Hydroxy Bonded Directly To A Bicyclo Ring System Which Is Between The Azo Groups (h Of Hydroxy May Be Replaced By A Substituted Or Unsubstituted Ammonium Ion Or A Group Ia Or Iia Light Metal) Patents (Class 534/827)
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Publication number: 20150073132Abstract: Disclosed is a method for continuously preparing a water-soluble azo dye by coupling a nebulizer with a pipeline. According to the method, the nebulizer is coupled with a pipeline with an interception tower plate, atomized and mixed reaction liquid flow flows through the pipeline with the interception tower plate, and mixing and reacting are further enhanced through turbulent mixing on the tower plate, so that instant separation of reaction heat generated in an atomizing contact reaction from a reactant is achieved, and normal-temperature rapid continuous production of the water-soluble azo dye is achieved. Fog drops which are atomized by using the nebulizer have small particle diameter and large specific surface area, so that a diazo salt and a coupling component are sprayed separately, move face to face and can be fully contacted, and mixing and reacting speeds are increased.Type: ApplicationFiled: November 30, 2012Publication date: March 12, 2015Inventors: Shufen Zhang, Bingtao Tang, Rongwen Lv, Dong Liang
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Patent number: 8962815Abstract: This invention relates to bis-azo colorants for use as bluing agents, laundry care compositions comprising bis-azo colorants that may serve as bluing agents, processes for making such bluing agents and laundry care compositions and methods of using the same. The bluing agents are generally comprised of at least two components: at least one chromophore component and at least one polymeric component. These bluing agents are advantageous in providing a whitening effect to fabrics, while not building up over time and causing undesirable blue discoloration to the treated fabrics.Type: GrantFiled: January 24, 2013Date of Patent: February 24, 2015Assignee: Milliken & CompanyInventors: Robert L Mahaffey, Jr., Xiaoyong Michael Hong, Eduardo Torres, Dominick J Valenti, Gregory Scot Miracle
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Patent number: 8834620Abstract: Black disazo dyes of general formula (V) wherein A is a moiety of formula (VI) or of formula (VII) and B is a moiety of formula (VII) or of formula (IX) and wherein M, R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, R11, R12, R13, R14, R15, R16, R17, R18, R19, R20, R21, R22, R23, and R24, are as defined in the specification, are excellent black dyes for dying and printing cellulose containing materials and textile materials and, in particular, for preparation of recording liquids for ink jet printing and for writing utensils.Type: GrantFiled: October 17, 2011Date of Patent: September 16, 2014Assignee: Ilford Imaging Switzerland GmbHInventors: Kurt Baettig, Jean-Luc Gremaud, Damien Moigno
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Publication number: 20140026333Abstract: Reactive dyes of formula (1), wherein R1 and R2 are each independently of the other hydrogen or unsubstituted or substituted C1-C4alkyl, one of the radicals D1 and D2 is a radical of the formula (2), the other one of the radicals D1 and D2 is a radical of the formula (3a), or (3b), wherein (R3)n denotes n identical or different substituents selected from the group C1-C4alkyl, C1-C4alkoxy and sulfo, Z1 is a radical of the formula —SO2—Y (4a), —CONH—(CH2)p—SO2—Y (4b), —NH—CO—CH(Hal)-CH2-Hal (4c), —NH—CO—C(Hal)?CH2 (4d), or (4e), wherein X1 is halogen, T1 independently has the definition of X1, is a non-fibre-reactive substituent or is a fibre-reactive radical of the formula (5a), —NH—(CH2)2-3—SO2—Y (5b), or —NH—(CH2)2-3—O—(CH2)2-3—SO2—Y (5c), R4 is hydrogen or unsubstituted or substituted C1-C4alkyl, (R5)0-2 denotes from 0 to 2 identical or different substituents from the group C1-C4alkyl, C1-C4alkoxy and sulfo, Hal is halogen, Y is vinyl or a —CH2—CH2—U radical and U is a group that is removable under alkalineType: ApplicationFiled: March 5, 2012Publication date: January 30, 2014Inventors: Georg Roentgen, Laszlo Fekete, Michael Nicollet
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Patent number: 8465577Abstract: A novel black ink composition is provided. In the black ink composition of the present invention, the dye compounds include a blue dye compound of formula (I), a red dye compound of formula (II) and a yellow dye compound of formula (III). The black ink composition of the present invention is suitable for inkjet printing to improve light-fastness and printing property.Type: GrantFiled: June 30, 2010Date of Patent: June 18, 2013Assignee: Everlight USA, Inc.Inventors: Hsiao-San Chen, Jen-Fang Lin
