Plural Ring Hetero Atoms In The Hetero Ring Patents (Class 549/89)
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Patent number: 8563779Abstract: A description is given of (4-trifluoromethyl-3-thiobenzoyl)cyclohexanediones of the formula (I) and of their use as herbicides. In this formula (I), X, R1, R2, R3, and R4 are radicals such as hydrogen and organic radicals such as alkyl. A and Z are oxygen or alkylene.Type: GrantFiled: July 19, 2011Date of Patent: October 22, 2013Assignee: Bayer CropScience AGInventors: Hartmut Ahrens, Andreas Van Almsick, Elmar Gatzweiler, Dieter Feucht, Isolde Haeuser-Hahn, Stefan Lehr, Christopher Hugh Rosinger
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Publication number: 20130040209Abstract: A non-aqueous electrolyte solution containing a cyclic sulfone compound having a 1,3-dithietane-1,1,3,3-tetraoxide structure is provided. The cyclic sultone compound is preferably a compound represented by formula (I) [wherein in formula (I), R1 to R4 each represent a hydrogen atom, a halogen atom, a substituted or unsubstituted alkyl group, or the like].Type: ApplicationFiled: April 25, 2011Publication date: February 14, 2013Applicant: MITSUI CHEMICALS, INC.Inventors: Shigeru Mio, Mitsuo Nakamura, Hidenobu Nogi, Takashi Hayashi, Takeshi Kobayashi
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Publication number: 20100197759Abstract: Dithiolane compounds having the structural formula (I): are useful for reinforcing and/or preserving the natural antioxidant protection of the skin against oxidative stress caused, especially, by UV radiation, e.g., by increasing the level of intracellular glutathione.Type: ApplicationFiled: September 24, 2009Publication date: August 5, 2010Applicant: L'OREALInventors: Xavier Marat, Karine Lucet-Levannier
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Patent number: 7679078Abstract: Optoelectronic materials are provided that are bistable organic tautomeric compositions that intraconvert dithio or diseleno carbamate esters and cyclic 1,3-dithia- or -diselena-2-iminium salts of ?-conjugated bis-anthracenyl compounds. Specifically disclosed are compounds having the formula: where X is sulfur or selenium; where the R and R1 groups are alkyl or alkyl that together form a ring of carbon atoms; where An is the anion of a strong acid; and where the Z element is a chiral ring-completing system of atoms that changes chirality on tautomerization. These molecules are in themselves molecular-sized optoelectronic switching devices.Type: GrantFiled: March 10, 2005Date of Patent: March 16, 2010Assignee: California Molecular Electronics CorporationInventors: Robert R. Schumaker, James J. Marek, Jr., James Parakka
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Publication number: 20100035960Abstract: Production and use of a sulfur-containing compound, tropodithietic acid (TDA), from the roseobacter Silicibacter sp. TM1040 is described. Specifically, a biosynthetic and regulatory pathway for TDA biosynthesis in roseobacters is described. The TDA produced from roseobacters, specifically Silicibacter sp. TM1040, is shown to have antibacterial activity, in particular against Vibrio anguillarium, Vibrio cholerae, Vibrio coralliilyticus, Vibrio shiloi, Halomonas spp., Mycobacterium marinum, Mycobacterium tuberculosis, Pseudomonas elongate, Spongiobacter nikelotolerans, and Staphylococcus aureus (MRSA).Type: ApplicationFiled: May 26, 2009Publication date: February 11, 2010Applicant: UNIVERSITY OF MARYLAND BIOTECHNOLOGY INSTITUTEInventors: Robert Belas, Haifeng Geng, Ryan Powell
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Publication number: 20090215225Abstract: Precursors for use in depositing tellurium-containing films on substrates such as wafers or other microelectronic device substrates, as well as associated processes of making and using such precursors, and source packages of such precursors. The precursors are useful for deposition of chalcogenide thin films in the manufacture of nonvolatile Phase Change Memory (PCM), by deposition techniques such as chemical vapor deposition (CVD) and atomic layer deposition (ALD).Type: ApplicationFiled: February 24, 2009Publication date: August 27, 2009Applicant: ADVANCED TECHNOLOGY MATERIALS, INC.Inventors: Matthias Stender, Chongying Xu, Tianniu Chen, William Hunks, Philip S.H. Chen, Jeffrey F. Roeder, Thomas H. Baum
