Heat Treatment Of Rosin Or Derivative In The Absence Of Nonrosin Organic Reactants, Or Product Thereof (e.g., Forming Rosin Oil; Disproportionated, Dehydrogenated, Or Isomerized Rosin; Etc.) Patents (Class 530/226)
  • Patent number: 8334260
    Abstract: This disclosure relates to a peptide motif and proteins containing the motif that are capable of binding to secreted Frizzled-related protein family members. Accordingly, the disclosure also includes methods of regulating the interaction of sFRP-1 with proteins containing the motif.
    Type: Grant
    Filed: January 24, 2008
    Date of Patent: December 18, 2012
    Assignees: The United States of America as represented by the Secretary of the Department of Health and Human Services, St. Vincent's Institute of Medical Research
    Inventors: Jeffrey S. Rubin, Aykut Üren, Brian K. Kay, Bernard Weisblum, Matthew Todd Gillespie, Nicole Joy Horwood
  • Patent number: 6087318
    Abstract: A process for disproportionating rosins using iodide catalysts. In one embodiment, a tall oil rosin is heated in the presence of a lithium iodide catalyst. In another embodiment, a catalyst system is formed from a mixture of lithium iodide and ferrous iodide. The mixed catalyst system completes disproportionation of tall oil rosin in about three hours. Phosphoric acid may be added to remove iron colored impurities when using the mixed catalyst system. Another aspect of the invention involves preparing a soap from the disproportionated rosin by adding a defoamer and a base, such as potassium hydroxide.
    Type: Grant
    Filed: October 19, 1998
    Date of Patent: July 11, 2000
    Assignee: Georgia-Pacific Resins, Inc.
    Inventor: Jalandar Y. Jadhav
  • Patent number: 6034210
    Abstract: Disclosed is a process for producing a highly reactive modified phenolic resin, which comprises mixing a heavy oil or pitch with 0.3 to 10 mol of a phenol, 0.2 to 9 mol in terms of formaldehyde, of a formaldehyde compound and 0.01 to 3.0 mol of an acid catalyst, each amount being based on 1 mol of the heavy oil or pitch calculated from an average molecular weight; and heating the resulting mixture with stirring, thereby to polycondensate the heavy oil or pitch, phenol and formaldehyde compound. According to this invention, there can be provided a process for producing simply and stably a highly reactive modified phenolic resin having low melt viscosity, excellent heat resistance and high reactivity with an epoxy resin, in one step.
    Type: Grant
    Filed: February 17, 1998
    Date of Patent: March 7, 2000
    Assignee: Kashima Oil Co., Ltd.
    Inventors: Masao Tashima, Hiromi Miyasita, Haruhiko Takeda, Tomoaki Fujii, Tatsushi Ishizuka, Makoto Hasegawa
  • Patent number: 5716623
    Abstract: Isolated viral proteins, and compositions made therefrom, are disclosed which are capable of binding to Class II Major Histocompatibility Complex antigen, thereby functioning to inhibit an antigen-specific response. The isolated viral proteins also act as superantigens.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: February 10, 1998
    Assignee: Immunex Corporation
    Inventors: Zhengbin Yao, Melanie K. Spriggs, Mark Alderson, Richard J. Armitage
  • Patent number: 5698668
    Abstract: Toluene-soluble modified natural-resin acid esters which can be prepared by reacting at least one compound from each of the component groups: A) natural resins or natural-resin acids; B) .alpha.,.beta.-ethylenically unsaturated carboxylic acids or their anhydrides; C) phenols which are polyfunctional with respect to oxo compounds; D) aldehydes or aldehyde acetals; E) alcohols having at least two hydroxyl groups; and, if desired, further compounds from the substance groups: F) fatty acids or fatty acid esters; G) ethylenically unsaturated monomers; H) ethylenically unsaturated hydrocarbon resins in the presence of: I) monovalent or divalent metal compounds or mixtures thereof at a temperature of from 100.degree. to 300 .degree. C., with elimination of water, to an acid number of less than 100 mg of KOH/g of resin, and then reacting the resulting products with: J) carboxylic acids which contain at least two carboxyl groups and are not .alpha.,.beta.
    Type: Grant
    Filed: June 3, 1996
    Date of Patent: December 16, 1997
    Assignee: Vianova Resins GmbH
    Inventor: Albert Bender
  • Patent number: 5594099
    Abstract: A modified resinate prepared by reactingA) rosins or rosin acids withB) aldehyde components and optionallyC) .alpha.,.beta.-olefinically unsaturated carboxylic acids or anhydrides thereof, subsequently reacting the resultant adduction products withD) phenols and optionallyE) alcohols containing at least two hydroxyl groups and subsequently forming resinates withF) basic compounds of divalent metals, useful as resin binders of high viscosity in low solid printing inks for intaglio printing of illustrations.
