Ether Or Thioether Compound Contains Three Or More -xh Groups Patents (Class 528/77)
  • Patent number: 7169844
    Abstract: An emulsion of resin having a function of oxidation inhibition obtained by subjecting an antioxidant (A) having two or more alcoholic hydroxy groups, a polyol compounds (B) as an optical ingredient, a compound (C) having a carboxy group and an active-hydrogen group, and an organic polyisocyanate (D) to urethanation reaction in an organic solvent, neutralizing the resultant resin solution with a neutralizing agent (E), and then dispersing the solution in water. A resin having the function of oxidation inhibition is obtained from the emulsion.
    Type: Grant
    Filed: January 21, 2003
    Date of Patent: January 30, 2007
    Assignee: Daicel Chemical Industries, Ltd.
    Inventor: Kiyotaka Inokami
  • Patent number: 7160976
    Abstract: Pressure-sensitive adhesive based on polyurethane, characterized in that the polyurethane is composed of the following starting materials which are reacted with one another in the stated proportions: a) at least one aliphatic or alicyclic diisocyanate having in each case an asymmetrical molecular structure, b) a combination of at least one polypropylene glycol diol and at least one polypropylene glycol triol, the ratio of the number of hydroxyl groups in the diol component to the number of hydroxyl groups in the triol component being between 0.7 and 9.0, preferably between 1.5 and 2.5, additionally the ratio of the number of isocyanate groups to the total number of hydroxyl groups being between 0.9 and 1.1, preferably between 0.95 and 1.
    Type: Grant
    Filed: April 1, 2004
    Date of Patent: January 9, 2007
    Assignee: tesa Aktiengesellschaft
    Inventors: Bernd Lühmann, Philippe Hesse, Sianty Sunarto, Uwe Schümann, Kirstin Weiland, Carsten Böhmer
  • Patent number: 7067607
    Abstract: A polyurethane resin which is the reaction product of at least one diisocyanate and a group of components having isocyanate reactive functional groups. The group of components includes a first group of one or more polyether polyols each having an average molecular weight in the range of 1000 to 10000 g/mol, a second group of one or more polyether polyols each having an average molecular weight in the range of 400 to 10000 g/mol and being hydrophilic and water-soluble, a third group of one or more polyols each having an average molecular weight equal to or less than 800 g/mol, at least one amine, and a reaction terminating agent. The ratio of the equivalent weights of the diisocyanate to the components having isocyanate reactive functional groups is selected such that essentially all of the isocyanate groups of the diisocyanate are present only as the reaction product with one of said isocyanate reactive functional groups.
    Type: Grant
    Filed: March 6, 2003
    Date of Patent: June 27, 2006
    Assignee: SICPA Holding S.A.
    Inventor: Denis Eugene
  • Patent number: 7045573
    Abstract: Isocyanate-functional polyurethane prepolymers and aqueous dispersions therefrom which are useful for the production of flat materials having excellent resistance to alcoholic solvents are described. The prepolymers are prepared by reacting: A) an isocyanate selected from the group consisting of i) an aliphatic and/or a cycloaliphatic isocyanate, ii) a mixture of an aromatic isocyanate and an aliphatic and/or a cycloaliphatic isocyanate, B) a di- or polyhydroxy compound having a number average molecular weight of from 700 to about 16,000, and C) optionally, a dihydroxy and/or polyhydroxyl compound having a number average molecular weight of less than 700, with the provisos that a) at least one of components A), B or C) has a functionality of more than 2 and b) if both component A) and component B) are difunctional, component C) cannot be a trihydroxy component of the formula: R—(OH)3 ?where R is a saturated straight chain or branched chain aliphatic group of from 2 to 8 carbon atoms.
    Type: Grant
    Filed: October 2, 2003
    Date of Patent: May 16, 2006
    Assignees: Bayer MaterialScience LLC, Bayer MaterialScience AG
    Inventors: Eduard Mayer, Thomas Muenzmay, Yuliya Berezkin, Poli C. Yu, Richard R. Roesler, Mary A. Crisci
  • Patent number: 7045650
    Abstract: A polyol composition having a number average molecular weight of from about 1,000 to about 3,000 Daltons is made up of (1) at least 60% by weight of a low monol polyoxypropylene polyol having a number average molecular weight of from about 2,000 to 12,000 Da and a degree of unsaturation less than or equal to 0.02 meq/g and (2) no more than 40% by weight of a polyol having a number average molecular weight of from about 400 to about 1,000 Da and a polydispersity index greater than 1.1. This polyol composition is reacted with a diisocyanate, a polyisocyanate, an isocyanate-terminated prepolymer or an isocyanate-terminated quasi-prepolymer to produce polyurethane elastomers having good physical and mechanical properties. Any of the known processes for producing polyurethane elastomers, including one-shot processes, may be used to produce elastomers in accordance with the present invention.
