Boron Or Silicon Containing Patents (Class 544/69)
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Patent number: 5032165Abstract: There are disclosed a (3-substituted phenyl)pyrazole derivative represented by the general formula ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4 and X are various substituents and a salt thereof, and its production process. Said pyrazole derivative or its salt is useful as a herbicide for controlling various injurious weeds.Type: GrantFiled: August 30, 1989Date of Patent: July 16, 1991Assignee: Nihon Nohyaku Company, Ltd.Inventors: Yuzo Miura, Tsutomu Mabuchi, Mitsuru Kajioka, Isao Yanai
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Patent number: 5013827Abstract: Triggerable dioxetanes with a fluorescent molecule containing group bonded or tethered in the dioxetane so as to produce fluorescence from the group are described. The compounds are useful in immunoassays and in probes using enzymes or other chemicals for triggering the dioxetanes to produce light from the fluorescent molecule in the group as a signal.Type: GrantFiled: November 13, 1989Date of Patent: May 7, 1991Assignee: Board of Governors of Wayne State UniversityInventor: Arthur P. Schaap
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Patent number: 5001241Abstract: Processes and intermediates are disclosed for the formation of compounds of formula (I) and (II): ##STR1##Type: GrantFiled: February 2, 1990Date of Patent: March 19, 1991Assignee: Merck & Co., Inc.Inventors: Gerald E. Stokker, Ta J. Lee
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Patent number: 4997943Abstract: Compounds of formula (I): ##STR1## (in which R.sup.1 is alkoxy, R is alkyl, haloalkyl, alkylamino, cycloalkyl or optionally substituted phenyl, X is chlorine or fluorine and Y is selected from certain specific heterocycles) have excellent antibacterial activity. They may be prepared by introducing the group represented by Y into the corresponding compound in which Y is replaced by a halogen atom.Type: GrantFiled: March 31, 1987Date of Patent: March 5, 1991Assignees: Sankyo Company Limited, Ube Industries LimitedInventors: Masayuki Iwata, Tomio Kimura, Yoshimi Fujihara, Tetsushi Katsube
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Patent number: 4977259Abstract: Reactive stabilizing compounds, able to stabilize organic polymers, contain in their molecule a sterically hindered amino group and a hydrolyzable silyl function. In stabilizing organic polymers, said reactive stabilizing compounds can be hydrolyzed at the silyl function with the formation of silanol groups, which are made to interact in order to form complex resinous stabilizing structures. These latter are added in stabilizing quantities to the polymer to be stabilized. According to one particular embodiment, the hydrolysis at the silyl function and the formation of the resinous structure take place spontaneously within the polymer to be stabilized. According to a further embodiment, the reactive stabilizing compound is added to the polymer after being stably supported on a solid support by reaction with an inorganic solid having surface hydroxyl groups.Type: GrantFiled: May 14, 1987Date of Patent: December 11, 1990Assignee: Enichem Sintesi S.p.A.Inventors: Alberto Greco, Carlo Busetto, Luigi Cassar, Carlo Neri
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Patent number: 4977291Abstract: A process of producing a silanic or siloxanic compound containing at least one cycloalkyl ring by the hydrogenation of a corresponding compound containing at least one aromatic ring, in the presence of a Raney nickel catalyst having a granulometry comprised essentially between 10 and 150 micrometers and a surface area of at least 80 m.sup.2 /g.Type: GrantFiled: September 15, 1989Date of Patent: December 11, 1990Assignee: Istituto Guido Donegani S.p.A.Inventors: Francesco Gementi, Loris Sogli, Raffaele Ungarelli
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Patent number: 4963568Abstract: Novel compounds which are selective dopamine agonists are useful for treating disorders characterized by abnormal dopamine levels, such as Parkinson's Disease, as well as cardiovascular disorders.Type: GrantFiled: May 31, 1989Date of Patent: October 16, 1990Assignee: Abbott LaboratoriesInventors: Robert W. Schoenleber, John W. Kebabian, Yvonne C. Martin, Michael P. DeNinno, Richard J. Perner, David M. Stout, Chi-Nung W. Hsiao, Stanley DiDomenico, Jr., John F. DeBernardis, Fatima Z. Basha, Michael D. Meyer, Biswanath De
