Acyclic Chain Which Contains -ch=n- (substitution May Be Made For Hydrogen Only) Patents (Class 534/738)
  • Publication number: 20110177315
    Abstract: A light absorption anisotropic film, having at least one dichroic dye, in which the light absorption anisotropic film shows a diffraction peak derived from a periodic structure in a direction in a plane of the light absorption anisotropic film in X-ray diffraction measurement and the diffraction peak has a half width of 1.0 ? or less.
    Type: Application
    Filed: September 3, 2009
    Publication date: July 21, 2011
    Applicant: FUJIFILM CORPORATION
    Inventors: Nobutaka Iwahashi, Masashi Ogiyama, Shinichi Morishima
  • Publication number: 20080306030
    Abstract: The present invention is directed to methods of enhancing insulin release, GLP-1 release, and insulin sensitivity, methods of increasing insulin gene expression, methods of decreasing gastric secretion and emptying and glucagons secretion, and methods of inhibiting food intake, and methods of treating diabetes mellitus, insulin resistance syndrome, hyperglycemia, and obesity comprising administering to a subject an effective amount of a TRPM5 inhibitor.
    Type: Application
    Filed: February 4, 2008
    Publication date: December 11, 2008
    Applicant: Redpoint Bio Corporation
    Inventors: S. Paul Lee, Peihong Zhou, M.N. Tulu Buber, Rok Cerne, Robert Bryant, F. Raymond Salemme, Gillian Morgan
  • Patent number: 7405280
    Abstract: The invention relates to chromogenic compounds and the use thereof for the determination of enzymes of the family of carboxypeptidases N and carboxypeptidases U. The above is more specifically a compound of formula (I) in which A=(1), (2), (3), (4) or (5), R1, R2=H, —CH3, —CH(CH3)2, —OCH3, —Cl,—CF3,—OCF3,—SCH3, R3=an amino acid group which may be hydrolysed by a carboxypeptidase A and R4=a basic amino acid group.
    Type: Grant
    Filed: January 5, 2004
    Date of Patent: July 29, 2008
    Assignee: Diagnostica Stago
    Inventor: Gérard Quentin
  • Patent number: 7186748
    Abstract: The present invention provides novel compounds of the general Formula (I) as ligands to the melanocortin receptors and/or for treatment of disorders in the melanocortin system: wherein X is (CH2)n where n is 0, 1 or 2; R1, R2, R3, R4 and R5 may be the same or different and are selected from hydrogen, halogen, alkyl having 1 to 5 carbon atoms, alkoxy having 1 to 5 carbon atoms, hydroxy, alkylsulphonyloxy, cyano, nitro, trihaloalkyl, sulpho or one of the structures given in Scheme 1; or two of R1, R2, R3, R4 and R5 may together form a methylenedioxy or ethylenedioxy moiety; R6, R7, R8 and R9 are the same or different and are selected from hydrogen, halogen, alkyl having 1 to 5 carbon atoms, alkoxy having 1 to 5 carbon atoms, hydroxy, amines (primary, secondary or tertiary) having 0, 1 or 2 carbon atoms, cyano, nitro, trihaloalkyl, amide or sulpho, and z where shown represents the point of attachment of the residue to the phenyl or pyrrole ring; and the pharmacologically active salts thereof.
    Type: Grant
    Filed: August 6, 2002
    Date of Patent: March 6, 2007
    Assignee: Action Pharma A/S
    Inventors: Torbjörn Lundstedt, Anna Skottner, Arne Boman, Per Andersson, Elisabeth Seifert, Victor Andrianov
  • Patent number: 6492502
    Abstract: Azo compounds of the 2-(4-amino)phenyldiazinecarboximidamide type and 2-(4-amino)phenylhydrazinecarboximidamide type, a process for their synthesis, their use for dyeing keratin fibers, dye compositions containing them, and dyeing processes.
    Type: Grant
    Filed: December 18, 2000
    Date of Patent: December 10, 2002
    Assignee: L'Oreal, S.A.
    Inventors: Jean-Christophe Henrion, Michel Philippe
  • Patent number: 6407219
    Abstract: The invention concerns a method for preparing an azoiminoether hydrochloride which consists in reacting an azonitrile with an alcohol and hydrochloric acid in an aromatic solvent, wherein the molar ratio R=HCl/azonitrile is >2 when the alcohol is methanol and >3 when the alcohol is ethanol or a higher alcohol. The invention also concerns a method for preparing an azocarboxylic acid ester which consists in the synthesis of an azoiminoether hydrochloride by the inventive method and, hydrolysis in the presence of the resulting azoiminoether hydrochloride. Said methods enable to obtain liquid composition of azocarboxylic acid esters. The invention further concerns mixed azoiminoether salts of formula (II′). The invention also concerns mixed azoiminocarboxylic acid esters corresponding to the formula (III′).
    Type: Grant
    Filed: September 28, 2001
    Date of Patent: June 18, 2002
    Assignee: Atofina
    Inventor: Paul Bourdauducq
  • Patent number: 6221535
    Abstract: A photorefractive composite comprises a charge transport matrix and an electrooptic dye having an aliphatic group of four or more carbon atoms.
    Type: Grant
    Filed: January 11, 1999
    Date of Patent: April 24, 2001
    Assignee: The Victoria University of Manchester
    Inventors: Alan M. Cox, Richard D. Blackburn, Frances A. Wade, David P. West, Terence A. King, David Leigh
  • Patent number: 5834603
    Abstract: A polymerization initiator composition, comprising an azobisamidine salt represented by the general formula (1) ##STR1## wherein R.sup.1 and R.sup.2 independently represent an alkyl group or a cycloalkyl group, providing that R.sup.1 and R.sup.2 may together form an aliphatic ring, and Y represents --C(.dbd.NR.sup.3)--NH--R.sup.4 or a guanyl group represented by the formula (2) ##STR2## wherein R.sup.3 and R.sup.4 independently represent a hydrogen atom, an alkyl group, a substituted alkyl group, a cycloalkyl group, an allyl group, a phenyl group, or a substituted phenyl group, R.sup.5 represents a lower alkylene group optionally containing a substituent group, and R.sup.6 represents a hydrogen atom or a hydroxyalkyl group, and X represents a chlorine atom, a bromine atom, or a CH.sub.3 COO-- group, and a hydrophilic organic compound.
