Boron Reactant Contains A Nitrogen Atom Patents (Class 528/7)
  • Patent number: 11910697
    Abstract: A copolymer having a structural unit represented by Chemical Formula 1 is provided. The copolymer may improve performance, e.g., luminous efficiency, of an electroluminescence device. In Chemical Formula 1, the definition of each substituent is as described in the detailed description.
    Type: Grant
    Filed: September 9, 2021
    Date of Patent: February 20, 2024
    Assignee: SAMSUNG ELECTRONICS CO., LTD.
    Inventors: Fumiaki Kato, Masashi Tsuji, Takao Motoyama, Yusaku Konishi, Keigo Furuta, Takahiro Fujiyama, Tae Ho Kim, Won Sik Yoon, Ha Il Kwon, Dae Young Chung, Eun Joo Jang
  • Patent number: 11672136
    Abstract: An object of one embodiment of the present invention is to provide a multicolor light-emitting element that utilizes fluorescence and phosphorescence and is advantageous for practical application. The light-emitting element has a stacked-layer structure of a first light-emitting layer containing a host material and a fluorescent substance, a separation layer containing a substance having a hole-transport property and a substance having an electron-transport property, and a second light-emitting layer containing two kinds of organic compounds that form an exciplex and a substance that can convert triplet excitation energy into luminescence. Note that a light-emitting element in which light emitted from the first light-emitting layer has an emission spectrum peak on the shorter wavelength side than an emission spectrum peak of the second light-emitting layer is more effective.
    Type: Grant
    Filed: February 18, 2021
    Date of Patent: June 6, 2023
    Assignee: Semiconductor Energy Laboratory Co., Ltd.
    Inventors: Nobuharu Ohsawa, Yusuke Nonaka, Takahiro Ishisone, Satoshi Seo, Takuya Kawata
  • Patent number: 11518830
    Abstract: Described herein are organoborane polymers and methods for the oxidation of these organoborane polymers to poly (vinyl alcohol) PVA. The organoborane polymers of the present invention respond to an external trigger by changing from a hydrophobic to a hydrophilic state.
    Type: Grant
    Filed: October 16, 2018
    Date of Patent: December 6, 2022
    Assignee: The Johns Hopkins University
    Inventors: Rebekka Klausen, Heidi Lee VanDeWouw, Jae Young Lee
  • Patent number: 10683395
    Abstract: A dual-curable sealant composition includes a polysulfide having an —SH group, a metal oxide catalyst, and an alkylborane amine catalyst. A cured sealant is also formed from the dual-curable sealant composition. Moreover, a dual-cured sealant is formed that includes the polymerization product of the polysulfide reacted in the presence of the metal oxide catalyst and the alkylborane amine catalyst. Further, a dual-curable sealant system includes a first component including the polysulfide and the alkylborane amine catalyst and a second component including the metal oxide catalyst. An article is formed that includes a substrate and the cured sealant disposed on the substrate. Even further, a method of forming the dual-curable sealant composition includes the steps of providing the polysulfide, the alkylborane amine catalyst, and the metal oxide catalyst, and combining the polysulfide, the alkylborane amine catalyst, and the metal oxide catalyst to form the dual-curable composition.
    Type: Grant
    Filed: April 7, 2017
    Date of Patent: June 16, 2020
    Assignee: BASF SE
    Inventors: John Michael Davis, Ralph Dieter Maier, Karl Matos, Kevin M. Neigh, Kristin Schroeder
  • Patent number: 10358521
    Abstract: This disclosure relates to new injectable hydrogel materials that consist of water gellants comprising linear hydrophilic polymers that comprise hydrogen bonding units in the backbone combined with cross-linkable end groups, resulting in dynamic yet firm hydrogel materials that are easily processable, are highly elastic, show adhesive properties and are self-healing and are especially suitable for biomedical applications.
    Type: Grant
    Filed: July 24, 2015
    Date of Patent: July 23, 2019
    Assignee: SUPRAPOLIX B.V.
    Inventors: Joris Wilhelmus Peeters, Tristan Mes, Henricus Marie Janssen, Anton Willem Bosman
  • Patent number: 10093770
    Abstract: A mixture may include at least one polymerizable species and at least one thermoresponsive supramolecular initiator complex involving a host-guest interaction. Processes for making resins may include mixing at least one polymerizable species with at least one thermoresponsive supramolecular initiator complex involving a host-guest interaction; subjecting the mixture to a temperature above about 30° C. thereby promoting the dissociation of the at least one thermoresponsive supramolecular initiator; and allowing the mixture to cure at the temperature for a period of time.
