The Sulfonyl Or -c(=x)- Is Bonded Directly To The Ring Patents (Class 534/651)
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Patent number: 7750130Abstract: Provided is the azobenzene derivative denoted by general formula (I). In general formula (I), R1 denotes a hydrogen atom or the like; Ar1 and Ar2 each independently denote an arylene group optionally comprising a substituent R or an aromatic heterocycle optionally comprising a substituent R, wherein Ar1 and Ar2 which are bonded through an azo group comprise at least two substituents denoted by R in total and multiple atoms and/or substituents denoted by R may be identical or different; R denotes a halogen atom or the like; X denotes an alkylene group optionally comprising a hetero atom; X1 denotes —NH— or the like; Y denotes a hydrogen atom or the like; a denotes an integer ranging from 0 to 2; and m and n each independently denote an integer ranging from 1 to 8.Type: GrantFiled: May 10, 2007Date of Patent: July 6, 2010Assignee: RikenInventors: Mina Han, Masahiko Hara
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Publication number: 20090314995Abstract: Conducting polymers based on renewable resource materials are very attractive because of their wide availability and lower cost compared to petroleum based products. Here we developed a novel dopant for electrically conducting polyaniline from renewable resource cardanol, the main component of cashew nut shell liquid (CNSL). The novel dopant 2-?-unsaturated-4-hydroxy-4?-sulfinic acid azo benzene or otherwise known as cardanol azo sulfonic acid (1) is synthesized by reaction of diazotized sulphanilic acid (4-aminophenylsulfonicacid) with cardanol under the basic condition. The new cardanol azo sulfonic acid (1) has a long alkyl chains at the 2 positions, which increases the solubility of the dopant as well as polyaniline doped materials in common solvents for many applications.Type: ApplicationFiled: June 30, 2008Publication date: December 24, 2009Inventors: Manickam Jayakannan, Chennakkatu Krishna Sadasivan Pillai, Sundeep Kumar Dhawan, Dinesh Chandra Trivedi, Radhakrishnan Subramaniam
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Patent number: 6730780Abstract: An oil-soluble dye prepared by subjecting a water-soluble dye having at least one group selected from the group consisting of sulfonate group and carboxyl group in its molecule to amidation: a water-based ink comprising the oil-soluble dye: and a process for preparing an oil-soluble dye, comprising halogenating a water-soluble dye having at least one group selected from the group consisting of sulfonate group and carboxyl group in its molecule, and thereafter subjecting the resulting halogenated water-soluble dye to amidation. The Oil-soluble dye of the present invention can be suitably and favorably used for inks for inkjet recording, inks for ball-points pens, inks for markers, toners, paints such as lacquers, inks for felt pens, and the like.Type: GrantFiled: October 19, 2001Date of Patent: May 4, 2004Assignee: Kao CorporationInventors: Shigemi Wakabayashi, Takehiro Tsutsumi, Kenji Kaida, Makoto Sakakibara
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Patent number: 6646111Abstract: Disclosed are compounds of the formula The compounds are useful as colorants, particularly in applications such as phase change inks.Type: GrantFiled: June 27, 2002Date of Patent: November 11, 2003Assignee: Xerox CorporationInventors: Rina Carlini, James M. Duff, Jeffrey H. Banning, Bo Wu, James D. Mayo
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Patent number: 6590082Abstract: Disclosed are compounds of the formula The compounds are useful as colorants, particularly in applications such as phase change inks.Type: GrantFiled: June 27, 2002Date of Patent: July 8, 2003Assignee: Xerox CorporationInventors: Jeffrey H. Banning, Rina Carlini, James D. Mayo, James M. Duff, C. Wayne Jaeger
