Processes Of Forming Anthraquinone Per Se Or Enolic Form Thereof By Reacting An Organic Acid, Aldehyde, Anhydride Or An Indane (e.g., Reacting Phthalic Anhydride, Methyl Phenylindane, Etc.) Patents (Class 552/268)
  • Patent number: 11655405
    Abstract: A method of manufacturing a cerium dioxide powder is provided. The method includes mixing a cerium salt, an amine and solvent to form a mixed solution, in which the amine includes a secondary amine, a tertiary amine or a combination thereof, and the tertiary amine is selected from the group consisting of hexamethylenetetramine, triethylenediamine and a combination thereof. A solvothermal reaction of the mixed solution is performed to form the cerium dioxide powder. The cerium dioxide powder manufactured by the method is also provided herein.
    Type: Grant
    Filed: September 11, 2015
    Date of Patent: May 23, 2023
    Assignee: Taiwan Semiconductor Manufacturing Company Limited
    Inventors: Chung-Hsin Lu, Yong-Jian Liu, Shu-Hao Huang, Chi-Ming Yang
  • Patent number: 11486049
    Abstract: A method of detecting space debris includes: generating a virtual space debris in accordance with the law of conservation of mass by applying a debris breakup model to an object of breakup origin; calculating an orbit of each virtual space debris based on a debris orbit propagation model; and generating appearance frequency distribution of a motion vector of each virtual space debris on the celestial sphere based on the orbit calculation. The above operations are executed multiple times. The method further includes setting a search range vector based on a motion vector having a high level of the appearance frequency distribution of the motion vector, and applying a stacking method to regions in images captured at time intervals during the fixed point observation, the regions being shifted along the search range vector sequentially in the order of capture, thereby detecting space debris appearing on the images.
    Type: Grant
    Filed: November 20, 2019
    Date of Patent: November 1, 2022
    Assignee: BASF SE
    Inventors: Cornelia Roeger-Goepfert, Roman Benedikt Raether, Harald Hoerhammer, Marco Arnold, Charlotte Emnet, Dieter Mayer
  • Patent number: 7901594
    Abstract: The present invention relates to polyacene derivatives represented by general formula (I) below: (wherein R1 to R10, etc. each represents hydrogen atom, hydrocarbon group, or an alkoxy group; A1 and A2 are hydrogen atom, a halogen atom, a hydrocarbon group, an alkoxy group, cyano group, etc.; n is an integer of not less than 1; R6 and R7 may be linked to each other to form a ring); and a process for preparing the polyacene derivatives from polyhydro compounds as well as electrically conductive materials comprising the polyacene derivatives. According to the process for preparing the polyacene derivatives of the present invention, optional substituents can be introduced into any carbon atoms of the polyacene, and the number of aromatic rings can be increased.
    Type: Grant
    Filed: February 28, 2001
    Date of Patent: March 8, 2011
    Assignee: Japan Science and Technology Corporation
    Inventor: Tamotsu Takahasi
  • Patent number: 7504495
    Abstract: The present invention provides novel quencher composition comprising anthraquinone quencher moieties. The anthraquinone quencher moieties are useful as quencher labels when attached to biomolecules such as natural or modified polynucleotides, oligonucleotides, nucleosides, nucleotides, carbohydrates and peptides. For example, polynucleotides can be labeled at the 3? terminus with fluorescence quencher solid support compositions, and polynucleotides can be labeled at internally or at the 5? terminus. The detectable probes may have a format like molecular beacons, scorpion probes, sunrise probes, conformationally assisted probes and TaqMan probes.
    Type: Grant
    Filed: November 19, 2004
    Date of Patent: March 17, 2009
    Assignee: Exiqon A/S
    Inventors: Christian Lomholt, Henrik M. Pfundheller, Michael Meldgaard
  • Patent number: 6727372
    Abstract: Disclosed are novel colorant compounds which contain one or more ethylenically-unsaturated (vinyl), photopolymerizable radicals which may be copolymewrized (or cured) with ethylenically-unsaturated monomers to produce colored compositions such as colored acrylic coatings and polymers, e.g., coatings and polymers produced from acrylate and methacrylate esters, colored polystyrenes, and similar colored polymeric materials derived from other ethylenically-unsaturated monomers. The present invention also pertains to processes for the preparation of certain of the photopolymerizable colorant compounds.
