Pine Oleoresin Starting Material Used In Process, Or Product Thereof (e.g., Using Gum Turpentine, Pine Gum, Pine Resin, Etc., As Starting Material) Patents (Class 530/204)
  • Publication number: 20140148572
    Abstract: A method for preparing pimaric acid type resin acids includes: step (1) adding refined resin acid, turpentine, or rosin along with maleic anhydride at a mass ratio of 1:0.3-1.5 into a reaction bottle, dissolving the ingredients into a C1-C10 lower fatty acid solvent, the mass ratio of the C1-C10 low fatty acid to refined resin acid is 0.05-30:1, then carrying out additional reaction by heating directly or with assistance of a microwave, subsequently cooling, crystallizing, filtering, and washing; and step (2) combining the filtrates collected in step (1), stripping the solvent by vacuum distillation to obtain pimaric acid type resin acid coarse product, dissolving the resulting coarse product in NaOH aqueous solution to prepare aqueous solution of pimaric acid type resin acid salt, adjusting the pH to 6-14 with a mineral acid or an organic acid, and either directly purifying or acidifying followed by purifying to obtain the final product.
    Type: Application
    Filed: January 31, 2014
    Publication date: May 29, 2014
    Applicant: INSTITUTE OF CHEMICAL INDUSTRY OF FOREST PRODUCTS, CAF
    Inventors: Zhendong Zhao, Yuxiang Chen, Liangwu Bi, Yan Gu, Dongmei Li, Jing Wang, Yanju Lu
  • Patent number: 8680232
    Abstract: A method for preparing pimaric acid type resin acids includes the following steps: step (1) adding refined resin acid, turpentine, or rosin along with maleic anhydride at a mass ratio of 1:0.3-1.5 into a reaction bottle, dissolving the ingredients into a C1-C10 lower fatty acid solvent, the mass ratio of the C1-C10 low fatty acid to refined resin acid is 0.05-30:1, then carrying out additional reaction by heating directly or with assistance of a microwave, subsequently cooling, crystallizing, filtering, and washing; and step (2) combining the filtrates collected in step (1), stripping the solvent by vacuum distillation to obtain pimaric acid type resin acid coarse product, dissolving the resulting coarse product in NaOH aqueous solution to prepare aqueous solution of pimaric acid type resin acid salt, adjusting the pH level to 6-14 with a mineral acid or an organic acid while stirring, and either directly purifying or acidifying followed by purifying, the resulting precipitation to obtain the final product.
    Type: Grant
    Filed: March 18, 2010
    Date of Patent: March 25, 2014
    Assignee: Institute of Chemical Industry of Forest Products, CAF
    Inventors: Zhendong Zhao, Yuxiang Chen, Liangwu Bi, Yan Gu, Dongmei Li, Jing Wang, Yanju Lu
  • Publication number: 20120004390
    Abstract: A method for preparing pimaric acid type resin acids includes the following steps: step (1) adding refined resin acid, turpentine, or rosin along with maleic anhydride at a mass ratio of 1:0.3-1.5 into a reaction bottle, dissolving the ingredients into a C1-C10 lower fatty acid solvent, the mass ratio of the C1-C10 low fatty acid to refined resin acid is 0.05-30:1, then carrying out additional reaction by heating directly or with assistance of a microwave, subsequently cooling, crystallizing, filtering, and washing; and step (2) combining the filtrates collected in step (1), stripping the solvent by vacuum distillation to obtain pimaric acid type resin acid coarse product, dissolving the resulting coarse product in NaOH aqueous solution to prepare aqueous solution of pimaric acid type resin acid salt, adjusting the pH level to 6-14 with a mineral acid or an organic acid while stirring, and either directly purifying or acidifying followed by purifying, the resulting precipitation to obtain the final product.
    Type: Application
    Filed: March 18, 2010
    Publication date: January 5, 2012
    Inventors: Zhendong Zhao, Yuxiang Chen, Liangwu Bi, Yan Gu, Dongmei Li, Jing Wang, Yanju Lu
  • Patent number: 7601371
    Abstract: A liquid carrier for topical administration is provided that contains a mineral oil, turpentine and, optionally, camphor, and optionally other terpenoid components containing pinene, and its use to provide an antifungal composition containing a mixture of antifungal essential oils and the carrier system, wherein the mixture of antifungal essential oils includes an effective amount of each of Eucalyptus globulus, peppermint, cedarwood, and Manuka; along with the use of this composition in the topical treatment of fungal infection, particularly of the nail.