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Patent number: 6194534Abstract: The invention relates to organopolysiloxanes with dye residues comprising units of the general formula R1a(RO)bAcR2dSiO(4−a−b−c−d)/2 (I) wherein R can be identical or different and is hydrogen atom or monovalent, substituted or unsubstituted hydrocarbon radical, R1 can be identical or different and is hydrogen atom or monovalent, SC-bonded hydrocarbon radical, R2 can be identical or different and is substituted, monovalent, Si—C bonded hydrocarbon radical, A can be identical or different and is a radical of a water-soluble organic dye containing at least one of sulfonic acid groups, sulfonate groups, or metal complexes thereof, a is 0, 1, 2, or 3, b is 0, 1, 2 or 3, d is 0, 1, 2, or 3 and c is 0, 1 or 2 with the proviso that the sum of a, b, c and d is less than or equal to 3, the organopolysiloxanes have at least one radical, and, in the units of the formula (I) where c is other than 0, d is 0.Type: GrantFiled: September 20, 1999Date of Patent: February 27, 2001Assignee: Wacker-Chemie GmbHInventors: Frank Baumann, Gunter Mahr, Bernward Deubzer
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Patent number: 6090927Abstract: The invention relates to novel intermediates in a process for preparing compounds having the formula: ##STR1## wherein R.sub.3, R.sub.4, R.sub.6 and Ar are as defined in the description, by reaction of a compound of formula (I) with a compound of formula (II) according to the following reaction scheme: ##STR2## The compounds of formula (IV) are useful as pesticides.Type: GrantFiled: February 16, 1999Date of Patent: July 18, 2000Assignee: Rhone-Poulenc Inc.Inventor: Peter Wyatt Newsome
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Patent number: 6005085Abstract: The present invention provides novel condensed azo compounds using bisamide compounds of 2-hydroxynaphthalene-3,6-dicarboxylic acid, amide, or ester as the couplers, which have excellent properties such as excellent water resistance, chemical resistance, solvent resistance, and heat resistance.Type: GrantFiled: November 18, 1998Date of Patent: December 21, 1999Assignee: Kabushiki Kaisha Ueno Seiyaku Oyo KenkyujoInventors: Ryuzo Ueno, Masaya Kitayama, Kenji Minami, Hiroyuki Wakamori, Katsunori Tanikawa
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Patent number: 5962656Abstract: A photographic element comprising a support having situated thereon at least one silver halide emulsion layer, the layer containing a photographic coupler represented by the formulaCOUP--T.sup.1 --T.sup.2 --(T.sup.3).sub.b --PUGwhereinCOUP is a coupler moiety having a coupling site to which T.sup.1 is attached;T.sup.1 and T3 are timing or linking groups;T.sup.2 is an indazole timing or linking group which, after release from T.sup.1, functions by electron transfer down a conjugated chain to release T.sup.3 or PUG, and which is represented by the formula: ##STR1## wherein ** denotes the point of attachment to T.sup.1 and *** denotes the point of attachment to T.sup.3 or PUG;R.sup.1 and R.sup.2 are independently selected from hydrogen, or an aliphatic, carbocyclic, or heterocyclic group, or may be bonded together to form a 5, 6, or 7 membered ring;V is independently a substituent group as further defined;q is 0, 1, 2, 3 or 4;b is 0 or 1; andPUG is a photographically useful group.Type: GrantFiled: June 10, 1997Date of Patent: October 5, 1999Assignee: Eastman Kodak CompanyInventors: William James Begley, Teh Hsuan Chen, Donald Singleton, Jr., Frank Dino Coms
