyol, between 3 and 7 wt. % of an aromatic diamine chain extender, and between 0.1 and 1.5% of a reactivity catalyst; Part B includes between 1 and 15 wt. % of a short aromatic diisocyanate and between 5 and 35 wt. % of an aromatic diisocyanate prepolymer that is the reaction product of a short aromatic diisocyanate and a diol. The polyurethaneurea system may further comprise an elastomer-surface activator comprising a second short aromatic diisocyanate and a second aromatic diisocyanate prepolymer, wherein at least one of the second diisocyanates may be the same as at least one of the diisocyanates of Part B.

Abstract: The invention provides conductivity control agent comprised of a polymeric material containing hydroxyalkylphosphonium (2-hydoxyethoxycarbonyl) arylsulfonate salts. The conductivity control agents can be used with semi-conductive rolls, belts and other biasable members. The inclusion of the conductivity control agent in the polymeric or polyurethane elastomers extends the electrical life of the polyurethane biasable member in low humidity environments. Additionally, the resistivity of the elastomeric polyurethane or polymer on the biasable member is controlled to a desirable value by adjusting the conductivity control agent level in the polymeric or polyurethane elastomers.

Abstract: A polyurea adhesive composition that is obtainable by reaction of reaction components that include a polyisocyanate comprising isocyanurate rings, the polyisocyanate having a functionality equal to or greater than 3, a polyamine having an average molecular weight greater than about 500 dalton and a carboxylic acid. Additionally, the reaction components may comprise an aromatic diamine chain extender. The molar ratio of the isocyanate groups to whole amine and carboxylic acid functions of the reaction components is between 1.5 and 3.5. Further provided is an article comprising a component bonded to the article with the polyurea adhesive described above. The bonded faces between the component and the article may be of cross-linked rubber composition. The article may be, for example, a tire, a tread band and/or a patch applied to the tire.

Abstract: The present invention provides conductivity control agents derived from the trans esterification of dialkyl phosphonium 5-sulfoisophthalate salts with poly(alkylene glycols). The conductivity control agents can be used with semi-conductive rolls, belts and other biasable members. The inclusion of the conductivity control agent in the polymeric or polyurethane elastomers extends the electrical life of the polymer biasable member in low humidity environments. Additionally, the resistivity of the elastomeric polymers or polyurethane on the biasable member is controlled to a desirable value by adjusting the conductivity control agent level in the polymer elastomers.

Abstract: In accordance with an exemplary embodiment of the present invention, an optically clear polyurethane/polyurea polymer may be prepared by reacting a cycloaliphatic diisocyanate with polyesters, polyethers, and polycarbonates which may comprise hydroxyl groups and/or primary amine groups. This reaction may be carried out using 0.5 to 0.9 equivalents of the hydroxyl/amine groups followed by the reaction of 0.1 to 0.5 equivalents of water. The glycol, amine, and water may then be reacted with a cycloaliphatic diisocyanate in a ratio of about 1.77 to about 3.5 NCO for each OH, HOH, NH2. The resulting prepolymer may then be reacted with an aromatic diamine curing agent such as diethyltoluene diamine in an equivalent ratio of about 0.85 NH2/1.0 NCO to about 1.1 NH2/1.0 NCO, and in one embodiment, from about 0.90 NH2/1.0 NCO to 0.98 NH2/1.0 NCO. In one embodiment, 0.2 to 0.3 comprises the range of water equivalents for the water diisocyanate reaction.

Abstract: A power transmission belt having a main belt body portion of elastomeric material, a tensile reinforcement such as carbon fiber cord, disposed in said body portion, and a sheave contact portion integral with said main body portion. The elastomeric material includes the reaction product of a polyisocyanate prepolymer composition and a chain extender. The polyisocyanate prepolymer composition is prepared by reacting a diisocyanate and a polyol substantially free of moieties oxidative at less than about 150° C. and at least one triol crosslinker selected from the same group of polyols. Either before or after reacting the prepolymer, a plasticizer selected from the group consisting of alkyl-ether di-alkylesters such as polyethylene glycol di-alkylester is added thereto. The chain extender is an aromatic symmetric primary or secondary diamine chain extenders.