    Type: Grant
    Filed: August 12, 2013
    Date of Patent: October 9, 2018
    Assignees: SCHLUMBERGER TECHNOLOGY CORPORATION, FONDS DE L'ESPCI GEORGE CHARPAK
    Inventors: Thomas Vidil, Francois-Genes Tournilhac, Ludwik Leibler
  • Patent number: 9315701
    Abstract: Provided are two part hybrid adhesives that comprise an organoborane amine complex, a polyamine, a component polymerizable by free radical polymerization, and a polyisocyanate component. An isocyanate terminated prepolymer can advantageously be used in the practice of the invention. The adhesive is particularly well suited for low surface energy plastic bonding.
    Type: Grant
    Filed: April 30, 2014
    Date of Patent: April 19, 2016
    Assignee: Henkel IP & Holding GmbH
    Inventors: Yongxia Wang, Charles W. Paul
  • Patent number: 9217002
    Abstract: The present invention relates to novel cluster boron compounds and their use as sodium channel blockers. In particular, the novel cluster boron compounds may be lidocaine analogs where the aromatic ring of the lidocaine molecule is replaced with a cluster boron group. The invention also provides methods for making the cluster boron compounds comprising contacting a halogenated cluster boron with an amino acetamide in the presence of a catalyst, a proton acceptor, and a ligand.
    Type: Grant
    Filed: September 13, 2012
    Date of Patent: December 22, 2015
    Assignee: The Curators of the University of Missouri
    Inventors: George R. Kracke, Yulia Sevryugina, Marion Frederick Hawthorne
  • Patent number: 9017577
    Abstract: The invention relates to conjugated polymers comprising indacenodithiophene or indacenoselenophene units or derivatives thereof, to methods of their preparation, to novel monomer units used therein, to the use of the polymers in organic electronic (OE) devices, and to OE devices comprising the polymers.
    Type: Grant
    Filed: July 24, 2009
    Date of Patent: April 28, 2015
    Assignee: Merck Patent GmbH
    Inventors: Steven Tierney, Clare Bailey, William Mitchell, Weimin Zhang
  • Publication number: 20150108408
    Abstract: The present invention relates to cross-linkable and cross-linked polymers, methods for the production thereof, the use of said cross-linked polymers in electronic devices, especially in OLEDs (OLED=Organic Light Emitting Diode), and to electronic devices, especially organic electroluminescent devices which contain the cross-linked polymers.
    Type: Application
    Filed: April 12, 2013
    Publication date: April 23, 2015
    Inventors: Fabrice Eckes, Anja Gerhard, Anna Hayer, Holger Heil, Dominik Joosten
  • Patent number: 9012584
    Abstract: In various embodiments, the present invention provides an organoboronate nanoparticle. The nanoparticle includes a polymer, which includes a repeating unit that includes at least one organoboronate functional group. Various embodiments provide compositions including the nanoparticles, surface functionalized nanoparticles, nanoparticles including an encapsulant, methods of making the nanoparticles, and methods of using the nanoparticles, such as methods of stimuli-responsive release of encapsulants.
    Type: Grant
    Filed: March 12, 2014
    Date of Patent: April 21, 2015
    Assignee: University of Massachusetts
    Inventors: Sankaran Thayumanavan, Conghui Yuan
  • Publication number: 20150076415
    Abstract: The present invention relates to polymers containing oligo-triarylamine repetition units that are substituted in the ortho position, a method for the production thereof, and use thereof in electronic devices, particularly in organic electroluminescence devices, known as OLEDs (OLED=organic light emitting diodes). The present invention further relates to organic electroluminescence devices containing these polymers.