    Type: Grant
    Filed: November 19, 1997
    Date of Patent: November 10, 1998
    Assignee: Nippoh Chemicals Co., Ltd.
    Inventors: Tsuneo Tsubakimoto, Toshiyasu Sato, Hisayuki Suzuki
  • Patent number: 5650498
    Abstract: The present invention provides a process for producing a spherical granule of a water-soluble azo compound, which comprises dispersing a water-soluble azo compound in a water-insoluble solvent and then add dropwise water or a hydrophilic solvent dissolving the water-soluble azo compound with stirring to granulate the water-soluble azo compound in the solution, and produce the spherical granule of the water-soluble azo compound.
    Type: Grant
    Filed: October 19, 1994
    Date of Patent: July 22, 1997
    Assignee: Otsuka Kagaku Kabushiki Kaisha
    Inventors: Hideo Amo, Masaya Kajimoto, Akihiko Goto
  • Patent number: 5569749
    Abstract: An organic photoconductive material is represented by the following general formula [1]:A.sub.1 --N.dbd.N--B--N.dbd.N--A.sub.2 [1],wherein B is a divalent organic group bonded to nitrogen atoms forming azo groups, A.sub.1 and A.sub.2 are groups different from each other, A.sub.1 is represented by the following general formula [A1]: ##STR1## wherein X is an atomic group which is necessary for forming an aromatic hydrocarbon ring or an aromatic hetero-ring by condensation with the benzene ring, Y is a hydrogen atom, an alkyl group, an alkoxy group or a halogen atom, m is an integer of 1 to 4, R is an aromatic hydrocarbon ring group or an aromatic hetero-ring group and n is 1 or 2, and A.sub.2 is a group represented by one of the following general formulae [A2] and [A3]: ##STR2## wherein a.sub.1 is a group selected from R, --N.dbd.CH--R and ##STR3## R, X, Y, m and n are the same as those in the general formula [A1] and p is 0 or 1.
    Type: Grant
    Filed: January 18, 1996
    Date of Patent: October 29, 1996
    Assignee: Dainichiseika Color & Chemicals Mfg. Co., Ltd.
    Inventors: Hisao Kouno, Shyouichi Takahashi, Kazuhiro Higashide, Nakaji Komiyama, Osamu Suda, Masaru Hasegawa
  • Patent number: 5554735
    Abstract: Azo oxime ethers of formula (I), in which X is CH or N, R.sub.1 is hydrogen, C.sub.1 -C.sub.3 alkyl, trifluoromethyl or cylclopopy and R.sub.2 is aryl or heteroaryl, have an activity against phytopathogenic fungi. They can be used in the form of formulaions as crop protection products, seed-dressing products and wood preservatives.
    Type: Grant
    Filed: August 26, 1994
    Date of Patent: September 10, 1996
    Assignee: Ciba-Geigy Corporation
    Inventors: Hugo Ziegler, Stephan Trah
  • Patent number: 5506346
    Abstract: An organic photoconductive material is represented by the following general formula [1]:A.sub.1 -N.dbd.N-B-N.dbd.N-A.sub.2 [1],wherein B is a divalent organic group bonded to nitrogen atoms forming azo groups, A.sub.1 and A.sub.2 are groups different from each other, A.sub.1 is represented by the following general formula [A1]: ##STR1## wherein X is an atomic group which is necessary for forming an aromatic hydrocarbon ring or an aromatic hetero-ring by condensation with the benzene ring, Y is a hydrogen atom, an alkyl group, an alkoxy group or a halogen atom, m is an integer of 1 to 4, R is an aromatic hydrocarbon ring group or an aromatic hetero-ring group and n is 1 or 2, and A.sub.2 is a group represented by one of the following general formulae [A2] and [A3]: ##STR2## wherein a.sub.1 is a group selected from R, -N.dbd.CH-R and ##STR3## R, X, Y, m and n are the same as those in the general formula [A1] and p is 0 or 1.
    Type: Grant
    Filed: February 28, 1994
    Date of Patent: April 9, 1996
    Assignee: Dainichiseika Color & Chemicals Mfg. Co., Ltd.
    Inventors: Hisao Kouno, Shyouichi Takahashi, Kazuhiro Higashide, Nakaji Komiyama, Osamu Suda, Masaru Hasegawa
  • Patent number: 5308869
    Abstract: N,N'-disubstituted-amidines, e.g., of the formula ##STR1## wherein R, R' and R" are substituted or unsubstituted hydrocarbon and/or heterocyclic groups.Methods are provided for the treatment or prophylaxis of anxiety in an animal, for treating psychosis, and for treating hypertension by administering an effective amount of an N,N'-disubstituted amidine which, preferably, has a high affinity for the sigma receptor.
    Type: Grant
    Filed: March 30, 1992
    Date of Patent: May 3, 1994
    Assignee: State of Oregon, acting by and through the Oregon State Board of Higher Education
    Inventors: John F. W. Keana, Eckard Weber
  • Patent number: 5302704
    Abstract: Dyes of formula ##STR1## wherein D is the radical of a diazo component of the benzene or naphthalene series or of the heterocyclic series, R.sub.1 is hydrogen or C.sub.1 -C.sub.4 alkyl and R.sub.2 is phenyl or substituted phenyl, give dyeings of good fastness properties on nitrogen-containing or hydroxyl group containing fibre materials.