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Publication number: 20120090503Abstract: Black disazo dyes of general formula (V) wherein A is a moiety of formula (VI) or of formula (VII) and B is a moiety of formula (VIII) or of formula (IX) and wherein M, R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, R11, R12, R13, R14, R15, R16, R17, R18, R19, R20, R21, R22, R23 and R24 are as defined in the specification, are excellent black dyes for dying and printing cellulose containing materials and textile materials and, in particular, for the preparation of recording liquids for ink jet printing and for writing utensils.Type: ApplicationFiled: October 17, 2011Publication date: April 19, 2012Inventors: Kurt BAETTIG, Jean-Luc Gremaud, Damien Moigno
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Patent number: 7438753Abstract: The present invention relates to a diazo dyestuff compound of the following formula (I) wherein, M is H, Na, or Li. The formula (I) compound is particularly suitable for using as a component in a black dye composition for ink-jet printing ink, and inkjet printing inks with good light-fastness are obtained.Type: GrantFiled: June 15, 2006Date of Patent: October 21, 2008Assignee: Everlight USA, Inc.Inventors: Jen-Fang Lin, Tzu-Kwei Sun, Hsiao-San Chen, Wen-Chin Lin
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Patent number: 7220843Abstract: This invention relates to monoazo, disazo and trisazo colorants of the formula (I) where M represents two hydrogen atoms or one metal ion selected from the group consisting of Cu, Co, Ni, Mn, Zn and Al; A is the radical of a substituted naphthyl or pyrazolyl radical.Type: GrantFiled: March 31, 2004Date of Patent: May 22, 2007Assignee: Clariant Produkte (Deutschland) GmbHInventors: Dominique Pflieger, Hans Joachim Metz
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Patent number: 7070715Abstract: The present invention provides a disazo compound of the formula (I) or a salt thereof wherein A represents 4-sulfophenyl or 6,8-disulfo-2-naphtyl, one of R1 and R2 represents hydrogen or methyl. The present invention also provides a dye-based polarizing film comprising a base material and the disazo compound of the formula (I) or the salt thereof contained in the base material. The disazo compound of the present invention provides a polarizing film, which is excellent in light resistance and initial polarizing performance, particularly light resistance when used as a polarizing element.Type: GrantFiled: August 18, 2003Date of Patent: July 4, 2006Assignee: Sumitomo Chemical Company, LimitedInventors: Toru Ashida, Yoshiteru Ohta, Narutoshi Hayashi
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Patent number: 6699976Abstract: A polyazo compound or salt thereof covering the region of from 500 to 580 nm and manifesting high initial polarization ability and represented by the following formulae (I) or (II): wherein, A represents a phenyl having sulfo and/or carboxyl and optionally having a lower alkyl or lower alkoxy, or a naphthyl having 1 to 3 sulfos, R1 to R6 represent hydrogen, lower alkyl or alkoxy, m and n each independently represent 0 or 1, R7 represents hydrogen or sulfo, D and E each independently represents —NHCO— or —N═N—, G represents —CH2—, alkylene having 2-4 carbon atoms, phenylene or —CH═CH—, and R8 represents sulfo, carboxyl or lower alkoxycarbonyl; is provided.Type: GrantFiled: July 5, 2002Date of Patent: March 2, 2004Assignee: Sumitomo Chemical Company, LimitedInventors: Toru Ashida, Yoshiteru Ohta, Narutoshi Hayashi
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Patent number: 6417178Abstract: Amyloid binding compounds which are derivatives of Chrysamine G, pharmaceutical compositions containing, and methods using such compounds to identify Alzheimer's brain in vivo and to diagnose other pathological conditions characterized by amyloidosis, such as Down's Syndrome are described. Pharmaceutical compositions containing Chrysamine G and derivatives thereof and methods using such compositions to prevent cell degeneration and amyloid-induced toxicity in amyloidosis associated conditions are also described. Methods using Chrysamine G derivatives to stain or detect amyloid deposits in biopsy or post-mortem tissue are also described. Methods using Chrysamine G derivatives to quantify amyloid deposits in homogenates of biopsy and post-mortem tissue are also described.Type: GrantFiled: November 6, 1997Date of Patent: July 9, 2002Assignee: University of PittsburghInventors: William E. Klunk, Jay W. Pettegrew, Chester A. Mathis, Jr.
