With Reactant Having Two -xh Groups Patents (Class 528/65)
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Patent number: 6638616Abstract: The present invention relates to a radiation-curable solvent-free coating composition for optical fiber having a radiation-curable urethane (meth)acrylate oligomer comprising an alkyd backbone, a reactive diluent, a photoinitiator and, optionally, an additive.Type: GrantFiled: October 15, 1999Date of Patent: October 28, 2003Assignee: DSM N.V.Inventors: Anthony J. Tortorello, Eva Montgomery, Chander P. Chawla
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Patent number: 6639041Abstract: A low set (at low temperatures) spandex, based on copoly(alkylene ethers), which are copolymers containing tetramethylene ether and either ethylene ether or 1,2-propylene ether moieties, is provided.Type: GrantFiled: May 31, 2002Date of Patent: October 28, 2003Assignee: DuPont-Toray Co. Ltd.Inventors: Hiroshi Nishikawa, Masao Umezawa
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Patent number: 6632877Abstract: The present invention is directed at a dual curable coating that exhibits superior adhesion to ultraviolet curable inks and base coats. The present invention is preferably utilized as a top coat for a golf ball. The dual curable coating may be a tinted top coat or a clear coat. The dual curable coating includes a dual-curing component that is selected from the group of pentaerythritol tetraacrylate, hydroxy ethyl acrylate, hydroxy ethyl methacrylate, hydroxy propyl acrylate, hydroxy propyl methacrylate, caprolactone acrylate and polyproplene glycol monomethacrylate.Type: GrantFiled: April 16, 2002Date of Patent: October 14, 2003Assignee: Callaway Golf CompanyInventors: Steven C. Crast, Walter Skrabski, Kevin A. Heene, David A. Valia, Allen Brent Puder
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Patent number: 6626988Abstract: The invention relates to polyurethane materials, cross-linked by silane polycondensation, containing alkoxylsilane functional polyurethanes, alkaline fillers, phosphorous compounds aminosilanes, organometallic compounds and optionally additional auxiliary agents, to a method for their production and to the use thereof.Type: GrantFiled: November 15, 2001Date of Patent: September 30, 2003Assignee: Bayer AktiengesellschaftInventors: Lutz Schmalstieg, Ralf Lemmerz, Ulrich Walter, Alexander Eckhardt
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Patent number: 6624282Abstract: The present invention relates to reactive compositions containing (A) NCO prepolymers based on (cyclo)aliphatic polyisocyanates having an NCO content of 1 to 8 wt. % and a monomeric polyisocyanate content of less than 2 wt. %, (B) amine-free chain extenders containing at least 50 equivalent percent of a compound melting between 50° and 160° C. having formula (I) HO—X—Y—X—OH (I) wherein Y denotes methylene, ethylene, —C≡C—, 1,4-, 1,3-, or 1,2-cyclohexylene, or 1,4-, 1,3-, or 1,2-phenylene, and X denotes methylene, —OCH2CH2— (wherein oxygen is bonded to group Y), or 1,4-, 1,3-, or 1,2-cyclohexylene, and (C) 0 to 20 wt. %, relative to component (A), of inert organic solvents, wherein the equivalent ratio of the free NCO groups of component (A) to the NCO-reactive groups of component (B) is 0.90 to 1.35.Type: GrantFiled: August 7, 1997Date of Patent: September 23, 2003Assignee: Bayer AktiengesellschaftInventors: Stefan Groth, Josef Pedain, Lutz Schmalstieg, Detlef-Ingo Schütze
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Patent number: 6624277Abstract: The present invention relates to polyurethane polyol compositions comprising the reaction product of a polyisocyanate, a polyol, and a Guerbet alcohol having at least 12 carbon atoms or a Guerbet alcohol mixture having an average of at least 12 carbon atoms. Preferred polyols are &agr;,&bgr; diols and &agr;,&ggr; diols. The polyurethane polyol compositions exhibit very low viscosity and are particularly useful in very low VOC coating compositions. The resulting cured coating provides surprisingly improved properties.Type: GrantFiled: December 12, 2001Date of Patent: September 23, 2003Assignee: AKZO Nobel N.V.Inventors: Alexander Leo Yahkind, Robert Brian Feisel, Michael Todd Render, Dhruv Vrajlal Parekh
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Patent number: 6624281Abstract: Segmented polyurethane/ureas useful for the production of spandex are produced by chain extending, in the presence of a solvent, an isocyanate-terminated prepolymer prepared by reacting a stoichiometric excess of an isocyanate with an isocyanate-reactive component which includes: (1) from about 5 to about 30 equivalent percent of a polyoxy-propylene diol having a molecular weight of at least 1500 Da and an unsaturation level less than or equal to 0.03 meq/g; (2) from about 20 to about 60 equivalent percent of a polytetramethylene ether glycol having a molecular weight less than 1000 Da; and (3) from about 25 to about 65 equivalent percent of a polytetramethylene ether glycol having a molecular weight greater than or equal to 1000 Da.Type: GrantFiled: May 30, 2002Date of Patent: September 23, 2003Assignee: Bayer CorporationInventor: Bruce D. Lawrey