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Patent number: 4948888Abstract: Stabilizers for organic polymers are disclosed, of the type of sterically hindered phenols or amines, which are obtained by means of the reaction of a sterically hindered phenol or amine bearing in the molecule at least in alkoxysilanol group with a mono- or poly-hydroxy aliphatic alcohol, by a transesterification reaction.The stabilizers so obtained are compatible with the organic polymers, wherein they remain stably.Type: GrantFiled: July 27, 1987Date of Patent: August 14, 1990Assignee: Enichem Sintesi S.p.A.Inventors: Alberto Greco, Luciano Pallini
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Patent number: 4948416Abstract: This invention relates to novel condensed ring sulfonylureas and their use as herbicides and growth regulants.Type: GrantFiled: March 27, 1989Date of Patent: August 14, 1990Assignee: E. I. du Pont de Nemours and CompanyInventor: Robert J. Pasteris
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Patent number: 4927812Abstract: Aryl substituted morpholinyl silanes, their preparation, compositions containing said compounds and their use as agricultural fungicides are disclosed.Type: GrantFiled: March 13, 1989Date of Patent: May 22, 1990Assignees: Atochem North America, Inc., The Dow Chemical CompanyInventors: Chrislyn M. Carson, Leonard G. Copping, Robert J. Ehr, Melvin H. Gitlitz, Maynard W. McNeil, Peter F. S. Street, John W. Liebeschuetz
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Patent number: 4921974Abstract: This invention relates to novel intermediates and novel processes for their preparation where said intermediates are useful in the preparation of 5'-oxygenated derivatives (I) of lovastation and analogs thereof at the 8'-acyl side chain and 6'-position of the polyhydronaphthyl ring. Derivatives (I) and analogs thereof are useful in treating hypercholesterolemia.Type: GrantFiled: September 29, 1988Date of Patent: May 1, 1990Assignee: Merck & Co., Inc.Inventor: Mark E. Duggan
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Patent number: 4914206Abstract: The present invention provides lankacidin derivatives of the formula ##STR1## and procedures for the production thereof. The lankacidin derivatives [1] show excellent antimicrobial activities and thus can be used for prophylaxis and treatment of infectious disease in animals.Type: GrantFiled: December 15, 1988Date of Patent: April 3, 1990Assignee: Takeda Chemical Industries, LTD.Inventors: Isao Minamida, Naoto Hashimoto
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Patent number: 4906749Abstract: Novel chromophor derivatives of cyclic anhydrides are provided which have the ability to react with a variety of organic substrates forming adducts which are useful in analytical techniques for the detection and measurement of biological compounds.Type: GrantFiled: January 24, 1989Date of Patent: March 6, 1990Assignee: Viomedics Inc.Inventor: Spyros Theodoropulos
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Patent number: 4892870Abstract: A novel class of 5, 6 or 7 member heterocycles which belong to the 3-isoxazolidinone, 2H-1,2-oxazin-3 (4H)-one and 3-isoxazepinone series of compounds and which are substituted at the 4-carbon by a benzylidene radical. The compounds have utility as analgesic agents, immunomodulating agents, anti-inflammatory agents and anti-pyretic agents and they may be combined with excipients to provide formuations which are useful in treating arthritis and conditions generally associated with that disease.Type: GrantFiled: August 1, 1988Date of Patent: January 9, 1990Assignee: Biofor, Ltd.Inventor: Sung J. Lee
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Patent number: 4877779Abstract: Novel compounds and their salts are disclosed having the Formulas: ##STR1## wherein: R.sub.1 is hydrogen, phenyl, 9H-fluoren-9-yl, 10,11-dihydro-5H-dibenzo [a,d]cyclohepten-5-yl, 5H-dibenzo[a,d]cyclohepten-5-yl, 1,2,3,4-tetrahydro-1-naphthyl, 9H-xanthen-9-yl, 9H-thioxanthen-9-yl, 2-chloro-9H-thioxanthen-9-yl, 4H-chromanyl, diphenylmethyl, phenylcycloalkylmethyl wherein the bridgehead methylene may optionally be substituted with a hydroxy group and any of the phenyl or benzo-fused rings may be substituted with one or more R.sub.5 groups wherein R.sub.5 is selected from halogen, trifluoromethyl, lower alkyl, hydroxy or lower alkoxy groups; andR.sub.2 and R.sub.3, which may be the same or different, are hydrogen, lower alkyl, phenylalkyl (C.sub.1 -C.sub.5), wherein the phenyl ring may be substituted with one or more R.sub.5 groups or NR.sub.2 R.sub.Type: GrantFiled: May 17, 1988Date of Patent: October 31, 1989Assignee: Marion Laboratories, Inc.Inventors: Waclaw J. Rzeszotarski, Maria E. Guzewska, John P. Carter, Theodore C. Adams, Andrea C. Dupont, Carl Kaiser