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Publication number: 20020049309Abstract: Provided are novel black azo dyes which are useful in ink compositions, especially ink jet ink compositions. The dyes and ink compositions of the present invention exhibit a good balance of optical density, print reliability, water fastness and light fastness.Type: ApplicationFiled: June 18, 2001Publication date: April 25, 2002Inventors: Bradley Leonard Beach, Ann P. Holloway, James F. Feeman
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Patent number: 6049428Abstract: The present invention provides dyes of formula I-XXXIV, described in detail below, and dichroic light polarizers based on the dyes. In the dichroic light polarizers of this invention the dye molecules are aggregated into particles oriented in a predetermined direction on a surface of a substrate to enable the dye to polarize light transmitted through the dye. In another embodiment, a dichroic light polarizer includes a molecularly oriented layer of an organic dye on a surface of a substrate. The layer has a non-periodic arrangement of different polarizing elements. Each of the polarizing elements have differing orientations of the polarization vector in the substrate plane and/or differing colors. The dichroic light polarizer may contain one or more additional dye layers and may have a transparent layer intermediate to the dye layer.Type: GrantFiled: August 4, 1997Date of Patent: April 11, 2000Assignee: Optiva, Inc.Inventors: Ir G Khan, Yuri A. Bobrov, Leonid Y. Ignatov, Elena Y. Shishkina, Pavel I Lazarev, Alexey V. Kurbatov
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Patent number: 5834602Abstract: Disazo dyes of the formula ##STR1## where the ring A may be benzofused,X is hydrogen or C.sub.1 -C.sub.4 -alkyl,R.sup.1 is hydrogen, C.sub.1 -C.sub.4 -alkyl, halogen, carboxyl, C.sub.1 -C.sub.4 -alkoxycarbonyl or hydroxysulfonyl,R.sup.2 is hydrogen, C.sub.1 -C.sub.4 -alkyl, halogen, carboxyl or C.sub.1 -C.sub.4 -alkoxycarbonyl, or R.sup.1 and R.sup.2 together are a radical of the formula L--NZ--CO, where L is methylene or carbonyl and Z is substituted or unsubstituted C.sub.1 -C.sub.4 -alkyl or substituted or unsubstituted phenyl, andR.sup.3 is hydrogen, C.sub.1 -C.sub.4 -alkyl, hydroxyl, C.sub.1 -C.sub.4 -alkoxy, phenoxy, C.sub.1 -C.sub.4 -alkanoyloxy or benzoyloxy,are useful for dyeing natural or synthetic substrates.Type: GrantFiled: January 26, 1998Date of Patent: November 10, 1998Assignee: BASF AktiengesellschaftInventors: Gunther Lamm, Helmut Reichelt
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Patent number: 5700296Abstract: An azo compound of the following formulae (I) or (II): ##STR1## wherein Q.sub.1 represents a phenyl group or a naphthyl group, Q.sub.2 represents a phenyl group; R represents hydroxy group; R.sub.1 and R.sub.2 each independently represent a hydrogen atom, a hydroxy group, a C.sub.1 -C.sub.4 alkyl group, a C.sub.1 -C.sub.4 alkoxy group or a halogen atom; R.sub.3 and R.sub.4 each independently represent a hydrogen atom, a hydroxy group, a C.sub.1 -C.sub.4 alkyl group, a C.sub.1 -C.sub.4 alkoxy group or a substituted amino group; and X represents --NH--, --NHCO-- or --N.dbd.N--; or a salt thereof;and a polarizing film containing the same.Type: GrantFiled: February 20, 1996Date of Patent: December 23, 1997Assignee: Sumitomo Chemical Company, LimitedInventors: Kazuya Ogino, Kaneo Yokoyama, Narutoshi Hayashi, Takashi Omura, Setsuko Yamamoto
