Hetero Ring Containing Patents (Class 534/731)
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Patent number: 8979947Abstract: The present invention relates to dyes of the formula (I) in which R1 to R10, D1 and D2 are defined as given in claim 1, a process for preparing them, and their use for dyeing and printing hydroxyl- and/or carboxamido-containing materials.Type: GrantFiled: November 24, 2011Date of Patent: March 17, 2015Assignee: DyStar Colours Distribution GmbHInventors: Roxana Barbieru, Vajiravelu Sivamurugan
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Publication number: 20140066410Abstract: This disclosure relates generally to compounds and compositions comprising one or more diphenylethylene, diphenylethylyne, and azobenzene analogs. These compounds are useful for treating diseases associated with NF-kB and p53 activity, such as cancer and inflammatory disease.Type: ApplicationFiled: February 23, 2012Publication date: March 6, 2014Applicant: ICAHN SCHOOL OF MEDICINE AT MOUNT SINAIInventors: Ming-Ming Zhou, Michael Ohlmeyer, Shiraz Mujtaba, Alexander Plotnikov, David Kastrinsky, Guangtao Zhang
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Patent number: 8389124Abstract: Disclosed is an azo compound represented by the formula (1) or (2) below, or a salt thereof. (In the formulae, A represents a substituted phenyl group or a naphthyl group having 1-3 sulfonic acid groups; X represents —N?N— or —NHCO—; R1-R4 independently represent a hydrogen atom, a lower alkyl group or a lower alkoxyl group; m represents a number of 1-3; and n represents 0 or 1.Type: GrantFiled: July 13, 2011Date of Patent: March 5, 2013Assignees: Nippon Kayaku Kabushiki Kaisha, Polatechno Co., Ltd.Inventors: Yuichi Sadamitsu, Hiroaki Ohno, Takahiro Higeta
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Patent number: 8389122Abstract: Disclosed is an azo compound represented by the formula (1) or (2) below, or a salt thereof. (In the formulae, A represents a substituted phenyl group or a naphthyl group having 1-3 sulfonic acid groups; X represents —N?N— or —NHCO—; R1-R4 independently represent a hydrogen atom, a lower alkyl group or a lower alkoxyl group; m represents a number of 1-3; and n represents 0 or 1).Type: GrantFiled: June 12, 2007Date of Patent: March 5, 2013Assignees: Nippon Kayaku Kabushiki Kaisha, Polatechno Co., Ltd.Inventors: Yuichi Sadamitsu, Hiroaki Ohno, Takahiro Higeta
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Publication number: 20110225742Abstract: The present invention relates to a) a non-oxidative colouring agent for keratin fibres, in particular human hair, comprising at least one dye according to formula (I) or (II), b) an oxidative colouring agent for keratin fibres, in particular human hair, which comprises at least one oxidizing agent (e.g. hydrogen peroxide), at least one oxidative dye precursor and at least one dye according to formula (I) or (II), and c) a lightening agent for keratin fibres, in particular human hair, which comprises at least one oxidizing agent (e.g. hydrogen peroxide) and at least one dye according to formula (I) or (II), with R4 being a cationic group.Type: ApplicationFiled: June 3, 2011Publication date: September 22, 2011Inventors: Markus SPECKBACHER, Jessica Chassot, Hans-Jürgen Braun
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Publication number: 20110117337Abstract: A compound of Formula (1) and salts thereof: wherein: A is optionally substituted heterocyclyl; X is N or C—CN; R1 is H or a substituent; R2 and R3 are independently H, optionally substituted alkyl, optionally substituted aryl, optionally substituted heterocyclyl or —SO2R4, wherein R4 is optionally substituted optionally substituted aryl or optionally substituted heterocyclyl; and provided that the compound of Formula (1) has attached, either directly or through a substituent, at least one ionic water solubilising group selected from the group consisting of CO2H, COSH, SO3H and PO3H2. Also compositions, inks, ink-jet printing processes, printed materials and ink-jet cartridges.Type: ApplicationFiled: June 24, 2009Publication date: May 19, 2011Applicants: FUJIFILM IMAGING COLORANTS LIMITED, FUJIFILM CORPORATIONInventors: Gavin Wright, Toshiki Fujiwara