Abstract: A golf ball comprising a core, an inner cover layer, and an outer cover layer, the outer cover layer being formed from a polyurea including a caprolactone-free prepolymer of an aliphatic isocyanate mixture comprising dimerized uretdione of HDI and trimerized isocyanurate of HDI (or, optionally, trimerized biuret of HDI) and a first amount of modified polyoxypropylene diamine having a formula: where x=1-70; R1 and R2 each independently=a C1-20 alkyl group, phenyl, or a mixture thereof; and R3?H, CH3, or a mixture thereof; and a curative including a mixture of 3,5-diethyl-2,4-toluenediamine and 3,5-diethyl-2,6-toluenediamine.

Abstract: The invention provides a conductivity control agent comprised of a polymeric material containing diphosphonium bis(sulfoarylcarbonyloxy) glycol salts as conductivity control agent. The conductivity control agents can be used with semi-conductive rolls, belts and other biasable members. The inclusion of the conductivity control agent in the polymeric or polyurethane elastomers extends the electrical life of the polymeric biasable member in low humidity environments. Additionally, the resistivity of the elastomeric polymer on the biasable member is controlled to a desirable value by adjusting the conductivity control agent level in the elastomers.

Abstract: An ionomer modified by an amine-functionalized chemical for use in sporting equipment. The ionomer modified by an amine-functionalized chemical facilitates high COR, compression, durability, and ease of processing.

Abstract: Polyurethane elastomer articles formed from prepolymer mixtures having free diphenylmethane diisocyanate (MDI) content from 2.0 to 5.0 wt %, based on the weight of the prepolymer mixture. The prepolymer mixtures comprise a polyester, polyether, or polycaprolactone (PCL) prepolymer and MDI. The polyurethane elastomer articles are formed by curing the prepolymer mixture with a chain extender, such as a curative comprising a methylenedianiline-sodium chloride complex. The articles have good physical properties that may weigh over 225 kg, and have a three-axis thickness greater than 10.2 cm.

Abstract: Compositions for golf balls including oxirane functional endcapped polymers and, in particular, compositions formed from polyurethane-based or polyurea-based prepolymers that are endcapped with an oxirane functional group. The oxirane functionality is opened with a suitable curing agent to provide a composition that has flexibility via the prepolymer backbone and stiffness via the oxirane functional endcaps.

Abstract: Polyurethane prepolymers having a reduced amount of unreacted monomeric diisocyanate, particularly diphenylmethane diisocyanate (MDI), prepared by distilling the prepolymer reaction product in the presence of at least one inert solvent whose boiling point is slightly below that of the monomeric diisocyanate; and to high performance cast polyurethane elastomers from the thus obtained prepolymers using diamine and/or diol chain extenders.

Abstract: The invention relates to a method for producing a roller shell or roller lining of a roller made from a PPDI-based polyurethane plastic. The green strength shortcomings are to be overcome as quickly as possible to prevent stress cracks by the fact that the hardener added to the polyurethane shortens the working life to 5 to 60 seconds. The invention also relates to a PPDI polyurethane for the production of a roller shell or roller lining of a roller made by mixing a PPDI prepolymer with a hardener, in particular to carry out the method, wherein it is important that the hardener consists of 60 to 99% 1,4-butanediol, a maximum of 40% diamine, and at most 1% catalyst.

Abstract: A golf ball having a layer composed of a polyurethane/polyurea material formed from reaction injection molding a polyol component and an isocyanate component. The polyol component preferably comprises a polytetramethylene ether glycol having a molecular weight of approximately 1000 and a 3,5-diethyl-2,4 toluenediamine. The layer is preferably a cover layer having a thickness ranging from 0.010 inch to 0.025 inch.

Abstract: Golf equipment having improved cut and shear resistance that includes a polyurea composition, preferably saturated and/or water resistant, formed of a polyurea prepolymer and a curing agent, wherein the polyurea prepolymer includes an isocyanate and an amine-terminated compound, and wherein the curing agent includes a hydroxy-terminated curing agent, amine-terminated curing agent, or a mixture thereof.