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Patent number: 5612464Abstract: The invention is concerned with compounds according to the formula ##STR1## and their salts whereinR.sub.1 represents hydrogen or --SO.sub.3 H,R.sub.2 represents hydrogen, methyl, --NHCONH.sub.2 or --NHCOCH.sub.3 and,R.sub.3 represents hydrogen, C.sub.1-4 alkyl, preferably methyl or ethyl, or C.sub.1-4 alkyl substituted with CN, OH, Cl, F or --SO.sub.3 H.These compounds are useful as fiber-reactive dyestuffs in dyeing and printing hydroxy-group-containing and nitrogen-containing organic substrates.Type: GrantFiled: May 2, 1996Date of Patent: March 18, 1997Assignee: Clariant Fiance (BVI) LimitedInventor: Rainer Nusser
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Patent number: 5510468Abstract: There are described benzophenoneazo dyes of the formula ##STR1## where the ring A can be benzofused and a benzofused ring A can be overbridges,m is 1 or 2,K is the radical of a coupling component,Y is hydrogen or arylazo,one of the two radicals X.sup.1 and X.sup.2 is hydrogen and the other is hydroxysulfonyl,R.sup.1, R.sup.2 and R.sup.3 are independently of the others hydrogen, halogen, C.sub.1 -C.sub.12 -alkyl, cyclohexyl, phenyl, 2-hydroxy-ethylsulfonyl or C.sub.1 -C.sub.4 -alkoxy or, when m is 1 and Y is hydrogen, one of these substituents can also be the radical of the formula ##STR2## where L.sup.1 is a chemical bond or a bridge member, and X.sup.1, X.sup.2, R.sup.4, K and the ring A are each as defined above, andR.sup.4 is hydrogen, halogen or C.sub.1 -C.sub.Type: GrantFiled: July 27, 1994Date of Patent: April 23, 1996Assignee: BASF AktiengesellschaftInventors: Gunther Lamm, Helmut Reichelt, Ortwin Schaffer
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Patent number: 5380859Abstract: There are described benzophenoneazo dyes of the formula ##STR1## where the ring A can be benzofused and a benzofused ring A can be overbridged,m is 1 or 2,K is the radical of a coupling component,Y is hydrogen or arylazo,one of the two radicals X.sup.1 and X.sup.2 is hydrogen and the other is hydroxysulfonyl,R.sup.1, R.sup.2 and R.sup.3 are independently of the others hydrogen, halogen, C.sub.1 -C.sub.12 -alkyl, cyclohexyl, phenyl, 2-hydroxyethylsulfonyl or C.sub.1 -C.sub.4 -alkoxy or, when m is 1 and Y is hydrogen, one of these substituents can also be the radical of the formula ##STR2## where L.sup.1 is a chemical bond or a bridge member, andX.sup.1, X.sup.2, R.sup.4, K and the ring A are each as defined above, andR.sup.4 is hydrogen, halogen or C.sub.1 -C.sub.Type: GrantFiled: July 16, 1993Date of Patent: January 10, 1995Assignee: Basf AktiengesellschaftInventors: Gunther Lamm, Helmut Beichelt, Ortwin Schaffer
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Patent number: 5378269Abstract: A recording liquid for ink-jet recording comprising coloring matter, which is an image-forming component, and a liquid medium for dissolving the coloring matter therein. The liquid medium is ethanol and the coloring matter is a dye represented by the following general formula (A): ##STR1## or the following general formula (B): ##STR2## as an image-forming component.Type: GrantFiled: December 29, 1993Date of Patent: January 3, 1995Assignee: Scitex Digital Printing, Inc.Inventors: Louis J. Rossi, Sunita P. Chavan