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Patent number: 6617412Abstract: This invention relates to fertilizer encapsulation with polyurethanes wherein the isocyanate-reactive composition contains sulfur. The process of the present invention comprises applying a polyisocyanate composition to fertilizer particles, applying an isocyanate-reactive composition which contains sulfur to the polyisocyanate coated fertilizer particles, or applying an isocyanate-reactive composition which contains sulfur to fertilizer particles and then applying a polyisocyanate composition to the isocyanate-reactive coated fertilizer particles, and repeating these steps as necessary to form sulfur containing polyurethane encapsulated fertilizer particles.Type: GrantFiled: October 12, 2001Date of Patent: September 9, 2003Assignee: Bayer CorporationInventors: Peter H. Markusch, Robert L. Cline
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Patent number: 6613864Abstract: A polyurethane composition useful for the manufacture of an elastomeric part is provided. The polyurethane composition comprises a polyisocyanate prepolymer and an active hydrogen containing compound, wherein from about 10 to about 60 percent by weight of the composition is a butylene oxide adduct and from about 70 to about 100 percent of the butylene oxide adduct is present in the polyisocyanate prepolymer. A method for preparing a polyurethane polymer from the polyurethane composition is also provided. Also, a method for preparing a polyurethane article from the polyurethane composition is provided.Type: GrantFiled: August 17, 2001Date of Patent: September 2, 2003Assignee: Dow Global Technologies Inc.Inventors: James R. Porter, Allan James, Kenneth B. Arnold
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Patent number: 6610811Abstract: Polyurethanes having improved tear resistance which are the reaction product of the following components: A) a polyol component containing dimer diol and/or trimer triol and/or an OH-terminated polyester produced from polycarboxylic acids, preferably dimer fatty acid and/or trimer fatty acid, and diols and B) an isocyanate component containing prepolymers obtained by reacting polyfunctional isocyanates with dimer diol and/or trimer triol and/or an OH-terminated polyester produced from polycarboxylic acids, preferably dimer fatty acid and/or trimer fatty acid, and diols; and processes for their manufacture.Type: GrantFiled: August 24, 1999Date of Patent: August 26, 2003Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Alfred Westfechtel, Roland Gruetzmacher, Rainer Hoefer
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Patent number: 6605669Abstract: Coating compounds curable by means of high-energy radiation, comprising as binder A) at least one (meth)acrylic copolymer containing olefinic double bonds capable of free-radical polymerization and hydroxyl groups with a C═C equivalent weight from 100 to 10,000 and an OH-value from 20 to 250 mg KOH/g, which is prepared from monomers comprising: A1) at least one olefinically unsaturated, epoxy-functional monomer capable of free-radical polymerization, A2) at least one olefinically unsaturated, carboxy-functional monomer capable of free-radical polymerization and A3) at least one further olefinically unsaturated monomer capable of free-radical polymerization which is different from A1) and A2), and B) at least one component with free isocyanate groups and process for multilayer coating using the coating compounds.Type: GrantFiled: April 3, 2001Date of Patent: August 12, 2003Assignee: E. I. du Pont de Nemours and CompanyInventors: Morenike Awokola, Carmen Flosbach, Helmut Loeffler, Volker Paschmann
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Publication number: 20030125501Abstract: Compositions comprising a reaction product of a) an asymmetrical, saturated polyisocyanate that is non-cyclic, non-aromatic, and has at least 3 carbon atoms in the polyisocyanate per isocyanate group, b) a material that is at least one of i) a primary carbamate material having at least one functional group reactive with an isocyanate and at least one primary carbamate group or a group convertible to a primary carbamate group and ii) a reaction product of the primary carbamate material and an extending agent, and c) optionally, a chain extension agent that has at least difunctional reactivity with an isocyanate. Also, methods of making these compositions.Type: ApplicationFiled: December 12, 2002Publication date: July 3, 2003Applicant: BASF CORPORATIONInventors: Walter H. Ohrbom, Craig S. Schang, Joanne Casale, Thaddeus J. Lepkowski
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Patent number: 6573354Abstract: A vegetable oil-based polyol is made by adding a peroxyacid to vegetable oil wherein said peroxyacid reacts with said vegetable oil to form epoxidized vegetable oil and adding said epoxidized vegetable oil to a mixture of an alcohol, water, and a catalytic amount of fluoboric acid so as to form a vegetable oil-based polyol. A further embodiment of the present invention involves making a vegetable oil-based polyol using an epoxidized vegetable oil as the starting material. The epoxidized vegetable oil undergoes hydroxylation by the same process as outlined above. According to another aspect of the present invention, the vegetable oil-based polyol formed by the novel methods of this invention may be reacted with an isocyanate to form a polyurethane. Alternatively, a filler such as silica may be combined with the vegetable oil-based polyol before it is reacted with the isocyanate. These polyurethanes made from vegetable oil-based polyols may be used to form electroinsulating casting resins.Type: GrantFiled: May 10, 2000Date of Patent: June 3, 2003Assignee: Pittsburg State UniversityInventors: Zoran Petrovic, Andrew Guo, Ivan Javni