    Type: Grant
    Filed: September 2, 2004
    Date of Patent: May 16, 2006
    Assignee: Bayer Materialscience LLC
    Inventors: Bruce D. Lawrey, Kurt C. Frisch, Nigel Barksby
  • Patent number: 7015300
    Abstract: A multilayer golf ball formed of a core, a cover layer and an optional intermediate layer disposed between the core and cover, wherein at least one layer includes a composition including a diisocyanate, a polyol or amine-terminated compound, and a curing agent, wherein the curing agent includes a diol or secondary diamine.
    Type: Grant
    Filed: July 10, 2003
    Date of Patent: March 21, 2006
    Assignee: Acushnet Company
    Inventors: Murali Rajagopalan, Shenshen Wu
  • Patent number: 7005477
    Abstract: A one component moisture-curing polyurethane adhesive composition having a long pot life that does not cause its user to experience breathing difficulty is described. In one embodiment the adhesive is prepared from a mixture of a high molecular weight component selected from the group consisting of polyols, diamines, and mixtures thereof; an isocyanate; and a low molecular weight component selected from the group consisting of diols, diamines, and mixtures thereof.
    Type: Grant
    Filed: May 16, 2002
    Date of Patent: February 28, 2006
    Assignee: MCP Industries, Inc.
    Inventors: Thomas M. Garrett, Xian Xian Du
  • Patent number: 6989406
    Abstract: A process for preparing oil and petroleum-resistant cellular to solid (polyurea)polyurethanes (PURS) with improved physical properties in which a polyether polyol component having a number average molecular weight of from 1000 to 8000 and a polyester polyol component having a number average molecular weight of from 1000 to 6000 are reacted with a polyisocyanate and the (polyurea) polyurethanes produced by that process. The (polyurea)polyurethanes are particularly useful for personal safety equipment and in the construction of automobiles.
    Type: Grant
    Filed: June 2, 2000
    Date of Patent: January 24, 2006
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hans-Detlef Arntz, Klaus Brecht, Bernhard John, Peter Seifert, Michael Schneider
  • Patent number: 6924321
    Abstract: The present invention discloses a process for producing a polyurethane product with autocatalytic polyols. These autocatalytic polyols are based on an initiator that contains a tertiary amine. These autocatalytic polyols are reacted with a polyisocyanate in the presence of other additives and/or auxiliary agents known per se to produce polyurethane products.
    Type: Grant
    Filed: August 16, 2001
    Date of Patent: August 2, 2005
    Assignee: Dow Global Technologies Inc.
    Inventors: Francois Casati, Jean-Marie Louis Sonney
  • Patent number: 6884824
    Abstract: Process for preparing a polyurethane elastomer having an apparent overall density of more than 150 kg/m3 comprising reacting a polyisocyanate and an isocyanate-reactive composition, optionally in the presence of water, wherein the reaction is conducted at an isocyanate index of 85 to 120, the polyisocyanate comprising: a) 80-100% by weight of a diphenylmethane diisocyanate comprising at least 40% by weight of 4,4?-diphenylmethane diisocyanate and/or a derivative of said diphenylmethane diisocyanate which derivative is liquid at 25° C.
    Type: Grant
    Filed: January 3, 2003
    Date of Patent: April 26, 2005
    Assignee: Huntsman International LLC
    Inventors: Gerhard Jozef Bleys, Eric Huygens
  • Patent number: 6884904
    Abstract: An MDI/polypropylene polyether prepolymer composition consisting essentially of at least 80 wt % perfect prepolymers and less than 2 wt % free MDI monomer suitable for use in polyurethane adhesive compositions optionally also comprising a curative for isocyanate groups.
    Type: Grant
    Filed: April 12, 2001
    Date of Patent: April 26, 2005
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Andrea Karen Smith, Richard Joseph Goddard, Evelyn Jennifer Lin Paulsen
  • Patent number: 6858699
    Abstract: Polyurethane elastomers having a defined node density are produced from specific polyetherester polyols. These elastomers are particularly useful for the production of microcellular and solid polyurethane elastomer components.
    Type: Grant
    Filed: October 20, 2003
    Date of Patent: February 22, 2005
    Assignee: Bayer Aktiengesellschaft
    Inventors: Erhard Michels, Hartmut Nefzger, Stephan Schleiermacher
  • Patent number: 6855765
    Abstract: A two-component polyurethane sealant composition is described. The polyurethane sealant of the invention exhibits improved resistance to degradation by heat and hot water. The composition of the invention includes a novel hindered amine antioxidant.