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Publication number: 20110014435Abstract: A process for printing an image on a substrate, the process comprising applying to the substrate an ink composition which comprises a liquid medium and a compound selected from the group consisting of compounds of Formula (1I), compounds of Formula (1II), compounds of Formula (1III) and compounds of Formula (1IV): wherein: A and D each independently represent optionally substituted aryl or optionally substituted heteroaryl; E represents optionally substituted pyrazolyl; Z represents H, halogen, nitro, cyano, hydroxy, amino, carboxy, optionally substituted alkyl, optionally substituted alkoxy or optionally substituted aryloxy; and p is an integer from 0 to 5. Preferably, the printing process is ink jet printing. Also provided are compounds of Formula (1I), (1II), (1III) and (1IV) and ink compositions comprising the same.Type: ApplicationFiled: July 31, 2006Publication date: January 20, 2011Inventors: Lilian Monahan, Philip John Double, Roy Bradbury, Lynn Patricia Bradbury
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Publication number: 20100245509Abstract: An ink includes at least one coloring matter represented by a formula (I): wherein R1 represents one of an alkyl group, an alkenyl group, an alkynyl group, an aralkyl group, an aryl group, a heterocyclic group, an acyl group, an alkyloxycarbonyl group, an aryloxycarbonyl group, a carbamoyl group, an alkylsulfonyl group, an arylsulfonyl group and a sulfamoyl group, which may have a substituent; X1 represents one of —CR2? and a nitrogen atom, R2 represents one of a hydrogen atom and a substituent, and when R2 represents a substituent, R2 may have a substituent; X2 represents one of —CR3? and a nitrogen atom, and R3 represents an electron-withdrawing group having a ?p value of 0.20 or more; when X1 represents —CR2?, a pair of R1 and R2 and/or when X2 represents —CR3?, a pair of R2 and R3 each may combine to form a 5- to 7-membered ring; the coloring matter may form one of a dimer and a trimer through R1, R2, R3 or A; and A represents a prescribed aryl group or heterocyclic group etc.Type: ApplicationFiled: January 19, 2007Publication date: September 30, 2010Applicant: FUJIFILM CORPORATIONInventor: Keiichi Tateishi
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Publication number: 20100233450Abstract: The present invention relates to a water-soluble azo compound represented by the following formula (1) or a salt thereof: (wherein, R represents an alkyl group having 1 to 4 carbon atoms, n represents an integer number of 1 or 2, x represents an integer number of 2 to 4 and y represents an integer number of 2 to 11, respectively) and an ink composition containing this; and provides a yellow coloring matter which has a highly vivid hue suitable for inkjet recording, gives various high fastnesses to recorded matter and is excellent in storage stability when prepared as an ink composition, and an ink composition containing this.Type: ApplicationFiled: October 17, 2008Publication date: September 16, 2010Inventors: Ryoutarou Morita, Yoshiaki Kawaida