Abstract: The present invention relates to NCO prepolymers having a low content of free monomeric diisocyanate, to a process for the production of these NCO) prepolymers, to polyurethanes prepared from these NCO prepolymers and to processes for the production of these polyurethanes.

Abstract: A cross-linked thermoplastic polyurea is formed by heating a mixture containing a thermoplastic urethane base material, a monomeric and/or polymeric di-isocyanate comprising between 1 to 10% of the total weight of the mixture, and a diamine comprising between 1 to 10% of the total weight of the mixture. A thermoplastic polyurethane may be formed by substituting hydroquinone for the diamine. The mixture is heated to a temperature within the range of 250° F. to 550° F. The heated mixture, which is flowable, is then injected into at least one injection molding device. The mixture is then cured at a temperature between 150° F. to 250° F. for a period of time between 2 and 36 hours. The cross-linked thermoplastic polyurethane/polyurea retains the excellent flowability characteristics of a thermoplastic urethane while the same time exhibits good abrasion, tensile strength, rebound, and compression set characteristics which are similar to those found in thermoset urethanes.

Abstract: A golf ball having a layer composed of a polyurethane/polyurea material formed from reaction injection molding a polyol component and an isocyanate component. The polyol component preferably comprises a polytetramethylene ether glycol having a molecular weight of approximately 1000 and a 3,5-diethyl-2,4 toluenediamine. The layer is preferably a cover layer having a thickness ranging from 0.010 inch to 0.025 inch.

Abstract: A golf ball having a core and at least one layer disposed about the core is disclosed. The at least one layer is formed from a composition having multiple reactive and/or non-reactive ingredients. At least one of these ingredients is a sterically hindered polyamine, preferably formed from an active hydrogen functional compound and an amine/acid ortho- or meta-substituted cyclic compound.

Abstract: A golf ball having a core and at least one layer disposed about the core is disclosed. The at least one layer is formed from a composition having multiple reactive and/or non-reactive ingredients. At least one of these ingredients is a telechelic polydiene polyahl having a polydispersity of 1.35 or less.

Abstract: A cross-linked thermoplastic polyurea is formed by heating a mixture containing a thermoplastic urethane base material, a monomeric and/or polymeric di-isocyanate comprising between 1 to 10% of the total weight of the mixture, and a diamine comprising between 1 to 10% of the total weight of the mixture. A thermoplastic polyurethane may be formed by substituting hydroquinone for the diamine. The mixture is heated to a temperature within the range of 250° F. to 550° F. The heated mixture, which is flowable, is then injected into at least one injection molding device. The mixture is then cured at a temperature between 150° F. to 250° F. for a period of time between 2 and 36 hours. The cross-linked thermoplastic polyurethane/polyurea retains the excellent flowability characteristics of a thermoplastic urethane while the same time exhibits good abrasion, tensile strength, rebound, and compression set characteristics which are similar to those found in thermoset urethanes.

Abstract: A golf ball having a core and at least one layer disposed about the core is disclosed. The core may further include a center and an outer core layer disposed about the center. The layer is formed from a composition having a prepolymer and a curative, the prepolymer being formed from an isocyanate and a blend of two or more telechelic polyahls, wherein a first telechelic polyahl has a first functionality of 3 or greater, which is greater than a second functionality of a second telechelic polyahl in the blend. The layer displays an enhanced shear resistance.

Abstract: The invention is directed to polyurethane prepolymers having a reduced amount of unreacted monomeric diisocyanate, particularly diphenylmethane diisocyanate (MDI), prepared by distilling the prepolymer reaction product in the presence of at least one inert solvent whose boiling point is slightly below that of the monomeric diisocyanate; and to high performance cast polyurethane elastomers from the thus obtained prepolymers using diamine and/or diol chain extenders.