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Patent number: 5811530Abstract: There are described image-recording materials which include an image dye-providing compound comprising a novel naphthol azo cyan dye having a 3-aminobenzoisothiazole moiety. The image dye-providing compound includes a diffusion control moiety such as a hydroquinonyl developer group, a precursor thereof or a thiazolidine moiety and, may be diffusible or nondiffusible as a function of the diffusion control moiety.Image-recording materials according to the invention including those which contain high potential developers such as aminoreductone allow sufficient cyan chromophore to diffuse to the image-receiving layer to provide an acceptable photograph and result in no appreciable reduction of the 3-aminobenzoisothiazole moiety of the novel naphthol azo cyan dye.Type: GrantFiled: August 20, 1997Date of Patent: September 22, 1998Assignee: Polaroid CorporationInventors: Michael J. Arnost, Peter Viski, David P. Waller, David C. Whritenour
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Patent number: 5504199Abstract: A dye which is either 2-naphthalenol (phenylazo) phenyl azo alkyl derivatives and 1,4-dialkylamino anthraquinone is added to sufficient non-ionic surfactant to compatibilize it with ethanol and an solvent to produce a homogeneous solution. The homogeneous solution is added to ethanol in an amount to provide a desired amount of coloration to the ethanol.Type: GrantFiled: October 28, 1994Date of Patent: April 2, 1996Assignee: Morton International, Inc.Inventors: Alejandra Zimin, Peter A. Caputo, Michael R. Friswell, David L. Booth, Michael P. Hinton
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Patent number: 5245021Abstract: Named compounds are useful in making dry analytical elements for assaying lithium in serum. The compounds have the general structure: ##STR1## wherein R, R.sub.1, R.sub.2 and X are as presented below:______________________________________ R R.sub.1 R.sub.2 X ______________________________________ n-C.sub.12 H.sub.25 SO.sub.2 CH.sub.3 CH.sub.3 CH n-C.sub.12 H.sub.25 NO.sub.2 CH.sub.3 CH CH.sub.3 SO.sub.2 N(n-C.sub.6 H.sub.13).sub.2 CH.sub.3 CH CH.sub.2 C.sub.6 H.sub.5 SO.sub.2 N(n-C.sub.6 H.sub.13).sub.2 CH.sub.3 CH CH.sub.2 C.sub.6 H.sub.5 SO.sub.2 N(CH.sub.3)-n-C.sub.18 H.sub.37 CH.sub.3 CH CH.sub.3 NO.sub.2 n-C.sub.7 H.sub.15 CH n-C.sub.12 H.sub.25 H CH.sub.Type: GrantFiled: May 28, 1991Date of Patent: September 14, 1993Assignee: Eastman Kodak CompanyInventors: Ronald H. Engebrecht, Thomas R. Welter
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Patent number: 5241058Abstract: Azo dye salts corresponding to formula I are suitable as masking couplers. ##STR1## In Formula I, A denotes an optionally substituted aryl group;CC denotes a group optionally carrying a ballast group and capable of coupling under the conditions of photographic color development to produce a dye preferably a cyan dye (color coupler residue);L denotes a linking member which is attached at the coupling position of the color coupler residue by an oxygen, sulphur or nitrogen atom;Z denotes a group conferring solubility in alkalies;R denotes NH--CO--R.sup.1, NH--SO.sub.2 --R.sup.1, COOR.sup.2 or NR.sup.1 --R.sup.2 ;R.sup.1 denotes an optionally substituted alkyl or aryl group;R.sup.2 denotes H or a group such as R.sup.1 ;[M.sup..sym. ] denotes a mixture of organic and inorganic cations optionally containing protons, in which the proportion of organic cation amounts to at least 1/2 mol per mol of dye;m stands for 0, 1 or 2; andn stands for 1, 2, 3 or 4; n.gtoreq.m.Type: GrantFiled: May 15, 1991Date of Patent: August 31, 1993Assignee: Agfa-Gevaert AktiengesellschaftInventors: Gunter Renner, Hans Langen, Ulrich Klein
