Oxygen Containing Ring Or Halogen Containing Material Used In The Esterification, Or Product Thereof (e.g., Using Alkylene Oxides, Polysaccharides, Alkyl Halides, Etc.) Patents (Class 530/217)
  • Patent number: 10253215
    Abstract: An object of the present invention is to provide an adhesive composition that is substantially odorless and has an extremely good color and excellent adhesive properties or tack at low temperatures of about 5° C. and in which deterioration over time caused by heat or light is suppressed. The present invention relates to an adhesive composition comprising a liquid rosin ester compound, the liquid rosin ester compound being obtained by reacting a rosin compound with a C1-10 monohydric alcohol compound and having a Gardner color of 1 or less, a glass transition temperature of ?20° C. or less, a degree of esterification of 93 wt % or more, and a ratio (Y?/Y) of the total area of peaks in 16- to 22-min retention time region (Y?) to the total area of all the peaks (Y) measured by gas chromatography under the following conditions of 200 ppm or less.
    Type: Grant
    Filed: March 11, 2015
    Date of Patent: April 9, 2019
    Assignee: ARAKAWA CHEMICAL INDUSTRIES, LTD.
    Inventors: Takashi Nakatani, Yoshimasa Sato, Tetsuya Kashihara, Yasushi Funakoshi
  • Patent number: 10144812
    Abstract: Compositions useful as bioplasticizers that include a functionalized fatty acid oil having an ester head group and a fatty acid backbone.
    Type: Grant
    Filed: September 27, 2016
    Date of Patent: December 4, 2018
    Assignee: Regents of the University of Minnesota
    Inventors: Dharma R. Kodali, Lucas J. Stolp
  • Publication number: 20140170545
    Abstract: The present disclosure provides a bio-based, branched polyester resin comprising the condensation product of a hydroxyl donor and a cyclic polyhydroxyl acceptor that may be used with a polyacid to form a polyester which may be used in manufacturing toner for imaging devices.
    Type: Application
    Filed: December 18, 2012
    Publication date: June 19, 2014
    Applicant: XEROX CORPORATION
    Inventors: Valerie M. Farrugia, Rosa M. Duque
  • Patent number: 8207292
    Abstract: The invention provides a method for the treatment of COPD and/or gastrointestinal disease conditions ameliorated by histamine management in a subject, comprising administering to the subject an effective amount of a histidine decarboxylase inhibitor.
    Type: Grant
    Filed: February 12, 2008
    Date of Patent: June 26, 2012
    Inventors: Michalis Nicolaou, Emile Loria, Gaetan Terrasse, Yves Trehin
  • Patent number: 7411036
    Abstract: An ink formulation comprising an acrylated resin prepared by mixing a hydroxyalkyl acrylate and an isocyanate and reacting said mixture with a resin containing one or more hydroxyl functional groups and derived from a natural product.
    Type: Grant
    Filed: November 23, 2005
    Date of Patent: August 12, 2008
    Assignee: Sun Chemical Corporation
    Inventor: Kai-Uwe Gaudl
  • Patent number: 7411035
    Abstract: An acrylated resin prepared by mixing a hydroxyalkyl acrylate and an isocyanate and reacting said mixture with a resin containing one or more hydroxyl functional groups and derived from a natural product.
    Type: Grant
    Filed: November 23, 2005
    Date of Patent: August 12, 2008
    Assignee: Sun Chemical Corporation
    Inventor: Kai-Uwe Gaudl
  • Patent number: 7001981
    Abstract: A method of acrylating a resin containing one or more hydroxyl functional group and derived from a natural product, comprising preparing a mixture of a hydroxyalkyl acrylate and an isocyanate; and reacting said mixture with said resin.
    Type: Grant
    Filed: April 25, 2003
    Date of Patent: February 21, 2006
    Assignee: Sun Chemical Corporation
    Inventor: Kai-Uwe Gaudl
  • Patent number: 6765116
    Abstract: A process to prepare an improved fluid rare earth phosphate catalyst composition useful in preparing alkylene oxide adducts of organic compounds having active hydrogen atoms is provided. The catalyst is prepared by dissolving a rare earth salt in a C9-C30 active hydrogen containing organic compound and then adding phosphoric acid to the organic compound rare earth mixture.
