The Alkylene, Alkenyl Or Alkenylene And The Ring Are Both Bonded Directly To The Same Sulfonyl Group Patents (Class 534/642)
  • Patent number: 5849887
    Abstract: Dye mixtures comprising at least one reactive dye of formula ##STR1## together with at least one reactive dye of formula ##STR2## give dyeings having good fastness properties on nitrogen-containing or hydroxyl group-containing fiber materials.
    Type: Grant
    Filed: March 30, 1998
    Date of Patent: December 15, 1998
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Urs Lehmann, Rolf Deitz, Hans Reichert, Athanassios Tzikas
  • Patent number: 5847090
    Abstract: A monoazo compound useful for dyeing or printing a fiber material represented by the following general formula (I): ##STR1## wherein R.sup.1 represents a hydrogen atom or alkyl; U.sup.1 and U.sup.2 represent a group of the following general formula (U1), (U2) or (U3): ##STR2## wherein Y.sup.1, Y.sup.2 and Y.sup.3 represent --CH.dbd.CH.sub.2 or --CH.sub.2 CH.sub.2 Z wherein Z represents a group which can be eliminated by the action of an alkali; and X.sup.1 and X.sup.2 represent halogeno, pyridinio or a group of the following general formula (X1), (X2), (X3) or (X4): ##STR3## or a salt thereof.
    Type: Grant
    Filed: June 4, 1997
    Date of Patent: December 8, 1998
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Nobutaka Kunimi, Atsushi Inoue, Toshiyuki Araki
  • Patent number: 5831039
    Abstract: Fiber reactive azo dyes of the Formula (1) ##STR1## wherein the variables are as defined in the specification are useful for the dyeing of hydroxy- and carboxamido-containing materials, especially textile fiber materials, in clear shades with a high degree of fixation.
    Type: Grant
    Filed: April 15, 1998
    Date of Patent: November 3, 1998
    Assignee: DyStar Textilfarben GmbH & Co. Deutschland KG
    Inventor: Christian Schumacher
  • Patent number: 5817779
    Abstract: Described are compounds of formula ##STR1## which are suitable as fibre-reactive dyes for dyeing and printing a very wide range of different fibre materials.
    Type: Grant
    Filed: January 15, 1997
    Date of Patent: October 6, 1998
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Rolf Deitz, Paul Herzig, Athanassios Tzikas
  • Patent number: 5801230
    Abstract: Azo reactive dyestuffs have the following formulaD.sup.1 --N.dbd.N--K.sup.1 --Y--K.sup.2 --N.dbd.N--D.sup.2 (1)wherethe radicals D.sup.1 and D.sup.2 are identical or different and are the radical of a diazo component of the formulaXSO.sub.2 --B--D-- (2).
    Type: Grant
    Filed: May 22, 1996
    Date of Patent: September 1, 1998
    Assignee: Bayer Aktiengesellschaft
    Inventors: Horst Jager, Frank-Michael Stohr
  • Patent number: 5795971
    Abstract: The novel aminomethylnaphthalenecarboxylic acid dyestuffs of the formula (I) ##STR1## in which the substituents and indices have the meaning given in the description, are outstandingly suitable for dyeing cellulosic materials, in particular paper.
    Type: Grant
    Filed: September 2, 1997
    Date of Patent: August 18, 1998
    Assignee: Bayer Aktiengesellschaft
    Inventor: Klaus Kunde
  • Patent number: 5789557
    Abstract: Reactive dyes of the formula ##STR1## where n is 1 or 2,R.sup.1 is hydrogen or hydroxysulfonyl,R.sup.2 is hydrogen or hydroxyl,R.sup.3 is substituted C.sub.1 -C.sub.4 -alkyl, C.sub.5 -C.sub.7 -cycloalkyl or substituted phenyl,R.sup.4 is hydrogen or R.sup.3 and R.sup.4, together with the nitrogen atom linking them, form a heterocyclic radical andD is a radical of a diazo or tetrazo component, each having at least one mechanism,their use for dyeing or printing hydroxyl-containing or nitrogen-containing organic substrates, and novel aminonaphthalenes.
    Type: Grant
    Filed: March 27, 1997
    Date of Patent: August 4, 1998
    Assignee: Basf Aktiengesellschaft
    Inventors: Jurgen Dornhagen, Heike Kilburg, Manfred Patsch, Hermann Loffler, Ortwin Schaffer
  • Patent number: 5780602
    Abstract: Mixtures of fiber-reactive azo dyestuffs with which black dyeings, including prints, are obtained on fiber materials containing hydroxy and/or carboxamide groups, such as cellulosic fiber materials, wool and synthetic polyamide fibers, are described. These dyestuffs mixtures comprise one or more dyestuffs of the following formulae (1) and (2): ##STR1## in which the substituents have the meaning given in the specification.