    Type: Grant
    Filed: December 12, 2001
    Date of Patent: February 15, 2005
    Assignee: National University of Singapore
    Inventors: Yit Lin Chew, Suat Hong Goh, Xu Zhou
  • Patent number: 6838516
    Abstract: The present invention relates to a water dispersible polyisocyanate composition comprising (a) an aliphatic polyisocyanate or a mixture of aliphatic polyisocyanates or a mixture of aliphatic polyisocyanates with other polyisocyanates; and (b) a reaction product of component (a) with a component selected from the group consisting of: (ii) a polyether diol or triol or a mixture thereof wherein a weight ratio of ethylene oxide (EO) to propylene oxide (PO) of the polyether diol and triol is greater than about 60:40, and the polyether diol has a molecular weight of about 300 to 1600 g/mole, and the polyether triol has a molecular weight of about 450 to 2400 g/mole; and (ii) a mixture of polyether monol and polyether polyol, wherein the polyether polyol is selected from the group consisting of polyether diol, triol and a mixture thereof wherein a weight ratio of EO to PO of the polyether monol, diol and triol is greater than about 60:40, and the polyether diol and triol have the molecular weights as defined abo
    Type: Grant
    Filed: July 26, 2002
    Date of Patent: January 4, 2005
    Assignee: Great Eastern Resins Industrial Co., Ltd.
    Inventors: Shenghong A. Dai, Jui-Ming Chang, Tsai-Lung Chen, Will Yang
  • Patent number: 6830705
    Abstract: The invention relates to liquid stable MDI prepolymers and curative systems which are suitable for room temperature casting and which yield high performance low-shrinkage urethane elastomers upon room-temperature curing, the prepolymer and curative components, the elastomers themselves, and separately packaged prepolymer component and its complementary curative component provided as a single unit or kit.
    Type: Grant
    Filed: June 14, 2000
    Date of Patent: December 14, 2004
    Assignee: AZON USA Inc.
    Inventors: Gerard Scott Freeland, James E. Doyle
  • Patent number: 6824703
    Abstract: A polyol composition having a number average molecular weight of from about 1,000 to about 3,000 Daltons is made up of (1) at least 60% by weight of a low monol polyoxypropylene polyol having a number average molecular weight of from about 2,000 to 12,000 Da and a degree of unsaturation less than or equal to 0.02 meq/g and (2) no more than 40% by weight of a polyol having a number average molecular weight of from about 400 to about 1,000 Da and a polydispersity index greater than 1.1. This polyol composition is reacted with a diisocyanate, a polyisocyanate, an isocyanate-terminated prepolymer or an isocyanate-terminated quasi-prepolymer to produce polyurethane elastomers having good physical and mechanical properties. Any of the known processes for producing polyurethane elastomers, including one-shot processes, may be used to produce elastomers in accordance with the present invention.
    Type: Grant
    Filed: March 8, 2002
    Date of Patent: November 30, 2004
    Assignee: Bayer MaterialScience LLC
    Inventors: Bruce D. Lawrey, Kurt C. Frisch, Nigel Barksby
  • Patent number: 6818724
    Abstract: A golf ball comprising a center comprising a polybutadiene having a molecular weight of greater than 200,000 and a resilience index of at least about 40; and a cover layer comprising a polyurethane composition formed from a prepolymer having no greater than 7.5 percent by weight unreacted isocyanate groups.
    Type: Grant
    Filed: September 11, 2002
    Date of Patent: November 16, 2004
    Assignee: Acushnet Company
    Inventors: Shenshen Wu, Edmund A. Hebert, Laurent Bissonnette, David A. Bulpett, Murali Rajagopalan, Peter Voorheis, Mark N Wrigley
  • Patent number: 6815467
    Abstract: A method for producing a polyoxyalkylene polyol which comprises subjecting propylene oxide and ethylene oxide to ring-opening addition polymerization with an initiator in the presence of a catalyst, wherein the polyoxyalkylene polyol is a polyoxyalkylene polyol obtained by subjecting propylene oxide to ring-opening addition polymerization with an initiator in the presence of a double metal cyanide complex catalyst to form an oxypropylene block chain, subjecting ethylene oxide and propylene oxide to ring-opening addition polymerization randomly to form an oxyalkylene random chain, changing the catalyst and subjecting ethylene oxide to ring-opening addition polymerization in the presence of an alkali metal catalyst to form an oxyethylene block chain, and the polyoxyalkylene polyol is a polyoxyalkylene polyol having a hydroxyl value of from 5 to 56 mgKOH/g, a proportion of an initiator residue of at most 25 mass %, a proportion of the oxypropylene block chain of from 5 to 50 mass %, a total oxyethylene group c
    Type: Grant
    Filed: July 18, 2002
    Date of Patent: November 9, 2004
    Assignee: Asahi Glass Company, Limited
    Inventors: Yoshinori Toyota, Akio Horie, Hiroshi Wada, Kayoko Sugiyama, Etsuko Akagi
  • Patent number: 6806342
    Abstract: Process for preparing a polyurethane material having no glass transition temperature below 25 C, which process involves using a polyoxyethylene polyoxypropylene polyol having a high oxyethylene content and a polyisocyanate having a high 4,4′-diphenylmethane diisocyanate (4,4′-MDI) content, wherein the reaction is conducted at an isocyanate index of 80 to 140.
