Halogen Bonded Directly To The Anthracene Configured Ring System Patents (Class 552/244)
  • Publication number: 20130225517
    Abstract: The invention provides compounds of formula I: or salts thereof as described herein. The invention also provides pharmaceutical compositions comprising a compound of formula I and therapeutic methods for treating cancer.
    Type: Application
    Filed: February 22, 2013
    Publication date: August 29, 2013
    Applicant: University of Iowa Research Foundation
    Inventor: University of Iowa Research Foundation
  • Patent number: 8058460
    Abstract: The present invention relates to anthraquinone derivatives which act as a fluorophore, to a process for producing said anthraquinone derivatives and their use as fluorophores for staining membranes in live or fixed cells.
    Type: Grant
    Filed: September 20, 2007
    Date of Patent: November 15, 2011
    Assignee: Universität Heidelberg
    Inventors: Zuhal Kaya, Roland Krämer
  • Patent number: 7901496
    Abstract: Disclosed is a phase change ink composition comprising a phase change ink carrier and a colorant compound of the formula wherein Y is a hydrogen atom or a bromine atom, n is an integer of 0, 1, 2, 3, or 4, R1 is an alkylene group, an arylene group, an arylalkylene group, or an alkylarylene group, provided that no oxygen atom creates a linkage, X is —O— or —NR3— wherein R3 is a hydrogen atom, an alkyl group, an aryl group, an arylalkyl group, or an alkylaryl group, and R2 is a hydrogen atom, an alkyl group, an aryl group, an arylalkyl group, or an alkylaryl group.
    Type: Grant
    Filed: July 29, 2004
    Date of Patent: March 8, 2011
    Assignee: Xerox Corporation
    Inventors: Jeffrey H. Banning, Wolfgang G. Wedler, C. Wayne Jaeger
  • Patent number: 7683192
    Abstract: Disclosed is a colorant compound of the formula wherein Y is a hydrogen atom or a bromine atom, n is an integer of 0, 1, 2, 3, or 4, R1 is an alkylene group, an arylene group, an arylalkylene group, or an alkylarylene group, provided that no oxygen atom creates a linkage, X is —O— or —NR3— wherein R3 is a hydrogen atom, an alkyl group, an aryl group, an arylalkyl group, or an alkylaryl group, and R2 is a hydrogen atom, an alkyl group, an aryl group, an arylalkyl group, or an alkylaryl group.
    Type: Grant
    Filed: July 29, 2004
    Date of Patent: March 23, 2010
    Assignee: Xerox Corporation
    Inventors: Jeffrey H. Banning, Wolfgang G. Wedler, C. Wayne Jaeger
  • Publication number: 20100064452
    Abstract: The present invention concerns dyes of the general formula I where X and Y represent hydrogen, bromine or chlorine, but not simultaneously hydrogen; R represents F, Cl, Br, COOR1 or CF3; R? represents H or F; R1 represents C1-C6-alkyl; and one of W1 and W2 represents hydroxyl and the other nitro and Y is always ortho to the hydroxyl group; but not compounds in which R represents Cl attached to the phenyl nucleus in a is position ortho to the NH group nor compounds in which W1 represents nitro, W2 represents hydroxyl, Y represents hydrogen, X represents chlorine and R represents bromine attached to the phenyl nucleus in a position meta to the NH group, mixtures with further dyes, and also their preparation and use.
    Type: Application
    Filed: August 24, 2007
    Publication date: March 18, 2010
    Applicant: DyStar Textilfarben GmbH & Co. Deutschland KG
    Inventor: Hartwig Jordan
  • Publication number: 20090291467
    Abstract: The present invention relates to anthraquinone derivatives which act as a fluorophore, to a process for producing said anthraquinone derivatives and their use as fluorophores for staining membranes in live or fixed cells.
    Type: Application
    Filed: September 20, 2007
    Publication date: November 26, 2009
    Applicant: Universitat Heidelberg
    Inventors: Zuhal Kaya, Roland Krämer
  • Patent number: 7524979
    Abstract: A process for preparing a colorant of the formula which comprises preparing a first reaction mixture by admixing leucoquinizarin and, optionally, quinizarin, an aminobenzene substituted with an alcohol group of the formula —R1—OH, boric acid, and an optional solvent, and heating the first reaction mixture to prepare an alcohol-substituted colorant of the formula followed by converting the colorant thus prepared to either an ester-substituted colorant by reaction with an esterification compound which is either an anhydride of the formula or an acid of the formula R2COOH in the presence of an optional esterification catalyst, or a urethane-substituted colorant by reaction with an isocyanate compound of the formula R4—N?C?C?O, and brominating the colorant thus prepared, wherein either conversion to ester or urethane can be performed before bromination or bromination can be performed before conversion to ester or urethane.