    Type: Grant
    Filed: September 5, 1997
    Date of Patent: July 14, 1998
    Assignee: Pystar Textilfarben GmbH & Co. KG
    Inventors: Christian Schumacher, Werner Hubert Russ
  • Patent number: 5770709
    Abstract: Water-soluble azo compounds, processes for their preparation and their use as dyestuffs.Water-soluble azo compounds are described which have fiber-reactive properties and are suitable as dyestuffs for dyeing material, in particular fiber material, containing hydroxy and/or carboxamide groups, such as, for example, cellulosic fiber materials, such as those of cotton, wool or nylon, and which have, as the radical of a diazo component, a radical of the formula ##STR1## in which R is hydrogen, alkyl having 1 to 4 carbon atoms, alkoxy having 1 to 4 carbon atoms, halogen or sulfo, R.sup.o is hydrogen, alkyl having 1 to 4 carbon atoms, halogen, carboxy, aminocarbonyl, alkoxycarbonyl having 2 to 5 carbon atoms, sulfo or phenyl and R.sup.10 is hydrogen, alkyl having 1 to 4 carbon atoms or halogen, and which contain a fiber-reactive radical bonded to the coupling component via an amino group.
    Type: Grant
    Filed: September 8, 1997
    Date of Patent: June 23, 1998
    Assignee: DyStar Textilfarben GmbH & Co Deutschland KG
    Inventor: Christian Schumacher
  • Patent number: 5756690
    Abstract: A red reactive dye having the following formula (I) in its free acid form: ##STR1## wherein X is --CH.dbd.CH.sub.2 or --C.sub.2 H.sub.4 W (wherein W is a group splittable by alkali), A is a C.sub.2-3 alkylene group or a C.sub.2-3 alkylenoxy C.sub.2-3 alkylene group, E is a hydrogen atom, a C.sub.1-3 alkyl group or --A--SO.sub.2 X (wherein A and X are as defined above), n is 0 or 1, l is 1 or 2, m is 0 or 1, and R is a hydrogen atom, --OH, --CN, --CH.sub.3, --CF.sub.3, --SO.sub.3 H, --COOH, --CH.sub.2 SO.sub.3 H or --CH.sub.2 SO.sub.2 X (wherein X is as defined above), provided that a compound of the formula (I) wherein R is a hydrogen atom, each of m and n is 0, l is 1, and --SO.sub.2 X is --SO.sub.2 CH.dbd.CH.sub.2 which is bonded at the ortho position to the azo group, is excluded.
    Type: Grant
    Filed: April 25, 1996
    Date of Patent: May 26, 1998
    Assignee: DyStar Japan Ltd.
    Inventors: Toshio Hihara, Yousuke Takahashi
  • Patent number: 5717078
    Abstract: Reactive dyes of the formula ##STR1## in which R.sub.1, R.sub.2, R.sub.3 and R.sub.4 independently of one another are hydrogen or substituted or unsubstituted C.sub.1 -C.sub.4 alkyl,X.sub.1 and X.sub.2 are halogen,B.sub.1 is an aromatic or aliphatic bridge member, or the radical of the formula --N(R.sub.2)--B.sub.1 --N(R.sub.3)-- is a piperazine radical,A.sub.1 is the radical of a monoazo, polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan or dioxazine chromophore and,A.sub.2 is a radical of the formula ##STR2## in which D.sub.1 is substituted or unsubstituted phenyl or naphthyl,R.sub.5 and R.sub.6 independently of one another are hydrogen or substituted or unsubstituted C.sub.1 -C.sub.4 alkyl, alk is substituted or unsubstituted C.sub.2 -C.sub.6 alkylene andZ is vinyl or a radical --CH.sub.2 --CH.sub.2 --U.sub.1, and U.sub.1 is a leaving group, andthe radicals A.sub.1 and A.sub.
    Type: Grant
    Filed: August 22, 1996
    Date of Patent: February 10, 1998
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Athanassios Tzikas, Peter Aeschlimann
  • Patent number: 5717077
    Abstract: A phthalocyanine monoazo compound which is represented by the following formula (I): ##STR1## wherein Pc represents a phthalocyanine group; M represents nickel, cobalt or copper;R.sub.1 represents a hydrogen atom or a lower alkyl group;R.sub.2 and R.sub.3 represent a hydrogen atom, a lower alkyl group, a lower alkoxy group or a sulfo group;R.sub.4 represents a hydrogen or a lower alkyl group;A represents a group containing a triazine group or a pyrazole group and/or --SO.sub.2 X wherein X represents --CH.dbd.CH.sub.2 or --CH.sub.2 CH.sub.2 Y and Y represents a group splittable by the action of an alkali;p is a number of 0-2; q is a number of 1-3; r is a number of 1-2; p+q+r is 4 or lessor which is a salt of the compound of formula (I).
