Abstract: Monoazo compounds of the formula ##STR1## in which one of the two substituents R.sub.1 or R.sub.2 or both substituents are C.sub.3 -C.sub.8 -alkyl or a group of the formula ##STR2## in which R.sub.3 and R.sub.4 are independently of each other hydrogen or C.sub.1 -C.sub.4 -alkyl and R.sub.5 is hydrogen, halogen or C.sub.1 -C.sub.4 -alkyl and the other of the two substitutents R.sub.1 or R.sub.2, when the two are not C.sub.3 -C.sub.8 -alkyl or a group of the formula (1a), is hydrogen, halogen or C.sub.1 -C.sub.4 -alkyl, and KK is the radical of a coupling component which is free of water-solubilizing groups the two described. These compounds can be used as dyes for dyeing or printing for example polyester fibre materials.
Abstract: A monoazo compound, or a salt thereof, of the formula, ##STR1## wherein W is a hydrogen atom or a carbamoyl group, R.sub.1 is a lower alkyl group, R.sub.2 and R.sub.3 are independently a hydrogen atom or a lower alkyl group, A is an unsubstituted or substituted phenylene or naphthylene group, Y is --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 CH.sub.2 Z, in which Z is a group capable of being split by the action of an alkali, and X is an aromatic or aliphatic group substituted with one or two members selected from sulfonic acid group and carboxylic acid group, which is useful for dyeing fiber materials to give dyed products of a characteristic yellow color excellent in various fastness properties.
Abstract: A pigment composition consisting of 100 parts by weight of a pigment, and from 0.1 to 30 parts by weight of a pigment dispersant of formula ##STR1## in which Q is (a) an anthraquinone dye or pigment radical, (b) an azo dye or pigment radical, (c) a benzimidazolone dye or pigment radical, (d) a phthalocyanine dye or pigment radical, (e) a quinacridone dye or pigment radical, (f) a dioxazine dye or pigment radical, (g) an anthrapyrimidine dye or pigment radical, (h) an anthanthrone dye or pigment radical, (i) an indanthrone dye or pigment radical, (j) a falvanthrone dye or pigment radical, (k) a pyranthrone dye or pigment radical, (l) a perinone dye or pigment radical, (m) a perylene dye or pigment or (n) a thioindigo dye or pigment radical; X is a direct bonds, --CH.sub.2 --; ##STR2## Y.sub.1 is NH or --O--; Z is in which Y.sub.2 is --NH-- or --O--, or --NH--X--Q when n is 1; R.sub.1 and R.sub.
Abstract: Azo dyes of the formula ##STR1## and external salts thereof, wherein F is the residue of a monoazo or disazo compound in 1:1 metal complex form or of a trisazo, disazoazoxy or tetrakisazo compound in metal-free or 1:1 metal complex form,each X is independently --NR.sub.2 --Q--NR.sub.3 R.sub.4 or --NR.sub.2 --Q--N.sup..sym. R.sub.5 R.sub.6 R.sub.7,whereinQ is linear or branched C.sub.2-6 alkylene or --NH--CO--CH.sub.2 --,R.sub.2 is hydrogen or C.sub.1-4 alkyl,each of R.sub.3 and R.sub.4 is independently hydrogen; C.sub.1-6 alkyl; C.sub.2-6 alkyl monosubstituted by cyano or hydroxy in the 2-, 3-, 4-, 5- or 6-position; phenyl(C.sub.1-3 alkyl); phenyl(C.sub.1-3 alkyl) having, on the phenyl ring, 1, 2 or 3 substituents selected from chloro, C.sub.1-4 alkyl and C.sub.1-4 alkoxy; C.sub.5-6 cycloalkyl or C.sub.5-6 cycloalkyl substituted by 1, 2 or 3 C.sub.1-4 alkyl groups or --NR.sub.3 R.sub.
Abstract: Metal-free azo compounds of the formula ##STR1## wherein Ra is an aromatic group or an active methylene coupling component radical as defined in the specification,R.sub.t is an arylazo group or a group of the formula -Y-Z,whereinY is a direct bond or a bridging radical, andZ is a basic amino or quaternary ammonium group, ##STR2## wherein each of the variables is as defined above or below, X is a direct bond or a bridging radical,x is hydrogen, hydroxy C.sub.1-4 alkyl, C.sub.1-4 alkoxy, amino or carboxy,ring B is further unsubstituted or further substituted,d is 0, 1 or 2, andn is 0 or 1,with the provisos that (i) the compounds contain an average of at least 1.3 basic water-solubilizing groups, and (ii) the compounds are free of sulfo groups,and 1:1 and 1:2 metal complexes thereof,which metal-free compounds and metal complexes are useful as dyes for leather and paper.
Type:
Grant
Filed:
August 18, 1982
Date of Patent:
October 29, 1985
Assignee:
Sandoz Ltd.
Inventors:
Paul Doswald, Emil Moriconi, Helmut Moser, Horst Schmid
Abstract: Fibre-reactive dyes of the formula ##STR1## wherein D is the radical of a benzene or naphthalene azo dye which contains sulpho groups, each of R.sub.1, R.sub.2 and R.sub.3 is a hydrogen atom, B is an arylene group and A is an amino group.
Abstract: Symmetrical compounds of the formula, ##STR1## in which R.sub.1 is hydrogen, C.sub.1-4 alkyl or C.sub.1-4 alkoxy,R.sub.2 is hydrogen, C.sub.1-4 alkyl, C.sub.1-4 alkoxy or --NHCOR.sub.6,R.sub.3 is hydrogen or C.sub.1-4 alkyl,each of R.sub.4 and R.sub.5, independently, is hydrogen, C.sub.1-4 alkyl or hydroxy C.sub.2-4 alkyl,R.sub.6 is C.sub.1-4 alkyl, --NH.sub.2, --NC(C.sub.1-4 alkyl) or --N(C.sub.1-4 alkyl).sub.2,Hal is fluorine, chlorine or bromine, andX is either C.sub.2-10 alkylene, C.sub.3-10 alkenylene, mono- or dihydroxy C.sub.3-10 alkylene optionally containing one or two hetero atom linkages C.sub.5-7 cycloalkylene optionally substituted by 1 or 3 C.sub.1-4 alkyl groups,or X together with ##STR2## form a piperazine ring, with the proviso that X is other than unsubstituted C.sub.2-10 alkylene when R.sub.2 is --NHCOR.sub.