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Patent number: 4871719Abstract: Novel 13-spiro-2'-[tetrahydrofuran]-milbemycins of the formula I ##STR1## in which X represents one of the groups --CH(OR.sub.1)--, --C(.dbd.O)-- or --C(.dbd.N--OH)--;R.sub.1 represents hydrogen or a OH-protecting group;R.sub.2 represents methyl, ethyl, isopropyl or sec.-butyl or the group --C(CH.sub.3).dbd.CH--A in which A represents methyl, ethyl or isopropyl; andR.sub.3 represents hydrogen; C.sub.1 -C.sub.10 -alkyl; C.sub.1 -C.sub.10 -alkyl substituted by at least one substituent selected from the group consisting of halogen, C.sub.1 -C.sub.6 -alkoxy, C.sub.2 -C.sub.6 -alkoxyalkoxy C.sub.3 -C.sub.9 -alkoxyalkoxyalkoxy, C.sub.1 -C.sub.6 -alkylthio, C.sub.3 -C.sub.7 -cycloalkyl, C.sub.1 -C.sub.3 -alkyl-substituted C.sub.3 -C.sub.7 -cycloalkyl, hydroxy, benzyloxy, C.sub.1 -C.sub.6 -acyl and C.sub.1 -C.sub.6 -acyloxy, it being possible for each of the above-mentioned radicals representing or containing an alkoxy group to be terminally substituted at a terminal alkoxy group by hydroxy, halogen, C.sub.1 -C.sub.Type: GrantFiled: March 16, 1988Date of Patent: October 3, 1989Assignee: Ciba-Geigy CorporationInventor: Peter Maienfisch
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Patent number: 4863935Abstract: Mitomycin derivatives having potent anti-tumor activity against solid sarcoma 180 tumors and lymphocytic leukemia P-388 tumors.Type: GrantFiled: December 11, 1987Date of Patent: September 5, 1989Assignee: Kyowa Hakko Kogyo K.K.Inventors: Yasushi Shida, Tokuyuki Kuroda, Ikuo Matsukuma, Makoto Morimoto, Tadashi Ashizawa
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Patent number: 4852969Abstract: The present invention provides novel silyl 2-amidoacetates and silyl 3-amidopropionates which are the reaction products of azlactone and silanol reactants. The novel products result from nucleophilic addition of a soluble or insoluble, low or high molecular weight reactant containing one or more silanol groups and a soluble or insoluble, low or high molecular weight reactant containing one or more azlactone groups. The reaction products provide for high adhesion between the siliceous and azlactone reactants, as would be useful as protective coatings particularly on silicon-containing materials. It has been recognized in the present invention that silyl 2-amidoacetates and silyl 3-amidopropionates are useful linkages between silanol and azlactone derived materials.Type: GrantFiled: March 17, 1988Date of Patent: August 1, 1989Assignee: Minnesota Mining and Manufacturing CompanyInventors: Stefan A. Babirad, Fredrick Bacon, Steven M. Heilmann, Larry R. Krepski, Andrew S. Kuczma, Jerald K. Rasmussen
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Patent number: 4851397Abstract: Novel labdanes, intermediates and processes for the preparation thereof, and methods for reducing intraocular pressure utilizing compounds or compositions thereof are disclosed.Type: GrantFiled: June 10, 1988Date of Patent: July 25, 1989Assignee: Hoechst-Roussel Pharmaceuticals Inc.Inventors: Raymond W. Kosley, Jr., Robert J. Cherill
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Patent number: 4845237Abstract: A novel acylation process using an alkali metal bromide and a dialkylaminopyridine to form a sterically hindered ester functionality from an alkanoyl chloride and an alcohol is disclosed.Type: GrantFiled: April 15, 1987Date of Patent: July 4, 1989Assignee: Merck & Co., Inc.Inventors: Ann E. DeCamp, Leonard M. Weinstock, Thomas R. Verhoeven
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Patent number: 4843068Abstract: A pyrazole oxime derivative represented by the general formula (I) which is useful as an insecticide and fungicide, ##STR1## wherein the structural elements are defined in the specification, and the method of controlling said pests. The compounds represented by the general formula (I) can be synthesized by the methods disclosed in the specification.Type: GrantFiled: December 29, 1986Date of Patent: June 27, 1989Assignee: Nihon Nohyaku Co., Ltd.Inventors: Hiroshi Hamaguchi, Hideo Takaishi, Tetsuji Ohshima, Takamichi Konno, Yukio Miyagi, Shiraiwa Yutaka, Takayuki Akita
