From Heavy Metal Or Aluminum Reactant Having At Least One Hydrogen-to-heavy Metal Or -aluminum Bond Or At Least One Carbon-to-heavy Metal Or -aluminum Bond Patents (Class 528/9)
  • Publication number: 20100155649
    Abstract: Molecule-based magnetic polymers with high Curie temperature and methods of preparing are provided. In particular, magnetic polymers having repeating units of an electron-donor metallocene-containing monomer covalently bonded to an electron-acceptor monomer having a plurality of unpaired electrons are disclosed. Intrinsically homogeneous magnetic fluids (liquid magnets) and methods of preparing are also provided.
    Type: Application
    Filed: March 4, 2010
    Publication date: June 24, 2010
    Applicant: THE UNIVERSITY OF AKRON
    Inventors: Chang Dae Han, Wenyi Huang
  • Publication number: 20100148385
    Abstract: A first electrophoretic medium comprises an electrically charged particle suspended in a suspending fluid, the particle having a polymeric shell having repeating units derived from at least one monomer the homopolymer of which is incompatible with the suspending fluid. A second, similar electrophoretic medium comprises a suspending fluid, and first and second types of electrically charged particle suspended in the suspending fluid, the two types of particle having differing optical characteristics but both having polymeric shells. The polymeric shells are arranged such that homoaggregation of the two types of particles is thermodynamically favored over heteroaggregation.
    Type: Application
    Filed: February 25, 2010
    Publication date: June 17, 2010
    Applicant: E INK CORPORATION
    Inventors: Suzanne Balko, Alberto Goenaga, Peter J. Valianatos, Charles H. Honeyman, Elizabeth M. Gates, Matthew A. King
  • Patent number: 7736757
    Abstract: A polymer light emitting material, wherein the material has a light emitting mechanism based on transition from an excited triplet state to a ground state or transition through an excited triplet state to a ground state of an electron energy level, and the material comprises a nonionic light emitting part which constitutes a part of the polymer or is bound to the polymer. The polymer light emitting material exhibits high light emission efficiency above 5%, which is the limit of external quantum efficiency of fluorescence and can be designed so as to have a large area and hence are suitable for mass production of organic light emitting devices.
    Type: Grant
    Filed: February 6, 2008
    Date of Patent: June 15, 2010
    Assignee: Showa Denko K.K.
    Inventors: Masataka Takeuchi, Shuichi Naijo, Naoko Ito, Koro Shirane, Takashi Igarashi, Yoshiaki Takahashi, Motoaki Kamachi
  • Publication number: 20100133992
    Abstract: Provided are compounds containing a phosphorescence unit, an emitting polymer, and an organic light emitting device (OLED) containing an organic layer including the emitting polymer. The OLED is useful in portable electronic equipment where low power consumption and low driving voltage are desirable.
    Type: Application
    Filed: May 5, 2009
    Publication date: June 3, 2010
    Applicant: SAMSUNG ELECTRONICS CO., LTD.
    Inventors: Hye-yeon YANG, Jhun-mo SON, Won-jae JOO
  • Publication number: 20100136769
    Abstract: Germanium-based polymers are described. In one embodiment, a germanium-based polymer includes a structure given by the formula: [GeR]n, wherein n is a non-negative integer that is at least one, and R is selected from a wide variety of groups, such as alkyl groups, alkenyl groups, alkynyl groups, aryl groups, iminyl groups, and so forth. Also described are methods of forming germanium-based polymers, methods of forming nanoparticles from germanium-based polymers, methods of forming nanostructured materials from germanium-based polymers, nanoparticles formed from germanium-based polymers, nanostructured materials formed from germanium-based polymers, and devices formed from germanium-based polymers.
    Type: Application
    Filed: December 21, 2006
    Publication date: June 3, 2010
    Inventors: MAJID KESHAVARZ, Guojun Liu
  • Patent number: 7718087
    Abstract: The present invention provides compositions comprising at least one novel polymeric organic iridium compound which comprises at least one cyclometallated ligand and at least one ketopyrrole ligand. The polymeric organic iridium compositions of the present invention are referred to as Type (2) organic iridium compositions and are constituted such that at least one ligand of the novel organic iridium compound has a number average molecular weight of 2,000 grams per mole or greater (as measured by gel permeation chromatography). Type (2) organic iridium compositions are referred to herein as comprising “polymeric organic iridium complexes”. The novel organic iridium compositions are useful in optoelectronic electronic devices such as OLED devices and photovoltaic devices. In one aspect, the invention provides novel organic iridium compositions useful in the preparation of OLED devices exhibiting enhanced color properties and light output efficiencies.