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Publication number: 20030100626Abstract: The invention concerns a novel aqueous composition that can be hardened physically, thermally and/or with actinic radiation, containing a compound of general formula (I): X[NH—C(═O)—NH—Y—NH—C(═O)—OR]2 having at least one urea and urethane group, wherein the variables have the following meaning: R represents identical or different polyalkylene glycol ether radicals; X represents a bivalent substituted or unsubstituted arylene radical; Y represents identical bivalent substituted or unsubstituted arylene radicals, which are the same as or different from radical X or different bivalent substituted or unsubstituted arylene radicals of which none or one is identical to radical X. The invention also concerns the utilization of said compound for the production of novel aqueous coating materials, adhesives and sealants that can be hardened physically, thermally or thermally and with actinic radiation and their derivatives.Type: ApplicationFiled: July 12, 2002Publication date: May 29, 2003Inventors: Ekkehard Sapper, Anne Hupp, Egon Wegner, Willi Vesper, Karl-Heinz Josten, Jorg Schwarz
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Patent number: 6566482Abstract: Polyurethane elastomers are produced by reacting a polyether and/or polyester polyol having a starter functionality of at least 2 with an NCO-terminated prepolymer produced with a polyether and/or polyester polyol having a starter functionality of at least 4. These polyurethane elastomers exhibit improved processing characteristics combined with a high heat distortion temperature.Type: GrantFiled: December 11, 2001Date of Patent: May 20, 2003Assignee: Bayer AktiengesellschaftInventors: Peter Haas, Hans-Detlef Arntz
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Publication number: 20030089150Abstract: This invention relates to fertilizer encapsulation with polyurethanes wherein the isocyanate-reactive composition contains sulfur. The process of the present invention comprises applying a polyisocyanate composition to fertilizer particles, applying an isocyanate-reactive composition which contains sulfur to the polyisocyanate coated fertilizer particles, or applying an isocyanate-reactive composition which contains sulfur to fertilizer particles and then applying a polyisocyanate composition to the isocyanate-reactive coated fertilizer particles, and repeating these steps as necessary to form sulfur containing polyurethane encapsulated fertilizer particles.Type: ApplicationFiled: October 12, 2001Publication date: May 15, 2003Inventors: Peter H. Markusch, Robert L. Cline
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Publication number: 20030087982Abstract: A method of modifying a polymeric material which comprises the steps of activation-treatment and a hydrophilic polymer-treatment, or comprises the steps of activation-treatment, a hydrophilic polymer-treatment, and monomer grafting in this order, or comprises the step of a solvent-treatment followed by these steps. Thus, the polymeric material, e.g., polyolefin, is improved in hydrophilicity, adhesion, etc. without lowering the practical strength thereof The polymeric material thus improved in adhesion and other properties can be used in many applications where water absorption and adhesion are required, such as an absorption material, e.g., a wiping/cleansing material, a water retention material, a material for microorganism culture media, a separator for batteries (or cells), a synthetic paper, a filter medium, a textile product for clothing, a medical/sanitary/cosmetic supply, and reinforcing fibers for composite materials.Type: ApplicationFiled: August 27, 2001Publication date: May 8, 2003Inventor: Hitoshi Kanazawa
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Patent number: 6552100Abstract: A method of treating reaction injection molded polyurethane, polyurethane/urea and polyurea polymers comprising exposing a reaction injection molded polyurethane, polyurethane/urea or polyurea polymer to an amount of infrared energy sufficient to increase the temperature of the polymer to at least 175° C., and then maintaining the temperature of the polymer at or above that temperature, for a time sufficient to increase the Gardner impact property, as measured using ASTMD-3029, when compared to the same polymer which has been heated to the same temperature and maintained thereat for the same time in a convection oven. The invention produces marked improvements in impact, heat sag and heat distortion temperature properties, and thus is particularly suited to rapid preparation of parts using a mass production conveyor and is particularly well-suited to preparation of parts which are to be subjected to later high temperature processes, such as the “E-coat” process.Type: GrantFiled: February 8, 2001Date of Patent: April 22, 2003Assignee: The Dow Chemical CompanyInventors: John W. McLaren, Kenneth J. Rettmann
