Plural Sulfonyl Groups Or Plural Nitrogens Bonded Directly To The Bicyclo Ring System Patents (Class 534/879)
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Publication number: 20150073132Abstract: Disclosed is a method for continuously preparing a water-soluble azo dye by coupling a nebulizer with a pipeline. According to the method, the nebulizer is coupled with a pipeline with an interception tower plate, atomized and mixed reaction liquid flow flows through the pipeline with the interception tower plate, and mixing and reacting are further enhanced through turbulent mixing on the tower plate, so that instant separation of reaction heat generated in an atomizing contact reaction from a reactant is achieved, and normal-temperature rapid continuous production of the water-soluble azo dye is achieved. Fog drops which are atomized by using the nebulizer have small particle diameter and large specific surface area, so that a diazo salt and a coupling component are sprayed separately, move face to face and can be fully contacted, and mixing and reacting speeds are increased.Type: ApplicationFiled: November 30, 2012Publication date: March 12, 2015Inventors: Shufen Zhang, Bingtao Tang, Rongwen Lv, Dong Liang
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Patent number: 8420402Abstract: The present invention is generally directed to thiol quantitation assays, methods of performing the assays, and compounds used in the assays. It is more specifically directed to assays that include one or more disulfides and related molecules and methods. The disulfides contain a FRET pair.Type: GrantFiled: January 27, 2012Date of Patent: April 16, 2013Assignee: AnaSpec IncorporatedInventors: Jianjun He, Anita Hong, Qingheng Wang, Raman Khosrow Afshar, Ming Zhu, Vera Rakhmanova
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Patent number: 7097702Abstract: Disclosed are novel dyestuff for printing recording materials, especially textile fiber materials, paper and papery substrates and plastic films and plastic transparencies by the inkjet printing process of the formula (I) wherein all substituents are defined in the claims.Type: GrantFiled: December 18, 2002Date of Patent: August 29, 2006Assignee: Clariant Finance (BVI) LimitedInventor: Ludwig Hasemann
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Patent number: 6365721Abstract: Water-soluble monoazo dyes, their preparation and use Dyes of the formula (1): in which M is hydrogen, ammonium, an alkali metal or the equivalent of an alkaline earth metal; X is sulfonyl or —COCH2O—; R1, R2 and R3 independently of one another are hydrogen, halogen, for example fluorine, chlorine or bromine, unsubstituted or chloro- or hydroxy-substituted C1 to C4 alkoxy, for example 2-chloroethoxy or 2-hydroxyethoxy, and the sulfo group is in position 3 or 4 to the NH group, their preparation, and their use for dyeing or printing carboxamido-containing materials.Type: GrantFiled: September 18, 2001Date of Patent: April 2, 2002Assignee: DyStar Textilfarben GmbH & Co.Inventor: Aloys Engel
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Patent number: 6183549Abstract: Compounds of Formula (1) and salts thereof: wherein: Ar1 is substituted aryl wherein at least one substituent is —COOH; R1 is H or optionally substituted alkyl; L is substituted phenyl carrying at least one substituent at the 2-position, or optionally substituted naphthyl. Also claimed are compositions comprising a compound of the Formula (1) and a water-soluble magenta dye, liquid compositions, especially inks, containing a compound of Formula (1), an ink jet printing process using the inks, a substrate printed with the inks, and an ink jet printer cartridge and an ink jet printer containing the inks.Type: GrantFiled: August 27, 1999Date of Patent: February 6, 2001Assignee: Avecia LimitedInventor: Paul Wight
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Patent number: 5686585Abstract: An azo dye for use in color filters soluble in alkaline aqueous solutions and organic solvents and having in one molecule at least one sulfonamido group of which one hydrogen atom is substituted; and a method for producing a color filter having a plurality of color filter elements which comprises the steps of a) coating a substrate with an organic solvent solution of a photoresist composition containing said azo dye and drying the coat to form an adhering layer, b) exposing a specific part of said layer to radiation ray, c) developing the exposed or unexposed region with alkali to form a colored pattern, and d) repeating the steps a)-c) on every dye of different color present in said composition.Type: GrantFiled: November 18, 1994Date of Patent: November 11, 1997Assignee: Sumitomo Chemical Company, LimitedInventors: Yoshiki Hishiro, Naoki Takeyama, Shigeki Yamamoto