    Type: Grant
    Filed: August 14, 2006
    Date of Patent: May 18, 2010
    Assignee: General Electric Company
    Inventors: Kelly Scott Chichak, James Anthony Cella, Kyle Erik Litz, Joseph John Shiang, Qing Ye
  • Patent number: 7718277
    Abstract: The present invention provides electronic devices comprising novel polymeric organic iridium compositions which provide for enhanced device performance. The polymeric organic iridium compositions employed comprise a polymeric organic iridium compound comprising at least one cyclometallated ligand and at least one ketopyrrole ligand. The polymeric organic iridium compositions employed are referred to as Type (2) organic iridium compositions and are constituted such that at least one ligand of the polymeric organic iridium compound has a number average molecular weight of 2,000 grams per mole or greater (as measured by gel permeation chromatography). Type (2) organic iridium compositions are referred to herein as comprising “polymeric organic iridium complexes”. In one aspect, the present invention provides optoelectronic devices, such as OLED devices and photovoltaic devices. In another aspect, the invention provides OLED devices exhibiting enhanced color properties and light output efficiencies.
    Type: Grant
    Filed: August 16, 2006
    Date of Patent: May 18, 2010
    Assignee: General Electric Company
    Inventors: Kelly Scott Chichak, James Anthony Cella, Kyle Erik Litz, Joseph John Shiang, Qing Ye
  • Publication number: 20100113639
    Abstract: The present invention relates to initiators of the general formula {[M(L)a]Xb}n, wherein said initiators preferably have (SbF6?) as a counterion and are obtainable by a complexing reaction of a corresponding metal-SbF6 salt with a corresponding ligand (L). The present invention further relates to preparations and epoxy resin systems that contain such initiators and, in particular, are non-thermally and/or thermally curable.
    Type: Application
    Filed: October 18, 2007
    Publication date: May 6, 2010
    Inventors: Manfred Döring, Ulrich Arnold, Marcel Roth, Emilie Barriau, Ulrike Schmidt-Freytag, Volker Alstädt, Felipe Wolff Fabris, Jan Sandler
  • Patent number: 7705528
    Abstract: A halogenated aromatic monomer-metal complex useful for preparing a polymer for electronic devices such as a light-emitting diode (LED) device is described. The aromatic monomer-metal complex is designed to include a linking group that disrupts conjugation, thereby advantageously reducing or preventing electron delocalization between the aromatic monomer fragment and the metal complex fragment. Disruption of conjugation is often desirable to preserve the phosphorescent emission properties of the metal complex in a polymer formed from the aromatic monomer-metal complex. The resultant conjugated electroluminescent polymer has precisely controlled metal complexation and electronic properties that are substantially or completely independent of those of the polymer backbone.
    Type: Grant
    Filed: July 16, 2004
    Date of Patent: April 27, 2010
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Wanglin Yu, James J. O'Brien
  • Patent number: 7691493
    Abstract: A main chain-type or side chain-type polymeric compound having a structure wherein at least one metal complex segment having a plurality ligands is introduced into a main chain or a side chain is provided. In the case where the polymeric compound is the main chain-type polymeric compound, the metal complex segment has at least one ligand constituting a polymer main chain of the polymeric compound and having a carbon atom and oxygen atom bonded to a metal atom. On the other hand, in the case where the polymeric compound is the side chain-type polymeric compound, a polymer main chain thereof has a conjugated structure, preferably a conjugated double bond. A ligand for the polymeric compound includes a chain or cyclic ligand, of which a bidentate ligand having an organic cyclic structure is preferred, and the ligand has at least one carbon atom or oxygen atom and is bonded to a center metal atom, preferably iridium, via the carbon atom or oxygen atom.
    Type: Grant
    Filed: May 9, 2005
    Date of Patent: April 6, 2010
    Assignee: Canon Kabushiki Kaisha
    Inventors: Jun Kamatani, Shinjiro Okada, Akira Tsuboyama, Takao Takiguchi, Satoshi Igawa
  • Publication number: 20100069598
    Abstract: Cyclic esters are polymerized in the presence of a catalytic amount of a Group 4 transition metal hydride. The method is capable of producing high molecular weight polyesters with low polydispersities. These high molecular weight polyesters exhibit improved mechanical properties and are useful in a variety of product applications.
    Type: Application
    Filed: November 23, 2009
    Publication date: March 18, 2010
    Inventor: Alexandru Dragos Asandei
  • Publication number: 20100041851
    Abstract: Heteroelement siloxane polymers are described. The heteroelement siloxane polymers can have linear structure, cyclic structure, branched structure, and three-dimensional network structure and combinations thereof. The heterosiloxane polymers can be cured using curing chemistry derived from thermoset organosilicon polymers, and gels, coatings, plaques, parts and other useful articles can be prepared.
    Type: Application
    Filed: February 4, 2008
    Publication date: February 18, 2010
    Applicant: DOW CORNING CORPORATION
    Inventors: Dimitris Elias Katsoulis, Mark Jon Loboda, Elizabeth Mc Quiston, Luisel Rodriguez
  • Publication number: 20100028576
    Abstract: Disclosed is a process for producing a polyester composition which can be obtained by polycondensation of a dicarboxylic acid or ester-forming derivative thereof and a diol or ester-forming derivative thereof in presence of a polycondensation catalyst, in which a polyester having a good color tone can be obtained by adding a specific phosphorus compound after a polycondensation catalyst is added and pressure reduction in polymerization reactor is started and before the polycondensation of the polyester is substantially completed, and at a time in which the polyester reaches 75% or more of the intrinsic viscosity to be finally reached in said polymerization reactor.