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Publication number: 20100221430Abstract: An ink includes at least one coloring matter represented by a formula (1): wherein X1 represents one of —CR1? and a nitrogen atom; X2 represents one of —CR2? and a nitrogen atom; X3 represents one of —CR3? and a nitrogen atom; R1, R2 and R3 each independently represents one of a hydrogen atom and a substituent; when R1, R2 and R3 each represents a substituent, the substituent may have a substituent; A represents one group selected from a prescribed pyridine ring group, pyrimidine ring group and quinoline ring group.Type: ApplicationFiled: January 19, 2007Publication date: September 2, 2010Applicant: FUJIFILM CORPORATIONInventor: Keiichi Tateishi
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Publication number: 20100068475Abstract: The present invention relates to a water-soluble azo compound or a salt thereof represented by the following formula (1): (wherein, R represents a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, an alkoxy group having 1 to 4 carbon atoms or a sulfo group, n, m, x and y represent an integer of 1 or 2, 1 to 3, 2 to 4 and 1 to 3, respectively.) and an ink composition containing the same; the above compound or a salt thereof has a hue possessing a high vividness suitable for inkjet recording, provides various fastnesses to recorded matters, and is useful as a yellow coloring matter excellent in storage stability when prepared into an ink composition, and suitable for ink compositions, especially inks for inkjet recording.Type: ApplicationFiled: October 25, 2007Publication date: March 18, 2010Inventors: Ryoutarou Morita, Yoshiaki Kawaida
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Publication number: 20100015411Abstract: A compound of Formula (1) or a salt thereof: A-N?N-D-N?N—B—N?N-A???Formula (1) wherein A is an optionally substituted aryl, heteroaryl, non-aromatic heterocyclic or alkenyl group; D is an optionally substituted, optionally metallised 1,8-dihydroxynaphthalene group; B is an optionally substituted organic linking group; and A? is an optionally substituted pyrazolyl group which does not have an aromatic group as a substituent directly attached to either of the nitrogen atoms of the pyrazolyl ring. Also provided are compositions, inks, ink sets, substrates and cartridges all containing the compound or salt and printing processes using the compound or salt. The compounds and salts are especially useful for ink-jet printing.Type: ApplicationFiled: September 24, 2007Publication date: January 21, 2010Inventor: David Phillip Devonald
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Patent number: 7648839Abstract: To provide a novel copper ion indicator which is less influenced by interfering metal ions and which is useful for measurement of copper ion within a wide concentration range. The invention provides a copper ion indicator containing a compound represented by formula (1): [wherein each of R1, R2, R3, R4, R5, and R6 represents a hydrogen atom or an alkali metal atom], and a method for determining copper ion concentration, which employs the indicator.Type: GrantFiled: June 21, 2005Date of Patent: January 19, 2010Assignee: Kowa Co., Ltd.Inventors: Maria Sakairi, Katsumi Yabusaki
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Patent number: 6191265Abstract: Azo dyes of the formula wherein the substituents are each as defined in the description, are useful for dyeing and printing synthetic textile materials.Type: GrantFiled: December 14, 1999Date of Patent: February 20, 2001Assignee: DyStar Textilfarben GmbH & Co. Deutschland KGInventor: Rainer Hamprecht