    Type: Grant
    Filed: December 11, 1995
    Date of Patent: February 10, 1998
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Toshiyuki Araki, Takemi Tokieda, Shin-ichi Yabushita, Yasuyoshi Ueda, Bunzi Tsukise
  • Patent number: 5712376
    Abstract: Described are compounds of formula ##STR1## which are suitable as fiber-reactive dyes for dyeing a wide range of fiber materials.
    Type: Grant
    Filed: August 20, 1996
    Date of Patent: January 27, 1998
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Edmond Ruhlmann, Laszlo Fekete
  • Patent number: 5703215
    Abstract: A process for the coloration of a substrate, especially a textile, comprising the steps of:(a) applying to the substrate a mixture comprising an aqueous solvent and a water-soluble dye comprising molecules which contain a nucleophilic group and an electrophilic group; and(b) heating or basifying or heating and basifying the dye thereby causing molecules of the dye to join together.Also claimed are dyes, polymers and oligomers.
    Type: Grant
    Filed: May 30, 1995
    Date of Patent: December 30, 1997
    Assignee: Zeneca Limited
    Inventors: Andrew Hunter Morris Renfrew, Andrew Paul Shawcross
  • Patent number: 5696241
    Abstract: Novel sulfonated quinolone compounds used in the preparation of fiber reactive dyes having the formula: ##STR1## being N-alkyl substituted-4-hydroxy-6-sulfo-2-quinolone. The alkyl group bonded to the nitrogen in the quinolone has from 1 to 4 carbon atoms which may be further substituted by an hydroxy, amino, or sulfo group. The compounds of the invention may be prepared by the sulfonation of an N-alkyl substituted-4-hydroxy-2-quinolones, ##STR2## followed by selective desulfonation to yield the compounds of interest. New monoazo fiber reactive dyes having the formulas: ##STR3## and their metal complexes, may be prepared from these sulfonated compounds by the diazotization of an amine component, selected from an unsubstituted, or a substituted benzene or naphthalene compound, containing a fiber reactive group, and coupling the diazo component to the compounds of the invention.
    Type: Grant
    Filed: January 15, 1997
    Date of Patent: December 9, 1997
    Assignee: Dystar, L.P.
    Inventors: Philomen Z. deCroos, Ronald P. Pedemonte, Thomas S. Phillips
  • Patent number: 5686584
    Abstract: Compounds of the formula ##STR1## in which the variables are as defined in the claims, and which are suitable as fibre-reactive dyes for dyeing and printing widely varying fibre materials, are described.
    Type: Grant
    Filed: November 15, 1995
    Date of Patent: November 11, 1997
    Assignee: Ciba-Geigy Corporation
    Inventors: Rolf Deitz, Bernhard Muller, Athanassios Tzikas
  • Patent number: 5681937
    Abstract: Reactive dyes of the formula ##STR1## where n is 1 or 2R.sup.1 is hydrogen or hydroxyl andD is the radical of a diazo or tetrazo component with, in each case, at least one anchor radical of the formula SO.sub.2 --Y where Y is vinyl or substituted ethyl,and the use thereof for dyeing or printing organic substrates having hydroxyl groups or nitrogen atoms are described.
    Type: Grant
    Filed: March 26, 1996
    Date of Patent: October 28, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Manfred Patsch, Heike Kilburg, Andrea Zamponi
  • Patent number: 5629410
    Abstract: The invention relates to compounds of formula ##STR1## wherein the variables are as claimed in the claims and which are suitable as fibre-reactive dyes for dyeing a wide range of fibre materials.
    Type: Grant
    Filed: October 11, 1995
    Date of Patent: May 13, 1997
    Assignee: Ciba-Geigy Corporation
    Inventors: Rolf Deitz, Bernhard M uller, Athanassios Tzikas
  • Patent number: 5614613
    Abstract: A compound of the Formula (1) and salts thereof: ##STR1## wherein: R.sup.1 and R.sup.2 are each independently optionally substituted alkyl;R.sup.3 is H or optionally substituted alkyl;X is a labile atom or group;Y is a labile atom or group or a group of formula ##STR2## or --OR.sup.5 ; R.sup.4 is H or alkyl;R.sup.5 is H or optionally substituted alkyl or aryl; andm and n each independently have a value of 0 or 1.The compounds are useful for the coloration of textile materials.