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Patent number: 5071967Abstract: Compounds of the formula I ##STR1## in which R is a radical of the formula --OR.sub.5 or --NHR.sub.5, A is a radical of the formula II or III ##STR2## in which B is a radical of the formula ##STR3## in which n is the number 1 or 2, R.sub.1 and R.sub.3 independently of one another are --H or Cl, R.sub.2 and R.sub.4 independently of one another are --H, halogen, --NO.sub.2, --CN, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, --CF.sub.3, C.sub.2 -C.sub.5 alkoxycarbonyl, or --CONH-phenyl, --NHCO-phenyl or phenyloxy which is unsubstituted or substituted on the phenyl nucleus by one or two chlorine atoms or one or two methyl, methoxy or ethoxy groups, R.sub.5 is alkyl having at least 10 C atoms, R.sub.6 and R.sub.7 independently of one another are --H, halogen, --NO.sub.2, --CN, --CF.sub.3, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy, R.sub.8 is --H, --Cl, --Br, --CH.sub.3 or --OCH.sub.3 and X is --H, --Br, --OCH.sub.3, --CN or --NO.sub.2, are particularly suitable as pigments for coloring polyolefins.Type: GrantFiled: February 11, 1991Date of Patent: December 10, 1991Assignee: Ciba-Geigy CorporationInventors: Stefan Hari, Jost von der Crone
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Patent number: 5047516Abstract: An azo compound of the formula: ##STR1## wherein R is an non-hydrophilic aliphatic or cycloaliphatic group containing from 8 to 40 carbon atoms;m is 0 or 1;R.sup.1 is NO.sub.2, CN or COOR.sup.2 ;R.sup.2 is H or C.sub.1-4 -alkyl;n is from 1 to 4 andR.sup.3 is H, a metal or a group containing a tetravalent N atom.The compound has non-linear optical properties which make it suitable for use in an optical element such as a waveguide, for altering the characteristics of light passing through the element.Type: GrantFiled: May 5, 1988Date of Patent: September 10, 1991Assignee: Imperial Chemical Industries PLCInventors: Simon Allen, Paul F. Gordon
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Patent number: 4997920Abstract: Compounds of the formulae I and II ##STR1## in which A is a radical of the formulae III, IV or V ##STR2## R.sub.1 and R.sub.4 are --H or --Cl, R.sub.2 and R.sub.5 are --H, halogen, --NO.sub.2, --CN, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 alkoxy, --CF.sub.3 or phenyloxy which is unsubstituted or substituted by one or two chlorine atoms and/or one or two methyl or methoxy groups, and R.sub.3 is alkyl having at least 10 C atoms, X is a radical of the formulae --NH--, --O--, ##STR3## n is the number 1 or 2, Y is the radical of the formulae --COO--, --OOC--, --CONH-- or --NHCO-- or a radical of the formulae ##STR4## in which R.sub.1 and R.sub.2 are as defined above, D is an aromatic heterocyclic 5- or 6-membered ring, in which the ring contains 1 or 2 N atoms and may additionally contain an O atom or S atom, Z is --H, --Br, --OCH.sub.3, --CN or --NO.sub.2 and X.sub.1 and X.sub.2, independently of one another, are --H, halogen, --CH.sub.3, --OCH.sub.3, --OC.sub.2 H.sub.5 or --NO.sub.2 and X.sub.Type: GrantFiled: September 11, 1989Date of Patent: March 5, 1991Assignee: Ciba-Geigy CorporationInventors: Stefan Hari, Olof Wallquist, Jost von der Crone
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Patent number: 4994564Abstract: Thien-3-ylazo dyes of the formula: ##STR1## where X is cyano, nitro, C.sub.1 -C.sub.6 -alkanoyl, substituted or unsubstituted benzoyl, substituted or unsubstituted phenyl or the radical COOR.sup.1 or CONR.sup.1 R.sup.2 where R.sup.1 and R.sup.2 are identical or different and each is independently of each other substituted or unsubstituted C.sub.1 -C.sub.8 -alkyl, C.sub.5 -C.sub.7 -cycloalkyl, C.sub.3 -C.sub.4 -alkenyl, substituted or unsubstituted phenyl or together with the nitrogen atom linking them a 5- or 6-membered saturated heterocyclic radical, and R.sup.2 may additionally be hydrogen, Y is hydrogen, cyano, C.sub.1 -C.sub.6 -alkanoyl, substituted or unsubstituted benzoyl, C.sub.1 -C.sub.4 -alkylsulfonyl, substituted or unsubstituted phenylsulfonyl, substituted or unsubstituted phenyl or the radical COOR.sup.1 or CONR.sup.1 R.sup.2 where R.sup.1 and R.sup.2 are each as defined above, Z is hydrogen, substituted or unsubstituted C.sub.1 -C.sub.Type: GrantFiled: November 10, 1988Date of Patent: February 19, 1991Assignee: BASF AktiengesellschaftInventors: Karl-Heinz Etzbach, Helmut Reichelt, Guenter Hansen, Ernst Schefczik, Helmut Hagen, Gunther Lamm