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Patent number: 6008332Abstract: Disperse azo dyes of formula ##STR1## wherein R.sub.1 is hydrogen, C.sub.1 -C.sub.2 alkyl, halogen, NH--CO--R.sub.5 or O--SO.sub.2 --R.sub.6 ; R.sub.2 is hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, unsubstituted C.sub.1 -C.sub.8 alkoxy or C.sub.1 -C.sub.8 alkoxy which is substituted by halogen, cyano, phenyl, --Y--C.sub.1 -C.sub.8 alkyl or --Y-phenyl; R.sub.3 is unsubstituted C.sub.1 -C.sub.8 alkyl or C.sub.1 -C.sub.8 alkyl which is substituted by hydroxy, cyano, vinyl, phenyl, halogen, --X-phenyl or --X--C.sub.1 -C.sub.8 alkyl, and --X--C.sub.1 -C.sub.8 alkyl may be substituted by halogen or cyano and --X-phenyl may be substituted by C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy or halogen; R.sub.4 is hydrogen or, independently of R.sub.3, has the meaning of R.sub.3, and R.sub.3 and R.sub.4, together with the linking nitrogen atom, can also be a heterocyclic radical; R.sub.5 is unsubstituted C.sub.1 -C.sub.3 alkyl or C.sub.1 -C.sub.3 alkyl which is substituted by halogen, phenyl, cyano or C.sub.1 -C.sub.Type: GrantFiled: July 17, 1996Date of Patent: December 28, 1999Assignee: Ciba Specialty Chemicals CorporationInventors: Paul Herzig, Romeo Dreier
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Patent number: 5710258Abstract: The invention relates to compounds of formula ##STR1## The compounds of formula (1) are suitable as dye for dyeing or printing hydroxyl group-containing or nitrogen-containing fibre materials and give dyeings of prints having good allround fastness properties.Type: GrantFiled: February 5, 1996Date of Patent: January 20, 1998Assignee: Ciba Specialty Chemicals CorporationInventors: Jean-Marie Adam, Peter Sutter
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Patent number: 5436323Abstract: Cationic 1,3,4-thiadiazolyldiphenylamine dyestuffs and corresponding anhydro bases, the dyestuffs having the formula (I) ##STR1## their preparation and their use, and materials dyed with such dyestuffs.Type: GrantFiled: July 1, 1993Date of Patent: July 25, 1995Assignee: Bayer AktiengesellschaftInventors: Horst Berneth, Werner Hartwich, Karl-Heinrich Lange
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Patent number: 4997919Abstract: This invention relates to direct dyes for various substrates, in particular cellulosic fiber materials. The inventive dyes are high-temperature-resistant and highly suitable for the single bath, one step dyeing of polyester/cotton mixed fabrics with a disperse dye for the polyester fibers under the dyeing conditions for polyester fibers.The inventive dyes are of the formula ##STR1## in which A is a radical of the formula ##STR2## A' has the meaning of A or is a mono- or polyazo dye radical which is different from A, R and R', independently of one another, are hydrogen or C.sub.1 -C.sub.4 alkyl which is unsubstituted or substituted by chlorine, hydroxyl, cyano, carboxyl, sulfo, sulfato, methoxy, ethoxy, methoxycarbonyl or ethoxycarbonyl, R.sub.1 is hydroxyl, C.sub.1 -C.sub.4 alkoxy, halogen, C.sub.1 -C.sub.4 alkylthio, amino, N-mono- or N,N-di-C.sub.1 -C.sub.4 alkylamino which is unsubstituted or substituted in the alkyl moiety by hydroxyl, carboxyl or C.sub.1 -C.sub.Type: GrantFiled: June 19, 1989Date of Patent: March 5, 1991Assignee: Ciba-Geigy CorporationInventor: Rudolf Schaulin
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Patent number: 4997921Abstract: Monoazo dyes of the formula ##STR1## wherein R.sub.1 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, halogen, C.sub.2 -C.sub.4 alkanoylamino or is an unsubstituted or substituted arylsulfonyl, aryloxy or arylcarbonyl radical; R.sub.2 is hydrogen, halogen, an unsubstituted or substituted alkyl, aryloxy or aryloxysulfonyl radical or a radical of the formula ##STR2## R.sub.3 is an unsubstituted or substituted alkyl or aryl radical; R.sub.4 is hydrogen or alkyl; and R.sub.5 and R.sub.6 are each independently hydrogen or an unsubstituted or substituted alkyl, cycloalkyl or aryl radical, with the proviso that R.sub.1 may not be hydrogen or halogen if R.sub.2 is an unsubstituted or substituted aryloxysulfonyl radical, a radical of the formula ##STR3## or the trifluoromethyl group, and the sulfo group is attached to the benzene ring of the indole radical, produce dyeings of good light- and wetfastness properties on polyamide material.Type: GrantFiled: November 30, 1989Date of Patent: March 5, 1991Assignee: Ciba-Geigy CorporationInventor: Rudolf Hurter