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Patent number: 5542970Abstract: A monoazo compound of the general formula ##STR1## wherein; Y is hydrogen, methyl, methoxy, acetylamino, or nitro, or Y, cojointly with the carbon atom located in the benzene ring B at the 3-position with respect to the N.dbd.N group, may form a benzene ring; X is acetyl, benzoyl, p-toluenesulfonyl, or 4-chloro-6-hydroxy-1,3,5-triazine-2-yl; and M.sup.1, M.sup.2 and M.sup.3 each are a base selected from alkali metal atom, ammonium cation and amine salt cation. A recording liquid comprising a coloring matter, which is an image-forming component, and a liquid medium for dissolving or dispersing the coloring matter, said recording liquid being characterized by containing as coloring matter the above-mentioned monoazo compound.Type: GrantFiled: June 6, 1995Date of Patent: August 6, 1996Assignees: Canon Kabushiki Kaisha, Mitsubishi Chemical CorporationInventors: Konoe Miura, Hiroshi Takimoto, Tokuya Ohta, Masatsune Kobayashi
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Patent number: 5008099Abstract: The presence and location of amyloid deposits in an organ or body area of a patient is effected by intravenous administration of novel radioactive iodine-labeled amyloid binding compounds and preferably .sup.123 I-labeled compounds to the patient and sensing radiation emitted from the organ or body area. Novel non-radioactive iodine substituted amyloid binding compounds and amyloid binding compounds which are readily iodinated are further aspects or the invention.Type: GrantFiled: April 17, 1990Date of Patent: April 16, 1991Assignee: Salutar, Inc.Inventors: Steven C. Quay, Scott M. Rocklage, Warren K. Miller
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Patent number: 5003051Abstract: A process for the preparation of azo dyes of the formula ##STR1## in which X is --NH.sub.2 or --OH, A is a benzene or naphthalene radical which can be substituted by nitro, halogen, sulfo, C.sub.2 -C.sub.6 alkanoylamino, C.sub.1 -C.sub.6 -alkoxycarbonylamino, sulfonamido and sulfone groups and B is a benzene radical which is monosubstituted or disubstituted by C.sub.1 -C.sub.6 alkyl, or a naphthalene radical which can be substituted by amino, phenylamino, C.sub.1 -C.sub.6 alkylamino and sulfo, or a 1-phenyl-3-methyl-5-pyrazlone radical which can be substituted by halogen, C.sub.1 -C.sub.6 alkyl and C.sub.1 -C.sub.6 alkoy, these radicals being bound to the azo group in the o-position with respect to the hydroxyl or amino groups, comprises diazotizing in aqueous solution an amine of the formula ##STR2## in the presence of at least one ketone of the formula ##STR3## in which R.sub.1 and R.sub.2, independently of one another, are each C.sub.1 -C.sub.Type: GrantFiled: August 23, 1989Date of Patent: March 26, 1991Assignee: Ciba-Geigy CorporationInventors: Ulrich Schlesinger, Peter Loew, Alois Puntener
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Patent number: 4841030Abstract: They are useful for dyeing and printing materials containing hydroxyl groups or amide groups.Type: GrantFiled: December 4, 1981Date of Patent: June 20, 1989Assignee: Bayer AktiengesellschaftInventor: Horst Jager
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Patent number: 4725674Abstract: Water-soluble monoazo and disazo compounds which have fiber-reactive dyestuff properties and containing as diazo component an optionally substituted phenyl radical or naphthyl radical or an optionally substituted phenylazophenyl, phenylazonaphthyl, naphthylazophenyl or naphthylazonaphthyl radical, and as coupling component that of a naphthol, aminonaphthaline or aminobenzene and as fiber-reactive group a group of the formula ##STR1## in which both R.sup.1 s, identical to or different from one another, denote a hydrogen atom or an optionally substituted alkyl group of 1 to 4 carbon atoms, R is a hydrogen atom or a sulfo group and Y represents a vinyl group or a .beta.-thiosulfatoethyl, .beta.-phosphatoethyl, .beta.-chloroethyl or .beta.-sulfatoethyl group, this fiber-reactive grouping being bonded to the radical of the coupling component.Type: GrantFiled: March 19, 1986Date of Patent: February 16, 1988Assignee: Hoechst AktiengesellschaftInventors: Marcos Segal, Michael Kunze
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Patent number: 4530996Abstract: A compound represented by a free acid of the formula: ##STR1## wherein D is ##STR2## (R.sub.1 and R.sub.2 independently represent hydrogen, methyl or methoxy) or ##STR3## (n is 0 or 1, the mark * signifies the position of linkage to --N.dbd.N-- and the mark # signifies the position of linkage to Q mentioned below); Q is --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 CH.sub.2 R (R is a group capable of being split off by the action of alkali); one of X.sub.1 and X.sub.2 is hydrogen and the other is a sulfonic acid group; and m is 0 or 1, which is useful for dyeing cellulose fibers a blue-black color with good dyeability and excellent fastnesses, particularly chlorine fastness.Type: GrantFiled: June 4, 1982Date of Patent: July 23, 1985Assignee: Sumitomo Chemical Company, LimitedInventors: Takashi Omura, Naoki Harada, Yasuo Tezuka