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Patent number: 4965345Abstract: Solvent dyes of the formula ##STR1## where ##STR2## R.sup.1 and R.sup.2 are each, independently of the other, hydrogen, methyl, ethyl, methoxy or ethoxy,n is 0 or 1 andk, if n is 0, is the radical of a coupling component of the pyrazolone series or, if n is 1, is the radical of a coupling component of the pyrazolone, 2-naphthol, hydroxyquinoline, aniline, naphthylamine, pyridone or 2,6-diaminopyridine series,R.sup.3 and R.sup.4 each independently of the other being C.sub.1 -C.sub.22 -alkyl which may be substituted or interrupted by oxygen, imino or C.sub.1 -C.sub.4 -alkylimino, subject to the proviso that COR has more than 8 carbon atoms, are very highly suitable for coloring organic substrates.Type: GrantFiled: October 2, 1987Date of Patent: October 23, 1990Assignee: BASF AktiengesellschaftInventor: Hermann Loeffler
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Patent number: 4952681Abstract: Compounds of the formula I ##STR1## where X is fluorine, chlorine, bromine, SO.sub.2 E or unsubstituted or substituted hydroxyl or mercapto, E is alkyl, alkenyl, cycloalkyl, aralkyl, aryl, chlorine or unsubstituted or substituted hydroxyl or amino, Y is cyano, nitro, alkanoyl, aroyl, alkylsulfonyl, arylsulfonyl, carboxyl, a carboxylic ester group or unsubstituted or substituted carbamyl, T is hydrogen, C.sub.1 -C.sub.4 -alkyl, a radical which can be introduced by electrophilic substitution or a radical of the formula --CH.dbd.B, in which B is a radical of a methylene-active compound or of an amine, and K is a radical of a coupling component, are disclosed. They are useful for dyeing synthetic fibers or plastics.Type: GrantFiled: July 27, 1988Date of Patent: August 28, 1990Assignee: Sandoz AGInventors: Guenter Hansen, Ernst Schefczik, Karl-Heinz Etzbach, Helmut Reichelt, Hermann Loeffler
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Patent number: 4946948Abstract: Compounds of formula I: ##STR1## wherein R is a radical of the formula --OR.sub.3 or --NHR.sub.3, A is a radical of formula II or III: ##STR2## B is a radical of the formula ##STR3## n is the number 1 or 2, R.sub.1 is --H or --Cl, R.sub.2 is --H, halogen, --NO.sub.2, --CN, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, --CF.sub.3, C.sub.2 -C.sub.5 alkoxycarbonyl or --CONH-phenyl, --NHCO-phenyl or phenoxy which is unsubstituted or substituted on the phenyl ring by one or two chlorine atoms or one or two methyl, methoxy or ethoxy groups, R.sub.3 is alkyl containing at least 10 C atoms, R.sub.4 and R.sub.5 are each independently of the other --H, halogen, --NO.sub.2, --CN, --CF.sub.3, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy, R.sub.6 is --H, --Cl, --Br, --CH.sub.3 or --OCH.sub.3 and X is --H, --Br, --OCH.sub.3, --CN or --NO.sub.Type: GrantFiled: August 31, 1989Date of Patent: August 7, 1990Assignee: Ciba-Geigy CorporationInventors: Stefan Hari, Fridolin Babler
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Patent number: 4940492Abstract: Colorant mixtures for use in printing inks contain isoquinoline-azo pigments of the formula I ##STR1## where X is chlorine, bromine, C.sub.1 -C.sub.4 -alkoxy or nitro,n is 1, 2 or 3, and the ring A can be substituted, and an isoquinoline-azo dye of the formula II ##STR2## where Y is C.sub.6 -C.sub.20 -alkoxy which may be interrupted by one or more oxygen atoms, and the ring B can be substituted.Type: GrantFiled: June 22, 1988Date of Patent: July 10, 1990Assignee: BASF AktiengesellschaftInventors: Heinrich Kowarsch, Johannes P. Dix
