Abstract: A polymerized rosin compound includes a rosin dimer component (A) including a bifunctional rosin dimer component (a1) represented by formula (1): ROOC—X—COOR. In this formula, X represents a rosin dimer residue derived from abietic acid, neoabietic acid, or palustric acid, which are resin acids having conjugated double bonds; and R represents hydrogen, an alkyl group of I to 5 carbon atoms, or a benzyl group. The rosin dimer component (A) contains a bifunctional rosin dimer component (a1) in the amount of 80% by weight or more and a rosin trimer or higher oligomer component (B) in the range from 1.5 to 3.

Abstract: An electroconductive hole plug paste comprising about 60-80 wt % of platinum particles, about 10-20 wt % of Al2O3, and about 10-20 wt % of organic vehicle, based upon 100% total weight of the paste, wherein the organic vehicle includes at least one viscosity-modifying component in an amount sufficient to provide the electroconductive hole plug paste with a viscosity of about 800-1,500 kcPs, is provided. A ceramic substrate assembly for an implantable medical device having the electroconductive hole plug paste of the invention, and a method of forming the same, are also provided.

Abstract: The present invention relates to a method to prepare dimerized rosins dispersible in water in presence of extremely low level of dimerization acid catalyst. The present invention relates also to its use as a tackifier resin, solid or in water, and ink resin, and an adhesive composition and ink composition comprising the rosin resin.

Abstract: The present invention relates to a method to prepare dimerized rosins dispersible in water in presence of extremely low level of dimerization acid catalyst. The present invention relates also to its use as a tackifier resin, solid or in water, and ink resin, and an adhesive composition and ink composition comprising the rosin resin.

Abstract: The present invention relates to a method to prepare dimerized rosins dispersible in water in presence of extremely low level of dimerization acid catalyst. The present invention relates also to its use as a tackifier resin, solid or in water, and ink resin, and an adhesive composition and ink composition comprising the rosin resin.

Abstract: A polyester for a toner, obtainable by polycondensing an alcohol component and a carboxylic acid component containing a fumaric acid-modified rosin; and a toner containing the polyester for a toner. The polyester for a toner of the present invention is usable as a resin binder for a toner usable in, for example, developing electrostatic latent images formed in electrophotography, electrostatic recording method, electrostatic printing method or the like.

Abstract: Oxidized and maleated derivative compositions, such as chemically modified oxidized and maleated tall oil fatty acid compositions, can be prepared and used in a variety of industrial applications, including as emulsifiers, corrosion inhibitors, concrete admixtures, and in reverse flotation mining applications.

Abstract: The present invention relates to a method to prepare dimerized rosins dispersible in water in presence of extremely low level of dimerization acid catalyst. The present invention relates also to its use as a tackifier resin, solid or in water, and ink resin, and an adhesive composition and ink composition comprising the rosin resin.

Abstract: The specification describes a process for making gelled ink resins which exhibit improved properties such as lower viscosity under low shear and less viscosity decrease with increasing shear. In a preferred embodiment, a rosin-based or hydrocarbon-based resin is mixed with an organic solvent and reacted with a polyamine reactant, such as melamine-formaldehyde resin or hexamethylene diamine, under conditions sufficient to produce a substantially covalently cross-link gelled resin. The resulting gelled resin resists viscosity breakdown under high shear conditions and may be used directly for making ink compositions, obviating the need for further gelation and avoiding the use of conventional organo-metallic gelling agents.

Abstract: A one component adhesive composition is provided, which can be formulated from substantially or totally bio-based, renewable raw materials. Such adhesives can be formulated to have high strength and/or low or substantially no VOC emissions. This can be achieved by utilizing polymers that are derived or extracted from renewable plant materials such as soybeans, corn, sunflowers, wheat, etc. Adhesive compositions in accordance with the invention can include oils. The composition preferably contains bio-based oils only, but need not be completely free of fossil fuel or synthetic based oils. It should also include drying oils and/or similarly acting polymers, co-polymers, and fatty acids. Plasticizers, such as hydrogen oxide, derived from renewable sources are utilized to impart performance properties to the formulated adhesive. Metal napthanates can be used to catalyze the drying and/or curing speed when the adhesive composition is applied to a substrate.

Abstract: A polyester for a toner, obtainable by polycondensing an alcohol component and a carboxylic acid component containing a fumaric acid-modified rosin; and a toner containing the polyester for a toner. The polyester for a toner of the present invention is usable as a resin binder for a toner usable in, for example, developing electrostatic latent images formed in electrophotography, electrostatic recording method, electrostatic printing method or the like.