    Type: Application
    Filed: October 10, 2007
    Publication date: February 4, 2010
    Applicant: TORAY INDUSTRIES, INC.
    Inventors: Gen Hayashi, Kunihiro Morimoto, Tomio Kawaji, Masatoshi Aoyama
  • Publication number: 20100019669
    Abstract: Disclosed is a metal complex represented by the following formula (1). In the formula, M represents a metal atom; R1-R8 respectively represent a hydrogen atom, a halogen atom or a monovalent group; or alternatively R3 and R4, or R5 and R6 may combine together to form a ring.
    Type: Application
    Filed: December 27, 2007
    Publication date: January 28, 2010
    Inventors: Nobuhiko Akino, Rei Okamura
  • Patent number: 7649069
    Abstract: Free radical living polymerization attached nanocluster (metal oxide, e.g., gamma-Fe2O3 or FeO nanocluster or quantum dot (e.g., CdSe) nanocluster, are used for polymerization of polymer or copolymer to provide nanocomposite polymers or copolymer arms around nanoclusters.
    Type: Grant
    Filed: May 19, 2006
    Date of Patent: January 19, 2010
    Assignee: Cornell Research Foundation, Inc.
    Inventors: Dotsevi Y. Sogah, Sarav B. Jhaveri
  • Patent number: 7635527
    Abstract: A polymer light emitting material, wherein the material has a light emitting mechanism based on transition from an excited triplet state to a ground state or transition through an excited triplet state to a ground state of an electron energy level, and the material comprises a nonionic light emitting part which constitutes a part of the polymer or is bound to the polymer. The polymer light emitting material exhibits high light emission efficiency above 5%, which is the limit of external quantum efficiency of fluorescence and can be designed so as to have a large area and hence are suitable for mass production of organic light emitting devices.
    Type: Grant
    Filed: February 6, 2008
    Date of Patent: December 22, 2009
    Assignee: Showa Denko K.K.
    Inventors: Masataka Takeuchi, Shuichi Naijo, Naoko Ito, Koro Shirane, Takeshi Igarashi, Yoshiaki Takahashi, Motoaki Kamachi
  • Publication number: 20090264611
    Abstract: Polybutylene terephthalate has an intrinsic viscosity of 0.7 to 1.0 dL/g and an end carboxyl group concentration of 0.1 to 18 ?eq/g, which is produced in a presence of a catalyst comprising a titanium compound and a metal compound containing a metal of Group 2A of the Periodic Table. In the preferable embodiment of the present invention, the polybutylene terephthalate has a crystallization temperature of 170 to 195° C. as measured at a temperature drop rate of 20° C./min using a differential scanning calorimeter, an end vinyl group concentration of not more than 10 ?eq/g, and not more than 10% of a solution haze of a solution prepared by dissolving 2.7 g of said polybutylene terephthalate in 20 mL of a mixed solvent containing phenol and tetrachloroethane at a weight ratio of 3:2.
    Type: Application
    Filed: March 29, 2005
    Publication date: October 22, 2009
    Inventors: Toshiyuki Hamano, Masanori Yamamoto, Shinichiro Matsuzono, Kenji Noda
  • Publication number: 20090263656
    Abstract: The invention disclosed herein provides an organic-inorganic hybrid structure having nanoparticles attached to the surface thereof, wherein the structure comprises a self-assembled structure of a coordination polymer, which includes a metal-organic ligand complex, as well as a preparation method thereof. According to the invention, through the use of the self-assembly phenomenon of coordination polymer and the use of nanoparticles having a surface component, which is the same as or similar to that of the surface of the coordination polymer, an organic-inorganic hybrid structure, which has nanoparticles attached to the surface of a self-assembled structure of coordination polymer, can be prepared in a relatively simple process without needing several steps.
    Type: Application
    Filed: October 10, 2007
    Publication date: October 22, 2009
    Inventors: Byung-Joon Chae, Sung-Ho Yoon
  • Publication number: 20090253875
    Abstract: A rare earth metal complex represented by the formula (1): in which A represents a Group 14 element of the periodic table, Cp represents a group having a substituted or unsubstituted cyclopentadienyl anion moiety, Ln represents a Group 3 metal atom or a lanthanoid metal atom, R1 to R6 are the same or different, and represent a hydrogen atom, a halogen atom, an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, an aralkyl group having 7 to 20 carbon atoms, a silyl group substituted with a hydrocarbon group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, R7 represents an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, or an aralkyl group having 7 to 20 carbon atoms, Xs represent a monoanionic ligand, Ys represent a neutral ligand, m represents an integer of 1 to 3, and n represents an integer of 0 to 3. The rare earth metal complex is useful as, for example, a catalyst for polymerization reaction of olefins.
