Halogen Bonded Directly To Sulfur Or To A -c(=x)- Group, Wherein X Is Chalcogen Patents (Class 534/734)
  • Publication number: 20130117947
    Abstract: The present invention is directed to a disperse dye of formula (1) Wherein, X, Y and Z are, independently, hydrogen, halogen, cyano, nitro or SO2F; Wherein at least one of X, Y and Z is SO2F. R1 is hydrogen, methyl, hydroxyl or NHR4; R2 is hydrogen, chloro or methoxy; R3 is hydrogen, (C1-C4)-alkyl or —CH2(CH2)nCOOCH2CN; R5 is hydrogen, (C1-C4)-alkyl or —CH2(CH2)mCOOCH2CN; R4 is —COCH3, —CO C2H5, —SO2CH3 or SO2C2H5; n and m are independently 0,1 or 2, with the proviso: When, Y and Z both are Cl, R1 is other than methyl. When, R2 is Hydrogen and R3, R4 both are alkyl, R1 is selected from NHSO2CH3 or NHSO2C2H5. Disperse dyes of Formula (I) have excellent washing fastness and light fastness on polyester fiber and polyester blends.
    Type: Application
    Filed: December 23, 2010
    Publication date: May 16, 2013
    Applicant: COLOURTEX INDUSTRIES LIMITED
    Inventors: Pankaj Desai, Kiyoshi Himeno, Nikhil Desai, Jay Patel
  • Publication number: 20120184683
    Abstract: Compounds linked to a solid support through a divalent linker moiety are disclosed. In particular, compounds such as 1-hydroxybenzotriazole-6-carboxylic acid are directly linked to the support under mild conditions (i.e., in aqueous or organic solvents at neutral pH and at room temperature). The polymer bound 1-hydroxybenzotriazole-6-carboxylic acid can be used for the derivatization of amines as well as for single step amino group modification of proteins, peptides, and amines via acylation or sulfonylation reactions. A flow through device and method for the single step amino group modifications of proteins, peptides, and amines is disclosed. Also disclosed is a flow through device for the detection of amines in a sample. Additionally, a device and method for the detection of amines in a sample using 1-hydroxybenzotriazole-6-carboxylic acid are disclosed. In a preferred embodiment, the device is used to detect the presence of amines in a spoiled meat product.
    Type: Application
    Filed: January 20, 2012
    Publication date: July 19, 2012
    Applicant: The University of Maryland, Baltimore County
    Inventor: Aristotle G. KALIVRETENOS
  • Patent number: 6048370
    Abstract: Monoazo dyes having formula (1) ##STR1## wherein Q is --Br or --Cl; R.sup.1 and R.sup.2 each independently is H or is selected from the group consisting of C.sub.1-6 -alkyl and aryl groups, each of which may be unsubstituted or substituted by one or more nonionic substituents; and R.sup.3, R.sup.4, R.sup.5 and R.sup.6 each independently is H, F, Cl, Br, I, --SO.sub.2 F or an organic moiety selected from the group consisting of C.sub.1-6 -alkyl, C.sub.1-6 -alkoxy, C.sub.1-4 alkanoylamino, --NHSO.sub.2 alkyl, --NHCOC.sub.1-4 alkyl and --Ophenyl moieties, each organic moiety being unsubstituted or substituted by one or more nonionic substituents are provided. The dyes can be employed for the colouring of synthetic textile material.
    Type: Grant
    Filed: August 24, 1998
    Date of Patent: April 11, 2000
    Assignee: BASF Aktiengesellschaft
    Inventor: Nigel Hall
  • Patent number: 5998592
    Abstract: A monoazo dye of the formula: ##STR1## wherein: R.sup.1 represents --C.sub.3 H.sub.6 CN, --C.sub.2 H.sub.4 Cl, --C.sub.3 H.sub.6 Cl, --C.sub.2 H.sub.4 OCOCH.sub.3 or --C.sub.2 H.sub.4 OCOCH.sub.2 Cl;R.sup.2 and R.sup.3 each independently represent a C.sub.1-4 -alkyl group; andR.sup.4, R.sup.5 and R.sup.6 each independently represent H, F, Cl, Br, I, --SO.sub.2 F, or an organic moiety selected from the group consisting of C.sub.1-6 alkyl, C.sub.1-6 alkoxy, C.sub.1-4 alkanoylamino, --NHSO.sub.2 alkyl, --NHCOC.sub.1-4 alkyl and -Ophenyl moieties, each organic moiety being unsubstituted or substituted by at least one nonionic substituent.
    Type: Grant
    Filed: August 17, 1998
    Date of Patent: December 7, 1999
    Assignee: BASF Aktiengesellschaft
    Inventor: Nigel Hall
  • Patent number: 5973127
    Abstract: Dyes of formula (1) ##STR1## wherein the variables are as defined in the specification and at least one of R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 or a substituent on A being --SO.sub.2 F or a substituent to which at least one --SO.sub.2 F group is attached are water-insoluble monoazo dyes useful for coloring synthetic textile materials.