    Type: Application
    Filed: April 15, 2013
    Publication date: March 19, 2015
    Inventors: Holger Heil, Fabrice Eckes, Dominik Joosten, Anna Hayer, Katja Stegmaier
  • Publication number: 20150028262
    Abstract: The present invention relates to organic copolymers and organic semiconducting compositions comprising these materials, including layers and devices comprising such organic semiconductor compositions. The invention is also concerned with methods of preparing such organic semiconductor compositions and layers and uses thereof. The invention has application in the field of printed electronics and is particularly useful as a semiconducting material for use in formulations for organic thin film transistor (OTFT) backplanes for displays, integrated circuits, organic light emitting diodes (OLEDs), photodetectors, organic photovoltaic (OPV) cells, sensors, memory elements and logic circuits.
    Type: Application
    Filed: February 25, 2013
    Publication date: January 29, 2015
    Applicant: SmartKem Limited
    Inventor: Russell Jon Griffiths
  • Publication number: 20150028261
    Abstract: The present invention relates to organic copolymers and organic semiconducting compositions comprising these materials, including layers and devices comprising such organic semiconductor compositions. The invention is also concerned with methods of preparing such organic semiconductor compositions and layers and uses thereof. The invention has application in the field of printed electronics and is particularly useful as the semiconducting material for use in formulations for organic thin film-transistor (OFET) backplanes for displays, integrated circuits, organic light emitting diodes (OLEDs), photodetectors, organic photovoltaic (OPV) cells, sensors, memory elements and logic circuits.
    Type: Application
    Filed: February 25, 2013
    Publication date: January 29, 2015
    Inventor: Russell Jon Griffiths
  • Publication number: 20150018505
    Abstract: A polymer containing thiophene-benzene-thiophene unit has the following formula as (I): R1 represents C1 to C20 alkyl, R2 represents C1 to C20 alkyl, n is an integer from 10 to 100. An energy gap of the polymer containing thiophene-benzene-thiophene unit is narrow, and therefore the power conversion efficiency is improved greatly. A method of preparing the polymer containing thiophene-benzene-thiophene unit and a sonar cell device using the polymer containing thiophene-benzene-thiophene unit are also provided.
    Type: Application
    Filed: March 12, 2012
    Publication date: January 15, 2015
    Inventors: Mingjie Zhou, Ping Wang, Zhenhua Zhang, Hui Huang
  • Patent number: 8921506
    Abstract: A copolymer includes a first unit and at least two units different from the first unit. An organic solar cell includes a first electrode, a second electrode opposite the first electrode, and one or more organic material layers interposed between the first electrode and the second electrode and including a photoactive layer, and one or more of the organic material layers include the copolymer. A method for fabricating an organic solar cell includes preparing a substrate, forming a first electrode on a region of rear sides of the substrate, forming on the first electrode an organic material layer containing the copolymer, and forming a second electrode on the organic material layer.
    Type: Grant
    Filed: August 3, 2012
    Date of Patent: December 30, 2014
    Assignee: LG Chem, Ltd.
    Inventors: Taiho Park, Gang-Young Lee, Minjeong Im, Seulki Song, Jinseck Kim, Jaechol Lee, Hangken Lee, Songrim Jang, Keun Cho
  • Patent number: 8912308
    Abstract: A copolymer includes a first unit and at least one unit two units different from the first unit. An organic solar cell includes the copolymer in an organic material layer including a photoactive layer.
    Type: Grant
    Filed: August 3, 2012
    Date of Patent: December 16, 2014
    Assignee: LG Chem, Ltd.
    Inventors: Jinseck Kim, Jaechol Lee, Hangken Lee, Jeong Min Choi, Jiyoung Lee, Taiho Park, Gang-Young Lee, Minjeong Im, Seulki Song
  • Publication number: 20140339476
    Abstract: The present invention relates to hyperbranched polymers, to a process for the preparation thereof, and to the starting compounds necessary for the preparation. The present invention furthermore relates to the use of the hyperbranched polymers according to the invention in electronic devices and to the electronic devices themselves.
    Type: Application
    Filed: October 1, 2012
    Publication date: November 20, 2014
    Applicant: Merck Patent GmbH
    Inventors: Niels Schulte, Eva Maria Reis
  • Patent number: 8883043
    Abstract: Poly(anilineboronic acid)/phosphate nanoparticle dispersions are produced in high yields using the reactivity of the boronic acid moiety with phosphate in the presence of fluoride. The poly(anilineboronic acid)/phosphate dispersions have been characterized using spectroscopic, microscopic and electrochemical techniques. According to 11B NMR studies, the formation of anionic tetrahedral boronate group in phosphoric acid in the presence of fluoride forms the basis of self-doped, stabilized PABA nanoparticle dispersion. Transmission electron microscope images show that 25-50 nm diameter PABA nanoparticles are formed under these conditions. UV-vis, FT-IR-ATR spectroscopic and cyclic voltammetric results confirm the formation of the conducting form of PABA.