    Type: Grant
    Filed: August 23, 2002
    Date of Patent: July 20, 2004
    Assignee: Shell Oil Company
    Inventor: Charles Lee Edwards
  • Patent number: 6583263
    Abstract: A two-step method for introducing acrylic functions into high molecular weight natural resins, under mild conditions, without the risk of gellation, wherein an acrylated natural resin ester is prepared by esterifying one or more of the sterically hindered hydroxy groups of the natural resin ester in an inert solvent with a 3-halopropionic acid, to form a 3-halopropionate ester of the natural resin ester and dehydrohalogenated the 3-halopropionate ester by reacting it with an organic base.
    Type: Grant
    Filed: January 5, 2001
    Date of Patent: June 24, 2003
    Assignee: Sun Chemical Corporation
    Inventor: Kai-Uwe Gaudl
  • Publication number: 20030009059
    Abstract: A process to prepare an improved fluid rare earth phosphate catalyst composition useful in preparing alkylene oxide adducts of organic compounds having active hydrogen atoms is provided. The catalyst is prepared by dissolving a rare earth salt in a C9-C30 active hydrogen containing organic compound and then adding phosphoric acid to the organic compound rare earth mixture.
    Type: Application
    Filed: August 23, 2002
    Publication date: January 9, 2003
    Inventor: Charles Lee Edwards
  • Patent number: 5969092
    Abstract: The invention relates to a process for the preparation of a tall oil rosin ester with a low odor level, which process comprises an esterification step wherein a tall oil rosin is esterified with a polyol in order to form a product which contains a tall oil rosin ester, and evaporation is carried out on this product in order to remove odor components and other volatile components from the product, which evaporation is carried out in a short-path evaporator which has an evaporation surface and, in the vicinity of this surface, a condenser on which the vaporized components to be removed condense, whereupon a tall oil rosin ester with a low odor level is recovered from the evaporator.
    Type: Grant
    Filed: April 21, 1998
    Date of Patent: October 19, 1999
    Assignee: Arizona Chemical Oy
    Inventor: Mikko Kalevi Karvo
  • Patent number: 5922420
    Abstract: A granulate of wood or some other cellulose-containing material, pieces or particles of said material being at least partially esterified with 10-50% of a dicarboxylic acid anhydride and then impregnated with 2-25% of a polyol, the granulate being stable in storage and being possible to hot press or hot form later. A method for preparing the granulate by esterification at 80-160.degree. C. and, subsequently, impregnation at 150.degree. C. at most. A method for manufacturing formed articles by hot pressing or hot forming of the granulate, without the presence of a formaldehyde-containing adhesive and preferably without the presence of any other type of adhesive.
    Type: Grant
    Filed: February 13, 1997
    Date of Patent: July 13, 1999
    Assignee: Stora Kopparbergs Bergslags AB
    Inventors: Jorgen Dahlin, Ulf Nyberg
  • Patent number: 5874507
    Abstract: The specification discloses a method and additive for increasing the surface activity of non-polar polymeric materials, and a non-polar polymeric material exhibiting increased surface activity. The invention employs an additive of the formulaA-B-A.sup.1wherein each of the A and A.sup.1 blocks which may be the same or different has a number molecular weight in the range of from about 200 to about 1000 daltons and is selected from the group substituted and unsubstituted alkyl, cycloalkyl, alkenyl, cycloalkenyl, aryl and alkylaryl units derived from one or more esters, organic acids, organic halides or organic acid halides, and units derived from alkyl or aryl isocyanates or ester-amides. The B-block is a polyepichlorohydrin unit derived from a polyepichlorohydrin polyol having at least two terminal hydroxyl groups and having an average molecular weight in the range of from about 400 to about 4000 daltons.
    Type: Grant
    Filed: September 15, 1997
    Date of Patent: February 23, 1999
    Assignee: Arizona Chemical Company
    Inventors: Xinya Lu, Eric S. Gardiner
  • Patent number: 5830992
    Abstract: Rosin esters that are both light colored and color stable are produced by reacting polyhydric alcohol with an equivalent excess of rosin, in the presence of calcium bis(monoethyl(3,5-di-tert-butyl-4-hydroxybenzyl)phosphonate. When phosphinic acid is added to the reaction mixture, light colored and color stable rosin esters are produced regardless of whether the rosin or polyol are in equivalent excess, although preferably the rosin is in equivalent excess. It is preferred to include a phenol sulfide compound, such as Vultac.RTM. 2, with the calcium bis(monoethyl(3,5-di-tert-butyl-4-hydroxybenzyl)phosphonate, and to add the phosphinic acid incrementally after the acid number of the rosin and polyhydric alcohol reaction mixture has dropped to about 100. Excess rosin is preferably stripped from the product mixture at about 275.degree. C.