    Type: Grant
    Filed: March 5, 1999
    Date of Patent: October 26, 1999
    Assignee: BASF Aktiengesellschaft
    Inventor: Andrew John Greaves
  • Patent number: 5739299
    Abstract: A process for coloring a synthetic textile material or fibre blend thereof which comprises applying to the synthetic textile material a compound or mixture thereof, which is free from water solubilizing groups, of Formula (1):A--N.dbd.N--D Formula (1)whereinA and D each independently is an optionally substituted heterocyclic or carbocyclic group and at least one of A or D carries directly at least one --SO.sub.2 F group or carries a substituent to which at least one --SO.sub.2 F group is attached except for 4-(4-fluorosulphonylphenylazo)-N,N-dimethylaniline, provided that one of A or D is not 3,5-difluorosulphonylthien-2-yl, optionally substituted 1-phenyl-pyrazol-4-yl-5-one or ##STR1## or that one of A or D does not carry an --NCH.sub.2 CH(OH)CH.sub.2 Cl, --NCOCH.sub.2 Cl or --NCH.sub.2 CH.sub.2 SO.sub.2 F substituent.The presence of one or more --SO.sub.2 F groups in a dye molecule generally improves the properties of that dye and confers surprisingly good wet fastness and light fastness properties.
    Type: Grant
    Filed: July 15, 1996
    Date of Patent: April 14, 1998
    Assignee: Zeneca Limited
    Inventor: Nigel Hall
  • Patent number: 5298609
    Abstract: Compounds of formula I ##STR1## wherein R is a radical of formula --OR.sub.3 or --NHR.sub.3, A is a radical of formula II or III ##STR2## and B is a radical of formula ##STR3## wherein n is 1 or 2,R.sub.1 is --H or --Cl,R.sub.2 is --H, halogen, --NO.sub.2, --CN, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, --CF.sub.3, C.sub.2 -C.sub.5 alkoxycarbonyl, --CONH--phenyl, --NHCO-phenyl or phenoxy, each unsubstituted or substituted in the phenyl nucleus by one or two chlorine atoms or by one or two methyl, methoxy or ethoxy groups,R.sub.3 is C.sub.5 -C.sub.12 cycloalkyl, which is unsubstituted or substituted by 1 to 3 C.sub.1 -C.sub.4 alkyl or C.sub.5 -C.sub.6 cycloalkyl groups,R.sub.4 and R.sub.5 are each independently of the other --H, halogen, --NO.sub.2, --CN, --CF.sub.3, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy,R.sub.6 is --H, --Cl, --Br, --CH.sub.3 or --OCH.sub.3, andX is --H, --Br, --OCH.sub.3, --CN or --NO.sub.2,are suitable for use as pigments, especially for colouring polyolefins.
    Type: Grant
    Filed: July 14, 1993
    Date of Patent: March 29, 1994
    Assignee: Ciba-Geigy Corporation
    Inventor: Stefan Hari
  • Patent number: 4997920
    Abstract: Compounds of the formulae I and II ##STR1## in which A is a radical of the formulae III, IV or V ##STR2## R.sub.1 and R.sub.4 are --H or --Cl, R.sub.2 and R.sub.5 are --H, halogen, --NO.sub.2, --CN, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 alkoxy, --CF.sub.3 or phenyloxy which is unsubstituted or substituted by one or two chlorine atoms and/or one or two methyl or methoxy groups, and R.sub.3 is alkyl having at least 10 C atoms, X is a radical of the formulae --NH--, --O--, ##STR3## n is the number 1 or 2, Y is the radical of the formulae --COO--, --OOC--, --CONH-- or --NHCO-- or a radical of the formulae ##STR4## in which R.sub.1 and R.sub.2 are as defined above, D is an aromatic heterocyclic 5- or 6-membered ring, in which the ring contains 1 or 2 N atoms and may additionally contain an O atom or S atom, Z is --H, --Br, --OCH.sub.3, --CN or --NO.sub.2 and X.sub.1 and X.sub.2, independently of one another, are --H, halogen, --CH.sub.3, --OCH.sub.3, --OC.sub.2 H.sub.5 or --NO.sub.2 and X.sub.