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Patent number: 5326866Abstract: A liquid azo dye represented by the formula: ##STR1## (wherein, A stands for a phenylene group which may have a substituent, n is o or 1, Cp is a pyrazolone derivative residue or a naphthol derivative residue, X is --NH-- or --COO-- and R is an alkyl group having 3 to 12 carbon atoms).Type: GrantFiled: May 12, 1993Date of Patent: July 5, 1994Assignee: Orient Chemical Industries, Ltd.Inventors: Takashi Ono, Tatsuya Yagyu, Tetsui Akase
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Patent number: 5101020Abstract: Novel radio labeled dyes are provided for detecting proteins on gels.Type: GrantFiled: August 8, 1990Date of Patent: March 31, 1992Assignee: Linus Pauling Institute of Science and MedicineInventor: James E. Fleming
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Patent number: 4968783Abstract: Reactive dyes useful for dyeing natural and synthetic fibers of the formula ##STR1## in which D.sub.1 is a benzene or naphthalene radical, which can be substituted, D.sub.2 is a benzene radical, which can be substituted, R.sub.1 is hydrogen or C.sub.1-4 -alkyl, the bridge member --N(R.sub.1)-- is bonded to a ring carbon atom of D.sub.2, R.sub.2 is hydrogen or C.sub.1-4 -alkyl, which can be substituted, and R.sub.3 is hydrogen or substituted or unsubstituted alkyl, cycloalkyl, aralkyl or aryl.Type: GrantFiled: January 19, 1989Date of Patent: November 6, 1990Assignee: Ciba-Geigy CorporationInventors: Karl Seitz, Gert Hegar
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Patent number: 4956457Abstract: The new azo compounds are represented by the following general formula I ##STR1## Wherein R and R.sup.1 are hydrogen, --COCR.sub.3.sup.4 --COCHR.sub.2.sup.4, --SO.sub.2 CH.sub.3, --CO.sub.2 C.sub.2 H.sub.5, --CH.sub.2 CH.sub.2 R.sup.4, --( CH.sub.2 CH.sub.2 R.sup.4).sub.2, --CH.sub.2 CH.sub.2 OH, --CONHCH.sub.2 CH.sub.2 R.sup.4 or --CH.sub.2 CH.sub.2 OCONH.sub.2 and R.sup.4 is Cl or a group of the formula ##STR2## --NHCO.sub.2 CH.sub.3 CH.sub.2 OH, --NHCO.sub.2 C.sub.2 H.sub.5, --NHOH, --NHCONHOH, or --NHCH.sub.3, whereby R.sup.1 and R.sup.2 are similar or dissimilar.Type: GrantFiled: August 10, 1989Date of Patent: September 11, 1990Inventor: Takeo Takayanagi
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Patent number: 4918169Abstract: Reactive dyes suitable for dyeing and printing cellulosic fiber materials by the cold pad-batch process having the formula ##STR1## wherein Fa is a monoazo or polyazo, metal complex azo, anthraquinone, phthalocyanine, formazane, azomethine, dioxazine, phenazine, stilbene, triphenylmethane, xanthene, thioxanthone, nitroaryl, napthoquinone, pyrenequinone or perylene-tetracarbimide dye radical, X is halogen, C.sub.1 -C.sub.4 -alkylsulfonyl, phenylsulfonyl, a sulfonic acid or phosphonic acid group or a quaternized ammonium group, r is 1 or 2, R is hydrogen or C.sub.1 -C.sub.4 alkyl which is unsubstituted or substituted by halogen, hydroxyl, cyano, carboxyl, sulfo, sulfato, C.sub.1 -C.sub.4 -alkoxycarbonyl, C.sub.1 -C.sub.4 -alkoxy or phenyl, and A is a radical of the formula ##STR2## wherein R' is hydrogen, C.sub.1 -C.sub.4 alkyl which is unsubstituted or substituted by halogen, hydroxyl, cyano, carboxyl, sulfo, sulfato, C.sub.1 -C.sub.4 -alkoxycarbonyl, C.sub.1 -C.sub.4 -alkoxy or phenyl, C.sub.5 -C.sub.Type: GrantFiled: August 19, 1988Date of Patent: April 17, 1990Assignee: Ciba-Geigy CorporationInventor: Karl Hoegerle