    Type: Grant
    Filed: January 30, 2003
    Date of Patent: October 19, 2004
    Assignee: Huntsman International LLC
    Inventors: Gerhard Jozef Bleys, Eric Huygens, Anja Vanhalle
  • Patent number: 6800715
    Abstract: A polyurethane-polymer composition suitable for preparing a lightweight tire support includes at least one isocyanate, at least one polyol, and at least one chain extender. A polyurethane-polymer composition can also include an additive such as a catalyst, a filler, a surfactant, a colorant, and a mold-release agent. A lightweight tire support can be prepared from a polyurethane-polymer composition by, for example, reaction injection molding. Such a tire support desirably has temperature stability and load-bearing capability.
    Type: Grant
    Filed: February 7, 2003
    Date of Patent: October 5, 2004
    Assignee: Dow Global Technologies Inc.
    Inventors: Alan K. Schrock, Ralph D. Priester, Jr., Wayne R. Willkom, Robert E. O'Neill, Martin C. Cornell, Christopher P. Christenson
  • Patent number: 6797799
    Abstract: The present invention provides NCO prepolymers comprising the reaction product of (1) an allophanate-modified diphenylmethane diisocyanate having an NCO group content of 12 to 32.5% by weight and comprising the reaction product of, (a) an aliphatic alcohol or an aromatic alcohol; and (b) diphenylmethane diisocyanate comprising: (i) from 10 to 60% by weight of 2,4′-diphenylmethane diisocyanate, (ii) less than 6% by weight of 2,2′-diphenylmethane diisocyanate, and (iii) the balance being 4,4′-diphenylmethane diisocyanate, wherein the sum of the percentages by weight of (1)(b)(i), (1)(b)(ii), and (1)(b)(iii) total 100% by weight of (1)(b), and (2) a polyether polyol having a molecular weight of 134 to 10,000, an OH number of 420 to 14, and a functionality of at least 1.8. The NCO prepolymers of the present invention find use in preparing elastomeric coatings, adhesives, sealants, and the like.
    Type: Grant
    Filed: April 2, 2003
    Date of Patent: September 28, 2004
    Assignee: Bayer Materialscience LLC
    Inventors: William E. Slack, Edward P. Squiller, P. Richard Hergenrother
  • Patent number: 6787628
    Abstract: A polymer comprising the addition reaction product of a polyisocyanate having a functionality of from 2 to 10 and a succinylpolyether having a C6-30-alk(en)yl group and at least one group which is capable of reacting with the polyisocyanate and where the number of recurring ethyleneoxy groups in the polyether is from 4 to 800.
    Type: Grant
    Filed: April 2, 2003
    Date of Patent: September 7, 2004
    Assignee: Avecia Limited
    Inventors: Dean Thetford, Stuart Barnett
  • Patent number: 6784274
    Abstract: Methods for reducing the electrode impedance of implantable biosensors by coating the surface of the biosensor with a uniform hydrogel which allows unimpeded water movement around the sensor are provided. The surface coatings are compositions which are biocompatible and are capable of water uptake of at least 120% of their weight, more preferably at least 200% of their weight. Upon the uptake of water, the hydrogels used in the present invention will also swell and provide a layer of water around the electrodes to which the hydrogels are attached. The hydrogels can be prepared from (a) a diisocyanate, (b) a hydrophilic polymer which is a hydrophilic diol, a hydrophilic diamine, or a combination thereof, and optionally, (c) a chain extender.
    Type: Grant
    Filed: August 6, 2002
    Date of Patent: August 31, 2004
    Assignee: Minimed Inc.
    Inventors: William Peter Van Antwerp, Christian C. Decker, John J. Mastrototoro
  • Patent number: 6770730
    Abstract: A compact veneer is based on a reaction mixture comprising a) isocyanate, b) as compounds which are reactive toward isocyanates, a mixture (b1) comprising: b11) from 15 to 90% by weight, preferably from 50 to 80% by weight, based on the weight of the mixture (b1), of at least one polyether polyalcohol having a molecular weight of from 400 to 6000, preferably from 1000 to 4000 and a mean functionality of from 1.5 to 3 and based on hydroxyl-containing initiator substances and propylene oxide and also, if desired, ethylene oxide, b12) from 0 to 20% by weight, preferably from 0 to 10% by weight, based on the weight of the mixture (b1), of at least one polyether polyalcohol having a molecular weight of from 400 to 6000, preferably from 400 to 4000, and a mean functionality of from 1.
    Type: Grant
    Filed: November 15, 1999
    Date of Patent: August 3, 2004
    Assignee: BASF Aktiengesellschaft
    Inventors: Peter Roche, Thomas Bartz, Georg Knoblauch
  • Patent number: 6770729
    Abstract: Embodiments of the invention provide polymer coated implantable medical devices having a bioactive material posited in or on at least a portion of the coating layer, wherein the coating layer provides for the controlled release of the bioactive material from the coating layer. Preferably, the medical device is an intravascular stent.
    Type: Grant
    Filed: September 30, 2002
    Date of Patent: August 3, 2004
    Assignee: Medtronic MiniMed, Inc.