    Type: Grant
    Filed: November 25, 2009
    Date of Patent: November 11, 2014
    Assignee: University of Manitoba
    Inventors: Michael S. Freund, Bhavana A. Deore
  • Publication number: 20140318625
    Abstract: The present invention relates a conductive polymer containing a 3,6-carbazole group represented by Chemical Formula 1 and an organic polymer thin film solar cell including the same.
    Type: Application
    Filed: August 26, 2011
    Publication date: October 30, 2014
    Applicant: LG CHEM, LTD.
    Inventors: Taiho Park, Gang-Young Lee, Minjeong Im, Seulki Song, Jinseck Kim, Jaechol Lee, Jaesoon Bae, Hangken Lee
  • Publication number: 20140275417
    Abstract: In various embodiments, the present invention provides an organoboronate nanoparticle. The nanoparticle includes a polymer, which includes a repeating unit that includes at least one organoboronate functional group. Various embodiments provide compositions including the nanoparticles, surface functionalized nanoparticles, nanoparticles including an encapsulant, methods of making the nanoparticles, and methods of using the nanoparticles, such as methods of stimuli-responsive release of encapsulants.
    Type: Application
    Filed: March 12, 2014
    Publication date: September 18, 2014
    Applicant: University of Massachusetts
    Inventors: Sankaran Thayumanavan, Conghui Yuan
  • Patent number: 8785004
    Abstract: A fluorene-based copolymer of formula I includes a monomeric unit that includes a fluorene group and at least one steric hindering chemical group to provide sufficient steric interaction such that the spatial conformation of the fluorene-based copolymer is substantially non-planar. The fluorene-based copolymer exhibits UV light emission.
    Type: Grant
    Filed: January 30, 2009
    Date of Patent: July 22, 2014
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Zhang-Lin Zhou, Chung Ching Yang, Lihua Zhao
  • Publication number: 20140187716
    Abstract: Processes for the continuous production of conjugated polymers are disclosed. The processes provide excellent control over reaction parameters and are highly reproducible. The conjugated polymers find use in heterojunction devices.
    Type: Application
    Filed: July 13, 2012
    Publication date: July 3, 2014
    Applicant: The University of Melbourne
    Inventors: David John Jones, Wing Ho Wallace Wong, Andrew Bruce Holmes, Helga Seyler
  • Publication number: 20140175421
    Abstract: The present invention relates inter alia to oligomers and/or polymers with functionalized side groups which are bound to the backbone of the polymer via spacer.
    Type: Application
    Filed: June 28, 2012
    Publication date: June 26, 2014
    Applicant: Merck Patent GmbH
    Inventors: Junyou Pan, Frank Egon Meyer, Niels Schulte, René Peter Scheurich
  • Patent number: 8742050
    Abstract: Provided are two part hybrid adhesives that comprise an organoborane amine complex, a polyamine, a component polymerizable by free radical polymerization, and a polyisocyanate component. An isocyanate terminated prepolymer can advantageously be used in the practice of the invention. The adhesive is particularly well suited for low surface energy plastic bonding.
    Type: Grant
    Filed: March 28, 2008
    Date of Patent: June 3, 2014
    Assignee: Henkel US IP LLC
    Inventors: Yongxia Wang, Charles W. Paul
  • Publication number: 20140117289
    Abstract: The present invention describes copolymers containing indenocarbazole derivatives having electron- and hole-transporting properties, in particular for use in the interlayer, emission and/or charge-transport layer of electroluminescent devices, and the monomers which are necessary for the preparation of the copolymers. The invention furthermore relates to a process for the preparation of the copolymers according to the invention, and to electronic devices comprising same.
    Type: Application
    Filed: May 18, 2012
    Publication date: May 1, 2014
    Applicant: Merck Patent GmbH
    Inventors: Junyou Pan, Niels Schulte
  • Patent number: 8709290
    Abstract: The invention relates to conjugated polymers comprising benzo-bis(silolothiophene) units or derivatives thereof, to methods of their preparation, to novel monomer units used therein, to the use of the polymers in organic electronic (OE) devices, and to OE devices comprising the polymers.