    Type: Grant
    Filed: March 3, 1994
    Date of Patent: March 25, 1997
    Assignee: Zeneca Limited
    Inventor: John A. Taylor
  • Patent number: 5597904
    Abstract: Reactive dyes of formula ##STR1## wherein Z is a group of formula --CH.dbd.CH.sub.2 or --CH.sub.2 --CH.sub.2 --Y, and Y is a leaving group, and K is a radical of formula ##STR2## wherein X is a radical of formula --(CH.sub.2).sub.n --Cl, ##STR3## or --CH.dbd.CH.sub.2 ; Hal is halogen; and n is 1, 2, 3 or 4; R is hydrogen or unsubstituted or substituted C.sub.1 -C.sub.4 alkyl; R.sub.1 is amino or hydroxyl; R.sub.2 is methyl or carboxyl; and R.sub.3 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.2 -C.sub.4 alkanoylamino, halogen or carboxyl, are particularly suitable for dyeing or printing cellulosic fibre materials or natural or synthetic polyamide fibre materials in high tinctorial yield, and give dyeings and printings with good fastness properties.
    Type: Grant
    Filed: March 12, 1996
    Date of Patent: January 28, 1997
    Assignee: Ciba-Geigy Corporation
    Inventors: Athanassios Tzikas, Claudia Carisch
  • Patent number: 5596083
    Abstract: A monoazo compound suitable for dyeing or printing materials having a hydroxy group and/or amide group represented by the following general formula (I): ##STR1## wherein D represents a phenyl or naphthyl group; A represents a group represented by the following formula: ##STR2## or A represents a group represented by the following formula: ##STR3## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7, R.sub.8, R.sub.9, n and Y have the meaning given in the specification; and salts thereof.
    Type: Grant
    Filed: December 26, 1995
    Date of Patent: January 21, 1997
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Nobutaka Kunimi, Yasuyoshi Ueda, Takashi Omura
  • Patent number: 5569748
    Abstract: There are described novel monoazo dyes of the below-indicated and formula (1) which have fiber-reactive properties and are used as dyes for dyeing hydroxy- and/or carboxamido-containing material, in particular fiber material, such as wool and synthetic polyamide and in particular cellulose fiber materials, such as cotton. ##STR1## X, Y, M and m are as defined in claim 1.
    Type: Grant
    Filed: July 28, 1994
    Date of Patent: October 29, 1996
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Uwe Reiher, Werner H. Russ
  • Patent number: 5565553
    Abstract: Reactive dyes of the formula ##STR1## where A, K and Z are each as defined in the claims, are especially useful for dyeing or printing cellulosic fiber materials, producing dyeings and prints having good fastness properties in a high yield.
    Type: Grant
    Filed: January 11, 1996
    Date of Patent: October 15, 1996
    Assignee: Ciba-Geigy Corporation
    Inventors: Rolf Deitz, Paul Herzig, Athanassios Tzikas
  • Patent number: 5559215
    Abstract: Black fiber-reactive azo dye mixtures and use thereof for dyeing hydroxy- and/or carboxamido-containing fiber materialMixtures of fiber-reactive dyes are described which can be used to obtain deep black dyeings and prints on hydroxy- and/or carboxamido-containing fiber materials such as cellulose fiber materials, wool and synthetic polyamide fibers by the application methods which are customary in the art for fiber-reactive dyes. The dye mixtures comprise one or more disazo dyes of the formula (1) and one or more monoazo dyes of the formula (2) ##STR1## in which M is hydrogen or an alkali metal, R.sup.o is sulfo or carboxyl, R.sup.1 is hydrogen, methyl, ethyl, methoxy, ethoxy, sulfo or carboxy , R.sup.2 is hydrogen, methyl, ethyl, methoxy or ethoxy, Y is at each occurrence independently of the others vinyl, .beta.-chloroethyl, .beta.-phosphatoethyl, .beta.-thiosulfatoethyl or .beta.
    Type: Grant
    Filed: April 28, 1995
    Date of Patent: September 24, 1996
    Assignee: Hoechst Aktiengesellschaft
    Inventors: J org Dannheim, Werner H. Russ
  • Patent number: 5539088
    Abstract: Water-soluble azo compounds are described which possess fiber-reactive properties and which are suitable as dyes for the dyeing of material, in particular fiber material, which contains hydroxy and/or carboxamido groups, examples being cellulosic fiber materials such as cotton, wool and nylon, and which compounds possess, as the radical of a diazo component, a radical of the formula ##STR1## in which R is hydrogen, alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, halogen or sulfo and G forms to the benzene ring the radical of a heterocycle which is free from olefinic double bonds and which contains at least one carboxamide group of the formula --CO--N(R.sup.10)-- in which R.sup.