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Patent number: 7018802Abstract: Electrochemiluminescent-labels and enzyme substrates, which preferably are conjugated, are used in immunoassays and electrochemiluminescence is generated catalytically. In conventional electrochemiluminescence immunoassays, an anti-analyte antibody molecule can give rise to typically 6–8 electrochemiluminescence-active ruthenium atoms, while in the present invention, each enzyme-labeled anti-analyte molecule can give rise to thousands of electrochemiluminescence-active ruthenium atoms per second. An exemplary immunoassay is based on a catalytic process employing ?-lactamase-conjugated anti-analytes which enzymatically hydrolyze electrochemiluminescent-labeled substrates, making them strongly electrochemiluminescent. The electrochemiluminescence signal generated by each anti-analyte molecule (i.e., each analyte molecule) is much greater than with the conventional method. Accordingly, greater sensitivity can be gained in the measurement of low concentrations of a given immunoassay analyte.Type: GrantFiled: September 4, 2002Date of Patent: March 28, 2006Assignee: BioVeris CorporationInventors: Mark T. Martin, Rick Saul, Pam Liang
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Patent number: 6916591Abstract: Photoacid generators are provided by O-arylsulfonyl-oxime compounds having formula (1) wherein R is H, F, Cl, NO2, alkyl or alkoxy, n is 0 or 1, m is 1 or 2, r is 0 to 4, r? is 0 to 5, k is 0 to 4, and G? and G? are S or —CH?CH—. Chemically amplified resist compositions comprising the photoacid generators have many advantages including improved resolution, improved focus latitude, minimized line width variation or shape degradation even on long-term PED, and improved pattern profile after development. Because of high resolution, the compositions are suited for microfabrication, especially by deep UV lithography.Type: GrantFiled: March 21, 2003Date of Patent: July 12, 2005Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Youichi Ohsawa, Katsuhiro Kobayashi, Katsuya Takemura, Junji Tsuchiya, Kazunori Maeda
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Patent number: 6469146Abstract: The invention concerns radiopharmaceutical products suitable for the selective labeling of lymphomas containing a metal complex with the formula: [M(R1CS2)(R1CS3)2] in which M is chosen from among 99mTc, 186Re and 188Re, and R1 represents an alkyl, cycloalkyl, aralkyl or aryl group, optionally substituted, obtained by reaction of a pertechnetate or a perrhenate with a reducing agent such as SnCl2ZP2O in the presence of a dithiocarboxylate having the formula: (R1CS2)−Z2+.Type: GrantFiled: May 31, 2000Date of Patent: October 22, 2002Assignee: Cis Bio InternationalInventors: Roberto Pasqualini, Emmanuel Bellande, Franck Mevellec, Alain Roucoux, Nicolas Noiret, Henri Patin
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Patent number: 5723630Abstract: A process allows the preparation of a fluorinated beta-sultone by reacting a fluorinated olefin with oleum.Type: GrantFiled: February 18, 1997Date of Patent: March 3, 1998Assignee: Minnesota Mining and Manufacturing CompanyInventors: Yuri Cheburkov, William M. Lamanna
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Patent number: 5330981Abstract: This application describes 3-arylalkyl esters of 4,5-dihydro-9,10-dioxo-2-anthracenecarboxylic acid and a process for making them. Also described is a method of using the compounds in the treatment of arthritis.Type: GrantFiled: December 30, 1992Date of Patent: July 19, 1994Assignee: Istituto Gentili S.p.A.Inventors: Sergio Rosini, Maurizio Mian
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Patent number: 5283355Abstract: Compounds of the Formula (5) and processes for their preparation and use, particularly in the manufacture of unsymmetrical triphenodioxazine dyes: ##STR1## wherein: Y is H, alkyl, substituted alkyl, alkoxy, Cl or Br;R is a group of Formula (3) ##STR2## R.sup.1 and R.sup.2 are each independently alkyl, or R.sup.1 and R.sup.2 together with the carbon atom to which they are attached form an optionally substituted 4, 5 or 6 membered alicyclic or heterocyclic ring;R.sup.3 is H;Z is Cl, Br or A--NH; andA is H or the residue of a primary amine.Type: GrantFiled: October 22, 1991Date of Patent: February 1, 1994Assignee: Imperial Chemical Industries PLCInventor: William J. E. Norris