    Type: Grant
    Filed: August 3, 1992
    Date of Patent: April 12, 1994
    Assignee: Ciba-Geigy Corporation
    Inventors: Jean-Marie Adam, Thomas Eichenberger
  • Patent number: 5145952
    Abstract: Thiopheneazo dyes of the formula ##STR1## where X is cyano or C.sub.1 -C.sub.4 -alkoxycarbonyl,Y is halogen, hydroxyl, mercapto, substituted or unsubstituted C.sub.1 -C.sub.6 -alkoxy, C.sub.5 -C.sub.7 -cycloalkoxy, substituted or unsubstituted phenoxy, substituted or unsubstituted C.sub.1 -C.sub.6 -alkylthio, C.sub.5 -C.sub.7 -cycloalkylthio, substituted or unsubstituted phenylthio, C.sub.1 -C.sub.6 -alkylsulfonyl or substituted or unsubstituted phenylsulfonyl,Z is nitro, cyano, C.sub.1 -C.sub.4 -alkanoyl, benzoyl, C.sub.1 -C.sub.4 -alkylsulfonyl, phenylsulfonyl or a radical of the formula --CH.dbd.CB.sup.1 B.sup.2 or --CH.dbd.N--B.sup.3, in which B.sup.1 and B.sup.2 independently of the other are cyano, substituted or unsubstituted C.sub.1 -C.sub.6 -alkoxycarbonyl or C.sub.3 -C.sub.6 -alkenyloxycarbonyl or one of B.sup.1 and B.sup.2 is cyano and the other is C.sub.1 -C.sub.4 -alkylsulfonyl, substituted or unsubstituted phenyl, benzoyl, phenylsulfonyl or carbamoyl and B.sup.3 is hydroxyl, C.sub.1 -C.sub.
    Type: Grant
    Filed: December 29, 1989
    Date of Patent: September 8, 1992
    Assignee: BASF Aktiengesellschaft
    Inventors: Heinz Eilingsfeld, Karl-Heinz Etzbach, Guenter Hansen, Helmut Reichelt, Ernst Schefczik
  • Patent number: 5132411
    Abstract: Compounds of the formula ##STR1## wherein R is halo,R.sub.1 is cyano; (C.sub.1-6 alkoxy)carbonyl; (C.sub.3-6 alkenyl)oxycarbonyl; C.sub.1-4 alkylsulfonyl; phenylsulfonyl; (C.sub.1-4 alkyl)carbonyl; benzoyl; carbamoyl; (C.sub.1-4 alkyl)carbamoyl; N,N-di-(C.sub.1-4 alkyl)carbamoyl; phenylcarbamoyl; benzyloxycarbonyl; or (C.sub.1-6 alkoxy)carbonyl, (C.sub.3-6 alkenyl)oxycarbonyl, C.sub.1-4 alkylsulfonyl, phenylsulfonyl or (C.sub.1-4 alkyl)carbamoyl substituted by one or two substituents independently selected from chloro, bromo, C.sub.1-4 alkyl, C.sub.1-4 alkoxy, hydroxy, cyano and acyl, andR.sub.2 is formyl, cyano, --CH.dbd.C(R.sub.4).sub.2 or --CH.dbd.N--OH,wherein (1) each R.sub.4 is independently cyano; (C.sub.1-6 alkoxy)carbonyl; (C.sub.3-6 alkenyl)oxycarbonyl; (C.sub.3-6 alkynyl)oxycarbonyl; or (C.sub.1-6 alkoxy)carbonyl, (C.sub.3-6 alkenyl)oxycarbonyl or (C.sub.3-6 alkynyl)oxycarbonyl substituted by one or two substituents independently selected from chloro, bromo, C.sub.1-4 alkyl, C.sub.
    Type: Grant
    Filed: March 19, 1990
    Date of Patent: July 21, 1992
    Assignee: Sandoz Ltd.
    Inventors: Robert Egli, Beat Henzi
  • Patent number: 5118737
    Abstract: A water-soluble dye, free from cellulose reactive groups, of the formula: ##STR1## wherein R.sup.1 is --(C.sub.a H.sub.2a O).sub.m (C.sub.b H.sub.2b O).sub.n H,R.sup.2 is H or --(C.sub.a H.sub.2a O).sub.m (C.sub.b H.sub.2b O).sub.n H, orR.sup.1 and R.sup.2 together with the nitrogen atom form a morpholine ringa and b are different and from 1 to 8m is from 1 to 10;n is from 0 to 9;M is H, ammonium, or a monovalent metal;X (i) NR.sup.1 R.sup.2, (ii) NR.sup.3 R.sup.4, in which R.sup.3 and R.sup.
    Type: Grant
    Filed: June 22, 1990
    Date of Patent: June 2, 1992
    Assignee: Canon Kabushiki Kaisha
    Inventors: Anthony G. W. Baxter, Stephen B. Bostock, David Greenwood
  • Patent number: 4956255
    Abstract: The present invention relates to a photosensitive member containing a specific azo compound represented by the following general formula [I]; ##STR1## wherein A is a bivalent group of a condensed poly-cyclic ring which may have a substituent, a pyridine which may have a substituent, a diazine which may have a substituent, a quinoline which may have a substituent, or a benzoazine which may have a substituent; Cp is a residual group of a coupler, which is improved in photosensitive porperties, in particular, sensitivity.