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Patent number: 6548615Abstract: The invention relates to a reactive composition containing A) an isocyanate-containing compound, B) a polyol, C) an organic tin or bismuth compound, D) a thiol group-containing compound or a polyphenol which is able to react with an isocyanate group in the presence of a tertiary amine as activator and with adjacent hydroxyl groups and E) a hydrolyzable halogen compound, wherein the molar ratio SH and/or OH:metal is 2 to 500 and the molar ratio halogen/metal is 0.05 to 10.Type: GrantFiled: March 2, 2001Date of Patent: April 15, 2003Assignee: Bayer AktiengesellschaftInventors: Stefan Groth, Jan Mazanek, Rolf Langel, Detlef-Ingo Schütze, Jürgen Urban
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Patent number: 6545087Abstract: This invention relates to polyurethane prepolymers which comprise alkoxysilane terminal groups and which are based on special, very high molecular weight polyurethane prepolymers, to a method of producing them and to their use as binders for low-modulus sealing materials.Type: GrantFiled: April 12, 2001Date of Patent: April 8, 2003Assignee: Bayer AktiengesellschaftInventors: Lutz Schmalstieg, Ralf Lemmerz, Marie-Helene Walter, Oswald Wilmes
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Patent number: 6545114Abstract: A polysiloxane-urethane macromonomer having an unsaturated bond on one end thereof was co-polymerized with acrylic acid or acrylate monomers to form a copolymer having polysiloxane-urethane groups as a side chain thereof.Type: GrantFiled: August 9, 2001Date of Patent: April 8, 2003Assignee: Chung-Shan Institute of Science & TechnologyInventors: Jeng-Cheng Yang, Chen-chi Martin Ma, Hon-Bin Chen
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Publication number: 20030065124Abstract: The invention is directed to polyurethane prepolymers having a reduced amount of unreacted monomeric diisocyanate, particularly diphenylmethane diisocyanate (MDI), prepared by distilling the prepolymer reaction product in the presence of at least one inert solvent whose boiling point is slightly below that of the monomeric diisocyanate; and to high performance cast polyurethane elastomers from the thus obtained prepolymers using diamine and/or diol chain extenders.Type: ApplicationFiled: August 2, 2001Publication date: April 3, 2003Inventors: Ronald O. Rosenberg, Rui Xie, Ajaib Singh
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High powered radiation and/or thermal hardening coating powder with a functionalized based structure
Patent number: 6541535Abstract: The invention relates to a binder for powder coating materials having an oligomeric or polymeric substructure which are curable thermally and/or by means of high-energy radiation, said binder comprising in each case terminally and/or laterally at least one vinyl ether group a) and at least one group b) which is different from the vinyl ether groups a) but is coreactive with said groups a), there being on average at least one vinyl ether group a) and one coreactive group b) per oligomer or polymer molecule. The invention also relates to powder coating materials comprising such a binder and to the use of said powder coating materials for coating surfaces, especially in the form of an automotive top coat and a coil coating material.Type: GrantFiled: February 7, 2001Date of Patent: April 1, 2003Assignee: BASF Coatings AGInventors: Rainer Blum, Rodriguez Jorge Prieto -
Patent number: 6538046Abstract: The present invention provides a curable polyurethane polymer containing in copolymerized form A) from 10 to 60% by weight of at least one hydroxyl-containing prepolymer having at least one &agr;,&bgr;-ethylenically unsaturated double bond, B) from 0.1 to 30% by weight of at least one compound having at least one isocyanate-reactive hydroxyl group and/or primary or secondary amino group and, in addition, at least one polar functional group per molecule, C) from 0.Type: GrantFiled: July 11, 2000Date of Patent: March 25, 2003Assignee: BASF AktiengesellschaftInventors: Wolfgang Paulus, Werner Lebkücher, Klaus Menzel, Wolfgang Reich
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Patent number: 6538095Abstract: The solvent-free two-component adhesive composition of the present invention comprises a polyol component (A) and a polyisocyanate component (B), and the viscosity of the mixture at 80° C. immediately after the point of time the components (A) and (B) are mixed together is 900 mPa·s or higher. The component (A) may be a polyol having a number average molecular weight of 800 or larger, or a mixture thereof, and the viscosity of the component (B) at 25° C. may be 20,000 mPa·s or higher. The composition may be used for laminating metal foil of 5 to 15 m thickness with a plastic film. By using the composition of the present invention, the occurrence of blocking due to the seepage of the adhesive from metal foil is prevented. The present invention includes a process of lamination using the same.Type: GrantFiled: March 29, 2002Date of Patent: March 25, 2003Assignee: Mitsui Takada Chemicals Inc.Inventors: Akihiro Imai, Taiji Morimoto, Sachio Igarashi