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Patent number: 4835269Abstract: This invention relates to mixed silane reagents containing a complexon group in the reagent molecule, a method of making said reagents, and porous or nonporous inorganic materials having surface-bound complexon groups which are advantageously modified with the new reagents.The new mixed silane reagents are of the formula ##STR1## where R is methyl or ethyl and N is 0 or 1. The new reagents are produced by treatment of compounds of the formula(RO).sub.3 SiCH.sub.2 CH.sub.2 CH.sub.2 NHR.sup.2where R is methyl or ethyl with a dianhydride of the formula ##STR2## where n is 0 or 1. The new silane reagents II and III are used for the modification of inorganic materials, such as silicon dioxide, aluminum oxide, titanium dioxide, and glass, to obtain modified materials containing the complexon groups of the formulas ##STR3## where n is 0 or 1, and where the groups of Formulas V and VI are bound to the surface of the inorganic materials via the silicon atoms, shown above as incomplete valences.Type: GrantFiled: November 10, 1986Date of Patent: May 30, 1989Assignee: Ceskoslovenska akademie vedInventors: Jaroslav Kahovec, Bedrich Porsch
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Patent number: 4812161Abstract: Thia-diazole derivatives having the following partial structural formula had selective herbicidal activity on some crops.Type: GrantFiled: July 29, 1985Date of Patent: March 14, 1989Assignee: Nippon Soda Co., Ltd.Inventors: Kenji Hagiwara, Hisao Ishikawa, Hideo Hosaka, Hideo Inaba
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Patent number: 4803269Abstract: 4-Monosubstituted and 4,6-disubstituted phenoxazines, methods of preparing them and pharmaceutical compositions containing them. These compounds are useful as anti-inflammatories.Type: GrantFiled: August 14, 1987Date of Patent: February 7, 1989Assignee: Syntex (U.S.A.) Inc.Inventors: Joseph M. Muchowski, Robert J. Greenhouse, Angel Guzman
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Patent number: 4800202Abstract: Fungicidally active aminomethyltetrahydrofurans of the formula ##STR1## in which A represents a divalent alkylene or alkenylene chain which is in each case optionally substituted andR.sup.1 and R.sup.2 independently of one another each represent hydrogen, alkyl, alkenyl, alkinyl, alkoxyalkyl, dialkoxyalkyl, hydroxyalkyl, hydroxyalkoxyalkyl, dioxolanylalkyl, oxolanylalkyl, or dioxanylalkyl, or represent in each case optionally substituted cycloalkylalkyl, cycloalkyl, aralkyl, aralkenyl or aryl, orR.sup.1 and R.sup.2, together with the nitrogen atom to which they are bonded, represent an optionally substituted saturated heterocyclic radical, which can optionally contain further heteroatoms,or an acid addition salts thereof. Some intermediates therefor wherein NR.sup.1 R.sup.2 is replaced by halogen or sulphonyloxy are also new.Type: GrantFiled: January 25, 1988Date of Patent: January 24, 1989Assignee: Bayer AktiengesellschaftInventors: Joachim Weissmuller, Dieter Berg, Stefan Dutzmann, Paul Reinecke
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Patent number: 4789742Abstract: Novel Isomaleimido and isophthalimido derivatives of chromophoric compounds are provided which are useful in analytic techniques for the detection and measurement of biological compounds such as bacteria, enzymes, hormones and the like.Type: GrantFiled: July 14, 1986Date of Patent: December 6, 1988Inventor: Spyros Theodoropulos
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Patent number: 4785096Abstract: There is disclosed a process for the preparation of 1,4-diamino-2,3-dicyanoanthraquinones by reacting compounds of formula ##STR1## wherein X.sub.1 and X.sub.2 are hydroxyl, halogen, acetate or sulfato ester, or, when taken together, are an oxygen atom attached by a double bond to the boron atom, R is a substituent and n is 0, 1 or 2, with an inorganic cyanide in a polar aprotic solvent and in the presence of an oxidizing agent, and subsequently hydrolyzing the reaction product.Type: GrantFiled: January 19, 1988Date of Patent: November 15, 1988Assignee: Ciba-Geigy CorporationInventor: Jean-Marie Adam