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Patent number: 4954563Abstract: Monoazo dyes of the formula ##STR1## wherein R.sub.1 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, halogen, C.sub.2 -C.sub.4 alkanoylamino or is an unsubstituted or substituted arylsulfonyl, aryloxy or arylcarbonyl radical; R.sub.2 is hydrogen, halogen, an unsubstituted or substituted alkyl, aryloxy or aryloxysulfonyl radical or a radical of the formula ##STR2## R.sub.3 is an unsubstituted or substituted alkyl or aryl radical; R.sub.4 is hydrogen or alkyl; and R.sub.5 and R.sub.6 are each independently hydrogen or an unsubstituted or substituted alkyl, cycloalkyl or aryl radical, with the proviso that R.sub.1 may not be hydrogen or halogen if R.sub.2 is an unsubstituted or substituted aryloxysulfonyl radical, a radical of the formula ##STR3## or the trifluoromethyl group, and the sulfo group is attached to the benzene ring of the indole radical, produce dyeings of good light- and wetfastness properties on polyamide material.Type: GrantFiled: February 27, 1984Date of Patent: September 4, 1990Assignee: Ciba-Geigy CorporationInventor: Rudolf Hurter
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Patent number: 4910299Abstract: Disperse dyes suitable for dyeing textile material composed of polyester dyes of the formula ##STR1## in which D is the radical of a substituted or unsubstituted, homocyclic or heterocyclic diazo component belonging to the series comprising thienyl, thiazolyl, isothiazolyl, 1,2,4-thiadiazolyl, 1,3,4-thiadiazolyl, benzothiazolyl, benzoisothiazolyl, pyrazolyl, imidazolyl or phenyl,X is hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, acylamino, halogen or a group of the formula -NH-CO-NHQ in which Q is hydrogen, C.sub.1 -C.sub.4 -alkyl or phenyl,Y is hydrogen, halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkoxy-C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy-C.sub.1 -C.sub.4 -alkoxy,R is hydrogen, C.sub.1 -C.sub.12 -alkyl, C.sub.2 -C.sub.12 -alkenyl or phenyl, or Y and R, together with the nitrogen atom and the two C atoms linking them, form a 5-membered ring or 6-membered ring,B is a l inear or branched C.sub.2 -C.sub.6 -alkylene radical,W is halogen, C.sub.Type: GrantFiled: December 2, 1987Date of Patent: March 20, 1990Assignee: Ciba-Geigy CorporationInventors: Angelo D. Casa, Peter Liechti, Max Dempfle
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Patent number: 4837309Abstract: A monoazo dyestuff of the formula: ##STR1## wherein D represents substituted or unsubstituted phenyl, imidazolyl, pyridyl, thiazolyl, thiadiazolyl, thienyl, benzoisothiazolyl, pyridinoisothiazolyl, thienoisothiazolyl, thienothiazolyl or benzothiazolyl, R.sup.1 represents substituted or unsubstituted alkyl, cyclohexyl, alkenyl, aralkyl or aryl, R.sup.2 and R.sup.3 each represents hydrogen, alkyl optionally substituted by cyano, hydroxy, alkoxy or alkoxyalkoxy, alkenyl, cyclohexyl, aryl or aralkyl, or together represent a 5- or 6-membered nitrogen-containing heterocyclic ring formed by combining R.sup.2 and R.sup.3, A represents ##STR2## X represents fluorine or chlorine, and Y.sup.1 represents hydrogen, chlorine, methyl or acylamino. The monoazo dyestuff is especially useful in the dyeing of cellulose-containing fibers and exhibits good fastness properties including good wet color fastness and good light fastness.Type: GrantFiled: February 24, 1984Date of Patent: June 6, 1989Assignee: Mitsubishi Chemical Industries LimitedInventors: Toshio Niwa, Kiyoshi Himeno, Toshio Hihara, Yutaka Kurose, Yukiharu Shimizu