    Type: Grant
    Filed: February 22, 1989
    Date of Patent: September 11, 1990
    Assignee: Minolta Camera Kabushiki Kaisha
    Inventor: Hideaki Ueda
  • Patent number: 4952681
    Abstract: Compounds of the formula I ##STR1## where X is fluorine, chlorine, bromine, SO.sub.2 E or unsubstituted or substituted hydroxyl or mercapto, E is alkyl, alkenyl, cycloalkyl, aralkyl, aryl, chlorine or unsubstituted or substituted hydroxyl or amino, Y is cyano, nitro, alkanoyl, aroyl, alkylsulfonyl, arylsulfonyl, carboxyl, a carboxylic ester group or unsubstituted or substituted carbamyl, T is hydrogen, C.sub.1 -C.sub.4 -alkyl, a radical which can be introduced by electrophilic substitution or a radical of the formula --CH.dbd.B, in which B is a radical of a methylene-active compound or of an amine, and K is a radical of a coupling component, are disclosed. They are useful for dyeing synthetic fibers or plastics.
    Type: Grant
    Filed: July 27, 1988
    Date of Patent: August 28, 1990
    Assignee: Sandoz AG
    Inventors: Guenter Hansen, Ernst Schefczik, Karl-Heinz Etzbach, Helmut Reichelt, Hermann Loeffler
  • Patent number: 4950742
    Abstract: An azoimino ether, which is an intermediate for preparing polymerization initiators, is prepared by reacting a hydrazonitrile having a hydrazo group and at least one cyano group in the molecule with chlorine in the presence of an alcohol, in a non-aqueous organic solvent.
    Type: Grant
    Filed: March 6, 1989
    Date of Patent: August 21, 1990
    Assignee: Wako Pure Chemical Industries, Ltd.
    Inventors: Kazuo Ichiriki, Motoaki Tanaka, Toru Okugawa, Hiroyoshi Nawa
  • Patent number: 4942225
    Abstract: Preparation of diazo compounds by transfer of diazo groups to activated methylene compounds, characterized in that an azidoformamidinium salt is used as the diazo group transferring agent, and also preparation of azo compounds by this route.
    Type: Grant
    Filed: June 20, 1988
    Date of Patent: July 17, 1990
    Assignee: Bayer Aktiengesellschaft
    Inventor: Manfred Lorenz
  • Patent number: 4939053
    Abstract: The present invention relates to a photosensitive member containing a specific azo compound for a charge generating agent, which is improved in photosensitive properties, in particular, sensitivity. The specific azo compound is represented by the formula (1): ##STR1## wherein A represents an aromatic hydrocarbon or a heterocyclic ring; R.sub.1 and R.sub.2 independently represent a hydrogen, a halogen atom, or an alkyl, aralkyl, aryl, condensed polycyclic ring or condensed heterocyclic ring; or R.sub.1 and R.sub.2 combinedly form a cyclic ring; n represents an integer from 1 to 4.
    Type: Grant
    Filed: February 10, 1988
    Date of Patent: July 3, 1990
    Assignee: Minolta Camera Kabushiki Kaisha
    Inventor: Hideaki Ueda
  • Patent number: 4916216
    Abstract: Granules of azobisamidine salt can be produced by granulating a powder of azobisamidine salt using a limited amount of water or a mixture of water and a water-soluble organic solvent such as methanol are convenient in handling without deteriorating the quality and can be used as a water-soluble polymerization initiator.
    Type: Grant
    Filed: May 11, 1987
    Date of Patent: April 10, 1990
    Assignee: Wako Pure Chemical Industries, Ltd.
    Inventors: Motoaki Tanaka, Takanori Toyama, Hiroki Sugioka
  • Patent number: 4908437
    Abstract: The invention relates to novel thienone compounds useful in dyeing fibers, of the formula: ##STR1## where R.sup.1 is cyano, C.sub.1 -C.sub.4 -alkoxycarbonyl, carbamoyl or C.sub.1 -C.sub.4 -monoalkylcarbamoyl or -dialkylcarbamoyl,R.sup.2 is hydrogen, C.sub.1 -C.sub.8 -alkyl, substituted or unsubstituted phenyl, furyl, thienyl or halogen,X is nitrogen or CR.sup.4 where R.sup.4 is hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxycarbonyl, cyano or substituted or unsubstituted phenyl, andR.sup.3 is an aniline, thiazole, indole, styrol or isoindole radical, with the proviso that if R.sup.1 is cyano, X is CH and R.sup.3 is 4-dimethylaminophenyl or styryl, then R.sup.2 is not methyl or phenyl and that if R.sup.1 is cyano, X is CH and R.sup.3 is phenyl or 4-methoxyphenyl, then R.sup.2 is not phenyl.
    Type: Grant
    Filed: May 17, 1988
    Date of Patent: March 13, 1990
    Assignee: BASF Aktiengesellschaft
    Inventors: Guenter Hansen, Johannes P. Dix, Helmut Reichelt, Masahiro Hayashi
  • Patent number: 4904777
    Abstract: A thiophene-containing azo dye of the formula ##STR1## where R is substituted or unsubstituted alkyl, alkenyl, cycloalkyl or phenyl, X is hydrogen, halogen, hydroxyl, unsubstituted or substituted alkoxy, cycloalkoxy, phenoxy, mercapto, alkylthio, phenylthio, alkylsulfonyl, phenylsulfonyl or phenyl and Y is cyano, nitro, alkanoyl, substituted or unsubstituted benzoyl, alkylsulfonyl, phenylsulfonyl, Co-Z, where Z is unsubstituted or substituted phenoxy, amino, mono- or dialkyl-amino, pyrrolidino, piperidino, morpholino or N-alkyl-piperazino, and K is the radical of a coupling component is used as dyes for dyeing fiber material.
    Type: Grant
    Filed: October 19, 1987
    Date of Patent: February 27, 1990
    Assignee: BASF Aktiengesellschaft
    Inventors: Karl-Heinz Etzbach, Guenter Hansen, Ernst Schefczik, Helmut Reichelt
  • Patent number: 4882249
    Abstract: Disclosed are a photoconductive composition containing a new tetrakisazo compound of the following formula (1) and an electrophotographic photoreceptor having a photosensitive layer which contains the tetrakisazo compound of the formula (1): ##STR1## wherein R.sup.11, R.sup.12, A, Ar.sup.1, Ar.sup.2, Ar.sup.3, Ar.sup.4, Ar.sup.5, and Ar.sup.6 are defined hereinbefore. The electrophotographic photoreceptor has both high sensitivity and high durability, and the sensitivity thereof is barely lowered even after repeated use.