    Type: Application
    Filed: July 5, 2007
    Publication date: October 8, 2009
    Inventors: Taichi Senda, Hidenori Hanaoka
  • Publication number: 20090233017
    Abstract: The present invention relates to an inkjet recording element having outstanding dye keeping properties in time. Said recording element comprises at least one molecular imprinted polymer having sites of selective recognition of dye molecules corresponding to the dye molecules used in inks for inkjet printing.
    Type: Application
    Filed: September 2, 2005
    Publication date: September 17, 2009
    Applicant: EASTMAN KODAK COMPANY
    Inventors: Gerard A. Friour, Olivier J. Poncelet, Karsten O. Haupt, Laurence G. Poul
  • Publication number: 20090221762
    Abstract: The invention concerns compounds, oligomers, and polymers that contain: (I), (II), (III), or (IV) groups; where “-” indicates points of attachment.
    Type: Application
    Filed: January 10, 2007
    Publication date: September 3, 2009
    Applicant: THE TRUSSTEES OF THE UNIVERSITY OF PENNSYLVANIA
    Inventors: Michael J. Therien, Kimihiro Susumu
  • Patent number: 7582363
    Abstract: The present invention provides an organic polymer light-emitting element material having a gold complex structure as a part of the side chain or crosslinking group as represented by formulae (5) and (8) and an organic polymer light-emitting element comprising layer(s) comprising the organic polymer light-emitting element material. The present invention provides a polymer-based phosphorescent material useful for a multicolor or white light-emitting organic EL device having high luminous efficiency and capable of large-area formation and mass production.
    Type: Grant
    Filed: April 28, 2004
    Date of Patent: September 1, 2009
    Assignee: Showa Denko K.K.
    Inventors: Yoshiaki Takahashi, Isamu Taguchi, Koro Shirane
  • Publication number: 20090186960
    Abstract: The invention relates to a polymerizable composition which is characterized in that it contains at least one filler that is surface-functionalized with groups of formula (I), wherein groups of formula (I) (A)a-Z-Y—R2—SiR13?m—(O—)m ??(I), are bonded to the filler via at least one oxygen atom that is bound to the silicon atom of the group of formula (I). The invention also relates to a process for the preparation of the composition according to the invention and its use in particular as a dental material.
    Type: Application
    Filed: November 21, 2008
    Publication date: July 23, 2009
    Applicant: IVOCLAR VIVADENT AG
    Inventors: Norbert MOSZNER, Jorg ANGERMANN, Simone KLAPDOHR
  • Publication number: 20090165846
    Abstract: The present invention relates to light emitting compounds, especially to triplett emitters suitable for electrooptical applications. Compounds according to the invention are organometallic complexes of a metal, preferably Ir, having a backbone of one five-membered ring that is linked to a five- or six-membered ring, by an intermediate six-membered ring. These compounds are suitable for adaptation to the emission of light in the UV to NIR range by adaptation of atoms or groups within at least one of the five-membered or six-membered ring structures.
    Type: Application
    Filed: September 7, 2006
    Publication date: July 2, 2009
    Applicants: UNIVERSITAET BRAUNSCHWEIG, BASF SE
    Inventors: Hans-Hermann Johannes, Wolfgang Kowalsky, Sven Ammermann, Michael Kroener, Ute Jana Weinaug
  • Publication number: 20090171054
    Abstract: A homopolymer having a monomer unit such as an isopropylidene diallylmalonate unit; a process for producing said homopolymer comprising the step of homopolymerising a monomer such as isopropylidene diallylmalonate; a copolymer containing said monomer unit and an ethylene unit and/or ?-olefin unit; and a process for producing said copolymer comprising the step of copolymerizing a monomer such as isopropylidene diallylmalonate with at least ethylene and/or an ?-olefin.
    Type: Application
    Filed: June 28, 2006
    Publication date: July 2, 2009
    Applicant: Sumitomo Chemical Company, Limited
    Inventors: Kohtaro Osakada, Daisuke Takeuchi, Sehoon Park, Masayuki Fujita, Wataru Hirahata
  • Publication number: 20090148675
    Abstract: The methods and apparatus disclosed herein concern nanoparticle layers uniformly distributed on a surface or substrate. In certain embodiments of the invention, the nanoparticle layers are of use for Raman spectroscopy. In certain embodiments of the invention, a micelle-metal ion complex is formed and deposited on a surface. The polymer component of the micelle-metal ion complex may be removed resulting in formation of nanoparticles of a uniform size and distribution. The polymers may contain one or more ligands. The number and type of ligands in a micelle will determine the type and amount of metal ion bound to the micelle, in turn determining the metal composition and size of the nanoparticles. The distribution micelle-metal ion complexes on a surface may determine the distribution and periodicity of the nanoparticle layer. In other embodiments, rod or columnar-shaped nanoparticles may be generated. Other embodiments concern the generation of uniform alloy nanoparticles.