    Type: Grant
    Filed: March 12, 2007
    Date of Patent: October 13, 2009
    Inventor: Marc Selner
  • Patent number: 7597913
    Abstract: A liquid carrier for topical administration is provided that contains a mineral oil, turpentine and, optionally, camphor, and optionally other terpenoid components containing pinene, and its use to provide an antifungal composition a mixture of antifungal essential oils and the carrier system, wherein the mixture of antifungal essential oils includes an effective amount of each of eucalyptus globulus, peppermint, cedarwood, and Manuka; along with the use of this composition in the topical treatment of fungal infection, particularly of the nail.
    Type: Grant
    Filed: October 4, 2004
    Date of Patent: October 6, 2009
    Inventor: Marc Selner
  • Patent number: 6166131
    Abstract: Disclosed is a process for producing a highly reactive modified phenolic resin, which comprises mixing a heavy oil or pitch with 0.3 to 10 mol of a phenol, 0.2 to 9 mol in terms of formaldehyde, of a formaldehyde compound and 0.01 to 3.0 mol of an acid catalyst, each amount being based on 1 mol of the heavy oil or pitch calculated from an average molecular weight; and heating the resulting mixture with stirring, thereby to polycondensate the heavy oil or pitch, phenol and formaldehyde compound. According to this invention, there can be provided a process for producing simply and stably a highly reactive modified phenolic resin having low melt viscosity, excellent heat resistance and high reactivity with an epoxy resin, in one step.
    Type: Grant
    Filed: September 22, 1999
    Date of Patent: December 26, 2000
    Assignee: Kashima Oil Co., Ltd.
    Inventors: Masao Tashima, Hiromi Miyasita, Haruhiko Takeda, Tomoaki Fujii, Tatsushi Ishizuka, Makoto Hasegawa
  • Patent number: 6034210
    Abstract: Disclosed is a process for producing a highly reactive modified phenolic resin, which comprises mixing a heavy oil or pitch with 0.3 to 10 mol of a phenol, 0.2 to 9 mol in terms of formaldehyde, of a formaldehyde compound and 0.01 to 3.0 mol of an acid catalyst, each amount being based on 1 mol of the heavy oil or pitch calculated from an average molecular weight; and heating the resulting mixture with stirring, thereby to polycondensate the heavy oil or pitch, phenol and formaldehyde compound. According to this invention, there can be provided a process for producing simply and stably a highly reactive modified phenolic resin having low melt viscosity, excellent heat resistance and high reactivity with an epoxy resin, in one step.
    Type: Grant
    Filed: February 17, 1998
    Date of Patent: March 7, 2000
    Assignee: Kashima Oil Co., Ltd.
    Inventors: Masao Tashima, Hiromi Miyasita, Haruhiko Takeda, Tomoaki Fujii, Tatsushi Ishizuka, Makoto Hasegawa
  • Patent number: 5698668
    Abstract: Toluene-soluble modified natural-resin acid esters which can be prepared by reacting at least one compound from each of the component groups: A) natural resins or natural-resin acids; B) .alpha.,.beta.-ethylenically unsaturated carboxylic acids or their anhydrides; C) phenols which are polyfunctional with respect to oxo compounds; D) aldehydes or aldehyde acetals; E) alcohols having at least two hydroxyl groups; and, if desired, further compounds from the substance groups: F) fatty acids or fatty acid esters; G) ethylenically unsaturated monomers; H) ethylenically unsaturated hydrocarbon resins in the presence of: I) monovalent or divalent metal compounds or mixtures thereof at a temperature of from 100.degree. to 300 .degree. C., with elimination of water, to an acid number of less than 100 mg of KOH/g of resin, and then reacting the resulting products with: J) carboxylic acids which contain at least two carboxyl groups and are not .alpha.,.beta.
    Type: Grant
    Filed: June 3, 1996
    Date of Patent: December 16, 1997
    Assignee: Vianova Resins GmbH
    Inventor: Albert Bender
  • Patent number: 5691154
    Abstract: An improvement in enzyme linked immunoassays is disclosed wherein the enzyme is in the form of a water soluble polymer saccharide conjugate which is stable in hostile environments. The conjugate comprises the enzyme which is linked to the polymer at multiple points through saccharide linker groups.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: November 25, 1997
    Assignee: Cargill, Incorporated
    Inventors: Matthew R. Callstrom, Mark D. Bednarski, Patrick R. Gruber
  • Patent number: 5492821
    Abstract: This invention is directed to water soluble protein polymer conjugates which are stabile in hostile environments. The conjugate comprises a protein which is linked to an acrylic polymer at multiple points through saccharide linker groups.
    Type: Grant
    Filed: November 13, 1991
    Date of Patent: February 20, 1996
    Assignee: Cargill, Inc.
    Inventors: Matthew R. Callstrom, Mark D. Bednarski, Patrick R. Gruber