    Type: Grant
    Filed: March 31, 1995
    Date of Patent: January 14, 1997
    Assignee: Hoechst Aktiengesellschaft
    Inventor: Albert Bender
  • Patent number: 5395920
    Abstract: The present invention relates to a process for preparing a rosin ester, which comprises esterifying a purified product of a disproportionated rosin with an alcohol, and then subjecting the esterified rosin to dehydrogenation in the presence of a dehydrogenating catalyst, a process for preparing a rosin ester, which comprises heating a purified rosin and an alcohol in the presence of a disproportionating catalyst, simultaneously subjecting the resulting rosin to disproportionation and esterification, dehydrogenating the reactant in the presence of a dehydrogenating catalyst, and thereafter adding an organic phosphorus compound to the reaction system, a process for preparing a colorless rosin, which comprises simultaneously subjecting a purified rosin to disproportionation and dehydrogenation in the presence of a catalyst, and then adding an organic phosphorus compound to the reaction system and a process for preparing a colorless rosin, which comprises dehydrogenating a purified disproportionated rosin in the
    Type: Grant
    Filed: July 26, 1994
    Date of Patent: March 7, 1995
    Assignee: Arakawa Kagaku Kogyp Kabushiki Kaisha
    Inventors: Masao Maeda, Yukiharu Yamada, Yutaka Koba
  • Patent number: 5175250
    Abstract: A process for the production of a stabilized rosin and a stabilized rosin obtainable by the process. According to the process rosin is heated in the presence of a phosphoric acid or a strong acid in combination with a phosphate containing substance and disproportionated by addition of iodine. Preferably the rosin is first heated in the presence of the phosphoric acid or the strong acid in combination with the phosphate containing substance and thereafter disproportionated by the addition of iodine. Iodine is preferably added in at least two steps and the disproportionation is allowed to proceed between each step. The stabilized rosin can be used as a tackifier resin in adhesives and as a sizing agent for paper, paper boards and similar products.
    Type: Grant
    Filed: July 9, 1991
    Date of Patent: December 29, 1992
    Assignee: Eka Nobel
    Inventor: John C. Hazen
  • Patent number: 5073623
    Abstract: A rosin based condensation product produced by reacting in a multistage process the following reactants, rosin, phenolic compounds, formaldehyde, unsaturated C.sub.3 -C.sub.4 dicarboxylic acid or maleic anhydride, monounsaturated or polyunsaturated aliphatic monohydric or dihydric alcohol or amine or a monounsaturated or polyunsaturated C.sub.2 -C.sub.12 aminoalcohol or C.sub.2 -C.sub.12 alkanediol or C.sub.2 -C.sub.12 aminoalcohol, monounsaturated or polyunsaturated C.sub.8 C.sub.40 fatty acid.
    Type: Grant
    Filed: September 6, 1989
    Date of Patent: December 17, 1991
    Assignee: BASF Lacke+Farben Aktiengesellschaft
    Inventors: Bernhard Prantl, Rolf Walz, Erwin Stark
  • Patent number: 5021548
    Abstract: The color stability of rosin esters is improved by carrying out the esterification reaction in the presence of 0.05% to 5% sodium hydroxymethane sulfonate (SHS). The color stability of polymerized rosin is improved by heating at a temperature of 250.degree.-290.degree. C. in the presence of SHS.
    Type: Grant
    Filed: January 22, 1990
    Date of Patent: June 4, 1991
    Assignee: Hercules Incorporated
    Inventor: James Minn
  • Patent number: 4996258
    Abstract: The present invention relates to a hydroformylated thermal oil which is useful as a total or partial replacement for extender or processing oil in rubber formulations. The hydroformylated thermal oil is prepared by reacting decarboxylated rosin acid with carbon monoxide and hydrogen under hydroformylation conditions in the presence of a hydroformylation catalyst and organic reaction solvent.
    Type: Grant
    Filed: September 5, 1989
    Date of Patent: February 26, 1991
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Lawson G. Wideman, Paul H. Sandstrom
  • Patent number: 4992537
    Abstract: A novel 92-kDa type IV collagenase has been purified to homogeneity from SV-40 transformed fetal lung fibroblasts, its primary structure determined and characterized and a cDNA clone representing the full size protein has been developed.
    Type: Grant
    Filed: May 15, 1989
    Date of Patent: February 12, 1991
    Assignee: Washington University
    Inventors: Gregory I. Goldberg, Arthur Z. Eisen