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Patent number: 6534617Abstract: A method of manufacturing a thermoplastic polyurethane having a tensile strength of greater than 20 MPa is described, the method using a co-rotating reaction extruder to react the following: (i) an isocyanate having two isocyanate groups per molecule; (ii) a polydiene diol having from 1.6 to about 2 terminal hydroxyl groups per molecule and a number average weight of at least 500 and less than 20,000; and (iii) one or more chain extenders.Type: GrantFiled: November 22, 1999Date of Patent: March 18, 2003Assignee: KRATON Polymers U.S. LLCInventors: Alan Michael Batt, Dale Lee Handlin, Michael Alan Masse, Christinus Cornelis van de Kamp
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Patent number: 6530849Abstract: Disclosed herein is a golf ball comprising a core and a cover, said cover comprising a polyurethane elastomer comprising the reaction product of: A) at least one diisocyanate monomer; B) at least one polyol that is a homopolymer of propylene oxide having a molecular weight greater than 1000; and C) at least one hydroxy or amine functional chain extender; wherein the ratio of equivalents of chain extender plus polyol to equivalents of isocyanate is in the range of from about 0.6:1 to about 1.2:1, whereby said polyurethane elastomer possesses high shear resistance and good resilience.Type: GrantFiled: October 12, 2001Date of Patent: March 11, 2003Assignee: Uniroyal Chemical Company, Inc.Inventor: Thomas H. Peter
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Patent number: 6515070Abstract: The present invention is directed to a polymer component having controlled branching, formed from the reaction product of a prepolymer and a chain extender, which prepolymer is itself formed from the reaction product of a mixture of a non-self-associating isocyanate component, a diol component having a molecular weight from about 1500 to 6000 grams/mole and present in an amount greater than about 50% by weight based on the total weight of the prepolymer, and an ion-forming compound, where the chain extender includes an amine-containing compound and is present in an amount sufficient to react with at least about 99% of the isocyanate groups present after the prepolymer has been formed, wherein the controlled branching of the polymer includes at least one of: a hydroxy-functional component having hydroxyl functionality greater than 2.0 and a molecular weight from about 700 to 2000; or a low molecular weight component having more than two hydroxyl groups.Type: GrantFiled: September 18, 2001Date of Patent: February 4, 2003Assignee: Cytec Technology Corp.Inventors: Irina Kobylanska, David M. Konkus, David A. Iey
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Patent number: 6515164Abstract: A low-monomer PU prepolymer containing free NCO groups which is obtained from polyhydric alcohols and diisocyanates differing in their reactivity and which is distinguished by the ratio of the NCO groups of the partly slower-reacting diisocyanate to the NCO groups of the faster-reacting diisocyanate. It is greater than 6:1. Nevertheless the prepolymer according to the invention cures more quickly than a known prepolymer predominantly containing fast-reacting NCO groups. In a preferred embodiment, TDI is used as the partly slower-reacting diisocyanate while MDI is used as the faster-reacting diisocyanate. The prepolymer is produced in two stages. The prepolymer according to the invention is suitable for bonding plastic articles, metals and paper, especially films. The accelerated absence of migration is particularly noticeable in this regard.Type: GrantFiled: July 2, 1999Date of Patent: February 4, 2003Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Gerd Bolte, Guenter Henke, Markus Kruedenscheidt, Astrid Omoruyi
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Patent number: 6514439Abstract: Microcapsules of a microcapsule formed of a polyurea shell wall and an encapsulated ingredient or ingredients enclosed within the wall, the wall comprising at least one oligomeric acetal having the moiety in which R is (a) a moiety containing a chain of from 5 to about 40 optionally substituted carbon atoms, (b) a moiety containing a chain of from 4 to about 40 carbon atoms and one or more internally linked oxygen or sulfur atoms or —NH-groups, or (c) an optionally substituted ethylene or propylene moiety Z is (a) an optionally substituted phenyl group, (b) an optionally substituted C1-C20 alkyl, C2-C20 alkenyl, C3-C8 cycloalkyl or C5-C8 cycloalkenyl group, or (c) benzoyl, and n is 1 if R is (a) or (b), or is 2-20 if R is (c).Type: GrantFiled: December 11, 2001Date of Patent: February 4, 2003Assignee: Syngenta Ltd.Inventors: Juanita E. Van Koppenhagen, Herbert B. Scher, Kuo-shin Lee, Ian M. Shirley, Philip Wade, Richard Follows