    Type: Application
    Filed: February 12, 2009
    Publication date: June 11, 2009
    Applicant: INTEL CORPORATION
    Inventor: Lei Sun
  • Publication number: 20090137059
    Abstract: A method for detecting an analyze that may be present in ambient air, bound to a surface or as part of complex aqueous media that includes providing a metallole-containing polymer or copolymer, exposing the polymer or copolymer to a suspected analyze or a system suspected of including the analyze, and measuring a quenching of photoluminescence of the metallole-containing polymer or copolymer exposed to the system. Also included is a solid state inorganic-organic polymer sensor for detecting nitroaromatic compounds that includes a substrate and a thin film of a metallole-containing polymer or copolymer deposited on said substrate.
    Type: Application
    Filed: August 25, 2005
    Publication date: May 28, 2009
    Inventors: William C. Trogler, Sara A. Urbas, Sarah J. Toal, Jason Sanchez
  • Publication number: 20090130768
    Abstract: This application relates to vaprochromic coordination polymers useful for analyte detection. The vapochromism may be observed by visible color changes, changes in luminescence, and/or spectroscopic changes in the infrared (IR) signature. One or more of the above chromatic changes may be relied upon to identify a specific analyte, such as a volatile organic compound or a gas. The chromatic changes may be reversible to allow for successive analysis of different analytes using the same polymer. The polymer has the general formula MW[M?X(Z)Y]N wherein M and M? are the same or different metals capable of forming a coordinate complex with the Z moiety; Z is selected from the group consisting of halides, pseudohalides, thiolates, alkoxides and amides; W is between 1-6; X and Y are between 1-9; and N is between 1-5. Optionally, an organic ligand may be bound to M. In alternative embodiments of the invention M may be a transition metal, such as Cu and Zn.
    Type: Application
    Filed: July 8, 2008
    Publication date: May 21, 2009
    Applicant: SIMON FRASER UNIVERSITY
    Inventors: Julie LEFEBVRE, Michael Iacov KATZ, Daniel B. LEZNOFF
  • Publication number: 20090124780
    Abstract: Fabrication and arrangement of nanoparticles into one-dimensional linear chains is achieved by successive chemical reactions, each reaction adding one or more nanoparticles by building onto exposed, unprotected linker functionalities. Optionally, protecting groups may be used to control and organize growth. Nanoparticle spheres are functionalized in a controlled manner in order to enable covalent linkages. Functionalization of nanoparticles is accomplished by either ligand exchange or chemical modification of the terminal functional groups of the capping ligand. Nanoparticle chains are obtained by a variety of connectivity modes such as direct coupling, use of linker molecules, and use of linear polymeric templates. In particular, a versatile building block system is obtained through controlled monofunctionalization of nanoparticles.
    Type: Application
    Filed: January 12, 2009
    Publication date: May 14, 2009
    Applicant: Massachusetts Institute of Technology
    Inventors: Joseph M. Jacobson, David W. Mosley, Kie-Moon Sung
  • Publication number: 20090118453
    Abstract: The present invention describes novel metal complexes. Compounds of this type can be employed as functional materials in a number of different applications which can be ascribed to the electronics industry in the broadest sense. The compounds according to the invention are described by the formulae (1) and (1a).
    Type: Application
    Filed: July 24, 2006
    Publication date: May 7, 2009
    Applicant: Merck Patent GmbH
    Inventor: Jochen Schwaiger
  • Publication number: 20090096353
    Abstract: Disclosed is a light emitting polymer material comprising a (co)polymer comprising a structural unit derived from an iridium complex represented by the following formula (1): wherein R1 and R2 each independently represents an atom or a substituent selected from the group consisting of a hydrogen atom, a halogen atom, a cyano group, an alkyl group of 1 to 10 carbon atoms, an aryl group of 6 to 10 carbon atoms, an amino group which may be substituted with an alkyl group of 1 to 10 carbon atoms, an alkoxy group of 1 to 10 carbon atoms, and a silyl group; X1 represents a polymerizable functional group-containing substituent; and A1 to A3 each independently represents a divalent substituent having a cyclic structure.
    Type: Application
    Filed: June 12, 2006
    Publication date: April 16, 2009
    Applicant: SHOWA DENKO K.K.
    Inventors: Yoshiaki Takahashi, Tetsuhiko Yamaguchi
  • Publication number: 20090076208
    Abstract: A polymerizable composition including a compound represented by the following formula (1) and elemental sulfur. (In the following formula (1), M represents a metal atom; X1 and X2 each independently represent a sulfur atom or an oxygen atom; R1 represents a divalent organic group; m represents an integer of 0 or 1 or more; p represents an integer of 1 or more and n or less; n represents the valency of the metal atom M; Y each independently represent an inorganic or organic residue; and when n?p is 2 or more, Y's may bind to each other to form a ring containing the metal atom M.