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Patent number: 5264455Abstract: X is hydrogen or --S(O).sub.m --R.sup.1 and Y is hydrogen or S(O).sub.n --R.sup.2, except that X and Y are not both hydrogen, or one of X and Y is --S--alkyl--SH and the other is hydrogen; ##STR2## and the remaining symbols are as defined in the specification.Type: GrantFiled: July 1, 1991Date of Patent: November 23, 1993Assignee: E. R. Squibb & Sons, Inc.Inventors: Ravi K. Varma, Jeffrey O. Saunders, Sam T. Chao, Eric M. Gordon, Dinos P. Santafianos
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Patent number: 5260310Abstract: Novel compounds of the formula ##STR1## wherein Q, R.sup.1 and R.sup.2 are described herein, are disclosed along with pharmaceutical compositions, methods of use, and process for producing compounds of formula I which starts from the corresponding .beta.-hydroxycarboxylic acids.Type: GrantFiled: August 12, 1992Date of Patent: November 9, 1993Assignee: Hoffmann-La Roche Inc.Inventors: Romano Derungs, Hans P. Marki, Henri Stalder, Andre Szente
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Patent number: 5227398Abstract: Hepatopathy improvers contain as an effective ingredient one or more of benzodioxole derivatives represented by the following formula: ##STR1## wherein A means a particular N- or S-containing group. Most of these benzodioxole derivatives are novel.Type: GrantFiled: November 26, 1991Date of Patent: July 13, 1993Assignee: Tsumura & Co.Inventors: Masayuki Kimura, Shouichi Nishida, Shigefumi Takeda, Kunio Hosaka
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Patent number: 5103013Abstract: 2-(1,3-Dithietan-2-ylidene)-2-[N-(subsittuted)carbamoyl]acetate esters and 2-(1,3-dithiolan-2-ylidene)-2-[N-(substituted) carbamoyl]acetate esters, having potent therapeutic and prophylactic effect for hepatic disorders, are provided.Type: GrantFiled: October 23, 1989Date of Patent: April 7, 1992Assignee: Yuhan Corporation, Ltd.Inventors: Choong S. Kim, Jeong S. Chae, Ho Seong Yoo, Jong W. Lee, Jae G. Park, Jeong W. Lee
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Patent number: 4927845Abstract: Anthralin analogues containing a thio-substituent, especially in one or more of the positions 2-, 7- and 10- of the anthralin ring. They may be made by reacting an anthralin derivative (e.g. 10-bromoanthralin) with a thiol or a compound containing a group convertible to a thio-group. Alternatively, a 1,8-dihydroxy anthraquinone containing a thio-substituent may be reduced. Reactive intermediates may be made by introducing one or more nuclear allylic groups into a 1,8-dihydroxy anthraquinone and then converting them into a reactive form, e.g. by epoxidation or halide addition. The intermediate can then reduced to the oxidation state corresponding to anthralin.Additional products having the 10-carbon atom of the anthralin ring as part of a heterocyclic ring, may be made by anthralins containing various substitutes thioalkyl groups as the 10-substituent.The compounds are useful for treatment of psoriasis, and may be formulated in the conventional vehicles for topical application, for example petrolatum.Type: GrantFiled: August 15, 1989Date of Patent: May 22, 1990Assignee: The Victoria University of ManchesterInventor: John M. Bruce
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Patent number: 4897415Abstract: There are described new 2-imino-1,3-dithietanes of general formula I ##STR1## in which R is the group ##STR2## in which A is CFHal, C(CH.sub.3)C.sub.1-4 -alkyl, C(CH.sub.3)CHal.sub.3, C(CH.sub.3)CF.sub.2 Cl, C(CH.sub.3)CFCl.sub.2, C.sub.2 H.sub.4, C.sub.2 H.sub.3 Hal, C.sub.2 H.sub.2 Hal.sub.2, C.sub.2 HHal.sub.3, C.sub.2 F.sub.2 Cl.sub.2, C.sub.2 F.sub.4 or C.sub.2 F.sub.3 Cl, in which Hal is F or Cl,Y is nitrogen or CH,R.sup.1 is fluoro-C.sub.1-12 -alkyl, fluoro-C.sub.2-12 -alkenyl, fluoro-C.sub.2-12 -alkynyl, fluorocyclopropyl or fluorocyclopropylmethyl;X is oxygen or sulphur,2 is defined in the specification andn is 0, 1 or 2,as well as their acid addition salts, a process for their preparation and their use as pesticides. The new compounds are especially useful as nematicides.Type: GrantFiled: January 29, 1988Date of Patent: January 30, 1990Assignee: Schering AktiengesellschaftInventors: Dieter Hubl, Ernst-Albrecht Pieroh, Eberhard Richter, Reinhold Puttner