    Type: Grant
    Filed: August 20, 2009
    Date of Patent: April 29, 2014
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventors: Steven Tierney, Clare Bailey, William Mitchell, Nicolas Blouin
  • Publication number: 20140114040
    Abstract: This invention comprises a semiconducting polymer having a permittivity greater than 3.4 at 1000 Hz and a charge mobility in the pure state greater than 10?7 cm2V?1s?1 and more preferably greater than 10?6 cm2V?1s?1. Preferred polymers include repeating units of triarylamines which have specific cyano and/or alkoxy substitution. They are suitable for use in electronic components such as organic thin film transistors.
    Type: Application
    Filed: May 24, 2012
    Publication date: April 24, 2014
    Applicants: Peakdale Molecular Limited, Centre for Process Innovation Limited
    Inventors: Beverley Anne Brown, Simon Dominic Ogier, Marco Palumbo, Keri McCall, Raymond Fisher, Michael James Simms, Neil David Forrest, Aaron James Page, Stuart Edmund Willetts, Julie Diane Ellis Jones
  • Patent number: 8674046
    Abstract: A low dielectric constant material having an excellent water resistance obtained by heat-treating a borazine compound of the formula (1-2): or an inorganic or organic compound having a group derived from the borazine compound (1-2) to undergo a condensation reaction, thereby producing an oligomer or polymer, wherein R1 to R6 are independently a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, an aryl group, a substituted aryl group, an alkenyl group, an amino group, an alkylamino group, an alkoxyl group, a thioalkoxyl group, a carbonyl group, a silyl group, an alkylsilyl group, a phosphino group, an alkylphosphino group, or a group of the formula: Si(OR7)(OR8)(OR9), and at least one of R1 to R6 is not hydrogen atom.
    Type: Grant
    Filed: September 14, 2009
    Date of Patent: March 18, 2014
    Assignee: Mitsubishi Denki Kabushiki Kaisha
    Inventors: Hideharu Nobutoki, Teruhiko Kumada, Toshiyuki Toyoshima, Naoki Yasuda, Suguru Nagae
  • Publication number: 20130292657
    Abstract: Light-emitting composition and devices including the same, the composition including a fluorescent light-emitting material and a polymer having a conjugating repeat unit and a non-conjugating repeat unit in a backbone of the polymer, and in which the conjugating repeat unit provides at least one conjugation path between repeat units linked to it; the non-conjugating repeat unit reduces conjugation of the polymer as compared to a polymer in which the non-conjugating repeat unit is absent; and a triplet excited state energy level of the light-emitting material is higher than a triplet excited state energy level of the non-conjugating repeat unit.
    Type: Application
    Filed: October 13, 2011
    Publication date: November 7, 2013
    Applicants: Sumitomo Chemical Company Limited, Cambridge Display Technology, Ltd.
    Inventors: Natasha M.J. Conway, Jonathan Pillow, Thomas Pounds, Fredrik Jakobsson, Christian Nielsen
  • Publication number: 20130240843
    Abstract: A polymer and an organic light-emitting device including the polymer represented by Formula 1 wherein at least one of a first dihedral angle between an A1 ring of an nth repeating unit and a first aromatic ring of an (n?1)th repeating unit and a second dihedral angle between an A2 ring of the nth repeating unit and a second aromatic ring of a (n+1)th repeating unit is equal to or greater than an angle of ?50% represented by Equation 1.
    Type: Application
    Filed: September 7, 2012
    Publication date: September 19, 2013
    Applicant: SAMSUNG ELECTRONICS CO., LTD.
    Inventors: Hyeon-ho CHOI, Jhun-mo SON, Ho-suk KANG, Hye-yeon YANG, Yong-sik JUNG
  • Patent number: 8519077
    Abstract: N-type conjugated compounds are disclosed which include at least one conjugated electron-acceptor unit The conjugated electron-acceptor unit includes a diborylene unit. The compounds find application in an electron acceptor layer of an electronic device.