    Inventor: William P. Van Antwerp
  • Patent number: 6767959
    Abstract: A filler containing adhesive is described that also in the presence of large amounts of conductive fillers such as low or non-oxidized carbon black shows good antenna impedance. Said adhesive is characterized by the presence of polycarbonate prepolymers, in particular prepolymers containing a group or formula I: wherein R represents linear or branched, saturated or unsaturated aliphatic radical, a saturated or unsaturated cycloaliphatic radical, an araliphatic radical, or an aromatic radical with 3 to 10 carbon atoms, and n=1 to 8, preverably 2 to 5.
    Type: Grant
    Filed: January 2, 2002
    Date of Patent: July 27, 2004
    Assignee: Sika AG, Vorm. Kaspar Winkler & Co.
    Inventors: Bernhard Bosshard, Michael Schlumpf
  • Patent number: 6767985
    Abstract: The invention relates to liquid stable MDI prepolymers and curative systems which are suitable for room temperature casting and which yield high performance low-shrinkage urethane elastomers upon room-temperature curing, the prepolymer and curative components, the elastomers themselves, and separately packaged prepolymer component and its complementary curative component provided as a single unit or kit.
    Type: Grant
    Filed: November 26, 2001
    Date of Patent: July 27, 2004
    Assignee: Azon USA Inc.
    Inventors: Gerard Scott Freeland, James E. Doyle
  • Patent number: 6765080
    Abstract: This invention relates to high performance RIM (reaction injection molded) poly(urethane)urea elastomers, and to a process for their production. These elastomers comprise the reaction product of an allophanate-modified diphenylmethane diisocyanate prepolymer having an NCO group content of about 5 to about 30%, with an isocyanate-reactive component comprising a high molecular weight amine-terminated polyether polyol, an aromatic diamine chain extender, and, optionally, a chain extender or crosslinker selected from the group consisting of aliphatic amine terminated polyether polyols and aliphatic hydroxyl terminated polyether polyols, optionally, in the presence of an internal mold release agent, a surfactant and a filler.
    Type: Grant
    Filed: June 6, 2002
    Date of Patent: July 20, 2004
    Assignee: Bayer Corporation
    Inventors: Michael S. Super, David D. Steppan, William E. Slack, Bruce H. Potts, Michael F. Hurley
  • Patent number: 6750311
    Abstract: Methods are provided for the determination of the concentration of biological levels of polyhydroxylated compounds, particularly glucose. The methods utilize an amplification system that is an analyte transducer immobilized in a polymeric matrix, where the system is implantable and biocompatible. Upon interrogation by an optical system, the amplification system produces a signal capable of detection external to the skin of the patient. Quantitation of the analyte of interest is achieved by measurement of the emitted signal.
    Type: Grant
    Filed: December 14, 1999
    Date of Patent: June 15, 2004
    Assignees: MiniMed Inc., The Regents of the University of California
    Inventors: William Peter Van Antwerp, John Joseph Mastrototaro, Stephen M. Lane, Joe H. Satcher, Jr., Christopher B. Darrow, Thomas A. Peyser, Jennifer Harder
  • Patent number: 6723836
    Abstract: To provide low odor polyoxyalkylene polyol, a process for producing the same, and a low odor urethane prepolymer and a low odor urethane composition using the same as a raw material. The low odor polyoxyalkylene polyol comprising polyoxyalkylene polyol with amine added thereto, the amine having at least one amino group represented by the following formula (1): is provided, wherein R1, R2 and R3 independently represent hydrogen atom or an organic group which may contain a hetero atom in which an atom bonded to nitrogen atom is carbon atom.
    Type: Grant
    Filed: April 20, 2000
    Date of Patent: April 20, 2004
    Assignee: The Yokohama Rubber Co., Ltd.
    Inventors: Kiminori Araki, Kazunori Ishikawa
  • Patent number: 6720401
    Abstract: 1. A coating composition to form a coating layer or film of a hydrophilic polyurethane resin having a moisture permeability and being substantially non-porous, which comprises, as an essential component, an isocyanate group-containing prepolymer obtainable by reacting diphenylmethane diisocyanate with the following polyoxyalkylene polyol: A polyoxyalkylene polyol which contains at least 60 wt % of a polyoxyethylene polyol having at least three hydroxyl groups and having an oxyethylene group-content of at least 10 wt %, satisfies 3.0<n<3.5, where n is the average number of hydroxyl groups, and has an average oxyethylene group-content of from 60 to 90 wt %.
    Type: Grant
    Filed: June 6, 2001
    Date of Patent: April 13, 2004
    Assignee: Asahi Glass Company, Limited
    Inventors: Masanori Toyofuku, Satoru Mori, Josho Kashiwame, Kaoru Oguro
  • Patent number: 6709539
    Abstract: The present invention is a polyurethane prepolymer comprising the reaction product of: A) a polyisocyanate; B) one or more compounds or polymers having isocyanate-reactive moieties. C) a dispersion triol containing from about 10 to about 60 percent by weight based on the dispersion of particles of an organic polymer which is nonreactive with the polyols and polyisocyanates having a particle size of from about 5 to about 50 microns; wherein the prepolymer has a free isocyanate content of from about 0.8 to about 2.2 percent, the weight ratio of diol to triol and dispersion triol is from about 0.8 to about 1.2. In another embodiment the invention is a one-part adhesive composition comprising the polyurethane prepolymer of the invention and a catalyst capable of catalyzing the reaction of isocyanate moieties with water.