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Patent number: 4826998Abstract: Salts of sulfonic acids of the type formed in the sulfonation of alkenyl alkyl polyglycol ethers corresponding to the following formulaR--O (--C.sub.n H.sub.2n O).sub.x --R.sup.1with sulfur trioxide, followed by hydrolysis, are used as antistatic agents for plastics. R is a straight chain C.sub.10 -C.sub.22 alkenyl group, R.sub.1 is a C.sub.1 -C.sub.12 alkyl group, n is an integer of from 2 or 4, and x is an integer of from 0 to 35. The products show a particularly long-lasting effect as external antistatic agents on polyamide fibers.Type: GrantFiled: September 5, 1985Date of Patent: May 2, 1989Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Rudolf Veitenhansl, Wolfgang Froeschke, Robert Piorr
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Patent number: 4612036Abstract: Cyclohexane-1,3-dione derivatives of the formula ##STR1## where A is an unsubstituted or substituted, saturated or unsaturated 4-membered to 7-membered ring which contains 1 or 2 sulfinyl or sulfonyl groups, R.sup.1 is hydrogen, methoxycarbonyl, ethoxycarbonyl, methyl or cyano, R.sup.2 is alkyl and R.sup.3 is alkyl, alkenyl, haloalkenyl or propargyl, and salts of these compounds are used for controlling undesirable plant growth.Type: GrantFiled: July 2, 1985Date of Patent: September 16, 1986Assignee: BASF AktiengesellschaftInventors: Dieter Jahn, Rainer Becker, Michael Keil, Bruno Wuerzer
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Patent number: 4448976Abstract: Disclosed is a chiral, total synthesis of thienamycin from D-glucose which proceeds via intermediates I, II and III to known aldehyde IV which is known to be useful in the total synthesis of thienamycin (V): ##STR1## wherein: R is lower alkyl having 1-6 carbon atoms or bi-valent alkyl having 2-6 carbon atoms which joins the two sulfur atoms; R.sup.1 is lower alkyl or aralkyl, such as benzyl and the like; and R.sup.2 is hydrogen or a removable protecting group, such as triorganosilyl wherein the organo groups are independently selected from lower alkyl, phenyl and phenylloweralkyl.Type: GrantFiled: February 7, 1983Date of Patent: May 15, 1984Assignee: Merck & Co., Inc.Inventor: Philippe L. Durette
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Patent number: 4414153Abstract: Substituted 1,3-dithietane-2-carboxylic acid derivatives useful as intermediates for the preparation of highly effective penicillin and cephalosporin derivatives and the preparation thereof.Type: GrantFiled: September 23, 1981Date of Patent: November 8, 1983Assignee: Yamanouchi Pharmaceutical Co. Ltd.Inventors: Masaru Iwanami, Tetsuya Maeda, Yoshinobu Nagano, Masaharu Fujimoto, Noriaki Nagano, Atsuki Yamazaki, Kazaharu Tamazawa, Kiyoshi Murase, Tadao Shibanuma
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Patent number: 4382815Abstract: There are provided herbicidal 5-[2-chloro-4-(trifluoromethyl)phenoxy]-2-nitrobenzoyl derivatives of imino-dithiolanes.Type: GrantFiled: July 27, 1981Date of Patent: May 10, 1983Assignee: Rhone-Poulenc AgrochimieInventor: Stanley T. D. Gough
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Patent number: 4367349Abstract: The process for preparing hexafluoroisobutylene is disclosed which comprises reacting, in the liquid phase, formaldehyde or a formaldehyde-generating compound with hexafluorothioacetone dimer in an aprotic solvent containing at least a catalytic amount of an alkali metal fluoride or a sulfonic acid having general formula RSO.sub.3 H is disclosed. The preferred aprotic solvents are dimethylformamide, N-methyl pyrrolidone and dimethyl sulfoxide. The preferred alkali metal fluoride is KF; the preferred sulfonic acids are CH.sub.3 SO.sub.3 H and p-CH.sub.3 C.sub.6 H.sub.4 SO.sub.3 H. The production of hexafluoroisobutylene by contacting hexafluoropropene with elemental sulfur and a catalytic amount of an alkali metal fluoride such as KF in an aprotic solvent such as dimethyl sulfoxide or N-methyl pyrrolidone at a temperature of between about 40.degree. and about 70.degree. C.Type: GrantFiled: June 18, 1981Date of Patent: January 4, 1983Assignee: Allied CorporationInventor: Louis G. Anello