    Type: Application
    Filed: February 27, 2007
    Publication date: March 19, 2009
    Applicant: MITSUI CHEMICALS, INC.
    Inventors: Shinichi Usugi, Mitsuo Nakamura, Hiroshi Naruse
  • Publication number: 20090062498
    Abstract: A linking ligand compound includes three bidentate chemical moieties distributed about a central chemical moiety. Another linking ligand compound includes a bidentate linking ligand and a monodentate chemical moiety. Coordination polymers include a plurality of metal clusters linked together by residues of the linking ligand compounds.
    Type: Application
    Filed: August 30, 2007
    Publication date: March 5, 2009
    Applicant: THE REGENTS OF THE UNIVERSITY OF MICHIGAN
    Inventors: Adam J. Matzger, Antek G. Wong-Foy, Olivier Lebel
  • Publication number: 20090045725
    Abstract: A high-molecular compound, characterized by containing a chain consisting of repeating units represented by the general formula (1) and having an average number of repeating units constituting the chain of 3 or above and a ratio of bonds formed between the head and the tail to all the bonds formed between repeating units of 85% or above: (1) wherein Ar1 is a divalent aromatic group whose aromatic ring is an aromatic hydrocarbon ring; R1 is a substituent on Ar1; n is an integer of 0 to 30; when n is 2 or above, plural R1's may be the same or different from each other, when the carbon atoms of a repeating unit of the general formula (1) are numbered as a divalent group according to Nomenclature of Organic Chemistry by IUPAC, between the two carbon atoms having free valencies, the carbon atom with a smaller number is defined as the head and the carbon atom with a larger number is defined as the tail; and no repeating unit of the general formula (1) has a two-fold axis of symmetry intersecting the straight line j
    Type: Application
    Filed: June 9, 2006
    Publication date: February 19, 2009
    Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Daisuke Fukushima, Akihiko Okada, Takeshi Yamada, Kazuei Ohuchi, Hideyuki Higashimura, Nozomi Kogure
  • Publication number: 20090048414
    Abstract: A composition of matter for a polymeric material for magnetic coupling through strong hydrogen bonds. A hydrogen bound structural directing entity, such as the bifluoride ion, HF2?, or coordination polymers incorporating strong OH...F type interactions can be used to manufacture organic polymers which allow, via strong hydrogen bonds, the bridging across polymeric magnetic layers to couple spin-polarized electrons to the conduction band, in order to enable control of the electron spin state for spintronic applications.
    Type: Application
    Filed: August 16, 2007
    Publication date: February 19, 2009
    Inventors: John A. Schlueter, Jamie L. Manson
  • Publication number: 20090048415
    Abstract: The present invention describes novel metal complexes. Compounds of this type can be employed as functional materials in a number of different applications which can be ascribed to the electronics industry in the broadest sense, in particular as red-emitting compounds. The compounds according to the invention are described by the formulae (1) (1a), (1b) and (3).
    Type: Application
    Filed: August 25, 2006
    Publication date: February 19, 2009
    Applicant: Merck Patent GmbH
    Inventors: Arne Buesing, Rocco Fortte, Philipp Stoessel, Horst Vestweber, Holger Heil, Amir Parham
  • Publication number: 20090012253
    Abstract: A PBI compound includes imidazole nitrogens at least a portion of which are substituted with an organic-inorganic hybrid moiety. At least 85% of the imidazole nitrogens may be substituted. The organic-inorganic hybrid moiety may be an organosilane moiety, for example, (R)Me2SiCH2— where R is selected from among methyl, phenyl, vinyl, and allyl. The PBI compound may exhibit similar thermal properties in comparison to the unsubstituted PBI. The PBI compound may exhibit a solubility in an organic solvent greater than the solubility of the unsubstituted PBI. The PBI compound may be included in separatory media. A substituted PBI synthesis method may include providing a parent PBI in a less than 5 wt % solvent solution. Substituting may occur at about room temperature and/or at about atmospheric pressure. Substituting may use at least 5 equivalents in relation to the imidazole nitrogens to be substituted or, preferably, about 15.
    Type: Application
    Filed: July 3, 2007
    Publication date: January 8, 2009
    Inventors: John R. Klaehn, Eric S. Peterson, Alan K. Wertsching, Christopher J. Orme, Thomas A. Luther, Michael G. Jones
  • Publication number: 20090012254
    Abstract: Ruthenium and osmium carbene compounds that are stable in the presence of a variety of functional groups and can be used to catalyze olefin metathesis reactions on unstrained cyclic and acyclic olefins are disclosed. Also disclosed are methods of making the carbene compounds. The carbene compounds are of the formula where M is Os or Ru; R1 is hydrogen; R is selected from the group consisting of hydrogen, substituted or unsubstituted alkyl, and substituted or unsubstituted aryl; X and X1 are independently selected from any anionic ligand; and L and L1 are independently selected from any neutral electron donor. The ruthenium and osmium carbene compounds of the present invention may be synthesized using diazo compounds, by neutral electron donor ligand exchange, by cross metathesis, using acetylene, using cumulated olefins, and in a one-pot method using diazo compounds and neutral electron donors.