    Type: Grant
    Filed: August 2, 2001
    Date of Patent: April 27, 2004
    Assignee: Eastman Chemical Company
    Inventors: Michael John Cyr, Max Allen Weaver, Gerry Foust Rhodes, Jason Clay Pearson, Phillip Michael Cook
  • Patent number: 6399795
    Abstract: A method for producing 2-(4-methyl-3-pentenyl)anthraquinone (IHEAQ) that includes a Diels-Alder addition of naphtho-1,4-quinone and myrcene and an oxidation of the resulting adduct. The oxidation step is carried out in the presence of a solvent mixture that contains a polar and a nonpolar solvent. The oxidation takes place with air or an O2-containing gas in the presence of a combination of a strong inorganic base and an organic, especially a nitrogen-containing base. The method leads to a higher space-time yield and higher product purity.
    Type: Grant
    Filed: July 24, 2001
    Date of Patent: June 4, 2002
    Assignee: Degussa AG
    Inventors: Jürgen Glenneberg, Holger Sauerstein, Hubert Angert
  • Patent number: 6180804
    Abstract: A working solution for producing hydrogen peroxide, containing an alkylanthraguinone working compound dissolved in a solvent, is regenerated by contacting the working solution with a catalyst containing from 5% to 100% boehmite at a temperature of 25° C. to 150° C. At least a portion of the tetrahydro-alkylanthraquinone epoxide present in the working solution is converted to working compound to maintain the composition of the working solution within specified limits.
    Type: Grant
    Filed: September 10, 1998
    Date of Patent: January 30, 2001
    Assignee: FMC Corporation
    Inventor: Edward F. Dougherty
  • Patent number: 6057461
    Abstract: The invention relates to a process for the preparation of substituted anthraquinones represented by the general formula (I): ##STR1## by Diels-Alder reaction between a 1,4-naphthoquinone of general formula (II): ##STR2## and an acyclic diene of formula (III):CH.sub.2 .dbd.CR--CH.dbd.CH--OR.sub.3 (III)followed by an oxidizing deprotection reaction by means of the Jones reagent, in order to obtain the substituted anthraquinone of general formula (I).Application to the preparation of rheins of use in pharmaceuticals.
    Type: Grant
    Filed: October 2, 1998
    Date of Patent: May 2, 2000
    Assignee: Girex
    Inventors: Cyril Estanove, Fran.cedilla.ois Pruvost
  • Patent number: 5733880
    Abstract: A compound having the structural formula, ##STR1## where R.sup.1 and R.sup.2 are independently hydrogen or hydroxyl. R.sup.2 and R.sup.3 are independently oxo or hydrogen, one of R.sup.5 and R.sup.6 is A--B and the other is hydrogen, hydroxyl, or a group A, wherein each A is a spacer group providing --NH-- or --CO-- in the bond with B (if present); at least one A group does not provide the residue of an .alpha.-amino acid adjacent the anthraquinone nucleus and the A of any A--B moiety is joined to the anthraquinone nucleus via an --NH-- bond, and each B is a peptide group or a physiologically acceptable derivative thereof. The compounds are useful as antitumor compounds.
    Type: Grant
    Filed: March 28, 1996
    Date of Patent: March 31, 1998
    Assignee: Napier University Ventures Limited
    Inventor: David John Mincher
  • Patent number: 5424421
    Abstract: The invention relates to the synthesis of 6-deoxykermesates, 6-deoxykermesic acid, and carminic acid, based on a reaction of a 2-halogenonapthazarin with a bis-trimethylsilyl-diene.
    Type: Grant
    Filed: March 17, 1993
    Date of Patent: June 13, 1995
    Assignee: European Colour PLC
    Inventors: John H. P. Tyman, Alberto Fiecchi, deceased
  • Patent number: 5107004
    Abstract: The novel compound 2-neopentylanthraquinone which is prepared by Friedel-Crafts acylation of neopentylbenzene with phthalic anhydride and subsequent cyclization of the resulting 2-(4-neopentylbenzoyl)-benzoic acid in the presence of a strong, anhydrous acid, is a catalyst for the preparation of hydrogen peroxide.
    Type: Grant
    Filed: May 23, 1989
    Date of Patent: April 21, 1992
    Assignee: BASF Aktiengesellschaft
    Inventors: Manfred Eggersdorfer, Jochen Henkelmann, Walter Grosch
  • Patent number: 5041571
    Abstract: A process for the preparation of anthraquinone compounds comprises reaction of phthalic anhydride with a benzene derivative in a reaction mixture containing HF and BF.sub.3 as catalyst at a first temperature up to about 30.degree. C. and, subsequently, at an elevated temperature.
    Type: Grant
    Filed: March 29, 1990
    Date of Patent: August 20, 1991
    Assignee: Hoechst Celanese Corporation
    Inventors: Mohammad Aslam, Hans-Joachim Metz