    Type: Grant
    Filed: September 12, 1988
    Date of Patent: November 21, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Katsugi Kitatani, Satoshi Hoshi
  • Patent number: 4865990
    Abstract: A colored compound containing a cationic group and a cellulose reactive group, especially a compound of the formula:A--Y--B IY'--B IIwhereinA is the cationic group;Y is a chromophore;Y' is a cationic chromophoreandB is the reactive group, which is suitable for the preparation of a protein adsorbent or precipitant for use in the separation of mixtures of proteins.
    Type: Grant
    Filed: July 9, 1987
    Date of Patent: September 12, 1989
    Assignee: Imperial Chemical Industries Plc
    Inventors: Cecil V. Stead, Christopher R. Lowe
  • Patent number: 4846879
    Abstract: Herbicidally active compounds of the formula ##STR1## in which R.sup.1 represents halogen, cyano or C.sub.1 -C.sub.6 -alkyl (which is optionally substituted by fluorine, chlorine, bromine, cyano, C.sub.1 -C.sub.4 -alkoxy, C.sub.3 -C.sub.6 -cycloalkyl or phenyl), or represents C.sub.1 -C.sub.4 -alkoxy (which is optionally substituted by chlorine, bromine, cyano or C.sub.1 -C.sub.4 -alkoxy),R.sup.2 represents optionally substituted aryl,R.sup.3 represents hydrogen, halogen, hydroxyl, C.sub.1 -C.sub.6 -alkylamino or di-(C.sub.1 -C.sub.6 -alkyl)-amino, or represents optionally substituted C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy or C.sub.1 -C.sub.6 -alkylthio, andR.sup.4 represents hydrogen, halogen or hydroxyl, or represents optionally substituted C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy or C.sub.1 -C.sub.6 -alkylthio, or represents C.sub.1 -C.sub.6 -alkylamino or di-(C.sub.1 -C.sub.
    Type: Grant
    Filed: October 7, 1987
    Date of Patent: July 11, 1989
    Assignee: Bayer Aktiengesellschaft
    Inventors: Christa Fest, Hans-Jochem Riebel, Hans-Joachim Santel, Robert R. Schmidt, Robert H. Strang
  • Patent number: 4843153
    Abstract: Thienothiophene dyes of the formula ##STR1## wherein Z is carboxylate, acyl, carboxyl, substituted or unsubstituted carbamoyl, cyano or nitro, X is hydrogen, fluorine, chlorine, bromine, Z or a group of the formula ##STR2## T.sup.1 and T.sup.2 are identical or different and each is independently of the other cyano, substituted or unsubstituted alkoxycarbonyl, alkenyloxycarbonyl, carbamoyl or alkylcarbamoyl and W is hydrogen, methyl or ethyl, Y is hydrogen, chlorine or bromine and K is the radical of a coupling component, are highly suitable for dyeing synthetic fibers, in particular polyesters wherein the dyeing obtained have good fastness properties.
    Type: Grant
    Filed: July 1, 1987
    Date of Patent: June 27, 1989
    Assignee: BASF Aktiengesellschaft
    Inventors: Heinz Eilingsfeld, Karl-Heinz Etzbach, Guenter Hansen, Helmut Reichelt
  • Patent number: 4833235
    Abstract: Disazo compounds of the formula ##STR1## and salt thereof, D is the radical of a diazo component of the benzene or naphthalene series.K is the radical of a heterocyclic coupling component of the aminopyrazole-, pyridone- or barbituric acid-series, n is 1 to 4,R.sub.1 is hydrogen, C.sub.1-4 alkyl or substituted C.sub.1-4 alkyl,each of R.sub.2 and R.sub.3 is independently hydrogen, halo, C.sub.1-4 alkyl, substituted C.sub.1-4 alkyl, C.sub.1-4 alkoxy, substituted C.sub.1-4 alkoxy, --NHCO--Rhd 5, amino, substituted amino or a quaternary ammonium group, wherein R.sub.5 is C.sub.1-4 alkyl, substituted C.sub.1-4 alkyl, C.sub.1-4 alkoxy or amino,R.sub.4 is hydrogen, C.sub.1-4 alkyl, C.sub.
    Type: Grant
    Filed: October 7, 1987
    Date of Patent: May 23, 1989
    Assignee: Sandoz Ltd.
    Inventor: Reinhard Pedrazzi
  • Patent number: 4804747
    Abstract: (i) A compound of the formula: ##STR1## wherein R is H, a metal or a group containing a tetravalent N atom;X is S, O, ##STR2## R.sup.1 is NO.sub.2, CN or COOY; Y is H, C.sub.1-4 -alkyl, a metal or a group containing a tetravalent N atom;R.sup.2 and R.sup.3 are each independently H or a non-hydrophilic aliphatic or cycloaliphatic group containing up to 30 carbon atoms;R.sup.4 and R.sup.5 are each independently H or a non-hydrophilic aliphatic or cycloaliphatic group containing up to 30 carbon atoms; andR.sup.6 and R.sup.7 are each independently H or a non-hydrophilic group containing up to 4 carbon atoms; orR.sup.4 and R.sup.6 together comprise ring fused to Ring A and R.sup.5 and R.sup.7 are as hereinbefore defined; orR.sup.5 and R.sup.7 together comprise ring fused to Ring A and R.sup.4 and R.sup.6 are as hereinbefore defined; orR.sup.2 and R.sup.4 together with the N atom to which R.sup.2 is attached form a ring fused to Ring A and R.sup.3 and R.sup.5 are as hereinbefore defined; orR.sup.3 and R.sup.