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Patent number: 4843153Abstract: Thienothiophene dyes of the formula ##STR1## wherein Z is carboxylate, acyl, carboxyl, substituted or unsubstituted carbamoyl, cyano or nitro, X is hydrogen, fluorine, chlorine, bromine, Z or a group of the formula ##STR2## T.sup.1 and T.sup.2 are identical or different and each is independently of the other cyano, substituted or unsubstituted alkoxycarbonyl, alkenyloxycarbonyl, carbamoyl or alkylcarbamoyl and W is hydrogen, methyl or ethyl, Y is hydrogen, chlorine or bromine and K is the radical of a coupling component, are highly suitable for dyeing synthetic fibers, in particular polyesters wherein the dyeing obtained have good fastness properties.Type: GrantFiled: July 1, 1987Date of Patent: June 27, 1989Assignee: BASF AktiengesellschaftInventors: Heinz Eilingsfeld, Karl-Heinz Etzbach, Guenter Hansen, Helmut Reichelt
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Patent number: 4776886Abstract: A halftone gravure printing ink(A) about 2 to about 20% by weight of colorant,(B) about 10 to about 40% by weight of resin and(C) about 80 to about 50% by weight of solventwherein said colorant comprises azo dyestuff of the formula ##STR1## in which A.sub.1, A.sub.2 and A.sub.3 denote hydrogen, halogen, --CN, --NO.sub.2, C.sub.1 -C.sub.6 -alkyl, cycloalkyl, C.sub.1 -C.sub.18 -alkoxy, optionally substituted phenoxy, optionally substituted C.sub.1 -C.sub.18 -alkylsulphonyl, optionally substituted phenylsulphonyl, optionally substituted sulphamoyl, optionally substituted carbamoyl, optionally substituted phenylazo, C.sub.1 -C.sub.18 -alkoxycarbonyl, --CF.sub.3, --SCN, C.sub.1 -C.sub.12 -alkylmercapto, C.sub.1 -C.sub.6 -alkylcarbonyl, optionally substituted phenylcarbonyl or --OH,A.sub.4 and A.sub.5 denote hydrogen, halogen, optionally substituted C.sub.1 -C.sub.6 -alkyl, optionally substituted C.sub.1 -C.sub.6 -alkoxy, --NH--CO--CH.sub.2 CH.sub.2 OA.sub.8, --NH--CO--A.sub.8, --NH--SO.sub.2 --A.sub.Type: GrantFiled: August 4, 1986Date of Patent: October 11, 1988Assignee: Bayer AktiengesellschaftInventors: Manfred Lorenz, Rainer Hamprecht, Artur Haus
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Patent number: 4652635Abstract: A method for converting ether groups such as alkyl or aryl ether groups including hydroquinone ether groups to hydroxyl groups and ester groups such as alkyl or aryl ester groups to carboxylic acid groups which comprises reacting a compound including at least one ether and/or ester group with a 2-halo-1,3,2-benzodioxaborole to form an intermediate and hydrolyzing the intermediate such as by quenching it into water to form the desired final product.Type: GrantFiled: June 15, 1984Date of Patent: March 24, 1987Assignee: Polaroid CorporationInventor: Patrick F. King
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Patent number: 4605697Abstract: A nondiffusible sulfonamido compound which is alkali-cleavable upon oxidation to release a diffusible photographically useful material, said nondiffusible sulfonamido compound having the formula: ##STR1## wherein: (a) R.sup.1 is alkyl, aryl sulfamyl, carbamyl, carbonamido, carbonyl, carbonyloxy or sulfonamido;(b) R.sup.2 is alkyl having from 1 to 18 carbon atoms, aryl, or alkylphenyl having from 7 to 12 carbon atoms;(c) R.sup.3 and R.sup.4 are independently alkyl, or aryl, or R.sup.3 and R.sup.4, taken together, form a fused carbocyclic or heterocyclic ring;(d) NHSO.sub.2 PUG represents a sulfonamido group;(e) PUG represents a photographically useful group; and(f) at least one of R.sup.1, R.sup.2, R.sup.3, or R.sup.Type: GrantFiled: September 16, 1983Date of Patent: August 12, 1986Assignee: Eastman Kodak CompanyInventors: Claude F. Gerbal, Thomas E. Gompf, Pierre D. Collet