    Type: Grant
    Filed: December 12, 1996
    Date of Patent: November 3, 1998
    Assignee: Union Camp Corporation
    Inventor: David Mayo Whalen
  • Patent number: 5393337
    Abstract: This invention provides a rosin emulsion sizing agent for papermaking comprising a fortified or unfortified rosin-epoxy compound obtained by reacting a rosin and an epoxy compound, wherein the rosin-epoxy compound is dispersed in water with the aid of an emulsifying and dispersing agent, and paper sized therewith and a method of sizing using the same. The rosin emulsion sizing agent of the present invention exhibits an distinguished sizing effect in neutral papermaking systems even when calcium carbonate is contained therein and is excellent in mechanical and storage stabilities while causing little foaming in the papermaking system. In addition, the sizing agent presents no significant difficulties in its production.
    Type: Grant
    Filed: October 15, 1992
    Date of Patent: February 28, 1995
    Assignee: Japan PMC Corporation
    Inventors: Katsunori Nakamura, Kazuki Nagao, Masayuki Monobe
  • Patent number: 5266682
    Abstract: The invention relates to mixtures of nitrogen-containing surface-active agents which are obtained by esterification of oxyalkylates based on modified or nonmodified naturally occurring resin acids or resin amines or resin alcohols derived therefrom with dicarboxylic acids or anhydrides thereof and subsequent reaction with alkylenediamines or alkylenepolyamines. These nitrogen-containing surface-active agents are suitable as coupling auxiliaries, emulsifiers, dispersing agents, preparation agents for solids dispersions, corrosion protection and metal-working agents and as wetting agents and dyeing auxiliaries.
    Type: Grant
    Filed: May 14, 1992
    Date of Patent: November 30, 1993
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Heinz Uhrig, Siegfried Schwerin, Dieter Schnaitmann, Hans-Joachim Metz
  • Patent number: 5210325
    Abstract: Alkylene oxide adducts of organic compounds having active hydrogen atoms are prepared by a process which comprises contacting and reacting an alkylene oxide reactant comprising one or more vicinal alkylene oxides with an active hydrogen containing reactant comprising one or more compounds having active hydrogen atoms in the presence of a catalyst which comprises one or more compounds comprising a rare earth element and phosphorus supported on an inert porous support. The product alkoxylates are known to be useful, for instance, as nonionic surfactants, wetting and emulsifying agents, solvents, and chemical intermediates.
    Type: Grant
    Filed: August 10, 1992
    Date of Patent: May 11, 1993
    Assignee: Shell Oil Company
    Inventors: Richard A. Kemp, Paul R. Weider
  • Patent number: 5162589
    Abstract: Alkylene oxide adducts of organic compounds having active hydrogen atoms are prepared by a process which comprises contacting and reacting an alkylene oxide reactant comprising one or more vicinal alkylene oxides with an active hydrogen containing reactant comprising one or more compounds having active hydrogen atoms in the presence of a catalytically effective amount of sodium barium phosphate or potassium barium phosphate. The product alkoxylates are known to be useful, for instance, as nonionic surfactants, wetting and emulsifying agents, solvent, and chemical intermediates.
    Type: Grant
    Filed: June 8, 1992
    Date of Patent: November 10, 1992
    Assignee: Shell Oil Company
    Inventors: Rudolf J. Wijngaarden, Kees Latjes
  • Patent number: 5118870
    Abstract: Alkylene oxide adducts of organic compounds having active hydrogen atoms are prepared by a process which comprises contacting and reacting an alkylene oxide reactant comprising one or more vicinal alkylene oxides with an active hydrogen containing reactant comprising one or more compounds having active hydrogen atoms in the presence of a catalytically effective amount of a xerogel comprising one or more compounds comprising a rare earth element and phorphorus. The product alkoxylates are known to be useful, for instance, as nonionic surfactants, wetting and emulsifying agents, solvents, and chemical intermediates.