    Type: Grant
    Filed: August 7, 2001
    Date of Patent: March 23, 2004
    Assignee: Dow Global Technologies Inc.
    Inventor: Lirong Zhou
  • Publication number: 20040028742
    Abstract: Thickeners corresponding to the general formula (I):
    Type: Application
    Filed: May 28, 2003
    Publication date: February 12, 2004
    Inventors: Joaquin Bigorra Llosas, Cristina Amela Conesa, Maria Escoda, Rafael Pi Subirana
  • Patent number: 6646093
    Abstract: Water-soluble polyurethane according to the present invention is obtained from polyalkylene glycols, diisocyanates, and comb-shaped hydrophobic diols represented by the following general formula (3): wherein each of R1, R2 and R3 is a hydrocarbon group; each of Y and Y′ is hydrogen, a methyl group or a CH2Cl group; each of Z and Z′ is oxygen, sulfur or a CH2 group; n is an integer of 0 to 15 when Z is oxygen and is 0 when Z is sulfur or a CH2 group; n′ is an integer of 0 to 15 when Z′ is oxygen and is 0 when Z′ is sulfur or a CH2 group. The water-soluble polyurethane is used as, for example, an extruding auxiliary for cement materials, a mortar thickening agent, an underwater concrete thickening agent, a ceramics forming binder and a moisturizer for hair cosmetics, all of which are characterized by excellent water retention and high shape retention.
    Type: Grant
    Filed: December 12, 2000
    Date of Patent: November 11, 2003
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Manabu Tsuruta, Masahiko Mitsuzuka, Yunzhi Wu
  • Publication number: 20030166770
    Abstract: Branched polyurethanes which are preparable by reacting
    Type: Application
    Filed: February 20, 2003
    Publication date: September 4, 2003
    Inventors: Sandra Bauer, Dirk Edelmann, Eberhard Esselborn, Markus Hoschke, Gunthern Link, Stefan Silber
  • Patent number: 6610811
    Abstract: Polyurethanes having improved tear resistance which are the reaction product of the following components: A) a polyol component containing dimer diol and/or trimer triol and/or an OH-terminated polyester produced from polycarboxylic acids, preferably dimer fatty acid and/or trimer fatty acid, and diols and B) an isocyanate component containing prepolymers obtained by reacting polyfunctional isocyanates with dimer diol and/or trimer triol and/or an OH-terminated polyester produced from polycarboxylic acids, preferably dimer fatty acid and/or trimer fatty acid, and diols; and processes for their manufacture.
    Type: Grant
    Filed: August 24, 1999
    Date of Patent: August 26, 2003
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Alfred Westfechtel, Roland Gruetzmacher, Rainer Hoefer
  • Publication number: 20030149218
    Abstract: Fluorochemical urethane compositions comprising one or more fluorochemical urethane compounds, and one or more auxiliary compounds for treatment of a fibrous substrate are described. The fluorochemical compositions are capable of improving one or more of the oil- and/or water repellency, stain- and/or soil repellency and stain and/or soil release properties, with improved durability, of the fibrous substrate treated with the fluorochemical composition.
    Type: Application
    Filed: December 17, 2001
    Publication date: August 7, 2003
    Applicant: 3M Innovative Properties Company
    Inventors: Linda G. Cote', Mitchell T. Johnson, Larry A. Lien, Richard S. Buckanin
  • Patent number: 6590057
    Abstract: The invention provides polyurethane elastomers (PU elastomers), a process for their production using special catalyst mixtures and their use in particular for the manufacture of shoe soles.