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Patent number: 4775754Abstract: Oxazine, thiazine and diazine leuco dyes are synthesized through a reaction using a dicyclohexylcarbodiimide adduct. The adducts are themselves novel compounds.Type: GrantFiled: October 7, 1987Date of Patent: October 4, 1988Assignee: Minnesota Mining and Manufacturing CompanyInventors: Kim M. Vogel, Roger A. Mader
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Patent number: 4772698Abstract: Process for producing molded polyurethane parts using as internal release agents, compounds of the general formula ##STR1## in amounts of 0.5 to 10 weight percent, based on the reaction formulation, in which at least one R.sup.2 radical in the average molecule represents ##STR2## R.sup.3 is a divalent hydrocarbon radical with 2 to 4 carbon atoms and R.sup.4, R.sup.5 are univalent hydrocarbon radicals or together are part of a morpholine or a piperazine ring. The molded polyurethane parts can be removed from the mold using significantly lower tensional forces without residues being built up on the mold.Type: GrantFiled: June 24, 1987Date of Patent: September 20, 1988Assignee: Th. Goldschmidt AGInventors: Helmut Lammerting, Hans-Joachim Kollmeier
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Patent number: 4762826Abstract: The invention relates to novel heterocyclic organosilyl compounds of the general formula I ##STR1## wherein R.sub.1 is hydrogen, C.sub.1 -C.sub.10 alkyl, C.sub.3 -C.sub.7 cycloalkyl, phenyl or trimethylsilyl,R.sub.2 is hydrogen or C.sub.1 -C.sub.4 alkyl, orR.sub.1 and R.sub.2 together form a saturated or unsaturated ring containing 6 carbon atoms;R.sub.3 and R.sub.4 are each independently of the other hydrogen, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy, and R.sub.4 may also be C.sub.3 -C.sub.7 cycloalkyl;R.sub.5 to R.sub.12 are each independently hydrogen or C.sub.1 -C.sub.4 alkyl, andR.sub.8 and R.sub.9 together may also form a saturated or unsaturated ring containing 6 carbon atoms;X is CH.sub.2, oxygen or sulfur, andn and Z are each independently of the other 0 or 1, and, if Z is 0, to the acid addition salts thereof.The novel compounds have microbicidal properties and are suitable in particular for controlling phytopathogenic microorganisms.Type: GrantFiled: April 6, 1987Date of Patent: August 9, 1988Assignee: Ciba-Geigy CorporationInventor: Wolfgang Eckhardt
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Patent number: 4743602Abstract: According to the invention there are provided compounds useful for combatting fungi having the general formula (I): ##STR1## and stereoisomers thereof, wherein one of X and Y, but not both, is a group of the formula (II): ##STR2## and the other of X and Y is a hydrogen atom, a halogen atom, or an alkyl, cycloalkyl, cycloalkylalkyl, alkenyl, alkynyl, aryl, aralkyl, alkoxy, aryloxy or haloalkyl group or a ##STR3## group wherein R.sup.9, R.sup.10 and R.sup.11 can be alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkylalkyl or aryl, Z is an oxygen atom, a sulphur atom or an --NH-group, A and B have the same significance as X or Y excluding a group of formula (II), R.sup.1, R.sup.2, R.sup.3 and R.sup.4 each represent a hydrogen atom, a halogen atom or an alkyl group containing from 1 to 4 carbon atoms, R.sup.5 and R.sup.6 each represent a hydrogen atom or an alkyl group containing from 1 to 4 carbon atoms, and R.sup.7 and R.sup.8 each represent an alkyl group containing from 1 to 4 carbon atoms or R.sup.7 and R.sup.Type: GrantFiled: June 30, 1987Date of Patent: May 10, 1988Assignee: Imperial Chemical Industries PLCInventors: Paul A. Worthington, Vivienne M. Anthony
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Patent number: 4738800Abstract: There is disclosed a process for the preparation of 1,4-diamino-2,3-dicyanoanthraquinones by reacting compounds of formula ##STR1## wherein X.sub.1 and X.sub.2 are hydroxyl, halogen, acetate or sulfato ester, or, when taken together, are an oxygen atom attached by a double bond to the boron atom, R is a substituent and n is 0, 1 or 2, with an inorganic cyanide in a polar aprotic solvent and in the presence of an oxidizing agent, and subsequently hydrolyzing the reaction product.Type: GrantFiled: March 16, 1987Date of Patent: April 19, 1988Assignee: Ciba-Geigy CorporationInventor: Jean-Marie Adam