    Type: Grant
    Filed: February 21, 2006
    Date of Patent: April 28, 2009
    Assignee: Xerox Corporation
    Inventors: C. Wayne Jaeger, Jeffery H. Banning
  • Publication number: 20080168608
    Abstract: The subject of the present invention is the use, for dyeing in particular human keratin materials, of a specific direct anthraquinone dye by dry thermal transfer. Its subject is furthermore a method for dyeing keratin materials, in which at least one direct anthraquinone dye contained in a dry composition is applied to or close to the keratin materials, and a source of heat is applied, causing the thermal transfer of the direct dye(s) at the surface and/or inside the keratin materials. It relates furthermore to the dry composition and a method for preparing it.
    Type: Application
    Filed: February 28, 2006
    Publication date: July 17, 2008
    Inventors: Gregory Plos, Luc Gourlaouen, Jean-Dominique Bazin De Bezons
  • Patent number: 6958406
    Abstract: Disclosed are compounds of the formula wherein Y is a hydrogen atom or a bromine atom, n is an integer of 0, 1, 2, 3, or 4, R1 is an alkylene group or an arylalkylene group, and X is (a) a hydrogen atom, (b) a group of the formula wherein R2 is an alkyl group, an aryl group, an arylalkyl group, or an alkylaryl group, (c) an alkyleneoxy, aryleneoxy, arylalkyleneoxy, or alkylaryleneoxy group, or (d) a group of the formula wherein R4 is an alkyl group, an aryl group, an arylalkyl group, or an alkylaryl group.
    Type: Grant
    Filed: September 27, 2002
    Date of Patent: October 25, 2005
    Assignee: Xerox Corporation
    Inventors: Jeffery H. Banning, C. Wayne Jaeger
  • Publication number: 20040135117
    Abstract: Dichroic dyes, dichroic dye compositions, and liquid crystal composition and liquid crystal display element containing the dichroic dyes. The dichroic dye has increased solubility and stability.
    Type: Application
    Filed: May 23, 2003
    Publication date: July 15, 2004
    Applicant: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTE
    Inventors: Shih-Hsien Liu, Yang-Chu Lin, Woan-Shiow Tzeng, Jie-Hwa Ma, Kung-Lung Cheng, Long-Li Lai
  • Patent number: 5817843
    Abstract: This invention is to provide a novel quinizarin compound which has a quinizarin structure represented by a following formula (1) having one to four of the 5, 6, 7, and 8 positions and at least either the 6 or 7 position formed of at least one member selected from the class consisting of secondary amino groups, alkylthio groups, and optionally substituted phenylthio groups, and having the remaining positions thereof formed of at least one member selected from the class consisting of hydrogen atom, halogen atoms, amino group, hydroxy group, alkoxy groups, and optionally substituted phenoxy groups, a method for the production thereof, and a dye, an electrophotographic grade color toner composition, a thermal-transfer recording sheet, an optical recording medium, an ink jet grade ink composition and a color filter severally comprising the quinizarin compound.
    Type: Grant
    Filed: October 16, 1996
    Date of Patent: October 6, 1998
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Kiyoshi Masuda, Yukie Tamaura, Osamu Kaieda
  • Patent number: 5608091
    Abstract: This invention is to provide a novel quinizarin compound which has a quinizarin structure represented by a following formula (1) having one to four of the 5, 6, 7, and 8 positions and at least either the 6 or 7 position formed of at least one member selected from the class consisting of secondary amino groups, alkylthio groups, and optionally substituted phenylthio groups, and having the remaining positions thereof formed of at least one member selected from the class consisting of hydrogen atom, halogen atoms, amino group, hydroxy group, alkoxy groups, and optionally substituted phenoxy groups, a method for the production thereof, and a dye, an electrophotographic grade color toner composition, a thermal-transfer recording sheet, an optical recording medium, an ink jet grade ink composition and a color filter severally comprising the quinizarin compound.