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Patent number: 4863910Abstract: A complex of an azo compound of the formula ##STR1## wherein R and R' are selected from the group consisting of hydrogen, --COCR.sub.4.sup.3, --COCHR.sub.2.sup.4, --CO.sub.2 C.sub.2 H.sub.5, --CH.sub.2 CH.sub.2 R.sup.4, --(CH.sub.2 CH.sub.2 R.sup.4)2, --CH.sub.2 CH.sub.2 OH, --CONHCH.sub.2 CH.sub.2 R.sup.4 and --CH.sub.2 CH.sub.2 OCOHN.sub.2, R.sup.4 is selected from the group consisting of chlorine, ##STR2## --NHCO.sub.2 CH.sub.2 CH.sub.2 OH, --HNCO.sub.2 C.sub.2 H.sub.5, --NHOH, --NHCONHOH and --NHCH.sub.3 ; R.sup.1 and R.sup.2 are individually selected from the group consisting of ##STR3## --NHCH.sub.2 CH.sub.2 Cl, --NHCONHOH, --NHCO.sub.2 C.sub.2 H.sub.5, 6-mercapropurin, 5-fluoruracil and prenissolin, R.sup.3 is selected from the group consisting of hydrogen, --COCHR.sub.2.sup.4, --SO.sub.2 CH.sub.3, --COC.sub.2 H.sub.5, --CH.sub.2 CH.sub.2 R.sub.4 and --CONH.sub.2, R.sup.Type: GrantFiled: May 20, 1986Date of Patent: September 5, 1989Inventor: Takeo Takayanagi
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Patent number: 4748236Abstract: Reactive azo dyestuffs of the formula ##STR1## wherein D . . . radical of the benzene or naphthalene series, having a sulpho group in the o-position to the azo bridge,K . . . radical of a coupling component of the benzene, naphthalene, pyridone, pyrazolone or hydroxynaphthalene series, or an aryl-azo-aryl radical,R . . . hydrogen or C.sub.1 -C.sub.4 -alkyl,Y . . . OR.sub.1 or SR.sub.1, R.sub.1 representing an optionally substituted alkyl, aryl or heteroaryl radical, or NR.sub.2 R.sub.3, R.sub.2 representing hydrogen or an optionally substituted alkyl radical and R.sub.3 representing hydrogen or an optionally substituted alkyl or aryl radical, or R.sub.2 and R.sub.3 forming a ring, optionally with inclusion of a hetero-atom, andX . . . halogen, such as chlorine or fluorine and their use for dyeing and printing materials containing hydroxyl groups or containing amide groups.Type: GrantFiled: November 9, 1984Date of Patent: May 31, 1988Assignee: Bayer AktiengesellschaftInventors: Horst Jager, Richard Schwaebel
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Patent number: 4701525Abstract: Compounds of the formula(B--L.sub.m --A--L'--B'.sub.n, (1)in which A is the radical of a bisazo or trisazo dye, L and L' are organic radicals and B and B' are cyclic organic radicals and at least one of the radicals B and B' has spectral absorption in the UV region and one of the radicals B and B' is different from 2,4-dihydroxyphenyl, m is 1 or 2 and n is 0, 1 or 2.The compounds are suitable for use as image dyes in photographic silver dye bleach materials.Type: GrantFiled: June 2, 1986Date of Patent: October 20, 1987Assignee: Ciba-Geigy AGInventors: Thomas-Markus Rohr, Jakob Kuhn
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Patent number: 4673735Abstract: A compound of formula I ##STR1## in metal-free; 1:1 or 1:2 metal complex form and, when an acid group is present, in free acid or acid addition salt form, in which R.sub.1 is hydrogen or --N.dbd.N--D where D is a diazo component and R, T and B are organic radicals defined in the text.Type: GrantFiled: April 9, 1984Date of Patent: June 16, 1987Assignee: Sandoz Ltd.Inventors: Helmut Moser, Manfred Greve, Reinhard Pedrazzi, Roland Wald