    Type: Grant
    Filed: August 10, 2009
    Date of Patent: August 27, 2013
    Assignee: The University of Akron
    Inventor: Li Jia
  • Patent number: 8501887
    Abstract: A radical polymerizable composition includes a radical polymerizable compound and an organoborane-azole complex. The organoborane-azole complex includes an azole having at least two nitrogen atoms wherein at least one nitrogen atom is an sp3 nitrogen atom and is substituted. A method of forming the composition includes the step of combining the radical polymerizable compound and the organoborane-azole complex to form the composition. The method also includes the step of polymerizing the composition. A composite article which includes a substrate and a cured composition disposed on the substrate is also provided. The cured composition is formed from polymerization of the composition.
    Type: Grant
    Filed: July 27, 2009
    Date of Patent: August 6, 2013
    Assignee: Dow Corning Corporation
    Inventors: Dongchan Ahn, Gang Lu
  • Publication number: 20130157926
    Abstract: The present invention relates to a boronated polymer according to Formula (1): a process for making the boronated polymer according to Formula (1), drug 10 delivery systems, aggregates, nanoparticles and hydrogels comprising the boronated polymer according to Formula (1).
    Type: Application
    Filed: June 20, 2011
    Publication date: June 20, 2013
    Inventors: Johannes Franciscus Joseph Engbersen, Martin Piest
  • Patent number: 8461282
    Abstract: The present invention discloses an iridium complex containing a (pentaphenyl)phenyl ligand, having the following general equation: in which G is primary ligand, R? and R? are auxiliary ligands. On the other hand, the present invention discloses a compound with a 9-[(pentaphenyl)phenyl]carbazole structure and its polymeric derivative.
    Type: Grant
    Filed: December 2, 2009
    Date of Patent: June 11, 2013
    Assignee: National Taiwan University
    Inventors: Kuo-Huang Hsieh, Man-Kit Leung, Wen-Chang Chen, Chao-Hui Kuo, Hong-Jun Chen, Hsin-Chung Ke, Cheng-Hsiu Ku
  • Publication number: 20130056073
    Abstract: Disclosed herein are a 3,6-carbazole-containing copolymer, an organic solar cell comprising the copolymer in an organic material layer including a photoactive layer, and a method for fabricating the organic solar cell.
    Type: Application
    Filed: August 3, 2012
    Publication date: March 7, 2013
    Applicants: POSTECH ACADEMY-INDUSTRY FOUNDATION, LG CHEM, LTD.
    Inventors: Jinseok Kim, Jaechol Lee, Jaesoon Bae, Hangken Lee, Taiho Park, Gang-Young Lee, Minjeong Im, Seulki Song
  • Publication number: 20130056072
    Abstract: Disclosed herein are a 3,6-carbazole-containing copolymer, an organic solar cell comprising the copolymer in an organic material layer including a photoactive layer, and a method for fabricating the organic solar cell.
    Type: Application
    Filed: August 3, 2012
    Publication date: March 7, 2013
    Applicant: LG CHEM, LTD.
    Inventors: Taiho Park, Gang-Young Lee, Minjeong Im, Seulki Song, Jinseok Kim, Jaechol Lee, Hangken Lee, Songrim Jang, Keun Cho
  • Publication number: 20130043434
    Abstract: The invention relates to novel polymers of benzodithiophene, methods and materials for their preparation, their use as semiconductors in organic electronic (OE) devices, and to OE devices comprising these polymers.
    Type: Application
    Filed: March 23, 2011
    Publication date: February 21, 2013
    Applicant: MERCK PATENT GESELLSCHAFT MIT BESCHRANKTER HAFTUNG
    Inventors: Steven Tierney, Nicolas Blouin, William Mitchell, Changsheng Wang, Miguel Carrarsco-Orozco, Frank Egon Meyer
  • Publication number: 20130046072
    Abstract: Monomers having formula (I) and process for their synthesis which comprises the etherification reaction of a halogen-derivative (Z?Cl, Br, I) having formula (III) with the hydroxyl group of the glycerol derivative (IV), according to the following scheme:(Formula III, IV & I) (III) (IV) (I)
    Type: Application
    Filed: April 29, 2011
    Publication date: February 21, 2013
    Applicant: ENI S.p.A.