Abstract: Reduced-rosin compositions of printing inks and the resinate binders therein, and the processes of preparation thereof, are described. In said compositions, a portion of the rosin normally used in the art is replaced by Monomer, and is further reacted with ?,?-unsaturated carboxylic compound, alkaline metal salt, and solvent to produce the resinate binder product. Said resinate binder may then be formulated with a colorant to produce an ink, preferably for use in publication gravure.

Abstract: Reduced-rosin compositions of printing inks and the resinate binders therein, and the processes of preparation thereof, are described. In said compositions, a portion of the rosin normally used in the art is replaced by Monomer, and is further reacted with ?,?-unsaturated carboxylic compound, alkaline metal salt, and solvent to produce the resinate binder product. Said resinate binder may then be formulated with a colorant to produce an ink, preferably for use in publication gravure.

Abstract: The present invention provides an artificial chaperon useful for refolding the proteins having low voluntary folding ability and being difficult or unable to be a native form without a second (or assistant) of a molecular chaperon in a short time, and folding said proteins as an active form. The present invention relates to an artificial chaperon kit characterized in that the kit comprises cyclic saccharide cycloamylose and polyoxyethylenic detergent or cyclic saccharide cycloamylose and ionic detergent. The present invention also relates to a method for diluting the denaturant making the protein a denatured state by adding a specific detergent to a denatured protein, and preventing protein molecules from aggregation, thereafter adding cyclic saccharide cycloamylose, utilizing the inclusion ability thereof to strip detergent, accelerating the proper folding of protein into a correct higher-order structure with activity.

Abstract: This invention provides thermosetting adhesives which have properties advantageous for bonding electronic parts that are capable of being cured using a low dose of radiation such as electron beam. The thermosetting adhesive of the invention comprises (a) ethylene-glycidyl (meth)acrylate copolymer; (b) rosin having a carboxyl group; and (c) (meth)acrylate having a carboxyl group.

Abstract: Asphalt emulsions containing emulsifiers comprising alkali metal or ammonium salts of solidified pyrolytic wood tar oil. Resinous compositions useful as asphalt emulsifiers comprising: (a) solidified pyrolytic wood tar oil and salts thereof, and (b) rosins and salts thereof.

Abstract: The synthesis of moisture-resistant adhesive polypeptides, conditions for their use, and conditions for controlling characteristics of the crosslinked matrix are disclosed. By specifically manipulating the conditions under which these networks are formed, the characteristics of the networks may be precisely regulated. These manipulatable adhesive networks are water-based, show exceptional bonding capabilities toward wet materials (including biological tissues), and have a variety of biotechnological applications.

Abstract: Mixtures of dimeric and trimeric fatty acid C1-4 alkyl esters and processes for their preparation comprising either A) epoxidizing an unsaturated or partially hydrogenated fatty acid glyceride; B) transesterifying the epoxidized glyceride with a C1-4 alkanol to obtain epoxidized fatty acid C1-4 alkyl esters; and C) ring opening and dimerizing the epoxidized fatty acid C1-4 alkyl esters; or A) transesterifying an unsaturated or partially hydrogenated glyceride with a C1-4 alkanol to obtain olefinically unsaturated fatty acid C1-4 alkyl esters; B) epoxidizing the unsaturated fatty acid C1-4 alkyl esters; and C) ring opening and dimerizing the epoxidized fatty acid C1-4 alkyl esters.

Abstract: This invention relates to novel phenolic rosin resin compositions. In particular, the invention relates to novel phenolic rosin resin compositions and dienophile-modified phenolic rosin resin compositions which exhibit properties that make them useful in formulating vehicles for lithographic printing inks and other coating applications.

Abstract: Disclosed is a process for producing a highly reactive modified phenolic resin, which comprises mixing a heavy oil or pitch with 0.3 to 10 mol of a phenol, 0.2 to 9 mol in terms of formaldehyde, of a formaldehyde compound and 0.01 to 3.0 mol of an acid catalyst, each amount being based on 1 mol of the heavy oil or pitch calculated from an average molecular weight; and heating the resulting mixture with stirring, thereby to polycondensate the heavy oil or pitch, phenol and formaldehyde compound. According to this invention, there can be provided a process for producing simply and stably a highly reactive modified phenolic resin having low melt viscosity, excellent heat resistance and high reactivity with an epoxy resin, in one step.

Abstract: Disclosed is a process for producing a highly reactive modified phenolic resin, which comprises mixing a heavy oil or pitch with 0.3 to 10 mol of a phenol, 0.2 to 9 mol in terms of formaldehyde, of a formaldehyde compound and 0.01 to 3.0 mol of an acid catalyst, each amount being based on 1 mol of the heavy oil or pitch calculated from an average molecular weight; and heating the resulting mixture with stirring, thereby to polycondensate the heavy oil or pitch, phenol and formaldehyde compound. According to this invention, there can be provided a process for producing simply and stably a highly reactive modified phenolic resin having low melt viscosity, excellent heat resistance and high reactivity with an epoxy resin, in one step.