    Type: Grant
    Filed: September 11, 1989
    Date of Patent: March 5, 1991
    Assignee: Ciba-Geigy Corporation
    Inventors: Stefan Hari, Olof Wallquist, Jost von der Crone
  • Patent number: 4946948
    Abstract: Compounds of formula I: ##STR1## wherein R is a radical of the formula --OR.sub.3 or --NHR.sub.3, A is a radical of formula II or III: ##STR2## B is a radical of the formula ##STR3## n is the number 1 or 2, R.sub.1 is --H or --Cl, R.sub.2 is --H, halogen, --NO.sub.2, --CN, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, --CF.sub.3, C.sub.2 -C.sub.5 alkoxycarbonyl or --CONH-phenyl, --NHCO-phenyl or phenoxy which is unsubstituted or substituted on the phenyl ring by one or two chlorine atoms or one or two methyl, methoxy or ethoxy groups, R.sub.3 is alkyl containing at least 10 C atoms, R.sub.4 and R.sub.5 are each independently of the other --H, halogen, --NO.sub.2, --CN, --CF.sub.3, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy, R.sub.6 is --H, --Cl, --Br, --CH.sub.3 or --OCH.sub.3 and X is --H, --Br, --OCH.sub.3, --CN or --NO.sub.
    Type: Grant
    Filed: August 31, 1989
    Date of Patent: August 7, 1990
    Assignee: Ciba-Geigy Corporation
    Inventors: Stefan Hari, Fridolin Babler
  • Patent number: 4689403
    Abstract: The present invention concerns the disazo pigment of the formula ##STR1## The new pigment is useful for coloring plastic material in pure red shades of high tinctorial strength and outstanding fastness to light and migration.
    Type: Grant
    Filed: April 29, 1982
    Date of Patent: August 25, 1987
    Assignee: Ciba-Geigy AG
    Inventor: Karl Ronco
  • Patent number: 4605697
    Abstract: A nondiffusible sulfonamido compound which is alkali-cleavable upon oxidation to release a diffusible photographically useful material, said nondiffusible sulfonamido compound having the formula: ##STR1## wherein: (a) R.sup.1 is alkyl, aryl sulfamyl, carbamyl, carbonamido, carbonyl, carbonyloxy or sulfonamido;(b) R.sup.2 is alkyl having from 1 to 18 carbon atoms, aryl, or alkylphenyl having from 7 to 12 carbon atoms;(c) R.sup.3 and R.sup.4 are independently alkyl, or aryl, or R.sup.3 and R.sup.4, taken together, form a fused carbocyclic or heterocyclic ring;(d) NHSO.sub.2 PUG represents a sulfonamido group;(e) PUG represents a photographically useful group; and(f) at least one of R.sup.1, R.sup.2, R.sup.3, or R.sup.
    Type: Grant
    Filed: September 16, 1983
    Date of Patent: August 12, 1986
    Assignee: Eastman Kodak Company
    Inventors: Claude F. Gerbal, Thomas E. Gompf, Pierre D. Collet
  • Patent number: 4562247
    Abstract: There are described azo compounds of the formula ##STR1## wherein D.sub.1 and D.sub.2 are each the radical of a diazo component, R is C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 alkyl substituted by C.sub.1 -C.sub.4 -alkoxy or halogen or is phenyl or phenyl substituted by C.sub.1 -C.sub.4 -alkyl, halogen or C.sub.1 -C.sub.4 alkoxy, and Y is a basic or cationic group. These azo compounds can be used as dyes for dyeing and printing natural and synthetic, cationically dyeing substrates, particularly textile materials and paper.
    Type: Grant
    Filed: May 29, 1984
    Date of Patent: December 31, 1985
    Assignee: Ciba Geigy Corporation
    Inventor: Visvanathan Ramanathan
  • Patent number: 4558121
    Abstract: The invention provides novel symmetrical and unsymmetrical disazo dyes which in the form of the free acid have the formula I ##STR1## wherein each R independently of the other represents hydrogen or an alkyl group of 1 to 4 carbon atoms,each R.sub.1 independently of the other represents hydrogen, the methyl, ethyl, hydroxyethyl or cyanoethyl radical, but especially hydrogen,each X independently of the other represents hydrogen, halogen, an alkyl or alkoxy group, each of 1 to 4 carbon atoms,each Y independently of the other represents hydrogen or an alkoxy group of 1 to 4 carbon atoms,each Z independently of the other represents hydrogen, an acylamino group or an alkyl or alkoxy group, each of 1 to 4 carbon atoms, andB represents an acyl radical.
    Type: Grant
    Filed: October 23, 1980
    Date of Patent: December 10, 1985
    Assignee: Ciba Geigy Corporation
    Inventors: Alfred Fasciati, Arthur Buhler
  • Patent number: 4536570
    Abstract: This invention relates to novel mixtures consisting essentially of benzanilide bridged disazo compounds which are randomly substituted with x (N-substituted sulfonamido) groups, to acid-addition salts of said disazo compounds, useful as direct dyes particularly in the dyeing of cellulose, and to methods of preparation of said mixtures of (N-substituted sulfonamido) substituted disazo compounds.
    Type: Grant
    Filed: October 25, 1982
    Date of Patent: August 20, 1985
    Assignee: The Hilton-Davis Chemical Co.
    Inventor: Nathan N. Crounse