    Type: Grant
    Filed: February 2, 1995
    Date of Patent: July 23, 1996
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Christian Schumacher, Werner H. Russ
  • Patent number: 5532345
    Abstract: Compounds of the formula ##STR1## in which the variables are as defined in the claims, which are suitable as fibre-reactive dyes for dyeing or printing widely varying fibre materials, are described.
    Type: Grant
    Filed: May 26, 1995
    Date of Patent: July 2, 1996
    Assignee: Ciba-Geigy Corporation
    Inventors: Paul Herzig, Anton Andreoli
  • Patent number: 5530104
    Abstract: Reactive dyes of the formula ##STR1## in which K and Z are as defined in claim 1, are suitable in particular for the dyeing and printing of cellulose-containing fibre material and produce dyeings and prints having good fastness properties in high coloristic yield.
    Type: Grant
    Filed: October 18, 1994
    Date of Patent: June 25, 1996
    Assignee: Ciba-Geigy Corporation
    Inventors: Athanassios Tzikas, Claudia Carisch
  • Patent number: 5523397
    Abstract: Reactive dyes of formula ##STR1## wherein Z is a group of formula --CH.dbd.CH.sub.2 or --CH.sub.2 --CH.sub.2 --Y, and Y is a leaving group, and K is a radical of formula ##STR2## wherein X is a radical of formula ##STR3## Hal is halogen; and n is 1, 2, 3 or 4; R is hydrogen or unsubstituted or substituted C.sub.1 -C.sub.4 alkyl; R.sub.1 is amino or hydroxyl; R.sub.2 is methyl or carboxyl; and R.sub.3 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.2 -C.sub.4 alkanoylamino, halogen or carboxyl, are particularly suitable for dyeing or printing cellulosic fiber materials or natural or synthetic polyamide fiber materials in high tinctorial yield, and give dyeings and printings with good fastness properties.
    Type: Grant
    Filed: October 7, 1994
    Date of Patent: June 4, 1996
    Assignee: Ciba-Geigy Corporation
    Inventors: Athanassios Tzikas, Claudia Carisch
  • Patent number: 5510468
    Abstract: There are described benzophenoneazo dyes of the formula ##STR1## where the ring A can be benzofused and a benzofused ring A can be overbridges,m is 1 or 2,K is the radical of a coupling component,Y is hydrogen or arylazo,one of the two radicals X.sup.1 and X.sup.2 is hydrogen and the other is hydroxysulfonyl,R.sup.1, R.sup.2 and R.sup.3 are independently of the others hydrogen, halogen, C.sub.1 -C.sub.12 -alkyl, cyclohexyl, phenyl, 2-hydroxy-ethylsulfonyl or C.sub.1 -C.sub.4 -alkoxy or, when m is 1 and Y is hydrogen, one of these substituents can also be the radical of the formula ##STR2## where L.sup.1 is a chemical bond or a bridge member, and X.sup.1, X.sup.2, R.sup.4, K and the ring A are each as defined above, andR.sup.4 is hydrogen, halogen or C.sub.1 -C.sub.
    Type: Grant
    Filed: July 27, 1994
    Date of Patent: April 23, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Gunther Lamm, Helmut Reichelt, Ortwin Schaffer
  • Patent number: 5508389
    Abstract: If highly concentrated aqueous solutions of azo dyes are prepared directly by diazotization and coupling reactions, appreciable difficulties generally result as a consequence of the fact that the diazotization and coupling reactions give rise to viscous phases which lead to stirring problems in the reaction apparatus used, which in turn results in an incomplete synthesis. The novel process for preparing concentrated aqueous dye solutions of an anionic dye in an aqueous medium overcomes this disadvantage by carrying out the diazotization of the aromatic amine diazo component and/or the coupling reaction between the diazonium salt and the coupling component in the presence of an auxiliary which exerts a viscosity-reducing effect on pasty phases. Examples of such auxiliaries are optionally alkyl-substituted naphthalenesulfonic acid-formaldehyde condensation products, ligninsulfonates, polyacrylates and copolymers of maleic anhydride and methacrylic acid or acrylic acid.
    Type: Grant
    Filed: March 26, 1993
    Date of Patent: April 16, 1996
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Peter Mischke, Kurt Hohmann, Eckhard Schwab, Manfred Sittig
  • Patent number: 5502174
    Abstract: Fibre-reactive dyestuffs based on barbituric acid, of the following formula ##STR1## wherein the substituents have the meaning given in the description, are distinguished by improved properties.
    Type: Grant
    Filed: August 25, 1994
    Date of Patent: March 26, 1996
    Assignee: Bayer Aktiengesellschaft
    Inventors: Stefan Ehrenberg, Aloysius Engel, Hermann Henk
  • Patent number: 5493010
    Abstract: The dyestuffs of the formula ##STR1## in which D is the radical of a diazo component,SO.sub.2 X is the radical of a fibre-reactive group,and the remaining substituents have the meaning given in the descriptionare suitable for dyeing and printing hydroxyl- and amido-containing materials.