Abstract: This invention relates to novel phenolic rosin resins and the process for preparing them. In particular, the invention relates to novel phenolic rosin resin compositions which exhibit properties that make them useful in formulating vehicles for lithographic printing inks and other coating applications.

Abstract: The specification discloses a method and additive for increasing the surface activity of non-polar polymeric materials, and a non-polar polymeric material exhibiting increased surface activity. The invention employs an additive of the formulaA-B-A.sup.1wherein each of the A and A.sup.1 blocks which may be the same or different has a number molecular weight in the range of from about 200 to about 1000 daltons and is selected from the group substituted and unsubstituted alkyl, cycloalkyl, alkenyl, cycloalkenyl, aryl and alkylaryl units derived from one or more esters, organic acids, organic halides or organic acid halides, and units derived from alkyl or aryl isocyanates or ester-amides. The B-block is a polyepichlorohydrin unit derived from a polyepichlorohydrin polyol having at least two terminal hydroxyl groups and having an average molecular weight in the range of from about 400 to about 4000 daltons.

Abstract: The specification discloses a process for making high viscosity gelled ink resins which exhibit improved properties. In a preferred embodiment, a precursor resin is conducted through an extruder with a cross-linking agent, preferably a heat reactive phenolic resin, to induce formation of covalent cross-link bonds in the resin producing a high viscosity resin which resists viscosity breakdown under high shear conditions. The resulting gelled ink resins may be used directly in making ink, obviating the need for further gelation and avoiding the use of conventional organo-metallic gelling agents.

Abstract: Rosin esters that are both light colored and color stable are produced by reacting polyhydric alcohol with an equivalent excess of rosin, in the presence of calcium bis(monoethyl(3,5-di-tert-butyl-4-hydroxybenzyl)phosphonate. When phosphinic acid is added to the reaction mixture, light colored and color stable rosin esters are produced regardless of whether the rosin or polyol are in equivalent excess, although preferably the rosin is in equivalent excess. It is preferred to include a phenol sulfide compound, such as Vultac.RTM. 2, with the calcium bis(monoethyl(3,5-di-tert-butyl-4-hydroxybenzyl)phosphonate, and to add the phosphinic acid incrementally after the acid number of the rosin and polyhydric alcohol reaction mixture has dropped to about 100. Excess rosin is preferably stripped from the product mixture at about 275.degree. C.

Abstract: The specification describes a process for making gelled ink resins which exhibit improved properties. In a preferred embodiment, a rosin-based or hydrocarbon-based resin is mixed with an organic solvent and reacted with a crosslink agent under conditions sufficient to produce a substantially covalently cross-link gelled resin. The resulting gelled resin resists viscosity breakdown under high shear conditions and may be used directly for making ink compositions, obviating the need for further gelation and avoiding the use of conventional organo-metallic gelling agents.

Abstract: Toluene-soluble modified natural-resin acid esters which can be prepared by reacting at least one compound from each of the component groups: A) natural resins or natural-resin acids; B) .alpha.,.beta.-ethylenically unsaturated carboxylic acids or their anhydrides; C) phenols which are polyfunctional with respect to oxo compounds; D) aldehydes or aldehyde acetals; E) alcohols having at least two hydroxyl groups; and, if desired, further compounds from the substance groups: F) fatty acids or fatty acid esters; G) ethylenically unsaturated monomers; H) ethylenically unsaturated hydrocarbon resins in the presence of: I) monovalent or divalent metal compounds or mixtures thereof at a temperature of from 100.degree. to 300 .degree. C., with elimination of water, to an acid number of less than 100 mg of KOH/g of resin, and then reacting the resulting products with: J) carboxylic acids which contain at least two carboxyl groups and are not .alpha.,.beta.

Abstract: Resinous compositions comprising lignin and polymerized rosin. Use of salts of the resinous compositions as concrete air-entraining agents and asphalt emulsifiers.

Abstract: Resinous compositions comprising lignin and polymerized rosin. Use of salts of the resinous compositions as concrete air-entraining agents and asphalt emulsifiers.

Abstract: Disclosed is a process for the continuous production of rosins which have consistent, uniform properties and are suitable for use as printing ink resins, the process comprising reacting the reaction mixture in a continuously operated reaction vessel cascade comprising at least two reactors.