    Type: Grant
    Filed: August 27, 2002
    Date of Patent: July 8, 2003
    Assignee: Bayer Aktiengesellschaft
    Inventors: Klaus Brecht, Wolfgang Grimm, Stephan Schleiermacher, Marc Schütze
  • Patent number: 6576736
    Abstract: Products of the reaction between I) the reaction product of reactants comprising A) a linking agent of formula I R4(Y)3  (I)  wherein each Y group is a halogen atom or one Y group is a halogen atom and two Y groups represent an oxygen atom, which is attached to two adjacent carbon atoms in the R4 group to form an epoxy group, and R4 is an alkanetriyl group containing from 3 to 10 carbon atoms; and B) a compound formula II R3(EO)n(PO)m(BO)pX  (II)  wherein R3 is a substituted or unsubstituted, saturated or unsaturated, aliphatic or araliphatic oxy or thio group having from 1 to 36 carbon atoms or a secondary amino group having from 2 to 36 carbon atoms; n is a number of from 0 to 50; m is a number of from 0 to 50; p is a number of from 0 to 50; and X is hydrogen, or X can be a mercapto group or an amino group in place of a terminal —OH group, provided that when X is mercapto or amino; the sum of n, m, and p must be at least 1; and the mole ratio of A:B is from about 0
    Type: Grant
    Filed: March 6, 2002
    Date of Patent: June 10, 2003
    Assignee: Cognis Corporation
    Inventors: Michael S. Wiggins, Ronald W. Broadbent, Ramesh L. Narayan, Ayaz Khan
  • Patent number: 6569981
    Abstract: This invention relates to crystallizing polyether polyols which can be produced firstly by the reaction of propylene oxide and polyhydroxy compounds in the presence of an alkoxy compound which contains zinc and/or aluminium atoms to form a crystallizing polyether polyol with an average molecular weight Mn from 500 to 5000, followed by the further reaction of the crystallizing polyether polyol which is thus obtained with 10 to 90% by weight, with respect to the amount of crystallizing polyol, of an epoxide in the presence of a catalyst which does not polymerize propylene oxide stereospecifically, to form a crystallizing polyether polyol with an average molecular weight Mn from 1000 to 20,000. The invention further relates to a method for the production thereof and to the use thereof for the production of polyurethane materials, particularly polyurethane foams, polyurethane elastomers and polyurethane coatings.
    Type: Grant
    Filed: October 25, 2001
    Date of Patent: May 27, 2003
    Assignee: Bayer Aktiengesellschaft
    Inventors: Walter Schäfer, Jörg Hofmann, Pramod Gupta, Pieter Ooms
  • Patent number: 6548616
    Abstract: A polyurethane-polymer composition suitable for preparing a lightweight tire support includes at least one isocyanate, at least one polyol, and at least one chain extender. A polyurethane-polymer composition can also include an additive such as a catalyst, a filler, a surfactant, a colorant, and a mold-release agent. A lightweight tire support can be prepared from a polyurethane-polymer composition by, for example, reaction injection molding. Such a tire support desirably has temperature stability and load-bearing capability.
    Type: Grant
    Filed: December 13, 2000
    Date of Patent: April 15, 2003
    Assignee: Dow Global Technologies Inc.
    Inventors: Alan K. Schrock, Ralph D. Priester, Jr., Wayne R. Willkom, Robert E. O'Neill, Martin C. Cornell, Christopher P. Christenson
  • Publication number: 20030069383
    Abstract: Methods for reducing the electrode impedance of implantable biosensors by coating the surface of the biosensor with a uniform hydrogel which allows unimpeded water movement around the sensor are provided. The surface coatings are compositions which are biocompatible and are capable of water uptake of at least 120% of their weight, more preferably at least 200% of their weight. Upon the uptake of water, the hydrogels used in the present invention will also swell and provide a layer of water around the electrodes to which the hydrogels are attached. The hydrogels can be prepared from (a) a diisocyanate, (b) a hydrophilic polymer which is a hydrophilic diol, a hydrophilic diamine, or a combination thereof, and optionally, (c) a chain extender.
    Type: Application
    Filed: August 6, 2002
    Publication date: April 10, 2003
    Inventors: William Peter Van Antwerp, Christian C. Decker, John J. Mastrototaro
  • Patent number: 6545118
    Abstract: A series of polymeric compositions, methods of making the compositions and uses of the compositions are described. An exemplary composition is made by copolymerization of a trifunctional amine or hydroxy compound, a monofunctional amine or hydroxy compound and a polyisocyanate compound.
    Type: Grant
    Filed: November 8, 2001
    Date of Patent: April 8, 2003
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Jeffry J. Fedderly, John D. Lee, Gilbert F. Lee, Bruce Hartmann, Karel Dusek, Jan Somvarsky
  • Patent number: 6531566
    Abstract: A polyoxyalkylene polyol or monool (I) of the general formula (1) below, in which not less than 40% of the terminally located hydroxyl-containing groups, namely —AO—H groups, are primary hydroxyl-containing groups of the general formula (2) below, or; a method of producing ring-opening polymerization products, by subjecting a heterocyclic compound to ring-opening addition polymerization with an active hydrogen-containing compound, using as a catalyst tris(pentafluorophenyl)borane, tris(pentafluorophenyl)aluminum, etc.
    Type: Grant
    Filed: March 7, 2001
    Date of Patent: March 11, 2003
    Assignee: Sanyo Chemical Industries, Ltd.
    Inventor: Munekazu Satake
  • Patent number: 6521676
    Abstract: Safety clothing is produced by molding polyether-based plastic-forming compositions. Particularly preferred articles of safety clothing produced by this process are safety shoe soles.