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Patent number: 4737184Abstract: Novel N-(heterocyclicaminocarbonyl) substituted thiophene-, furan- and pyrrolesulfonamides, such as N-[(4-methoxy-6-methylpyrimidin-2-yl)aminocarbonyl]-6,7-dihydro-5H-thieno- [3,2-b]thiopyran-3-sulfonamide, 4,4-dioxide and N-[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]-6,7-dihydro-5H-thieno[3,2-b ]thiopyran-3-sulfonamide, 4,4-dioxide and their method-of-use as herbicides are described.Type: GrantFiled: May 10, 1985Date of Patent: April 12, 1988Assignee: E. I. Du Pont De Nemours and CompanyInventor: Robert J. Pasteris
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Patent number: 4729784Abstract: Novel dialkylmaleimides of the formula (I) ##STR1## and the use of the novel compounds as herbicides.Type: GrantFiled: June 23, 1987Date of Patent: March 8, 1988Assignee: Nihon Tokushu Noyaku Seizo K.K.Inventors: Toyohiko Kume, Toshio Goto, Atsumi Kamochi, Naoko Yamaguchi, Akihiko Yanagi, Hidenori Hayakawa, Shigeki Yagi
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Patent number: 4723987Abstract: Sulfonamides such as N-[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]-1,3-dihydro-6-methyl-3-oxof uro[3,4-c]pyridine-4-sulfonamide are useful as herbicides and plant growth regulants.Type: GrantFiled: April 22, 1986Date of Patent: February 9, 1988Assignee: E. I. Du Pont de Nemours and CompanyInventor: Mary A. Hanagan
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Patent number: 4713187Abstract: Disclosed herein are additives which are useful as dispersants and detergents in lubricating oils and fuels. In particular, this invention is directed toward polyamino alkenyl or alkyl succinimides wherein one or more of the amino nitrogens of the succinimide is substituted with ##STR1## wherein R.sub.4 is hydrocarbyl of from 1 to 30 carbon atoms; R.sub.5 is hydrocarbyl of from 2 to 30 carbon atoms or --R.sub.6 --(OR.sub.6).sub.p -- wherein R.sub.6 is alkylene of 2 to 5 carbon atoms and p is an integer from 1 to 100; and m is an integer of from 0 to 1.Type: GrantFiled: March 2, 1987Date of Patent: December 15, 1987Assignee: Chevron Research CompanyInventors: Thomas F. Buckley, III, Robert H. Wollenberg
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Patent number: 4707473Abstract: 4-Monosubstitued and 4,6-disubstituted phenoxazines, methods of preparing them and pharmaceutical compositions containing them. These compounds are useful as anti-inflammatories.Type: GrantFiled: May 30, 1986Date of Patent: November 17, 1987Assignee: Syntex (U.S.A.) Inc.Inventors: Joseph M. Muchowski, Robert J. Greenhouse, Angel Guzman
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Patent number: 4702851Abstract: Disclosed are additives which are useful as dispersants in lubricating oils, gasolines, marine crankcase oils and hydraulic oils. In particular, disclosed are additives prepared by (a) first reacting a polyamine with a cyclic carbonate; (b) reaction of this intermediate with an alkenyl or alkyl succinic anhydride; and (c) reaction of the product of (b) with a boron compound.Type: GrantFiled: October 8, 1986Date of Patent: October 27, 1987Assignee: Chevron Research CompanyInventor: Robert H. Wollenberg
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Patent number: 4684726Abstract: Reactive stabilizing compounds, able to stabilize organic polymers, contain in their molecule a sterically hindered amino group and a hydrolyzable silyl function.In stabilizing organic polymers, said reactive stabilizing compounds can be hydrolyzed at the silyl function with the formation of silanol groups, which are made to interact in order to form complex resinous stabilizing structures. These latter are added in stabilizing quantities to the polymer to be stabilized.According to one particular embodiment, the hydrolysis at the silyl function and the formation of the resinous structure take place spontaneously within the polymer to be stabilized.According to a further embodiment, the reactive stabilizing compound is added to the polymer after being stably supported on a solid support by reaction with an inorganic solid having surface hydroxyl groups.Type: GrantFiled: May 13, 1985Date of Patent: August 4, 1987Assignee: Enichem Sintesi, S.p.A.Inventors: Alberto Greco, Carlo Busetto, Luigi Cassar, Carlo Neri