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Patent number: 4521216Abstract: Compounds of the general formula I ##STR1## where R is hydroxyl or unsubstituted or substituted amino, R.sup.1 is hydrogen or C.sub.1 -C.sub.12 -alkyl, X.sup.1 and Y.sup.1 independently of one another are each a carboxylic acid ester or ether group and X.sup.2 and Y.sup.2 independently of one another are each hydrogen, nitro or chlorine, are very useful for coloring petroleum products, solvents and engine fuel additives.Type: GrantFiled: March 23, 1983Date of Patent: June 4, 1985Assignee: BASF AktiengesellschaftInventors: Herbert Armbrust, Johannes P. Dix, Guenter Hansen, Georg Zeidler
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Patent number: 4495098Abstract: Coordination complexes of a polyvalent metal ion and a nondiffusible compound capable of releasing at least one diffusible cyan dye moiety having the formula: ##STR1## wherein: (a) Y represents the atoms necessary to complete a 5- or 6-membered aromatic heterocyclic fused ring;(b) CAR represents a ballasted carrier moiety capable of releasing the diffusible cyan dye moiety as a function of development of a silver halide emulsion layer under alkaline conditions;(c) R represents a hydroxy group, a salt thereof, or a hydrolyzable precursor thereof, or CAR which is linked to the dye moiety through an oxygen atom thereon; and(d) n is 0, 1 or 2 with the proviso that when n is 0, then R is CAR which is linked to the dye moiety through an oxygen atom thereon.Type: GrantFiled: June 15, 1983Date of Patent: January 22, 1985Assignee: Eastman Kodak CompanyInventors: James A. Reczek, James K. Elwood
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Patent number: 4495100Abstract: Nondiffusible compounds capable of releasing at least one diffusible cyan dye moiety having the formula: ##STR1## wherein: (a) Y represents the atoms necessary to complete a 5- or 6-membered aromatic heterocyclic fused ring;(b) CAR represents a ballasted carrier moiety capable of releasing the diffusible cyan dye moiety as a function of development of a silver halide emulsion layer under alkaline conditions;(c) R represents a hydroxy group, a salt thereof, or a hydrolyzable precursor thereof, or CAR which is linked to the dye moiety through an oxygen atom thereon; and(d) n is 0, 1 or 2 with the proviso that when n is 0, then R is CAR which is linked to the dye moiety through an oxygen atom thereon.Type: GrantFiled: June 15, 1983Date of Patent: January 22, 1985Assignee: Eastman Kodak CompanyInventors: James A. Reczek, James K. Elwood
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Patent number: 4495099Abstract: Nondiffusible compounds capable of releasing at least one diffusible magenta dye moiety having the formula: ##STR1## wherein: (a) X represents the atoms necessary to complete a 5- or 6-membered heterocyclic ring;(b) Y represents the atoms necessary to complete a 5- or 6-membered heterocyclic fused ring;(c) CAR represents a ballasted carrier moiety capable of releasing the diffusible magenta dye moiety as a function of development of a silver halide emulsion layer under alkaline conditions;(d) R represents a hydroxy group, a salt thereof, or a hydrolyzable precursor thereof, or CAR which is linked to the dye moiety through an oxygen atom thereon; and(e) n is 0, 1 or 2, with the proviso that when n is 0, then R is CAR which is linked to the dye moiety through an oxygen atom thereon.Type: GrantFiled: June 15, 1983Date of Patent: January 22, 1985Assignee: Eastman Kodak CompanyInventors: Steven Evans, James K. Elwood