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Patent number: 6509409Abstract: A dispersant comprising the addition product of a polyisocyanate having an average functionality of from 2 to 10 and one or more poly(oxyalkylene carbonyl) chains (POAC chain) such as those containing a POAC chain derived from &egr;-caprolactone and &dgr;-valerolactone. The dispersants are used to disperse pigments in paints and printing inks.Type: GrantFiled: October 30, 2000Date of Patent: January 21, 2003Assignee: Avecia LimitedInventor: Dean Thetford
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Patent number: 6506814Abstract: A UV-curable acrylate-thiol-ene insulating coating composition for electrical conductors, a method of manufacturing a UV-curable acrylate-thiol-ene insulating coating composition for electrical conductors. The insulating coating being of about 2.5 &mgr;m to about 500 &mgr;m thickness, which cured coating has a dielectric dissipation factor (60 Hz, 24° C.) of lower than about 0.05.Type: GrantFiled: May 7, 1998Date of Patent: January 14, 2003Assignee: DSM N.V.Inventors: Vadim V. Krongauz, Chau T. M. Ha, Sangeeta Rampuria
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Patent number: 6503980Abstract: This invention relates to novel liquid, polyurethane plasticizers which contain less than 13% by weight, preferably less than 6% by weight of allophanate groups, carbodiimide groups, and/or uretonimine groups, and to a process for the preparation of these liquid polyurethane plasticizers.Type: GrantFiled: December 20, 2000Date of Patent: January 7, 2003Assignee: Bayer CorporationInventors: Richard S. Pantone, Peter H. Markusch
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Patent number: 6503997Abstract: A polyurethane/polyurethane urea resin obtained by reacting an isocyanate group-terminated polyurethane prepolymer (A) obtained by reaction of high molecular weight active hydrogen compound and a polyisocyanate compound, with a chain extender (B), in a solvent and thereafter by removing the solvent, wherein the isocyanate group-terminated polyurethane prepolymer (A) is an isocyanate group-terminated polyurethane prepolymer obtained by reacting the following polyol (1) with a polyisocyanate compound in the presence of an excess amount of an isocyanate group, followed by reacting the following polyol (2) with the reaction product of polyol (1) in the presence of an excess amount of an isocyanate group; Polyol (1): a polyoxyalkylene polyol having a hydroxyl group value of at most 70, a total unsaturation degree of at most 0.Type: GrantFiled: November 17, 2000Date of Patent: January 7, 2003Assignee: Asahi Glass Company, LimitedInventors: Joichi Saito, Josho Kashiwame
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Patent number: 6500549Abstract: The present invention includes a co-polymer film which can be applied over a surface of an article to form a continuous surface that is more biocompatible and has a smoother surface morphology than an untreated article. In general the co-polymer film of the invention can be formed by providing a hydrophobic polymer block, such as polydimethylsiloxane (PDMS) with functional —OH end groups and reacting the —OH ends with a conventional monomer or prepolymer of a film-forming polymer capable of reacting with —OH groups. Such reactions are exemplified, using as reactive PDMS a triblock copolymer of the polylactone-polysiloxane-polylactone (PL-PDMS-PL) type, or silicone polyesters. The —OH groups of the polylactone blocks can react with any of a variety of isocyanates in a suitable solvent to form a polymer having PDMS incorporated with its structure.Type: GrantFiled: October 8, 1999Date of Patent: December 31, 2002Assignee: Gambro ABInventors: Reinhold Deppisch, Ulrich Bauer, Werner Beck, Ruth Dietrich, Hermann Göhl, Katja Krämer
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Patent number: 6500876Abstract: The invention relates to coating compositions containing: a) urethane (meth)acrylates that contain (meth)acryloyl groups and free isocyanate groups, b) urethane (meth)acrylates that contain (meth)acryloyl groups and free hydroxyl groups, c) the UV initiators that initiate radical polymerization and d) optionally, one or more compounds that react with isocyanates.Type: GrantFiled: March 16, 2001Date of Patent: December 31, 2002Assignee: Bayer AktiengesellschaftInventors: Jan Weikard, Michael Sonntag, Holger Mundstock
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Patent number: 6476176Abstract: The invention provides a golf ball having a cover and intermediate layers comprising in whole or in part of a saturated polyurethane. The saturated polyurethane may be blended with conventional materials employed to form golf balls, cores and intermediate layers.Type: GrantFiled: December 17, 1999Date of Patent: November 5, 2002Assignee: Acushnet CompanyInventor: Shenshen Wu
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Publication number: 20020161137Abstract: Melt spun thermoplastic polyurethane polymers useful as textile fibers and having good tenacity and recovery and substantially no gelation are disclosed. The polymers are prepared by a three-step polymerization process including: preparation of “hard” segment oligomer, preparation of “soft” segment oligomer and final reaction of “hard” segment with “soft” segment in a twin-screw reaction extruder to obtain a final polyurethane product having relatively uniform distances between the “hard” segments. The “soft” segment oligomer comprises blocks of polymeric glycol (poly) urethanes end capped with isocyanate groups. The “hard” segment oligomer comprises blocks of low molecular weight C2-C6 glycol (poly) urethanes.Type: ApplicationFiled: April 30, 2001Publication date: October 31, 2002Inventor: W. Kenneth Wilkinson
