Plural Monocyclic Benzene Rings, Each Having Plural Hydroxy Groups Or Esters Thereof Bonded Directly Thereto Patents (Class 534/687)
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Patent number: 5178671Abstract: Provided is an ink comprising a recording agent and a liquid medium for dissolution or dispersion thereof, the recording agent being a compound represented by the general formula ##STR1## where R.sup.1 is a radical selected from the group of lower alkyl, lower alkoxy, --COOM, and --SO.sub.3 M; R.sup.2 and R.sup.3 are respectively a radical selected from the group of hydrogen, lower alkyl, lower alkoxy, amino, --NHCOCH.sub.3, --SO.sub.3 M, and --COOM; R.sup.4 and R.sup.5 are respectively a radical selected from the group of lower alkyl, lower alkoxy, --NHCOCH.sub.3, --SO.sub.3 M, and COOM; A is ##STR2## R.sup.6 is a radical selected from the group of acetyl, benzoyl, --SO.sub.2 C.sub.6 H.sub.5, --SO.sub.2 C.sub.6 H.sub.4 --CH.sub.3, phenyl, which is unsubstituted or substituted by --COOM or methyl, and ##STR3## R.sup.7 and R.sup.8 are respectively a radical selected from the group of hydrogen, hydroxyl, and --C.sub.2 H.sub.4 OH; R.sup.9 and R.sup.Type: GrantFiled: June 11, 1992Date of Patent: January 12, 1993Assignee: Canon Kabushiki KaishaInventors: Takao Yamamoto, Tsuyoshi Eida, Mayumi Yamamoto
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Patent number: 5127946Abstract: Provided is an ink containing a recording agent and a liquid medium for dissolution or dispersion thereof, said ink comprising, as the recording agent, a compound represented by the general formula (A) ##STR1## where n is 0 or 1; R.sub.1, R.sub.2, and R.sub.3 are respectively a substituent selected from the group consisting of hydrogen, methyl, methoxy, hydroxy, amino, acetylamino, and sulfonic acid; and M is an alkali metal, ammonium, or an organic ammonium.Type: GrantFiled: January 23, 1991Date of Patent: July 7, 1992Assignee: Canon Kabushiki KaishaInventors: Tsuyoshi Eida, Takao Yamamoto, Mayumi Yamamoto
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Patent number: 4841037Abstract: A naphthalene trisazo compound represented by the general formula (I) or (II): ##STR1## wherein A and B each represents a substituted or unsubstituted benzene or naphthalene ring; m represents zero or 1; and M represents an alkali metal atom, ammonium or H.Am (wherein Am represents an amine); or ##STR2## wherein X represents a hydrogen atom, a lower alkyl group, a phenyl group or a phenyl group substituted by --SO.sub.3 M; m represents zero or 1; M represents an alkali metal atom, ammonium or H.Am (wherein Am represents an amine); A, B and C each represents a substituted or an unsubstituted benzene or naphthalene ring, provided that B and C do not represent a naphthalene ring at the same time. A recording liquid containing these compounds is suitable for use in an ink-jet recording system.Type: GrantFiled: June 10, 1986Date of Patent: June 20, 1989Assignees: Canon Kabushiki Kaisha, Mitsubishi Chemical Industries LimitedInventors: Tokuya Ohta, Masatsune Kobayashi, Yuko Suga, Konoe Miura, Hiroshi Takimoto, Tomio Yoneyama
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Patent number: 4758659Abstract: A hexakisazo dye suitable for dyeing cellulose, natural or synthetic polyamide meterials, leather, represented by the formula ##STR1## wherein X is --CH.dbd.CH--, --CONH--, --CRH-- (wherein R is phenyl which is unsubstituted or substituted by H or a sulfonic acid group), -SO.sub.2 -- or --O--; Y is H, CH.sub.3 OCH.sub.3, Cl or SO.sub.3 M; A.sub.1 and A.sub.2 are each ##STR2## (wherein Z.sub.1 is H, Cl, CH.sub.3, OH, OCH.sub.3, OC.sub.2 H.sub.5 or SO.sub.3 M, and Z.sub.2 is H, CH.sub.3, NO.sub.2 or COOM); B.sub.1 and B.sub.2 are each ##STR3## (wherein Z.sub.3 is H, OH, NH.sub.2 Cl or COOM, Z.sub.4 is H, Cl, CH.sub.3, OH OCH.sub.3, NH.sub.2, COOM or SO.sub.3 M, and Z.sub.5 is H, C.sub.1 -C.sub.4 alkyl or OH); M is H, Na, K, Li or NH.sub.4 ; f is 0 or 1; m is 0, 1 or 2; and n is 0, 1 or 2.Type: GrantFiled: July 29, 1986Date of Patent: July 19, 1988Assignee: Orient Chemical Industries, Ltd.Inventors: Hisashi Senshu, Sadahiko Matsubara, Tamotsu Naito