    Type: Grant
    Filed: October 16, 1986
    Date of Patent: February 14, 1989
    Assignee: Imperial Chemical Industries PLC
    Inventors: Simon Allen, Paul F. Gordon, Richard A. Hann
  • Patent number: 4775747
    Abstract: Transition metal complexes of the compounds of the formulae I and II ##STR1## in which A is an isocylic or heterocyclic aromatic radical, R is --H, halogen, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy, R.sub.1 is --H, C.sub.1 -C.sub.4 -alkyl or phenyl which is unsubstituted or substituted by halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, --NO.sub.2, --CONH.sub.2, --CONHR.sub.2 or C.sub.2 -C.sub.5 -N-alkylcarbamoyl, X is --CH.dbd. or --N.dbd. andB is --H, C.sub.1 -C.sub.4 -alkyl, --NHCONH.sub.2, --NHCONH-C.sub.1 -C.sub.4 -alkyl, --NHCONR.sub.2, --NHCSNH.sub.2, --NHCSR.sub.3, --NHC(NH)NH.sub.2, --NHR.sub.2, --NHCOR.sub.3, --NHSO.sub.2 R.sub.3 or a heterocyclic aromatic radical, and R.sub.2 and R.sub.3 are phenyl or substituted phenyl, are suitable for pigmenting high-molecular organic material.
    Type: Grant
    Filed: February 17, 1987
    Date of Patent: October 4, 1988
    Assignee: Ciba-Geigy Corporation
    Inventors: Georg Cseh, Paul Lienhard
  • Patent number: 4767844
    Abstract: An azo lake pigment is obtained by coupling an aromatic diazo component having a sulfonic acid group with a mixture of 2-hydroxy-3-naphthoic acid and a 2-hydroxy-3-naphthoic acid derivative represented by formula [I] ##STR1## wherein R represents a hydrogen atom, a naphthalene residue, a cyclohexyl group, or a group of the formula ##STR2## in which each of X, Y and Z represents a hydrogen atom, a lower alkyl group, a lower alkoxy group, a halogen atom, an acetylamino group, a benzoylamino group, a carbomoyl group or a phenylcarbamoyl group, and X and Y together may form a cyclized benzimidazolone, benzthiazole or benzoxazole group,and laking the resulting dye with an alkaline earth metal salt or a manganese salt.
    Type: Grant
    Filed: August 21, 1987
    Date of Patent: August 30, 1988
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Hirohito Ando, Zenji Takada, Shigeto Aoki, Yuko Shigeta
  • Patent number: 4760003
    Abstract: An electrophotographic photosensitive member comprises a photosensitive layer on a substrate, said photosensitive layer comprising a disazo pigment represented by the formula (1).
    Type: Grant
    Filed: May 21, 1986
    Date of Patent: July 26, 1988
    Assignee: Canon Kabushiki Kaisha
    Inventors: Masakazu Matsumoto, Takao Takiguchi, Masataka Yamashita, Shoji Umehara, Shozo Ishikawa, Hajime Miyazaki
  • Patent number: 4734218
    Abstract: Provided are novel dichroic azo dyestuffs, which contain skeletons represented by the following general formula: ##STR1## at one terminals of the long axes of the molecules of the azo dyestuffs, and liquid crystal compositions containing the dichroic azo dyestuffs in forms dissolved in liquid crystals. These dichroic azo dyestuffs have large dichroic ratios and high durability, and their compositions are employed as useful display devices.
    Type: Grant
    Filed: July 18, 1986
    Date of Patent: March 29, 1988
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Keisuke Takuma, Kimitoshi Kato, Hiroshi Aiga, Yasuyuki Yamada, Tsutomu Nishizawa
  • Patent number: 4716220
    Abstract: The present invention provides a tetrazoneum salt compound represented by the general formula (I): ##STR1## (wherein, X stands for an anion functional group); a disazo compound represented by the general formula (II): ##STR2## wherein, A stands for ##STR3## (wherein, R stands for an alkyl group, an alkoxy group, a nitro group, halogen, a cyano group or a halomethyl group, n stands for an integer of 0, 1, 2 or 3, and in case n is an integer of 2 or 3 R may be the same or different); a method for the production thereof, and electrophotographic elements using the same or like disazo compounds as the charge carrier generating materials.
    Type: Grant
    Filed: July 9, 1985
    Date of Patent: December 29, 1987
    Assignee: Ricoh Co., Ltd.
    Inventor: Kyoji Tsutsui
  • Patent number: 4703113
    Abstract: A water-soluble dye, free from cellulose reactive groups, of the formula: ##STR1## wherein R.sup.1 is --(C.sub.a H.sub.2a O).sub.m (C.sub.b H.sub.2b O).sub.n H,R.sup.2 is H or --(C.sub.a H.sub.2a O).sub.m (C.sub.b H.sub.2b O).sub.n H, orR.sup.1 & R.sup.2 together with the nitrogen atom form a morpholine ringa & b are different and from 1 to 8m is from 1 to 10;n is from 0 to 9;M is H, ammonium, or a monovalent metal;X (i) NR.sup.1 R.sup.2, (ii) NR.sup.3 R.sup.4, in which R.sup.3 and R.sup.
