Abstract: A process for making methyl esters in high yields is provided. The process comprises contacting aliphatic or aromatic aldehydes and methanol with an iron catalyst, to catalyze the dehydrogenative coupling between aliphatic or aromatic aldehydes and methanol. The reaction is highly selective (<99.9%) toward the formation of methyl esters over homoesters and alcohols and operates at temperatures of less than 100° C. for 2-8 hours.
Type:
Grant
Filed:
November 13, 2018
Date of Patent:
March 17, 2020
Assignee:
Eastman Chemical Company
Inventors:
Sumit Chakraborty, Steven J. Adams, Robert Thomas Hembre, Leslie Sharon Depew
Abstract: The present invention relates to the synthesis of novel biologically active selenoquinone-derived organometallic complexes, and to the uses thereof in the context of preventing or treating cancer.
Type:
Grant
Filed:
July 22, 2010
Date of Patent:
February 5, 2013
Assignee:
Centre National de la Recherche Scientifique—CNRS
Abstract: An object of the present invention is to provide a near infrared absorbent dye capable of providing a near infrared shielding filter with excellent transparency as well as high heat resistance and hygrothermal resistance. The near infrared absorbent dye is characterized in that it is made of the amorphous form of diimmonium salt represented by formula (1).
Abstract: The present invention relates to the synthesis of novel biologically active selenoquinone-derived organometallic complexes, and to the uses thereof in the context of preventing or treating cancer.
Type:
Application
Filed:
July 22, 2010
Publication date:
July 19, 2012
Applicant:
CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE-CNRS-
Abstract: A molten salt and process for preparing a molten salt or hydrogen peroxide uses ionic hydroquinones or hydroquinone derivatives as O2 reduction catalysts.
Abstract: The present invention relates to ligands of the general formula (I). In addition, a process for the production thereof and the use thereof are demonstrated.
Type:
Grant
Filed:
December 12, 2006
Date of Patent:
April 22, 2008
Assignee:
Degussa AG
Inventors:
Armin Boerner, Jens Holz, Axel Monsees, Thomas Riermeier, Renat Kadyrov, Carsten A. Schneider, Uwe Dingerdissen, Karlheinz Drauz
Abstract: This invention provides a new class of squaraine dyes having moieties which serve for the covalent attachment to biological substrates and resulting in the fluorescent labeling of the substrates. The labeled substrates are intended for use in analytical techniques for the detection and measurement of biological and clinical compounds of interest.
Abstract: The invention is drawn to organic compounds of the general formulae L--A--Z or L--A'--L' as defined in the specification. The compounds are readily crystallizable and can be used for their ferromagnetic properties.
Type:
Grant
Filed:
September 16, 1997
Date of Patent:
December 8, 1998
Assignee:
Alcatel Alsthom Compagnie Generale D'Electricite
Abstract: The invention is drawn to organic compounds of the general formulae L--A--Z or L--A'--L' as defined in the specification. The compounds are readily crystallizable and can be used for their ferromagnetic properties.
Type:
Grant
Filed:
April 12, 1996
Date of Patent:
February 3, 1998
Assignee:
Alcatel Alsthom Compagnie Generale D'Electricite
Abstract: Agents for the diagnosis or treatment of hypoxic cells comprise a bioreductive moiety such as 2-nitroimidazole, and a metal chelating moiety which is a bis-amine oxime of which a carbon atom adjacent a nitrogen atom is linked to the bioreductive moiety. A chelated metal atom or ion preferably Technetium-99m. The agent diffuses into cells where the 2-nitroimidazole is reduced thus trapping the chelated metal in the cell.
Abstract: A novel initiator for photopolymerization is provided, which can polymerize cationically polymerizable organic material by only irradiating at wavelength of 200-500 nm without specific sensitizer and/or post-curing even when it is used at comparatively small amount, whereby the obtained cured product has good physical properties and electric properties.The initiator for photopolymerization of cationically polymerizable organic material according to the present invention comprises a composite obtainable from a reaction between (a) charge transfer complex consisting of biscyclopentadienyl iron derivative and quinoid and (b) at least one salt selected from a group consisting of tetrafluoroborates, hexafluorophosphates and hexafluoroantimonates.
Abstract: Processes for the preparation of tetracyano-1,4-hydroquinone and its conversion to tetracyano-1,4-benzoquinone via a disilver salt are disclosed.
Abstract: Polyphosphazene derivatives containing carbonyl groups and variously alkylated tertiary aminic groups, suited to undergo rapid and efficient photo-crosslinking processes and having general formula: ##STR1## wherein: X represents substituents linked to the polyphosphazene chain by means of hydroxylic or aminic functions and containing carbonyl groups;X' represents additional substituents linked to the polyphosphazene chain by means of hydroxylic or aminic functions and containing one or more variously alkylated tertiary aminic groups;(w+y+z) is an integer ranging from 20 to 15,000;w and z are integers having a value higher than or equal to zero and at any rate lower than 15,000;y is an integer having a value of from 20 to 15,000.
Type:
Grant
Filed:
July 17, 1990
Date of Patent:
November 9, 1993
Assignee:
Consiglio Nazionale Delle Ricerche
Inventors:
Mario Gleria, Francesco Minto, Lucia Flamigni