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Patent number: 4592756Abstract: A dye solution composition containing a black dye obtained by the action of at least one acid or its salt:HO(CH.sub.2).sub.n SO.sub.3 H, Cl(CH.sub.2).sub.n COOH, Br(CH.sub.2).sub.n COOH (n=1 or 2)on one or a mixture of dyes of the formula (I): ##STR1## wherein R is phenylene or naphthylene residue; X and X' are each H, sulfonic acid group or sulfonate group; Y and Y' are each H or alkali metal; R' is one of amino group-containing radicals: ##STR2## (the carboxyl group may be carboxylate group and the sulfonic acid group may be sulfonate group), except that when R' has not sulfonic acid group, X and X' are not the same and when R' has sulfonic acid group, X and X' are H. This is highly stable, preservative and water soluble, and is useful as ink composition for ball-point pen and ink jet recording.Type: GrantFiled: February 6, 1985Date of Patent: June 3, 1986Assignee: Taoka Chemical Company, LimitedInventors: Sinjiro Kawasaki, Hideo Kitagawa, Yutaka Nishii
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Patent number: 4537955Abstract: An unsymmetrical 1:2 chromium complex of a monoazo dyestuff and a disazo dyestuff which is non-fiber reactive and is free of sulfonamido and amino groups and which, in the form of the free acid has the formula: ##STR1## wherein A' is the radical of a 1-hydroxy-2-aminobenzene which is monosubstituted or disubstituted by chlorine, nitro, or sulfo, B' is a naphth-2-ol, resorcinol, p-(C.sub.1 -C.sub.6 -alkyl)-phenol, 1-phenol-3-methylpyrazol-5-one or acetoacetanilide radical, and the phenol group in the last two mentioned compounds can be substituted by C.sub.1 -C.sub.4 -alkyl C.sub.1 -C.sub.4 -alkoxy, chlorine or sulfo, K' is an unsubstituted or sulfo-substituted naphth-1-ol or naphth-2-ol radical, phenol which is substituted in the p-positioned by C.sub.1 -C.sub.6 -alkyl, an unsubstituted or sulfo-substituted 2-naphthylanime, and 1-phenol-3-methylpyrazol-5-one or an acetoactanilide radical, and the phenol group in the last two mentioned compounds can be substituted by C.sub.1 -C.sub.Type: GrantFiled: March 1, 1983Date of Patent: August 27, 1985Assignee: BASF AktiengesellschaftInventors: Klaus Grychtol, Hans Baumann
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Patent number: 4518435Abstract: A dispersing agent comprising the salt of a tertiary amine containing at least one poly(lower alkyleneoxy) chain and an aromatic acid having at least two benzene rings and a dispersion of an organic pigment, an organic dyestuff or carbon black in a polar organic solvent containing said dispersing agent is disclosed.Type: GrantFiled: January 18, 1983Date of Patent: May 21, 1985Assignee: Imperial Chemical Industries LimitedInventors: James F. Stansfield, James Toole, Arthur Topham
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Patent number: 4492654Abstract: Disazo compounds corresponding to the general formula (1) ##STR1## as well as their metal salts, in which D.sub.1 denotes the benzene or naphthalene nucleus, which can be further substituted by one or two substituents from the group of fluorine, chlorine, bromine, carboxy, lower alkyl, lower alkoxy and nitro and/or one, two or three sulfo groups, D.sub.2 is the benzene or naphthalene nucleus, which is substituted by the substituent X defined below and, in addition to the group --SO.sub.2 --Y, can be further substituted by one or two substituents from the group of carboxy, lower alkyl and lower alkoxy and/or by one substituent from the group of fluorine, chlorine, bromine and nitro and/or one, two or three sulfo groups, X denotes a fluorine, chlorine or bromine atom, which is necessarily bonded to D.sub.2 in ortho-position to the azo group, Y denotes the vinyl, .beta.-sulfatoethyl, .beta.-chloroethyl, .beta.-thiosulfatoethyl or a .beta.Type: GrantFiled: July 20, 1983Date of Patent: January 8, 1985Assignee: Hoechst AktiengesellschaftInventors: Ernst Hoyer, Folker Kohlhaas, Fritz Meininger