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Patent number: 4639286Abstract: Azlactone-functional compounds, which are liquid above 20.degree. C., and their method of preparation from alkenyl azlactones and nucleophilic group-substituted compounds are disclosed. The azlactone-functional compounds of the invention cure in the presence of nucleophilic chain-extending or crosslinking agents to form linear or crosslinked polyamide resin systems.Type: GrantFiled: August 17, 1984Date of Patent: January 27, 1987Assignee: Minnesota Mining and Manufacturing CompanyInventors: Jerald K. Rasmussen, Steven M. Heilmann, Frederick J. Palensky
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Patent number: 4628048Abstract: Organosilyl compounds of the general formula I ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are alkyl, substituted alkyl, alkenyl, alkynyl, cycloalkyl, phenyl or substituted aryl, R.sup.4 and R.sup.5 are alkyl or hydrogen and Y is CH.sub.2, oxygen, nitrogen or alkyl-substituted nitrogen, their salts and fungicides containing these compounds.Type: GrantFiled: March 18, 1986Date of Patent: December 9, 1986Assignee: BASF AktiengesellschaftInventors: Rolf-Dieter Acker, Ernst Buschmann, Ernst-Heinrich Pommer, Eberhard Ammermann
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Patent number: 4617152Abstract: A process is described for selectively obtaining 1-.beta.-methylcarbapenem intermediates. The desired chirality is obtained through the hydrogenation of certain bicyclic .beta.-lactam ring structures containing an exocyclic methylene double bond alpha to the .beta.-lactam ring, in the presence of a Group VIII metal hydrogenation catalyst. The hydrogenation results in a mixture of .alpha.- and .beta.-methyl epimers having a high .beta./.alpha. epimeric ratio. New 1-.beta.-methylcarbapenem intermediates made by the process are also described.Type: GrantFiled: February 19, 1985Date of Patent: October 14, 1986Assignee: Merck & Co., Inc.Inventors: Burton G. Christensen, Lovji D. Cama, Susan M. Schmitt
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Patent number: 4604460Abstract: Intermediates for preparaing an antibacterial 1-dethia-1-oxacephalosporins which are represented by the following formula: ##STR1## wherein R is a monovalent group (minus the carbonyl) from an acyl derived from a carboxylic or carbonic acid;Y.sup.1 is a divalent group of the following formula: ##STR2## wherein COB is carboxy or protected carboxy;X is hydrogen or a nucleophilic group; andZ is a leaving groupare prepared from a compound of the following formula: ##STR3## wherein R and Y.sup.1 are as defined aboveby the action of an acid.The new compounds of this invention shown by the following formula: ##STR4## wherein A is amino or substituted amino;E is hydrogen or methoxy; andY is a divalent group of the following formula: ##STR5## in which COB, X, and Z are as defined above are convertible into other compounds of the same formula by applying conventional methods in .beta.-lactam chemistry.Type: GrantFiled: October 17, 1983Date of Patent: August 5, 1986Assignee: Shionogi & Co., Ltd.Inventors: Mitsuru Yoshioka, Uyeo Shoichiro, Yoshio Hamashima, Ikuo Kikkawa, Teruji Tsuji, Wataru Nagata
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Patent number: 4595750Abstract: A process is described for selectively obtaining 1-.beta.-methylcarbapenem intermediates. The desired chirality is obtained through the hydrogenation of certain bicyclic .beta.-lactam ring structures containing an exocyclic methylene double bond alpha to the .beta.-lactam ring, in the presence of a Group VIII metal hydrogenation catalyst. The hydrogenation results in a mixture of .alpha.- and .beta.-methyl epimers having a high .beta./.alpha. epimeric ratio. New 1-.beta.-methylcarbapenem intermediates made by the process are also described.Type: GrantFiled: August 29, 1984Date of Patent: June 17, 1986Assignee: Merck & Co., Inc.Inventors: Burton G. Christensen, Lovji D. Cama, Susan M. Schmitt
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Patent number: 4587247Abstract: Novel substituted and unsubstituted 13-(alkoxy)methoxy derivatives of the avermectin aglycones are useful as anthelmintic and antiparasitic agents. The compounds are also useful as pesticides and insecticides against agricultural pests. Included herein are novel intermediates useful in the process for preparing said avermectin aglycone derivatives. Compositions of said derivatives and methods of administering said compositions are also disclosed.Type: GrantFiled: February 25, 1985Date of Patent: May 6, 1986Assignee: Merck & Co., Inc.Inventors: Bruce O. Linn, Helmut H. Mrozik