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Patent number: 6465539Abstract: The invention relates to an elastic coating system with which dry surfaces can be formed by UV curing of constituents containing (meth)acryloyl groups and by subsequent crosslinking of constituents containing NCO groups with constituents containing active hydrogen. The invention also relates to their use of this coating, system for coating, inter alia, components of plastic.Type: GrantFiled: September 11, 2000Date of Patent: October 15, 2002Assignee: Bayer AktiengesellschaftInventors: Jan Weikard, Wolfgang Fischer, Claus Kobusch, Wolfram Küttner
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Patent number: 6458866Abstract: The invention concerns a polyurethane elastomer containing structural units of type (a), in which: the group —O—R1—O—is a macrodiol group with a molecular weight of approximately 500 to 10000, R2 is a bivalent aliphatic, cycloaliphatic and/or aliphatic-cycloaliphatic group; and X is a short-chain olefinically unsaturated group, Y is NH or O, n is an integer from 1 to 10 and m is an integer of at least 4. The invention also concerns a method of preparing this polyurethane elastomer which can be melt-spun to form fibres or melt-extruded to form foils. The fibres or foils can be exposed to energy-rich radiation such that crosslinking of the polyurethane occurs. Fibres according to the invention display superior properties in terms of textile-mechanical properties, in particular good tensile strength, elongation at tear, residual elongation and heat distortion temperature.Type: GrantFiled: May 15, 1998Date of Patent: October 1, 2002Assignee: Rhodia S.A.Inventors: Wilhelm Oppermann, Frank Hermanutz, Peter Hirt, Michael Schweizer, Oliver Oess
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Patent number: 6455607Abstract: A one-part, cured, radiation-curable liquid matrix composition for affixing coated and inked optical fibers in a ribbon configuration which is peelable from the coated and inked fibers without damage to the integrity of itself or the fibers is disclosed. The composition comprises an aliphatic urethane acrylate oligomer; a reactive monomer having one or more acrylate or methacrylate moieties; a release agent; and an optional photoinitiator. Also disclosed are an optical fiber ribbon array prepared therefrom; a process for removing such matrix composition from inked and coated fibers; a process for preparing such ribbon array; and a radiation-curable coating composition generally applicable for coating a substrate.Type: GrantFiled: March 2, 1999Date of Patent: September 24, 2002Assignee: Borden Chemical, Inc.Inventor: Paul J. Shustack
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Patent number: 6444777Abstract: Compact and preferably cellular polyurethane elastomers based on polyisocyanate mixtures containing 3,3′-dimethylbiphenyl 4,4′-diisocyanate are produced by reacting a) relatively high molecular weight polyhydroxyl compounds and, if desired, b) low molecular weight hydroxyl-containing chain extenders and/or crosslinkers with c) 3,3′-dimethylbiphenyl 4,4′-diisocyanate and at least one additional aromatic diisocyanate selected from the group consisting of tolylene diisocyanate, diphenylmethane diisocyanate, 1,2-diphenylethane diisocyanate and phenylene diisocyanate, and/or at least one aliphatic diisocyanate having from 4 to 12 carbon atoms and/or at least one cycloaliphatic diisocyanate having from 6 to 18 carbon atoms, where the formative components (a), (c) and, if used, (b) are advantageously reacted by the prepolymer method, in the presence or absence of d) catalysts, e) blowing agents and f) additives.Type: GrantFiled: August 24, 1998Date of Patent: September 3, 2002Assignee: BASF AktiengesellschaftInventors: Manfred Genz, Gerhard Hellmann, Walter Haselhorst, Torsten Jeschke, Ute Nichau, Heinz Bollmann, Michael Strauss, Wolfgang Scholz, Hartmut Peuker, Rüdiger Voelkel
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Patent number: 6444721Abstract: A water-dispersible, radiation-curable polyurethane composed essentially of a) organic, aliphatic or alicyclic polyisocyanates, b) cycloaliphatic diols and/or cycloaliphatic diamines, c) compounds containing at least one isocyanate-reactive group and at least one free-radically polymerizable unsaturated group, d) compounds containing at least one isocyanate-reactive group and at least one dispersing-active group, e) if desired, compounds containing at least two isocyanate-reactive groups having a molecular weight <1000 g/mol, f) if desired, compounds other than a) to d) containing at least one isocyanate-reactive group.Type: GrantFiled: January 3, 2001Date of Patent: September 3, 2002Assignee: BASF AktiengesellschaftInventors: Reinhold Schwalm, Frank Völlinger, Klaus Menzel, Wolfgang Reich, Erich Beck, Thomas Jaworek