Abstract: A golf ball comprising a core, an inner cover layer, and an outer cover layer, the outer cover layer being formed from a polyurea comprising: a prepolymer comprising: an aliphatic isocyanate mixture comprising dimerized uretdione of HDI and trimerized isocyanurate of HDI; a first amount of modified polyoxypropylene diamine having a formula: ?where x=1-70; R1 and R2 each independently=a C1-20 alkyl group, phenyl, or a mixture thereof; and R3=CH3, or a mixture thereof; and a caprolactone; and a curative comprising a mixture of 3,5-diethyl-2,4-toluenediamine and 3,5-diethyl-2,6-toluenediamine.

Abstract: The present invention is directed to a method of forming a golf ball that contains an interpenetrating polymer network, or IPN, which includes at least two polymeric systems, in one or more of the layers. The first polymeric system may include a polyurethane-based or polyurea-based system having blocked isocyanate groups and the second polymeric system may include an epoxy-based or acrylic-based system, wherein the two systems are polymerized or cured simultaneously or sequentially to form an IPN.

Abstract: A two component polyurethane adhesive composition having one or more polyols as a first component and one or more isocyanates as a second component. The composition also comprises one or more catalysts and one or more blocking agents to delay the curing reaction. The composition provides long open time, improved wet out of the substrates to be bonded, a rapid cure rate and excellent final bond performance at room and elevated temperatures. Optional ingredients, such as fillers, chain extenders and plasticizers may be added as desired. In one embodiment, the catalyst is a tin catalyst such as dibutyl tin dilaurate which may optionally be combined with other catalysts such as tertiary amines. The blocking agent in one embodiment is 8-hydroxyquinoline.

Abstract: The present invention is directed to a method of forming a golf ball that contains an interpenetrating polymer network, or IPN, which includes at least two polymeric systems, in one or more of the layers. The first polymeric system may include a polyurethane-based or polyurea-based system having blocked isocyanate groups and the second polymeric system may include an epoxy-based or acrylic-based system, wherein the two systems are polymerized or cured simultaneously or sequentially to form an IPN.

Abstract: An anti-bacterial polymer of the present invention consists of a vapor deposition-polymerization reaction product of a diaminobenzoic acid monomer or halogen atom-containing diamine monomer and a monomer reactive with these monomers. The anti-bacterial polymer can be prepared by a method, which comprises the step of subjecting a gas obtained by evaporating a diaminobenzoic acid monomer or halogen atom-containing diamine monomer and a gas obtained by evaporating a monomer reactive with these monomers to vapor deposition-polymerization, in a vacuum, to thus form an anti-bacterial polymer. The method permits the formation of a film having a desired thickness even on the surface having a complicated shape such as the surface of, for instance, a heat exchanger.

Abstract: Golf balls comprising thermoplastic, thermoset, castable, or millable elastomer compositions are presently disclosed. These compositions comprise at least one polymer having a plurality of amide linkages and a plurality of anionic moieties attached thereto. These compositions can be used in any one or more portions of the golf balls, such as inner center, core, inner core layer, intermediate core layer, outer core layer, intermediate layer, cover, inner cover layer, intermediate cover layer, and/or outer cover layer.

Abstract: Golf balls comprising thermoplastic, thermoset, castable, or millable elastomer compositions are presently disclosed. These compositions comprise at least one polymer having a plurality of amide linkages and a plurality of cationic moieties attached thereto. These compositions can be used in any one or more portions of the golf balls, such as inner center, core, inner core layer, intermediate core layer, outer core layer, intermediate layer, cover, inner cover layer, intermediate cover layer, and/or outer cover layer.

Abstract: Thermally stable polymers comprising resorcinol arylate chain members are prepared using an interfacial method comprising the steps of: (a) combining at least one resorcinol moiety and at least one catalyst in a mixture of water and at least one organic solvent substantially immiscible with water; and (b) adding to the mixture from (a) at least one dicarboxylic acid dichloride while maintaining the pH between 3 and 8.5 through the presence of an acid acceptor, wherein the total molar amount of acid chloride groups is stoichiometrically deficient relative to the total molar amount of phenolic groups.