    Type: Grant
    Filed: May 17, 1999
    Date of Patent: February 18, 2003
    Assignee: Bayer Aktiengesellschaft
    Inventors: Klaus Brecht, Hans-Detlef Arntz, Bernhard John
  • Patent number: 6515125
    Abstract: This invention relates to storage-stable, liquid, partially trimerized polyisocyanates having an NCO group content of 24 to 40% by weight, and comprising 20 to 88% by weight of toluene diisocyanate and 12 to 80% by weight of a polyisocyanate of the diphenylmethane series. The present invention also relates to a process for the preparation of the storage-stable, liquid, partially trimerized polyisocyanates; to storage-stable, liquid urethane prepolymers of these partially trimerized polyisocyanates; and to a process for the production of these storage-stable, liquid, urethane prepolymers.
    Type: Grant
    Filed: March 9, 2001
    Date of Patent: February 4, 2003
    Assignee: Bayer Corporation
    Inventors: William E. Slack, Hersel T. Kemp, II, Kenneth P. Yonek
  • Patent number: 6495652
    Abstract: Prepolymers which contain isocyanate groups, have an NCO content of at least 30.0% by weight and can be prepared by reacting an isocyanate mixture consisting predominantly of diphenylmethane diisocyanates and polyphenylpolymethylene polyisocyanates and having a proportion of two-ring isomers of not more than 74% by weight with at least 4-functional polyols or a mixture of polyols having a mean functionality of at least 4, where the polyols or polyol mixtures have a hydroxyl number of from 200 to 1650 mg KOH/g and a number average molecular weight of less than 1100 g/mol.
    Type: Grant
    Filed: October 9, 2000
    Date of Patent: December 17, 2002
    Assignee: BASF Aktiengesellschaft
    Inventors: Michael Reichelt, Udo Rotermund, Renate Hempel, Peter Falke, Peter von Malotki, Holger Seifert
  • Patent number: 6462162
    Abstract: Methods for reducing the electrode impedance of implantable biosensors by coating the surface of the biosensor with a uniform hydrogel which allows unimpeded water movement around the sensor are provided. The surface coatings are compositions which are biocompatible and are capable of water uptake of at least 120% of their weight, more preferably at least 200% of their weight. Upon the uptake of water, the hydrogels used in the present invention will also swell and provide a layer of water around the electrodes to which the hydrogels are attached. The hydrogels can be prepared from (a) a diisocyanate, (b) a hydrophilic polymer which is a hydrophilic diol, a hydrophilic diamine, or a combination thereof, and optionally, (c) a chain extender.
    Type: Grant
    Filed: July 28, 1998
    Date of Patent: October 8, 2002
    Assignee: MiniMed Inc.
    Inventors: William Peter Van Antwerp, Christian C. Decker, John J. Mastrototoro
  • Patent number: 6448364
    Abstract: This invention relates to a process for the production of a polyurethane elastomer by reacting a reaction mixture comprising (A) an isocyanate-reactive component having a molecular weight of 400 to 12,000, a functionality of about 2 to about 8 and being capped with 13 to 21% by weight of ethylene oxide, wherein the isocyanate-reactive groups are hydroxyl groups, amine groups or mixtures thereof; (B) an isocyanate-reactive component comprising (1) an isocyanate-reactive component containing at least two hydroxyl groups and having a molecular weight of from 62 to 399, and (2) an isocyanate-reactive component selected from the group consisting of (a) an isocyanate-reactive group containing tertiary amine polyether corresponding to a specific formula, (b) at least one organic amine compound containing at least two amine groups which are reactive with isocyanate groups; (C) potassium halide; (D) an internal mold release agent; (E) at least one catalyst, and (F) a polyisocyanate component.
    Type: Grant
    Filed: March 16, 2001
    Date of Patent: September 10, 2002
    Assignee: Bayer Corporation
    Inventors: Jan L. R. Clatty, Michael T. Wellman, Stephen J. Harasin
  • Patent number: 6444777
    Abstract: Compact and preferably cellular polyurethane elastomers based on polyisocyanate mixtures containing 3,3′-dimethylbiphenyl 4,4′-diisocyanate are produced by reacting a) relatively high molecular weight polyhydroxyl compounds and, if desired, b) low molecular weight hydroxyl-containing chain extenders and/or crosslinkers with c) 3,3′-dimethylbiphenyl 4,4′-diisocyanate and at least one additional aromatic diisocyanate selected from the group consisting of tolylene diisocyanate, diphenylmethane diisocyanate, 1,2-diphenylethane diisocyanate and phenylene diisocyanate, and/or at least one aliphatic diisocyanate having from 4 to 12 carbon atoms and/or at least one cycloaliphatic diisocyanate having from 6 to 18 carbon atoms, where the formative components (a), (c) and, if used, (b) are advantageously reacted by the prepolymer method, in the presence or absence of d) catalysts, e) blowing agents and f) additives.
    Type: Grant
    Filed: August 24, 1998
    Date of Patent: September 3, 2002
    Assignee: BASF Aktiengesellschaft
    Inventors: Manfred Genz, Gerhard Hellmann, Walter Haselhorst, Torsten Jeschke, Ute Nichau, Heinz Bollmann, Michael Strauss, Wolfgang Scholz, Hartmut Peuker, Rüdiger Voelkel