    Inventors: Giuliana Schimperna, Riccardo Po', Andrea Pellegrino, Maria Caldararo
  • Publication number: 20130032791
    Abstract: Described herein are novel light absorbing conjugated polymeric electron donor materials for organic photovoltaic devices and other applications. In one embodiment, the polymer structure comprises a conjugated electron rich donor unit with an imine functionality at the bridgehead position and a conjugated electron deficient unit in the polymer backbone arranged in an alternating fashion. Monomers suitable for making the polymers, and devices utilizing the polymers, are also disclosed.
    Type: Application
    Filed: June 14, 2012
    Publication date: February 7, 2013
    Inventors: Guillermo C. Bazan, Jason D. Azoulay, Bruno Caputo
  • Publication number: 20130026459
    Abstract: A photoelectric conversion device that contains a polymer compound having a structural unit represented by formula (1) has high photoelectric conversion efficiency. (wherein, X1 and X2 are the same or different and represent a nitrogen atom or ?CH—. Y1 represents a sulfur atom, an oxygen atom, a selenium atom, —N(R1)— or —CR2?CR3—. R1, R2 and R3 are the same or different and represent a hydrogen atom or a substituent. W1 represents a cyano group, a monovalent organic group having a fluorine atom or a halogen atom. W2 represents a cyano group, a monovalent organic group having a fluorine atom, a halogen atom or a hydrogen atom.
    Type: Application
    Filed: April 21, 2011
    Publication date: January 31, 2013
    Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Ken Yoshimura, Kenichiro Ohya
  • Patent number: 8362199
    Abstract: Interlayer insulating films 5,7 (insulating films) provided in a memory capacitor cell 8 are formed between a gate electrode 3 and a counter electrode 8C formed on a silicon wafer 1. The interlayer insulating films 5,7 comprise a borazine-based resin, having a specific dielectric constant of no greater than 2.6, a Young's modulus of 5 GPa or greater and a leak current of no greater than 1×10?8 A/cm2.
    Type: Grant
    Filed: June 1, 2009
    Date of Patent: January 29, 2013
    Assignee: Hitachi Chemical Co., Ltd.
    Inventors: Hiroshi Matsutani, Makoto Kaji, Koichi Abe, Yuko Uchimaru
  • Publication number: 20130001474
    Abstract: The present invention relates to copolymers for solar cells based on acridonic units comprising: a monomeric unit (A) having general formula (I) wherein X is S or Se, Y is 0, S or NR? and R?, R?, the same or different, are C4-C24 alkyl groups, aryl groups optionally substituted with other functional groups, acyl groups or thioacyl groups; at least one monomer unit (B) having general formula (II) wherein Z is 0, S, Se or N—R?, wherein R? is a C4-C24 alkyl group, an aryl group op-tionally substituted with other functional groups, an acyl group or thioacyl group, said monomeric unit (B) being connected to any position available of a hetero-aromatic side ring of the unit (A) through one of the two positions indicated by the dashed lines in general formula (II). Photovoltaic devices comprising said alternating ?-conjugated polymers are also described.
    Type: Application
    Filed: December 15, 2010
    Publication date: January 3, 2013
    Applicant: ENI S.p.A.
    Inventors: Maria Caldararo, Andrea Pellegrino, Giuliana Schimperna, Riccardo Po'
  • Patent number: 8309672
    Abstract: Methods, compositions and articles of manufacture involving soluble conjugated polymers are provided. The conjugated polymers have a sufficient density of polar substituents to render them soluble in a polar medium, for example water and/or methanol. The conjugated polymer may desirably comprise monomers which alter its conductivity properties. In some embodiments, the inventors have provided cationic conjugated polymers (CCPs) comprising both solubilizing groups and conductive groups, resulting in conductive conjugated polymers soluble in polar media. The different solubility properties of these polymers allow their deposition in solution in multilayer formats with other conjugated polymers. Also provided are articles of manufacture comprising multiple layers of conjugated polymers having differing solubility characteristics. Embodiments of the invention are described further herein.
    Type: Grant
    Filed: September 6, 2005
    Date of Patent: November 13, 2012
    Assignee: The Regents of the University of California
    Inventors: Guillermo C. Bazan, Bin Liu, Xiong Gong, Alan J. Heeger, Wanli Ma, Parameswar K. Iyer
  • Publication number: 20120229017
    Abstract: The present invention provides green and red conversion films capable of keeping a sufficient intensity of converted light over a long period, and a multicolor emission organic EL device which exhibits light-emitting properties stably over a long period. The present invention includes a pendant-type polymeric compound characterized in that the pendant-type polymeric compound contains at least one repeating unit represented by a general formula (1) and at least one repeating unit represented by a general formula (2), (6) or (7), wherein n/(m+n)=1/100 to 100/100 provided that the molar ratio of (1):(2), (6) or (7) is m:n.