    Type: Grant
    Filed: April 23, 1990
    Date of Patent: June 2, 1992
    Assignee: Shell Oil Company
    Inventor: Richard A. Kemp
  • Patent number: 5059719
    Abstract: Alkylene oxide adducts of organic compounds having active hydrogen atoms are prepared by a process which comprises contacting and reacting an alkylene oxide reactant comprising one or more C.sub.2 to C.sub.4 vicinal alkylene oxides with an active hydrogen containing reactant comprising one or more compounds having active hydrogen atoms in the presence of a catalytically effective amount of one or more soluble basic compounds of one or more elements of the lanthanum series (atomic numbers 57-71, inclusive). The product alkoxylates are known to be useful, for instance, as nonionic surfactants, wetting and emulsifying agents, solvents, and chemical intermediates. When the process is applied to the preparation of alkylene oxide, particularly ethylene oxide, adducts of alkanols, particularly primary alkanols in the C.sub.6 to C.sub.24 range, the product is a valuable narrow range nonionic surfactant, characterized by relatively narrow distribution of alkylene oxide adducts.
    Type: Grant
    Filed: March 23, 1990
    Date of Patent: October 22, 1991
    Assignee: Shell Oil Company
    Inventor: Charles L. Edwards
  • Patent number: 5057627
    Abstract: Alkylene oxide adducts of organic compounds having active hydrogen atoms are prepared by a process which comprises contacting and reacting an alkylene oxide reactant comprising one or more vicinal alkylene oxides with an active hydrogen containing reactant comprising one or more compounds having active hydrogen atoms in the presence of a catalytically effective amount of one or more of the phosphate salts of the rare earth elements. The product alkoxylates are known to be useful, for instance, as nonionic surfactants, wetting and emulsifying agents, solvents, and chemical intermediates.
    Type: Grant
    Filed: February 20, 1990
    Date of Patent: October 15, 1991
    Assignee: Shell Oil Company
    Inventor: Charles L. Edwards
  • Patent number: 5057628
    Abstract: Alkylene oxide adducts of organic compounds having active hydrogen atoms are prepared by a process which comprises contacting and reacting an alkylene oxide reactant comprising one or more vicinal alkylene oxides with an active hydrogen containing reactant comprising one or more compounds having active hydrogen atoms in the presence of a catalytically effective amount of one or more compounds of one or more of the rare earth elements. The product alkoxylates are known to be useful, for instance, as nonionic surfactants, wetting and emulsifying agents, solvents, and chemical intermediates.
    Type: Grant
    Filed: February 20, 1990
    Date of Patent: October 15, 1991
    Assignee: Shell Oil Company
    Inventors: Charles L. Edwards, Richard A. Kemp
  • Patent number: 5026923
    Abstract: Alkylene oxide adducts of organic compounds having active hydrogen atoms are prepared by a process which comprises contacting and reacting an alkylene oxide reactant comprising one or more vicinal alkylene oxides with an active hydrogen containing reactant comprising one or more compounds having active hydrogen atoms in the presence of a catalytically effective amount of one or more of the borate salts of the rare earth elements. The product alkoxylates are known to be useful, for instance, as nonionic surfactants, wetting and emulsifying agents, solvents, and chemical intermediates.
    Type: Grant
    Filed: May 29, 1990
    Date of Patent: June 25, 1991
    Assignee: Shell Oil Company
    Inventor: Richard A. Kemp
  • Patent number: 4960952
    Abstract: Alkylene oxide adducts of organic compounds having active hydrogen atoms are prepared by a process which comprises contacting and reacting an alkylene oxide reactant comprising one or more vicinal alkylene oxides with an active hydrogen containing reactant comprising one or more compounds having active hydrogen atoms in the presence of a catalytically effective amount of one or more lanthanum compounds comprising silicate, metasilicate and mixtures thereof. The product alkoxylates are known to be useful, for instance, as nonionic surfactants, wetting and emulsifying agents, solvents, and chemical intermediates.
    Type: Grant
    Filed: August 31, 1989
    Date of Patent: October 2, 1990
    Assignee: Shell Oil Company
    Inventor: Richard A. Kemp