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Patent number: 4337362Abstract: The production of hexafluoroacetone by contacting, in the liquid phase, hexafluorothioacetone dimer with at least a stoichiometric amount of an aprotic solvent selected from the group consisting of dimethylacetamide, dimethylformamide, dimethyl sulfoxide and N-methyl pyrrolidone and at least a catalytic amount of an alkali metal fluoride or a sulfonic acid having general formula RSO.sub.3 H is disclosed. Dimethylformamide and dimethyl sulfoxide are the preferred aprotic solvents; KF is the preferred alkali metal fluoride; and CH.sub.3 SO.sub.3 H and pCH.sub.3 C.sub.6 H.sub.4 SO.sub.3 H are the preferred sulfonic acids. The production of hexafluoroacetone by contacting hexafluoropropene with elemental sulfur and a catalytic amount of an alkali metal fluoride in an aprotic solvent at a temperature of between about 40.degree. and about 70.degree. C. for a time sufficient to produce hexafluorothioacetone dimer combined with increasing the temperature to between about 90.degree. and 150.degree. C.Type: GrantFiled: June 8, 1981Date of Patent: June 29, 1982Assignee: Allied CorporationInventor: Louis G. Anello
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Patent number: 4326068Abstract: An improved process for the reaction of hexafluoropropene with elemental sulfur and alkali metal fluoride such as KF, in an aprotic solvent selected from the group consisting of acetonitrile dimethylacetamide, dimethylformamide, dimethyl sulfoxide and N-methyl pyrrolidone under substantially one atmosphere pressure and at tempertures of between about 25.degree. and 100.degree. C. is disclosed. The preferred alkali metal fluoride is KF and the preferred aprotic solvent is dimethylformamide.Type: GrantFiled: December 15, 1980Date of Patent: April 20, 1982Assignee: Allied CorporationInventors: Louis G. Anello, Michael Van Der Puy
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Patent number: 4324900Abstract: Disclosed is a chiral, total synthesis of thienamycin from D-glucose, which proceeds via intermediates I, II, and III and joins aldehyde IV or acid V, which are known to be useful in the total synthesis of thienamycin (VI): ##STR1## wherein R.sup.1 is hydrogen or a removable protecting group;R is lower alkyl having 1-6 carbon atoms or bi-valent alkyl having 2-6 carbon atoms which joins the two sulfur atoms.Type: GrantFiled: March 30, 1981Date of Patent: April 13, 1982Assignee: Merck & Co., Inc.Inventor: Philippe L. Durette
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Patent number: 4231783Abstract: Derivatives of 2-imino-1,3-dithiolane, 1,3-dithiole, 1,3-dithiane, 1,3-dithietane and 1,3-oxathiole have been found to reduce herbicidal injury to crop plants due to thiocarbamate and acetanilide herbicides.Type: GrantFiled: November 15, 1978Date of Patent: November 4, 1980Assignee: Monsanto CompanyInventor: Frederic G. Bollinger
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Patent number: 4206138Abstract: Hexafluoropropene is reacted with liquid sulfur trioxide in the presence of boric oxide, boron trichloride, boron trifluoride, tri(lower alkyl) borate, boron trioxychloride or boron trioxyfluoride at from 0.degree. C. to 150.degree. C. to form perfluoroallyl fluorosulfate and the sultone thereof. The perfluoroallyl fluorosulfate can be homopolymerized or copolymerized with various fluoroethylenes to form resins useful as ion exchange resins or catalysts. The fluorosulfate groups on the resins can be hydrolyzed to form carboxylic acid groups or various corresponding salts. The sultone of perfluoroallyl fluorosulfate can be rearranged to form .beta.-fluorocarbonyl-.beta.-fluorosulfonyl-trifluorethyl fluorosulfate.Type: GrantFiled: August 8, 1978Date of Patent: June 3, 1980Assignee: E. I. Du Pont de Nemours and CompanyInventor: David C. England
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Patent number: 4198339Abstract: Substituted 1,3-dithietane-2-carboxylic acid derivatives useful as intermediates for the preparation of highly effective penicillin and cephalosporin derivatives and the preparation thereof.Type: GrantFiled: June 7, 1978Date of Patent: April 15, 1980Assignee: Yamanouchi Pharmaceutical Co., Ltd.Inventors: Masaru Iwanami, Tetsuya Maeda, Yoshinobu Nagano, Masaharu Fujimoto, Noriaki Nagano, Atsuki Yamazaki, Kazaharu Tamazawa, Kiyoshi Murase, Tadao Shibanuma
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Patent number: RE33778Abstract: Substituted 1,3-dithietane-2-carboxylic acid derivatives useful as intermediates for the preparation of highly effective penicillin and cephalosporin derivatives and the preparation thereof.Type: GrantFiled: December 8, 1989Date of Patent: December 24, 1991Assignee: Yamanouchi Pharmaceutical Co., Ltd.Inventors: Masaru Iwanami, Tetsuya Maeda, Yoshinobu Nagano, Masaharu Fujimoto, Noriaki Nagano, Atsuki Yamazaki, Kasaharu Tamazawa, Kiyoshi Murase, Tadao Shibanuma