Abstract: The specification discloses a process for making high viscosity gelled ink resins which exhibit improved properties. In a preferred embodiment, a precursor resin is conducted through an extruder with a cross-linking agent, preferably a heat reactive phenolic resin, to induce formation of covalent cross-link bonds in the resin producing a high viscosity resin which resists viscosity breakdown under high shear conditions. The resulting gelled ink resins may be used directly in making ink, obviating the need for further gelation and avoiding the use of conventional organo-metallic gelling agents.

Abstract: The specification discloses a method for esterifying rosins with a polyol which comprises contacting rosin with the polyol in the presence of a bleaching mixture which includes both an alkaline earth hypophosphite and hypophosphorous acid and, preferably also, an organic sulfide, under esterification conditions to produce a rosin ester. The method enables production of rosin esters which have a color of less than about 5 Gardner neat. The preferred bleaching mixture includes from about 0.01% to about 0.10% of the alkaline earth hypophosphite and from about 0.10% to about 0.15% of active hypophosphorous acid, where the amounts are based on the weight of the rosin. The most preferred alkaline earth hypophosphite is calcium hypophosphite. The specification also describes a method for preparing an adhesive from the rosin ester.

Abstract: This invention relates to rosin carboxypyrrolidinone adducts. In particular, this invention relates to water-soluble resins derived from the reaction product of a modified rosin with a hydroxyl-containing carboxypyrrolidinone derivative. These resins can be used to make acrylic latex compositions which can, in turn, be utilized to produce water-based flexographic and gravure ink formulations.

Abstract: The invention relates to mixtures of nitrogen-containing surface-active agents which are obtained by esterification of oxyalkylates based on modified or nonmodified naturally occurring resin acids or resin amines or resin alcohols derived therefrom with dicarboxylic acids or anhydrides thereof and subsequent reaction with alkylenediamines or alkylenepolyamines. These nitrogen-containing surface-active agents are suitable as coupling auxiliaries, emulsifiers, dispersing agents, preparation agents for solids dispersions, corrosion protection and metal-working agents and as wetting agents and dyeing auxiliaries.

Abstract: The invention is ink pigment grinding resins for waterbased printing inks which are produced by the amidation of maleated or fumarated rosin with a polyamine containing a primary amine group to produce the water soluble polyaminoamidoimide resin. The resulting rosin resin may be employed over a wide range of pH values to produce stable low or high viscosity grind bases.

Abstract: Improved water soluble resins having qualities of adhesion, wettability and improved stability for use in packaging ink compositions are prepared as the reaction products of modified rosin and a compound containing two secondary amine groups, and further modifying said reaction products with a polyol, such as diethylene glycol.

Abstract: The color stability of polymerized rosin is improved by heating the polymerized rosin at a temperature of 250.degree.-290.degree. C. in the presence of 0.05% to 5% sodium hydroxymethane sulfonate.

Abstract: A water-soluble resin for packaging ink comprising the reaction product of fumarated or maleated rosin and a compound containing two secondary amine groups is disclosed. A resin with a higher softening point may be obtained by substituting a dicarboxylic acid, such as adipic acid or isophathalic acid, for part of the fumarated or maleated rosin. Water varnishes, pigment bases, and water based inks containing the resin are disclosed.

Abstract: The present invention relates to amide linked rosin acid derivatives which are useful as a total or partial replacement for extender or processing oil in rubber formulations. The amide linked rosin acid derivatives improve Strebler adhesion in rubber compositions and also significantly reduce rheometer t25 and t90 values. The amide linked rosin acids are prepared by reacting abietylamine or dehydroabietylamine with abietic acid or dehydroabietic acid under amidation conditions.

Abstract: Nitrogen-containing condensation products based on unmodified or modified natural resins, process for the preparation thereof and the use thereof.The invention relates to surface-active agents of the general formulaA--[(X--O).sub.n --Y--Z].sub.min which A is a radical of an unmodified or modified natural resin or esterification product thereof with a polyhydric alcohol, X is 1,2-ethylene or -propylene, Y is as defined for X or is --CH.sub.2 CHOHCH.sub.2 --, Z is OH or (Ia)(--NH--Q).sub.a --NR--(Q--NH--).sub.b H (Ia)in which R is H or C.sub.1 -C.sub.24 --alkyl or (--CH.sub.2 CH.sub.2 O).sub.p --H, with p being 1 to 100, or (--Q--NH).sub.c --H, Q is C.sub.1 -C.sub.24 ---alkylene which can be interrupted by oxygen atoms, a is 0-5 and c is 0-5,at least one Z being other than OH,n is 0 to 150 andm is 1 to 5.

Abstract: A nucleic acid-protein conjugate which is specific with respect to a selected living cell is prepared by linking said nucleic acid to a protein specific to said living cell.