    Type: Grant
    Filed: March 17, 1994
    Date of Patent: February 20, 1996
    Assignee: Bayer Aktiengesellschaft
    Inventors: Karl-Josef Herd, Konrad Bootz, Eckhard Bock, Manfred Hoppe, Klaus Kunde, Wolfram Reddig
  • Patent number: 5488098
    Abstract: A monoazo compound of the following formula, ##STR1## wherein D is phenylene or naphthylene; X is halogeno, pyridinio or ##STR2## B is --OR.sub.3, --SR.sub.4, ##STR3## in which R.sub.3, R.sub.4, R.sub.5 and R.sub.6 are each hydrogen, alkyl, phenyl, naphthyl or benzyl, r is 0 or 1, and E is O, SO, SO.sub.2, CH.sub.2 or NR.sub.8, in which R.sub.8 is hydrogen or C.sub.1 -C.sub.4 alkyl; R, R.sub.1, R.sub.2 and R.sub.7 are each hydrogen or alkyl; A.sub.1, A.sub.2 and A.sub.3 are each phenylene, naphthylene or alkylene; Z.sub.1, Z.sub.2 and Z.sub.3 are each --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 CH.sub.2 Y, in which Y is a splittable group; and p is 0 or 1; which compound is useful for dyeing or printing fiber materials to obtain a product dyed or printed in a color superior in various fastness properties with superior build-up property.
    Type: Grant
    Filed: February 7, 1994
    Date of Patent: January 30, 1996
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Masayuki Miki, Kingo Akahori, Yutaka Kayane, Takeshi Washimi
  • Patent number: 5488101
    Abstract: Herein is provided a trisazo compound represented by formula (I) in the free acid form: ##STR1## wherein Q.sub.1 is an unsubstituted or substituted phenylene or naphthylene group, Q.sub.2 is an unsubstituted or substituted phenyl or naphthyl group, Z is --SO.sub.2 CH.sub.2 CH.sub.2 OH or --SO.sub.2 CH.sub.2 CH.sub.2 SO.sub.3 H group, and L is 0 or 1. The trisazo compound provided herein is excellent in solubility and gives deep colored dyed product or image when used in dyeing or printing, so that it is useful as a dye and an ink. Herein are also provided a method for dyeing fiber materials, paper or leather by using said trisazo compound, and an ink containing said trisazo compound.
    Type: Grant
    Filed: June 5, 1992
    Date of Patent: January 30, 1996
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Kazuya Ogino, Kingo Akahori, Naoki Harada, Yutaka Kayane, Hideo Kawashita, Mituhiro Ohta
  • Patent number: 5484899
    Abstract: The invention relates to compounds of the formula ##STR1## in which the variables are as defined in the claims. The compounds are suitable as dyes, in particular for dyeing and printing cellulosic fibre materials, and produce dyeings and prints with good all-round fastness properties.
    Type: Grant
    Filed: May 3, 1994
    Date of Patent: January 16, 1996
    Assignee: Ciba-Geigy Corporation
    Inventors: Rolf Deitz, Athanassios Tzikas
  • Patent number: 5480976
    Abstract: Reactive dyes of formula ##STR1## wherein X, Z, R.sub.1, R.sub.2, R.sub.3, R.sub.4 and m are as defined in claim 1, are particularly suitable for dyeing or printing cellulosic fiber materials or natural or synthetic polyamide fiber materials in high tinctorial yield, and give dyeings and prints with good fastness properties.
    Type: Grant
    Filed: October 7, 1994
    Date of Patent: January 2, 1996
    Assignee: Ciba-Geigy Corporation
    Inventors: Athanassios Tzikas, Claudia Carisch
  • Patent number: 5478927
    Abstract: A bisazo compound of the following formula: ##STR1## wherein R.sup.1 and R.sup.3 are each hydrogen or alkyl; D is phenylene or naphthylene; one of X.sup.1 and X.sup.2 is NH.sub.2 and the other is OH; Z.sup.1 and Z.sup.2 are each --CH.dbd.CH.sub.2 or --CH.dbd.CH.sub.2 Z' in which Z' is a splittable group; B is monosulfophenylene, monosulfophenylene-methylene or mono- or di-sulfonaphthylene-methylene; U is phenylene or an aliphatic bridging group; and J is an amono-derivative group or, J may be alkoxy when X.sup.1 is OH and U is phenylene, and J may be alkoxy or phenoxy when X.sup.1 is OH and U is the aliphatic bridging group. This compound is useful for dyeing or printing fiber materials and gives a dyed or printed product having a color superior in various fastness properties with superior build-up property.