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Patent number: 4656256Abstract: Compounds of the formula ##STR1## where Y is chlorine or bromine, Z is hydrogen, chlorine, bromine, a sulfonic ester group, nitro or unsubstituted or substituted sulfamyl, X is --O-- or ##STR2## R is alkylene which may or may not be interrupted by oxygen, ##STR3## m is 1 or 2, n is 0 or 1, p is 0, 1 or 2, q is 1 or 2, R.sup.1 and R.sup.2 independently of one another are each hydrogen, unsubstituted or substituted alkyl, alkenyl, cycloalkyl, aralkyl or aryl, or R.sup.1 and R.sup.2, together with the nitrogen atom, form a heterocyclic structure, R.sup.3 is hydrogen or unsubstituted or substituted alkyl, B is hydrogen or C.sub.1 -C.sub.4 -alkyl, B.sup.1 is hydrogen, hydroxyl, C.sub.1 -C.sub.4 -alkoxy or C.sub.1 -C.sub.4 -alkyl, A.sup.- is an anion, R.sup.4 is unsubstituted or substituted alkyl, R.sub.5 is hydrogen or C.sub.1 -C.sub.Type: GrantFiled: May 16, 1985Date of Patent: April 7, 1987Assignee: BASF AktiengesellschaftInventors: Horst Colberg, Hans-Juergen Degen, Johannes P. Dix
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Patent number: 4631065Abstract: The invention relates to reactive dyes of the formula ##STR1## wherein D is the radical of a dye of the monoazo or polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan, azomethine, dioxazine, phenazine, stilbene, triphenylmethane, xanthene, thioxanthone, nitroaryl, naphthoquinone, pyrenequinone or perylenetetracarbimide series, each of R.sub.1 and R.sub.2 independently is hydrogen or an unsubstituted or substituted C.sub.1 -C.sub.4 alkyl radical, X.sub.1 is an unsubstituted or substituted aminofluoro-s-triazine radical, and X.sub.2 is a heterocyclic reactive radical which is attached direct to the radical D through the --N(R.sub.2) bridge member, excepting an unsubstituted or substituted aminofluoro-s-triazine.These dyes are particularly suitable for dyeing and printing cellulosic fibre material by the cold pad-batch method and give dyeings and prints of good fastness properties and high tinctorial strength.Type: GrantFiled: August 20, 1985Date of Patent: December 23, 1986Assignee: Ciba-Geigy CorporationInventors: Karl Seitz, Peter Scheibli, Herbert Seiler
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Patent number: 4619993Abstract: Compounds of the formula ##STR1## wherein K is a coupling component radical, are useful for dyeing textile materials comprising a synthetic or semisynthetic, hydrophobic, high molecular weight material, e.g., linear aromatic polyesters, cellulose 21/2 acetate, cellulose triacetate and synthetic polyamides.Type: GrantFiled: July 18, 1984Date of Patent: October 28, 1986Assignee: Sandoz Ltd.Inventor: Werner Baumann
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Patent number: 4602084Abstract: Monoazo dyes of the formula ##STR1## in which K is the radical of a coupling component of the benzene or naphthalene series or of the heterocyclic series, and R is a ##STR2## --CO--R.sub.2 or --SO.sub.2 --O--R.sub.2 group in which R.sub.1 is hydrogen or C.sub.1-4 -alkyl and R.sub.2 is a substituted or unsubstituted monosulfo-C.sub.1-12 -alkyl radical, a substituted or unsubstituted monosulfophenyl, disulfophenyl, monosulfonaphthyl or disulfonaphthyl radical, and X and Y, independently of each other, are hydrogen, C.sub.1-4 -alkyl, C.sub.1-4 -alkoxy, halogen, C.sub.2-6 -alkanoylamino, C.sub.1-5 -alkylsulfonylamino or a substituted or unsubstituted phenyl or phenoxy radical, produce dyeings on polyamide material which have good light and wet fastness properties.Type: GrantFiled: July 8, 1983Date of Patent: July 22, 1986Assignee: Ciba-Geigy CorporationInventor: Rudolf Hurter