    Type: Application
    Filed: September 10, 2010
    Publication date: September 13, 2012
    Applicant: ADEKA CORPORATION
    Inventors: Masaru Nagai, Mitsuhiro Okada, Koichi Shigeno
  • Publication number: 20120217490
    Abstract: A semiconductive hole transport material containing polar substituent groups, the polar substituent groups substantially not affecting the electronic properties of the hole transport material and the hole transport material being soluble in a polar solvent.
    Type: Application
    Filed: April 30, 2012
    Publication date: August 30, 2012
    Applicants: CDT OXFORD LIMITED, CAMBRIDGE DISPLAY TECHNOLOGY LIMITED
    Inventors: Carl R. Towns, Caroline Towns, Mary J. McKiernan, Annette Steudel
  • Publication number: 20120211702
    Abstract: The present invention relates generally to substituted polyaniline polymer/copolymer compositions, suitable slats thereof and uses therefore. In one embodiment, the present invention relates to conductive substituted polyaniline polymer/copolymer compositions, suitable slats thereof and uses therefore. In still another embodiment, the present invention relates to self-protonated substituted polyaniline polymer/copolymer compositions, suitable slats thereof and uses therefore. In yet another embodiment, the present invention relates to self-protonated sulfonic acid- or boric acid-substituted polyaniline polymer/copolymer compositions, suitable slats thereof and uses therefore. In still another embodiment, the one or more various polyaniline polymer/copolymer compositions of the present invention are both biodegradable and conducting polymer compositions.
    Type: Application
    Filed: August 2, 2010
    Publication date: August 23, 2012
    Applicant: THE OHIO STATE UNIVERSITY
    Inventors: Arthur J. Epstein, Yong Min, Jen-Chieh Wu
  • Publication number: 20120205596
    Abstract: The present invention provides a macromolecular compound by which the short-circuit current density and the photoelectric conversion efficiency are enhanced when the macromolecular compound is used in an organic layer contained in a photovoltaic cell.
    Type: Application
    Filed: October 29, 2010
    Publication date: August 16, 2012
    Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Ken Yoshimura, Kenichiro Ohya
  • Publication number: 20120097899
    Abstract: The present invention describes novel indenofluorene derivatives which can preferably be employed as matrix materials for phosphorescent dopants or as electron-transport materials, in particular for use in the emission and/or charge-transport layer of electroluminescent devices. The invention furthermore relates to polymers which comprise these compounds as structural units and to a process for the preparation of the compounds according to the invention and to electronic devices which comprise same.
    Type: Application
    Filed: June 1, 2010
    Publication date: April 26, 2012
    Inventors: Amir Hossain Parham, Christof Pflumm, Teresa Mujica-Fernaud, Arne Buesing, Holger Heil
  • Publication number: 20120097935
    Abstract: The present invention relates to novel compounds of the formula (I) wherein R1 and R1? independently of each other are H or a substituent, halogen or SiR6R4R5; R2 and R2? may be the same or different and are selected from C1-C25alkyl, C3-C12-cycloalkyl, C2-C25alkenyl, C2-C25alkynyl, C4-C25aryl, C5-C25alkylaryl or C5-C25aralkyl, each of which is unsubstituted or substituted, and under conditions as defined in claim 1, R2 and/or R2? may also be halogen or hydrogen; X is a divalent linking group selected from formula (Ia) and formula (Ib); Y and Y? independently are selected from formula (Ic), formula (Id), formula (Ie), formula (If), formula (Ig); n and p independently range from 0 to 6; where further symbols are as defined in claim 1, and to corresponding oligomers and (co)polymers. The compounds according to the invention are useful as semiconductors and have excellent solubility in organic solvents and excellent film-forming properties.
    Type: Application
    Filed: May 21, 2010
    Publication date: April 26, 2012
    Applicant: BASF SE
    Inventors: Hans Jürg Kirner, Natalia Chebotareva, Olivier Frédéric Aebischer