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Patent number: 4665162Abstract: Metal-free azo compounds of the formula ##STR1## wherein Ra is an aromatic group or an active methylene coupling component radical as defined in the specification,R.sub.t is an arylazo group or a group of the formula --Y--Z,whereinY is a direct bond or a bridging radical, andZ is a basic amino or quaternary ammonium group, ##STR2## wherein each of the variables is as defined above or below, x is a direct bond or a bridging radical,x is hydrogen, hydroxy, C.sub.1-4 alkyl, C.sub.1-4 alkoxy, amino or carboxy,ring B is further unsubstituted or further substituted,d is 0, 1 or 2, andn is 0 or 1,with the provisos that (i) the compounds contain an average of at least 1.3 basic water-solubilizing groups, and (ii) the compounds are free of sulfo groups, and 1:1 and 1:2 metal complexes thereof, which metal-free compounds and metal complexes are useful as dyes for leather and paper.Type: GrantFiled: June 18, 1985Date of Patent: May 12, 1987Assignee: Sandoz Ltd.Inventors: Paul Doswald, Emil Moriconi, Helmut Moser, Horst Schmid
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Patent number: 4587292Abstract: Metal-free azo compounds of the formula ##STR1## wherein Ra is an aromatic group or an active methylene coupling component radical as defined in the specification,R.sub.t is an arylazo group or a group of the formula --Y--Z, whereinY is a direct bond or a bridging radical, andZ is a basic amino or quaternary ammonium group,R is ##STR2## wherein each of the variables is as defined above or below, X is a direct bond or a bridging radical,x is hydrogen, hydroxy, C.sub.1-4 alkyl, C.sub.1-4 alkoxy, amino or carboxy,ring B is further unsubstituted or further substituted,d is 0, 1 or 2, andn is 0 or 1,with the provisos that (i) the compounds contain an average of at least 1.3 basic water-solubilizing groups, and (ii) the compounds are free of sulfo groups, and 1:1 and 1:2 metal complexes thereof, which metal-free compounds and metal complexes are useful as dyes for leather and paper.Type: GrantFiled: August 18, 1982Date of Patent: May 6, 1986Assignee: Sandoz Ltd.Inventors: Paul Doswald, Emil Moriconi, Helmut Moser, Horst Schmid
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Patent number: 4563520Abstract: Compounds containing sulfonic acid groups and of the general formula I ##STR1## where D.sup.1 is a radical of a diazo component, X.sup.1 and X.sup.2 independently of one another are each hydroxyl or unsubstituted or substituted amino, Y is hydrogen, chlorine, methyl, hydroxysulfonyl or a radical of the formulaD.sup.3 --N.dbd.N--and D.sup.2 is a radical of the formula ##STR2## D.sup.3 is a radical of a diazo component from the aniline or aminonaphthalene series, K is a radical of a coupling component from the benzene or naphthalene series, and the rings in the coupling component D.sup.2 may furthermore be substituted by chlorine, methyl, methoxy, hydroxysulfonyl, aminosulfonyl, hydroxyl or acylamino, and metal complexes of such compounds, give very fast, brown dyeings, particularly on leather.Type: GrantFiled: October 21, 1982Date of Patent: January 7, 1986Assignee: BASF AktiengesellschaftInventors: Udo Bergmann, Guenter Hansen, Dietrich Lach, Georg Zeidler