    Type: Grant
    Filed: September 30, 1994
    Date of Patent: March 4, 1997
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Kiyoshi Masuda, Yukie Tamaura, Osamu Kaieda
  • Patent number: 5493036
    Abstract: The invention relates to fibre-reactive anthraquinone dyes of formula ##STR1## wherein R.sub.1, R.sub.2, B, U, R and n are as defined in claim 1. The anthraquinone dyes of formula (1) are suitable for dyeing or printing hydroxyl group containing or nitrogen-containing fibre materials and give dyeings or prints of good allround fastness properties.
    Type: Grant
    Filed: September 19, 1994
    Date of Patent: February 20, 1996
    Assignee: Ciba-Geigy Corporation
    Inventor: Jean-Marie Adam
  • Patent number: 5480873
    Abstract: Pharmaceutical compounds of the formula ##STR1## in which R.sup.1 and R.sup.2 are each hydrogen, hydroxyl, halo, C.sub.1-4 alkyl, C.sub.1-4 alkoxy, acyloxy, --O-glucoside, optionally substituted phenyl or optionally substituted phenyl-C.sub.1-4 alkoxy;R.sup.3 istetrazolyl, orand R.sup.4 and R.sup.5 are each hydrogen, hydroxy, acyloxy, nitro, C.sub.1-4 alkyl, C.sub.1-4 alkoxy, halo, optionally substituted phenyl, --SO.sub.3 H or --NR'R" where R' and R" are each hydrogen or C.sub.1-4 alkyl;provided that when R.sup.3 is --CR'R".CHR'"CO.sub.2 H or tetrazolyl, R.sup.1 and R.sup.2 are each hydroxyl, halo, C.sub.1-4 alkyl, C.sub.1-4 alkoxy, acyloxy, --O-glucoside, optionally substituted phenyl or optionally substituted phenyl C.sub.1-4 alkoxy; andor a pharmaceutically acceptable salt or ester thereof.
    Type: Grant
    Filed: February 25, 1993
    Date of Patent: January 2, 1996
    Assignee: Lilly Industries Limited
    Inventors: Michael Brunavs, Colin P. Dell, David R. Dobson, Peter T. Gallagher, Terence A. Hicks, William M. Owton, Colin W. Smith
  • Patent number: 5132327
    Abstract: Compounds of formula (I) ##STR1## in which R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are each separately selected from hydrogen, X, NH--A--NHR and NH--A--N(O)R'R" wherein X is hydroxy, halogeno, amino, C.sub.1-4 alkoxy or C.sub.2-8 alkanoyloxy, A is a C.sub.2-4 alkylene group with a chain length between NH and NHR or N(O)R'R" of at least 2 carbon atoms and R, R' and R" are each separately selected from C.sub.1-4 alkyl groups and C.sub.2-4 hydroxyalkyl and C.sub.2-4 dihydroxyalkyl groups in which the carbon atom attached to the nitrogen atom does not carry a hydroxy group and no carbon atom is substituted by two hydroxy groups, or R' and R" together are a C.sub.2-6 alkylene group which with the nitrogen atom to which R" and R" are attached forms a heterocyclic group having 3 to 7 atoms in the ring, but with the proviso that at least one of R.sub.1 to R.sub.4 is a group NH--A--N(O)R'R", and physiologically acceptable salts thereof are of value in the treatment of cancer.
    Type: Grant
    Filed: April 10, 1991
    Date of Patent: July 21, 1992
    Assignee: National Research Development Corporation
    Inventor: Laurence H. Patterson
  • Patent number: 5082957
    Abstract: 1-Amino-2-bromo-4-hydroxy-anthraquinone (I) ##STR1## is prepared by brominating 1-amino-4-hydroxyanthraquinone (II) ##STR2## in an inert aprotic organic liquid.
    Type: Grant
    Filed: November 17, 1989
    Date of Patent: January 21, 1992
    Assignee: Basf Aktiengesellschaft
    Inventor: Gerhard Epple
  • Patent number: 4997960
    Abstract: 1-Amino-2-chloro-4-hydroxyanthraquinone (I) ##STR1## in prepared by chlorinating 1-amino-4-hydroxyanthraquinone (II) ##STR2## by a process in which the chlorination is carried out in 90-100% strength by weight sulfuric acid or in not more than 2% strength by weight oleum.
    Type: Grant
    Filed: September 7, 1989
    Date of Patent: March 5, 1991
    Assignee: BASF Aktiengesellschaft
    Inventor: Gerhard Epple