Abstract: A process for preparing symmetrical or asymmetrical trans-thiazineindigo pigments of the formula (1)
which comprises
a) condensing, in an aqueous medium, a compound of the formula (2) with a compound of the formula (3a) or (3b) or a compound of the formula (4) with a compound of the formula (3a) and/or (3b)
by maintaining the reaction mixture at a temperature between 30 and 65° C. for at least 1 hour and then
b) maintaining the reaction mixture at a temperature between 100 and 180° C. and a pressure between 2 and 50 bar for at least 1 hour in the presence of an amide.
Type:
Grant
Filed:
June 21, 2001
Date of Patent:
November 18, 2003
Assignee:
Clariant Finance (BVI) Limited
Inventors:
Petra Maria Rothe, Leonhard Unverdorben, Bruno Piastra