    Type: Grant
    Filed: August 12, 1985
    Date of Patent: October 27, 1987
    Assignee: Imperial Chemical Industries PLC
    Inventors: Anthony G. W. Baxter, Stephen B. Bostock, David Greenwood
  • Patent number: 4680385
    Abstract: Metal complex dyes that produce level, fast dyeings on textile materials are provided according to the formula ##STR1## wherein: D is a benzene, naphthalene or heterocyclic radical of a diazo component;Y is nitrogen or --CH;K is the radical of a coupling component if Y is nitrogen, or an o-hydroxyaldehyde radical if Y is --CH;Ka is a cation;Me is chromium or cobalt;Z.sub.1 is --O-- or --COO-- ortho to N.dbd.YZ.sub.2 is --O-- or --NR vicinal to N.dbd.Y, wherein R is hydrogen or a C.sub.1 -C.sub.4 alkyl or phenyl radical;R.sub.1 is a direct bond or a C.sub.1 -C.sub.8 -alkyl, C.sub.1 -C.sub.8 -alkenyl, or aryl radical or heterocyclic radial containing 1 to 3 sulfur, oxygen or nitrogen atoms;R.sub.2 is hydrogen or C.sub.1 -C.sub.8 -alkyl or aryl radical;R.sub.3 is hydrogen or a C.sub.1 -C.sub.8 alkyl, aryl or amino radical, or a heterocyclic radical containing 1 to 3 sulfur, oxygen or nitrogen atoms;V is a direct bond or oxygen;Q is oxygen or sulfur; andw is 0 or 1.
    Type: Grant
    Filed: March 28, 1985
    Date of Patent: July 14, 1987
    Assignee: Ciba-Geigy Corporation
    Inventor: Gerhard Back
  • Patent number: 4678851
    Abstract: Metal complex dyes that produce level, fast dyeings on textile materials are provided according to the formula ##STR1## wherein: D is a benzene, naphthalene or heterocyclic radical of a diazo component;Y is nitrogen or --CH;K is the radical of a coupling component if Y is nitrogen, or an o-hydroxyaldehyde radical if Y is --CH:Ka is a cation;Me is chromium or cobalt;Z.sub.1 is --O-- or --COO-- ortho to N.dbd.YZ.sub.2 is --O-- or --NR vicinal to N.dbd.Y, wherein R is hydrogen or substituted or unsubstituted C.sub.1 -C.sub.4 alkyl or phenyl;X is a fiber reactive radical bound directly to or through an amino or amino-containing group to the complex;R.sub.1 is a direct bond or substituted or unsubstituted C.sub.1 -C.sub.8 -alkyl, C.sub.1 -C.sub.8 -alkenyl, or aryl radical or heterocyclic radical containing 1 to 3 sulfur, oxygen or nitrogen atoms;R.sub.2 is hydrogen or substituted or unsubstituted C.sub.1 -C.sub.8 -alkyl or aryl;R.sub.3 is hydrogen or substituted or unsubstituted C.sub.1 -C.sub.
    Type: Grant
    Filed: March 28, 1985
    Date of Patent: July 7, 1987
    Assignee: Ciba-Geigy Corporation
    Inventors: Gerhard Back, Hans U. Schutz, Ulrich Schlesinger
  • Patent number: 4670486
    Abstract: High molecular weight organic material is effectively colored by the incorporation therein of a copper or nickel complex of the ligand compound of formula I ##STR1## wherein A is an isocyclic or heterocyclic aromatic moiety, R is H, halogen, lower alkyl or alkoxy, R.sub.1 is H, lower alkyl, phenyl or substituted phenyl, and B is H, lower alkyl, ureido or substituted ureido, guanidino, anilino, benzamido or a heterocyclic aromatic moiety.
    Type: Grant
    Filed: June 13, 1985
    Date of Patent: June 2, 1987
    Assignee: Ciba-Geigy Corporation
    Inventors: Georg Cseh, Paul Lienhard
  • Patent number: 4666805
    Abstract: The present invention relates to a novel disazo compound having the following general formula (I), ##STR1## wherein A represents ##STR2## (wherein R represents an alkyl, alkoxy, nitro, halogen, cyano or halomethyl group; n represents an integer of 0, 1, 2 or 3; and R may be the same or different when n is an integer of 2 or 3), and a method for preparing the same.The present invention further relates to a photosensitive material for use in electrophotography, characterized by providing a photosensitive layer containing a disazo pigment having the following general formula (VII), ##STR3## wherein A.sub.1 represents a coupler residue and R' represents hydrogen or a lower alkyl group.
    Type: Grant
    Filed: June 11, 1985
    Date of Patent: May 19, 1987
    Assignee: Ricoh Co., Ltd.
    Inventor: Mitsuru Hashimoto
  • Patent number: 4665163
    Abstract: Diaryl pigments having an excellent stability to heat are obtained by carrying out the coupling of bis-diazotized 3,3'-dichloro-4,4'-diaminobiphenyl with acetoacetanilides in the presence of an added quantity of acetoacetanilides which are monosubstituted or disubstituted in the 3-position or 4-position of the nucleus. As a result of their good heat stability, these pigments are particularly suitable for pigmenting plastics having processing temperatures above 200.degree. C.
    Type: Grant
    Filed: June 23, 1983
    Date of Patent: May 12, 1987
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Klaus Hunger, Heinrich Frolich, Hans-Joachim Lenz
  • Patent number: 4663442
    Abstract: A disazo compound, having the general formula, ##STR1## wherein Y represents a substituted or non-substituted cyclic hydrocarbon or substituted or non-substituted heterocycle; R represents hydrogen, substituted or non-substituted alkyl group, or substituted or non-substituted phenyl group; andZ represents a substituted or non-substituted cyclic hydrocarbon or heterocycle fused with phenyl nucleus.
    Type: Grant
    Filed: July 18, 1985
    Date of Patent: May 5, 1987
    Assignee: Ricoh Co., Ltd.