    Type: Grant
    Filed: January 31, 1994
    Date of Patent: December 26, 1995
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Sigeru Sasaki, Kingo Akahori, Takeshi Washimi, Takashi Omura, Toshiyuki Araki, Atsushi Inoue
  • Patent number: 5463032
    Abstract: A bisazo compound represented by the formula (I) in the free acid form, ##STR1## wherein D is unsubstituted or substituted phenyl or naphthyl; A and B are independently unsubstituted or substituted phenylene or naphthylene; R is hydrogen or unsubstituted or substituted lower alkyl; X is aromatic amino residue or aliphatic amino residue; arid Y is a group represented by the formula, ##STR2## wherein R.sup.1 is hydrogen or unsubstituted or substituted alkyl, W.sub.0 is unsubstituted or substituted alkylene; and Z is vinyl or --CH.sub.2 CH.sub.2 Z.sub.1, in which Z.sub.1 is a group capable of being split by the action of an alkali; is a reactive dye useful for dyeing or printing fiber materials having hydroxy groups and/or amide groups to brown or violet color, and can provide dyed or printed products with superior fastness properties and dyeing properties such as build-up property.
    Type: Grant
    Filed: November 23, 1993
    Date of Patent: October 31, 1995
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Kingo Akahori, Yoshiteru Ohta, Takashi Omura, Mahito Fujita, Naoki Harada
  • Patent number: 5463033
    Abstract: A monoazo fiber reactive dye of the formula: ##STR1## wherein X and Y are independently selected from .beta.-sulfatoethyl, .beta.-thiosulfatoethyl and .beta.-phosphatoethyl group and R is hydrogen, and C.sub.1 -C.sub.4 alkyl; preferably methyl. These dyes are useful in conducting exhaust dyeings at low dye bath salt concentrations.
    Type: Grant
    Filed: July 13, 1994
    Date of Patent: October 31, 1995
    Assignee: Hoechst Celanase Corporation
    Inventors: John W. Donovan, Frank P. Lavieri
  • Patent number: 5451666
    Abstract: A water-soluble dye having a reactive group of the Formula (1): ##STR1## wherein: R.sup.1 is H or optionally substituted alkyl;R.sup.2 is H or C.sub.1-4 -alkyl;L is a divalent organic spacer group; andV is vinyl or a group convertible to vinyl on treatment with aqueous alkali.The reactive dyes of the present invention are useful for coloring natural and artificial textile materials containing amino or hydroxyl groups.
    Type: Grant
    Filed: June 9, 1993
    Date of Patent: September 19, 1995
    Assignee: Zeneca Limited
    Inventor: Kenneth Anderton
  • Patent number: 5449762
    Abstract: Reactive dyes of the formula I ##STR1## where n is 0 or 1R.sup.1, R.sup.2 and R.sup.3 are in each case hydrogen, C.sub.1 -C.sub.4 -alkyl or phenyl,R.sup.4 is fluorine, chlorine, bromine, C.sub.1 -C.sub.4 -alkylsulfonyl, phenylsulfonyl or a radical of the formula ##STR2## L is a bridge member, A is unsubstituted or substituted C.sub.2 -C.sub.8 -alkylene,Y is vinyl or a radical of the formula --CH.sub.2 --CH.sub.2 --Q, Q being a group which can be removed under alkaline reaction conditions, andD is phenyl or naphthyl, it being possible for these radicals to be substituted, and a process for preparing reactive dyes by oxidation of the abovementioned compounds are described.
    Type: Grant
    Filed: February 1, 1995
    Date of Patent: September 12, 1995
    Assignee: BASF Aktiengesellschaft
    Inventors: Matthias Wiesenfeldt, Bernd Siegel, Manfred Patsch
  • Patent number: 5434252
    Abstract: Reactive dyes of the formula ##STR1## in which D, R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are as defined in claim 1, are particularly suitable for dyeing or printing cellulosic fiber materials or naturally occurring or synthetic polyamide fiber materials with a high tinctorial yield, and produce dyeings and prints having good fastness properties.
    Type: Grant
    Filed: October 25, 1994
    Date of Patent: July 18, 1995
    Assignee: Ciba-Geigy Corporation
    Inventors: Paul Herzig, Athanassios Tzikas, Anton Andreoli, Claudia Carisch
  • Patent number: 5434251
    Abstract: Symmetric azo dyestuffs of the formula ##STR1## wherein the substituents have the meaning given in the description, produce improved dyeings or prints on wool and cellulose materials.