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Publication number: 20020111453Abstract: Polyurethane elastomer are produced by reacting a polyether and/or polyester polyol having a starter functionality of at least 2 with an NHCO-terminated prepolymer produced with a polyether and/or polyester polyol having a starter functionality of at least 4. These polyurethane elastomers exhibit improved processing characteristics combined with a high heat distortion temperature.Type: ApplicationFiled: December 11, 2001Publication date: August 15, 2002Inventors: Peter Haas, Hans-Detlef Arntz
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Patent number: 6433123Abstract: Herein are disclosed a curable resin composition for overcoat of flexible circuit which comprises a hydrogenated polybutadiene polyol with a number-average molecular weight of 1,000-8,000 and having 2-10 hydroxyl groups per molecule (Polyol A), and a polybutadiene polyblock isocyanate (Isocyanate X), and other similar curable resin compositions, which can be an overcaoting agent which can give a coat film involving no such trouble that the coat film gets overhardened and the curling is increased.Type: GrantFiled: October 15, 1999Date of Patent: August 13, 2002Assignee: Ajinomoto Co., Inc.Inventor: Hiroshi Orikabe
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Publication number: 20020103325Abstract: A polyisocyanate-based elastomer having a ratio of the storage modulus (E′) at 20° C. and the storage modulus (E′) at 120° C. of between 0.75 and 1.5, a tan &dgr; at 100° C. of less than 0.1 and a maximum value of the tan &dgr; of more than 0.8, the tan &dgr; being the ratio of the loss modulus (E″) and the storage modulus (E′).Type: ApplicationFiled: February 4, 2002Publication date: August 1, 2002Applicant: Imperial Chemical Industries PLCInventors: Gerhard Jozef Bleys, Alan James Hamilton, Jan Willem Leenslag
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Patent number: 6423472Abstract: Butadiene-polyether prepolymers which can be used in photopolymer resins are prepared by reacting butadiene homopolymer with a stoichiometric excess of isocyanate and then reacting the product with polyether diol. Thereafter the composition is reacted with hydroxyalkyl(meth)acrylate and alkyldialkanolamine. Flexographic printing plates may be prepared using photopolymer resin comprising butadiene-polyether prepolymers.Type: GrantFiled: March 24, 2000Date of Patent: July 23, 2002Assignee: MacDermid Graphic Arts, Inc.Inventors: Ronald James Kumpfmiller, Martin Lewis Carter
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Patent number: 6423777Abstract: The invention relates to new high-functional polyaddition compounds which contain free isocyanate groups with an average isocyanate functionality of 2.1 to 8.0, a concentration of uretdione of 10 to 18 wt. %, a concentration of urethane of 10 to 20 wt. % and a concentration of ester groups —CO—O and/or carbonate groups —O—CO—O of 1 to 17 wt. %, a process for the preparation thereof and their use as starting components for the preparation of polyurethane plastics, in particular as cross-linking agents for heat-curable powder coatings.Type: GrantFiled: September 5, 2000Date of Patent: July 23, 2002Assignee: Bayer AktiengesellschaftInventors: Hans-Josef Laas, Ulrich Freudenberg, Reinhard Halpaap, Michael Grahl
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Patent number: 6420508Abstract: The present invention relates to polyisocyanate mixtures prepared from aliphatic and/or cycloaliphatic diisocyanates and having a) an average isocyanate functionality of at least 2.0, b) a content of isocyanate groups (calculated as NCO; molecular weight=42) of 4.0 to 28.0 wt. % and c) a content of alkoxy groups having up to 36 carbon atoms of 2.0 to 37.5 wt. %, wherein the alkoxy groups are constituents of allophanate groups or optionally urethane groups, provided that >50 mol % of the alkoxy groups are a constituent of allophanate groups that are connected to at least two polyisocyanate molecules which are each prepared from at least two diisocyanates. The present invention also relates to a process for preparing these polyisocyanate mixtures and to coating compositions, which are highly diluted or dilutable with non-polar solvents and contain these polyisocyanate mixtures and lacquer binders or binder components optionally containing isocyanate-reactive groups.Type: GrantFiled: June 8, 2000Date of Patent: July 16, 2002Assignee: Bayer AktiengesellschaftInventors: Karsten Danielmeier, Lutz Schmalstieg, Hans-Josef Laas, Harald Mertes, Reinhard Jahn
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Patent number: RE38201Abstract: The use of 3-[3-(dimethylamino)propyl]-propionamide (Formula I) and 3,3′-{[3-(dimethylamino)propyl]imino}bis-propanamide (Formula II) as catalysts in the production of polyurethanes. The use of 3-{[3-(dimethylamino)propyl]amino}-propionamide (Formula I) and 3,3′-{[3-(dimethylamino)propyl]imino}bis-propanamide (Formula II) as catalysts in the production of polyurethanes.Type: GrantFiled: March 22, 2002Date of Patent: July 22, 2003Assignee: Air Products and Chemicals, Inc.Inventors: Ning Chen, Richard Van Court Carr, Mark Leo Listemann, Richard Paul Underwood