    Type: Application
    Filed: October 30, 2007
    Publication date: January 8, 2009
    Applicant: CALIFORNIA INSTITUTE OF TECHNOLOGY
    Inventors: Robert H. GRUBBS, Peter SCHWAB, Sonbinh T. NGUYEN
  • Publication number: 20080312396
    Abstract: The present invention describes a process for the preparation of homoleptic and heteroleptic tris-ortho-metallated metal compounds which are used as colouring components as functional materials in a number of different applications which can be ascribed to the electronics industry in the broadest sense.
    Type: Application
    Filed: November 9, 2006
    Publication date: December 18, 2008
    Inventors: Philipp Stoessel, Rocco Fortte, Amir Parham, Esther Breuning, Holger Heil, Horst Vestweber
  • Publication number: 20080303418
    Abstract: Disclosed herein is a moisture-reactive composition having a moisture-reactive polysiloxane having a main chain and one or more side chains, wherein the main chain and/or the one or more side chains has a group represented by the formula: —MXmYn; and wherein M is selected from the group consisting of a multivalent metal atom, B, and P?O; X is a hydrogen atom, a substituted or nonsubstituted alkyl, alkenyl or alkoxy group; Y is a substituted or nonsubstituted alkoxy, siloxy, carboxyl, or diketolate group; m is from 1 to 3; and n is from 0 to 2.
    Type: Application
    Filed: February 17, 2006
    Publication date: December 11, 2008
    Inventors: Jun Fujita, Takashi Yamasaki
  • Publication number: 20080262184
    Abstract: The present invention provides polymer derived from a monomer of formula I and a polymerizable phosphorescent organometallic compound of formula L?2MZ?, wherein R1 is H or CH3; R2 is H or C1-C5 alkyl; R3 is H or CH3; R4 and R5 are independently H, CH3, t-butyl, triarylsilyl, trialkylsilyl, diphenyl phosphine oxide, or diphenyl phosphine sulfide; m ranges from 1 to about 20; n ranges from 1 to about 20; L? and Z? are independently bidentate ligands; at least one of L? and Z? comprises at least one substituent selected from C2-20 alkenyl, C2-20 alkynyl, C2-20 substituted alkenyl, C2-20 substituted alkynyl, C2-20 alkenyloxy, C2-20 alkynyloxy, styryl, acryloyl, and methacryloyl; and M is Ga, Al, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Y, Zr, Nb, Mo, Tc, Ru, Rh, Pd, Ag, Cd, Lu, Hf, Ta, W, Re, Os, Ir, Pt, Au, Hg, Lr, Rf, Db, Sg, Bbh, Hs, Mt, Ds, Rg, Uub, Eu, Tb, La, Po, or a combination thereof. The polymers of the invention are useful as light emissive layers in light emitting devices. Thus.
    Type: Application
    Filed: April 17, 2007
    Publication date: October 23, 2008
    Applicant: GENERAL ELECTRIC COMPANY
    Inventors: Qing Ye, Jie Liu, Kyle Erik Litz
  • Publication number: 20080262183
    Abstract: Dithienopyrrole-containing copolymers, and organic semiconductors formed therefrom, used as p-type and donor compounds in semiconductors for organic photovoltaic (OPV) applications, such as solar cells or transistors, such as organic field effect transistors (OFET). Organic semiconductors formed herein have a low bandgap and high absorbance, increasing the efficiency of a transistor or a solar cell. Such dithienopyrrole-containing copolymers also have excellent hole-conductivity which may be even further improved through oxidation.
    Type: Application
    Filed: April 17, 2007
    Publication date: October 23, 2008
    Inventor: Lutz Uwe Lehmann
  • Publication number: 20080249275
    Abstract: Nanoscopic metallized and nonmetallized nanoscopic silicon containing agents including polyhedral oligomeric silsesquioxane and polyhedral oligomeric silicate provide radiation absorption and in situ formation of nanoscopic glass layers on material surfaces. These property improvements are useful in space-survivable materials, microelectronic packaging, and radiation absorptive paints, coatings and molded articles.
    Type: Application
    Filed: August 30, 2007
    Publication date: October 9, 2008
    Inventors: Joseph D. Lichtenhan, Xuan Fu, Paul Wheeler
  • Patent number: 7433118
    Abstract: Bridged polysesquioxane compositions comprising: a bridged polysesquioxane host matrix comprising sesquioxane moieties and organic moieties, the sesquioxane moieties comprising a metallic element, the organic moieties interposed between sesquioxane moieties; and a guest molecule comprising a lanthanide atom; at least some of the organic moieties comprising a substituent selected from the group consisting of electron withdrawing functional groups and electron donating functional groups. Processes for making such bridged polysesquioxane compositions. Gain media and active materials for upconversion lasers comprising such bridged polysesquioxane compositions. Light can be amplified by fluorescence emissions from the bridged polysesquioxane compositions.
