Abstract: The present invention relates to processes for purifying guar comprising combining borate and guar in an aqueous solution and treating the aqueous solution with an organic solvent to induce precipitation of purified guar. Another embodiment of the present invention is directed to ophthalmic formulations comprising purified guar produced by the processes described.

Abstract: A process for disproportionating rosins using iodide catalysts. In one embodiment, a tall oil rosin is heated in the presence of a lithium iodide catalyst. In another embodiment, a catalyst system is formed from a mixture of lithium iodide and ferrous iodide. The mixed catalyst system completes disproportionation of tall oil rosin in about three hours. Phosphoric acid may be added to remove iron colored impurities when using the mixed catalyst system. Another aspect of the invention involves preparing a soap from the disproportionated rosin by adding a defoamer and a base, such as potassium hydroxide.

Abstract: Light-colored phenolic-modified rosin esters, suitable for use as, for example, tackifiers in adhesive compositions, are prepared by reacting together rosin, a phenolic compound, formaldehyde or a reactive equivalent thereof, and a non-phenolic hydroxyl-containing organic compound in the presence of at least one lightening agent selected from phenol sulfide compounds, phosphorous acid, esters of phosphorous acid, and hypophosphite salts. The formaldehyde or reactive equivalent is present in an amount ranging from about 1.1 to about 3.5 equivalents of --CHO moieties per 1 equivalent of Ar--OH moiety of the phenolic compound, in order to obtain rosin esters having desirably low color, and adequately low molecular weight to effectively function as tackifiers.

Abstract: Rosin esters that are both light colored and color stable are produced by reacting polyhydric alcohol with an equivalent excess of rosin, in the presence of calcium bis(monoethyl(3,5-di-tert-butyl-4-hydroxybenzyl)phosphonate. When phosphinic acid is added to the reaction mixture, light colored and color stable rosin esters are produced regardless of whether the rosin or polyol are in equivalent excess, although preferably the rosin is in equivalent excess. It is preferred to include a phenol sulfide compound, such as Vultac.RTM. 2, with the calcium bis(monoethyl(3,5-di-tert-butyl-4-hydroxybenzyl)phosphonate, and to add the phosphinic acid incrementally after the acid number of the rosin and polyhydric alcohol reaction mixture has dropped to about 100. Excess rosin is preferably stripped from the product mixture at about 275.degree. C.

Abstract: Tetra-[N-alkyl-2,2,6,6-tetramethylpiperidin-4-yl]-4,4'-diphenylbisphosphoni te Abstract of the DisclosureNovel compounds of formula I ##STR1## wherein R is C.sub.1 -C.sub.4 alkyl, allyl or benzyl, as stabilisers for protecting organic materials from thermal, oxidative or light-induced degradation.

Abstract: The present invention relates to a process for preparing a rosin ester, which comprises esterifying a purified product of a disproportionated rosin with an alcohol, and then subjecting the esterified rosin to dehydrogenation in the presence of a dehydrogenating catalyst, a process for preparing a rosin ester, which comprises heating a purified rosin and an alcohol in the presence of a disproportionating catalyst, simultaneously subjecting the resulting rosin to disproportionation and esterification, dehydrogenating the reactant in the presence of a dehydrogenating catalyst, and thereafter adding an organic phosphorus compound to the reaction system, a process for preparing a colorless rosin, which comprises simultaneously subjecting a purified rosin to disproportionation and dehydrogenation in the presence of a catalyst, and then adding an organic phosphorus compound to the reaction system and a process for preparing a colorless rosin, which comprises dehydrogenating a purified disproportionated rosin in the

Abstract: An improved, stable rosin ester tackifier consisting essentially of an adduct of rosin and a polyhydric alcohol selected from the group consisting of trimethylolpropane, trimethylolethane, and mixtures thereof, and hot melt adhesive compositions consisting essentially of said tackifier and a polymer component, said compositions containing a mixture of antioxidants containing a higher alkyl diester of thiopropionic acid, a hindered phenolic compound and a phenol sulfide compound, preferably an alkyl phenol disulfide oligomer.

Abstract: A process for the production of a stabilized rosin and a stabilized rosin obtainable by the process. According to the process rosin is heated in the presence of a phosphoric acid or a strong acid in combination with a phosphate containing substance and disproportionated by addition of iodine. Preferably the rosin is first heated in the presence of the phosphoric acid or the strong acid in combination with the phosphate containing substance and thereafter disproportionated by the addition of iodine. Iodine is preferably added in at least two steps and the disproportionation is allowed to proceed between each step. The stabilized rosin can be used as a tackifier resin in adhesives and as a sizing agent for paper, paper boards and similar products.

Abstract: The catalytic combination of a phosphite ester and a phenol sulfide is disclosed. The catalyst combination accelerates and mediates the esterification reaction of rosin with a polyhydric alcohol, resulting in esterified rosins having numerous advantageous characteristics and particular utility as tackifiers in hot melt adhesives.

Abstract: Rosin esters having improved viscosity stability are prepared by heating a mixture of rosin and a polyol in the presence of a catalyst mixture of 0.1% to 0.6% by weight calcium bis(ethyl 3,5-di-t-butyl-4-hydroxybenzyl phosphonate) and 0.02 to 1.0% by weight of a second calcium compound selected from calcium carbonate, calcium oxide and a calcium salt of an aliphatic carboxylic acid, all percentages being based on the weight of rosin.