    Type: Grant
    Filed: April 2, 1993
    Date of Patent: July 18, 1995
    Assignee: Bayer Aktiengesellschaft
    Inventor: Karl-Josef Herd
  • Patent number: 5432266
    Abstract: Preparation of water-soluble reactive dyes containing vinylsulphonyl and .beta.-sulphatoethylsulphonyl groups by the oxidation of dyes containing .beta.-hydroxyethylmercapto radicals, and then sulphation and, if appropriate, conversion of the .beta.-sulphatoethylsulphonyl radical to the vinylsulphonyl radical with bases.
    Type: Grant
    Filed: April 1, 1993
    Date of Patent: July 11, 1995
    Assignee: Bayer Aktiengesellschaft
    Inventors: Karl-Josef Herd, Peter Roschger
  • Patent number: 5424405
    Abstract: The fibre-reactive dyes of the formula ##STR1## where the variables are each as defined in the claims, are suitable in particular for dyeing nitrogen-containing and hydroxyl-containing fibre materials.
    Type: Grant
    Filed: November 19, 1993
    Date of Patent: June 13, 1995
    Assignee: Ciba-Geigy Corporation
    Inventors: Jean-Marie Adam, Guido Jordine
  • Patent number: 5420257
    Abstract: A reactive dye comprising a 1,3,5-s-triazine group having a chromophoric group at two of the 2-, 4- and 6-positions and a substituent at the remaining 2-, 4- or 6-position selected from H, optionally substituted alkyl, optionally substituted phenyl, --CH(CO.sub.2 R.sup.1).sub.2, --NR.sup.1 SO.sub.2 R.sup.2, and --SO.sub.2 R.sup.2, wherein each R.sup.1 is H or alkyl and R.sup.2 is alkyl. The reactive dyes may be used for the coloration of textile materials.
    Type: Grant
    Filed: September 17, 1993
    Date of Patent: May 30, 1995
    Assignee: Zeneca Limited
    Inventors: Kenneth Anderton, Andrew P. Shawcross
  • Patent number: 5403920
    Abstract: Reactive dyes of the formula ##STR1## in which A, U, R.sub.1, R.sub.2, Z and n are as defined in claim 1, are particularly suitable for dyeing or printing cellulosic fibre materials or naturally occurring or synthetic polyamide fibre materials with a high tinctorial yield and produce dyeings and prints with good fastness properties.
    Type: Grant
    Filed: July 19, 1993
    Date of Patent: April 4, 1995
    Assignee: Ciba-Geigy Corporation
    Inventors: Herbert Klier, Athanassios Tzikas
  • Patent number: 5391717
    Abstract: Reactive dyes of the formula ##STR1## in which D, R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are as defined in claim 1, are particularly suitable for dyeing or printing cellulosic fiber materials or naturally occurring or synthetic polyamide fiber materials with a high tinctorial yield, and produce dyeings and prints having good fastness properties.
    Type: Grant
    Filed: July 19, 1993
    Date of Patent: February 21, 1995
    Assignee: Ciba-Geigy Corporation
    Inventors: Athanassios Tzikas, Rolf Deitz
  • Patent number: 5391718
    Abstract: Reactive dyes of the formula ##STR1## in which K and Z are as defined in the disclosure, are suitable in particular for the dyeing and printing of cellulose-containing fibre material and produce dyeings and prints having good fastness properties in high coloristic yield.
    Type: Grant
    Filed: February 26, 1993
    Date of Patent: February 21, 1995
    Assignee: Ciba-Geigy Corporation
    Inventors: Athanassios Tzikas, Claudia Carisch
  • Patent number: 5380827
    Abstract: A water-soluble monoazodye having the following formula (I) in its free acid form: ##STR1## wherein X is --CH.dbd.CH.sub.2 or --CH.sub.2 CH.sub.2 W wherein W is a leaving group removable by alkali; R.sup.1 is methyl, --NHCONH.sub.2 or --NHCOT.sup.1 wherein T.sup.1 is methyl, ethyl, --CH.sub.2 CH.sub.2 COOH or --CH.dbd.CHCOOH; R.sup.2 is hydrogen, lower alkyl or lower alkoxy;and Z is ##STR2## wherein P is cyano or halogen, each of Q and U which are independent of each other, is halogen, V is halogen or ##STR3## and Y is halogen or a group of the following formula (1) or (2): ##STR4## wherein R.sup.3, A, R.sup.4 and E are as defined in the disclosure and G is as defined above, has a moderate yellow to orange color and is particularly suitable for dyeing cellulose fibers or nitrogen-containing fibers.
    Type: Grant
    Filed: April 20, 1993
    Date of Patent: January 10, 1995
    Assignee: Hoeshst Mitsubishi Kasei Co., Ltd.
    Inventors: Yousuke Takahashi, Yukiharu Shimizu, Toshio Hihara, Kiyoshi Himeno