    Type: Grant
    Filed: June 26, 2003
    Date of Patent: October 7, 2008
    Assignee: Lucent Technologies Inc.
    Inventor: Ralph E. Taylor-Smith
  • Publication number: 20080233429
    Abstract: A polymer compound comprising a repeating unit of the following formula (1) and which is useful as a light emitting material or charge transporting material and excellent in heat resistance, fluorescent intensity and the like: (wherein, ring A and ring B represent each independently an aromatic hydrocarbon ring optionally having a substituent, at least one of ring A and ring B is an aromatic hydrocarbon ring composed of a plurality of condensed benzene rings, Rw and Rx represent each independently a hydrogen atom, alkyl group, alkoxy group or the like, and Rw and Rx may mutually bond to form a ring).
    Type: Application
    Filed: December 10, 2004
    Publication date: September 25, 2008
    Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Jun Oguma, Kazuei Ohuchi, Takahiro Ueoka, Akiko Nakazono, Kiyotoshi Iimura, Katsumi Agata, Takeshi Yamada, Osamu Goto, Satoshi Kobayashi, Akihiko Okada
  • Publication number: 20080177020
    Abstract: A non-metallocene organometallic complex comprising a tridentate ligand and a metal bonded to a tridentate ligand, wherein two substituted aryl groups in the tridentate ligand are connected to a cyclic group at the ortho position via semi-rigid ring-ring linkages, and selected so to provide the resulting non-metallocene organometallic complex with a CS geometry, a C1 geometry, a C2 geometry or a C2v geometry.
    Type: Application
    Filed: September 21, 2007
    Publication date: July 24, 2008
    Inventors: Theodor Agapie, Suzanne Rose Golisz, Daniel Tofan, John E. Bercaw
  • Publication number: 20080177084
    Abstract: Disclosed are a monomer of iridium complex having a fluoro group as a functional group, a monomer of carbazole derivative having a hydroxy group as the functional group, and a copolymer containing the monomers in its main chain. The iridium complex used as a phosphorescent material and the carbazole derivative having an excellent hole transporting capability are synthesized as the monomer to form the copolymer. The content of iridium complex is easily controlled, and the carbazole derivative and iridium complex are contained in the main chain during the copolymer formation, thereby capable of manufacturing a light emitting device with higher heat resistance and chemical stability.
    Type: Application
    Filed: November 16, 2007
    Publication date: July 24, 2008
    Applicant: Gwangju Institute of Science and Technology
    Inventors: Jae-Suk Lee, Nam-Goo Kang, Hyo-jin Jeon
  • Publication number: 20080169756
    Abstract: A light emitting polymer includes a phosphorescence unit and a fluorescence unit. An organic light emitting device includes the light emitting polymer. The light emitting polymer can emit light of two or more colors according to a phosphorescent and fluorescent mechanisms, and thus the organic light emitting device including the light emitting polymer can have long lifetime, high brightness and excellent efficiency, and emit white light.
    Type: Application
    Filed: October 19, 2007
    Publication date: July 17, 2008
    Inventors: Jhun-Mo Son, Young-Hun Byun, Yu-Jin Kim, O-Hyun Kwon, Young-Mok Son
  • Patent number: 7396598
    Abstract: A polymer light emitting material, wherein the material has a light emitting mechanism based on transition from an excited triplet state to a ground state or transition through an excited triplet state to a ground state of an electron energy level, and the material comprises a nonionic light emitting part which constitutes a part of the polymer or is bound to the polymer. The polymer light emitting material exhibits high light emission efficiency above 5%, which is the limit of external quantum efficiency of fluorescence and can be designed so as to have a large area and hence are suitable for mass production of organic light emitting devices.
    Type: Grant
    Filed: June 20, 2002
    Date of Patent: July 8, 2008
    Assignee: Showa Denko K.K.
    Inventors: Masataka Takeuchi, Shuichi Naijo, Naoko Ito, Koro Shirane, Takeshi Igarashi, Yoshiaki Takahashi, Motoaki Kamachi
  • Patent number: 7393560
    Abstract: Organo-tin compound having the formula I: [R—(Y)a]b—SnX4-b wherein R stands for a polycyclic hydrocarbyl residue which optionally carries one or several substituents; Y stands for a bivalent linker group; X represents a hydrolysable group; a is an integer 0 or 1; and b is an integer 1 or 2. The preferably stands for an unsubstituted or substituted fused hydrocarbon ring system selected from naphthalene, antracene, phenanthrene, and pentacene. The novel compounds are useful for producing polymers which can be employed as thin film materials in optoelectronic devices.
    Type: Grant
    Filed: May 2, 2006
    Date of Patent: July 1, 2008
    Assignee: Braggone OY
    Inventors: Milja Hannu-Kuure, Ari Kärkkäinen