    Inventor: Masafumi Ohta
  • Patent number: 4656257
    Abstract: A disazo compound is provided which is represented by the formula (I): ##STR1## (wherein, R.sub.1 and R.sub.2 each stands for hydrogen, a lower alkyl group with 1-4 carbon atoms, a substituted or unsubstituted aralkyl group, a substituted or unsubstituted aromatic group, or a substituted or unsubstituted hetero ring group. R.sub.1 and R.sub.2 may be the same or different. And, R.sub.1 and R.sub.2 may mutually bond to form a ring).This disazo compound may be obtained by diazotating 2.6-diaminoanthraquinone and reacting the same with a coupler represented by the formula (IV): ##STR2## (wherein, R.sub.1 and R.sub.2 are the same as defined above). Further, a multilayer type electrophotographic element is provided which comprises a charge carrier generating layer and a charge transfer layer and uses, as a charge carrier generating substance, a disazo compound represented by the formula (I).
    Type: Grant
    Filed: June 20, 1985
    Date of Patent: April 7, 1987
    Assignee: Ricoh Co., Ltd.
    Inventor: Mitsuru Hashimoto
  • Patent number: 4652631
    Abstract: 1:2 chromium complex dyes suitable for dyeing nitrogen-containing materials and materials which contain hydroxyl groups, are disclosed which, in the form of the free acid, have the formula ##STR1## wherein each of the symbols independently has the following meanings: Z is nitrogen or a --CH,A is a benzene or naphthalene radical which carries the hydroxyl or carboxy ortho to the azo or azomethine group, or, if n is 1 and Z is a --CH, is the radical of an aliphatic, cycloaliphatic or aromatic aminocarboxylic acid,B and D are each independently of the other the radical of a coupling component which couples in the alpha- or o-position relative to X if Z is nitrogen, or the radical of an o-hydroxyaldehyde if Z is --CH,X is oxygen or --NR, wherein R is hydrogen or C.sub.1 -C.sub.4 alkyl, with the proviso that X must be oxygen if Z is --CH,Y is a bridge member of the formula --SO.sub.2 or --SO.sub.2 --NR--SO.sub.2 --, wherein R is hydrogen or C.sub.1 -C.sub.4 alkyl,n is 0 or 1, andp is an integer from 0 to 6.
    Type: Grant
    Filed: March 28, 1985
    Date of Patent: March 24, 1987
    Assignee: Ciba-Geigy Corporation
    Inventors: Fabio Beffa, Ulrich Schlesinger
  • Patent number: 4650859
    Abstract: Chrome azo-azomethine dyes are disclosed which contain a benzthiazolylphenyl or stilbenyl radical bound via an aldehyde group to the aldehyde moiety of the azomethine dyes. The dyes are particularly useful for dyeing wool, polyamide and leather.
    Type: Grant
    Filed: December 31, 1984
    Date of Patent: March 17, 1987
    Assignee: Ciba-Geigy Corporation
    Inventor: Fabio Beffa
  • Patent number: 4638052
    Abstract: An azo-pigment represented by the general formula: ##STR1## where R.sub.1 is a hydrogen atom, a C.sub.1 -C.sub.4 alkyl group, an unsubstituted phenyl group or a substituted phenyl group, R.sub.2 is a residue of a phenylenediamine, and R.sub.3 is a hydrogen atom, a methyl group, a methoxy group or a halogen atom. The azo-pigment of the present invention is useful in applications where azo-pigments are used.
    Type: Grant
    Filed: December 27, 1984
    Date of Patent: January 20, 1987
    Assignee: Dainichiseika Color & Chemicals Mfg. Co., Ltd.
    Inventors: Kimihide Kawamura, Shojiro Horiguchi, Hisao Okamoto
  • Patent number: 4628082
    Abstract: Azobarbituric acid derivatives characterized in that in their free acid form they have the following tautomeric structure are disclosed: ##STR1## The azobarbituric acid derivatives are characterized in that X and Y rings can each carry one or two substituents from the series comprising .dbd.O, .dbd.S, .dbd.NR.sub.7, --NR.sub.6 R.sub.7, --OR.sub.6, --SR.sub.6, --COOR.sub.6, --CN, --CONR.sub.6 R.sub.7, --SO.sub.2 R.sub.8, ##STR2## alkyl, cycloalkyl, aryl and aralkyl, the total number of the endocyclic and exocyclic double bonds for each of the rings X and Y being three.The new azobarbituric acid derivatives are other than those of azobarbituric acid, azouracil and uracil-5-azobarbituric acid and their salts. The compounds are useful as pigments which pigments are useful for pigmented paints, in printing inks, distempers or emulsion paints, inter alia.
    Type: Grant
    Filed: May 14, 1985
    Date of Patent: December 9, 1986
    Assignee: Bayer Aktiengesellschaft
    Inventors: Manfred Lorenz, Karl H. Schundehutte
  • Patent number: 4619994
    Abstract: A compound, useful as an anti-cancer drug or agent, having the formulaR.sub.1 --X--R.sub.2where X represents a polynuclear aromatic or heteroaromatic hydrocarbon having between two and four fused rings which may be substituted by hydroxyl, amino, alkylamino, alkoxy or halogeno, R.sub.1 represents: ##STR1## where y represents one member selected from: ##STR2## or alkylated derivatives thereof, and R.sub.2 represents hydrogen or R.sub.1, an acid addition salt of said compound, a nitrogen oxide derivative of said compound in the case where it contains a ring nitrogen atom or atoms, and a quaternary salt of said compound in the case where it contains a ring nitrogen atom or atoms.
    Type: Grant
    Filed: July 25, 1985
    Date of Patent: October 28, 1986
    Inventor: Douglas Shortridge
  • Patent number: 4605734
    Abstract: A compound, useful as an anti-cancer drug or agent, having the formula: ##STR1## where X represents hydroxyl, amino or alkylamino, Y represents one member selected from ##STR2## or alkylated derivatives thereof, and Z represents hydrogen or one of the basic groups of Y, an acid addition salt of the said compound, a nitrogen oxide derivative of the said compound in the case where it contains a ring nitrogen atom or atoms.
    Type: Grant
    Filed: September 25, 1984
    Date of Patent: August 12, 1986
    Inventor: Douglas Shortridge