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Patent number: 4569993Abstract: An antibacterial 7beta-substituted malonamido-7alpha-methoxy-3-tetrazolylthiomethyl-1-dethia-1-oxa-3-cephem-4 -carboxylic acid and its derivative represented by the following formula: ##STR1## (wherein R.sup.1 is alkyl, hydroxyaryl, or thienyl;R.sup.2 and R.sup.4 each is hydrogen, light metal or a carboxy-protecting group; andR.sup.3 is optionally protected hydroxyalkyl, carbamoylalkyl, dialkylaminoalkyl, or sulfamoylalkyl)are disclosed.Type: GrantFiled: December 6, 1984Date of Patent: February 11, 1986Assignee: Shionogi & Co., Ltd.Inventors: Masayuki Narisada, Fumihiko Watanabe, Yoshio Hamashima
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Patent number: 4562185Abstract: The present invention relates to combating pests with five-membered nitrogen-containing heterocyclic compounds of the formula (I) ##STR1## in which R.sup.1, R.sup.2, R.sup.3, X and Y have the meaning given in the description. Many of the compounds are new.Type: GrantFiled: March 15, 1984Date of Patent: December 31, 1985Assignee: Bayer AktiengesellschaftInventors: Gerhard Jager, Rudolf Fauss, Kurt Findeisen, Benedikt Becker, Bernhard Homeyer
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Patent number: 4556649Abstract: Insecticidally active novel substituted malonic acid diamide insecticides of the formula ##STR1## wherein R.sup.1 represents aryl or heteroaryl, each of which can optionally be substituted,R.sup.2 represents hydrogen or trialkylsilyl, and represents alkyl, cycloalkyl, alkenyl, alkinyl, aralkyl, alkylcarbonyl, arylcarbonyl, alkoxycarbonyl, aryloxycarbonyl, alkylsulphenyl, arylsulphenyl, alkylsulphonyl, arylsulphonyl, alkylaminosulphonyl, dialkylaminosulphonyl, arylaminosulphonyl or arylalkylaminosulphonyl, each of which can optionally be substituted, and represents radicals of the formula--CO--NR.sup.5 R.sup.6whereinR.sup.5 and R.sup.6 independently of one another represent hydrogen, alkyl, cycloalkyl, aryl, alkylaminocarbonyl, arylaminocarbonyl, alkylcarbonyl, arylcarbonyl, alkoxycarbonyl, aryloxycarbonyl, alkylsulphonyl or arylsulphonyl, it being possible for these radicals to be optionally substituted,R.sup.3 represents hydrogen or the radical R.sup.4,R.sup.7 and R.sup.Type: GrantFiled: December 21, 1984Date of Patent: December 3, 1985Assignee: Bayer AktiengesellschaftInventors: Herbert Salzburg, Rudolf Fauss, Kurt Findeisen, Bernhard Homeyer
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Patent number: 4533730Abstract: Intermediates for preparing an antibacterial 1-dethia-1-oxacephalosporins which are represented by the following formula: ##STR1## wherein R is a monovalent group (minus the carbonyl) from an acyl derived from a carboxylic or carbonic acid;Y.sup.1 is a divalent group of the following formula: ##STR2## wherein COB is carboxy or protected carboxy;X is hydrogen or a nucleophilic group; andZ is a leaving groupare prepared from a compound of the following formula; ##STR3## wherein R and Y.sup.1 are as defined above by the action of an acid. The new compounds of this invention shown by the following formula: ##STR4## wherein A is amino or substituted amino;E is hydrogen or methoxy; andY is a divalent group of the following formula: ##STR5## in which COB, X, and Z are as defined above are convertible into other compounds of the same formula by applying conventional methods in .beta.-lactam chemistry.Type: GrantFiled: October 19, 1983Date of Patent: August 6, 1985Assignee: Shionogi & Co., Ltd.Inventors: Mitsuru Yoshioka, Uyeo Shoichiro, Yoshio Hamashima, Ikuo Kikkawa, Teruji Tsuji, Wataru Nagata
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Patent number: 4532233Abstract: An antibacterial 7.beta.-(fluorinated methylthioacetamido)-7.alpha.-methoxy-3-(1-hydroxyalkyl-5-tetrazolyl)thiom ethyl-1-dethia-1-oxa-3-cephem-4-carboxylic acid and its derivatives at the carboxy or hydroxyalkyl represented by the following formula: ##STR1## wherein, R is FCH.sub.2 -- or F.sub.2 CH--; R.sup.1 is R.sup.3 O-substituted-alkyl in which R.sup.3 is hydrogen or a hydroxy-protecting group; and R.sup.2 is a hydrogen or light metal atom or a carboxy-protecting group, antibacterial drugs containing it, its use and production.Type: GrantFiled: December 22, 1983Date of Patent: July 30, 1985Assignee: Shionogi & Co., Ltd.Inventors: Teruji Tsuji, Hisao Sato, Yoshio Hamashima