Nitrogen Double Bonded Directly At The 1- And 4- Positions Patents (Class 552/301)
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Patent number: 9226883Abstract: The present invention relates to direct dyes of azomethine type of formula (I) below; and also to the use thereof for dyeing keratin fibers, in particular human keratin fibers such as the hair. The invention also relates to a composition for dyeing keratin fibers, comprising such direct dyes in a suitable dyeing medium. Similarly, a subject of the invention is a process for dyeing keratin fibers using the said dye composition, and also a device comprising the same. Finally, the present invention also relates to precursors of these direct dyes.Type: GrantFiled: December 11, 2012Date of Patent: January 5, 2016Assignee: L'OREALInventors: Stephane Sabelle, Madeleine Leduc
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Publication number: 20120248389Abstract: The synthesis of stable, water-soluble tris and tetrakis aminium dyes. More particularly, carboxylic-acid modified tris and tetrakis dye intermediates, as well as salts and near-infrared dyes formed therefrom, as well as compositions including the dyes.Type: ApplicationFiled: June 15, 2012Publication date: October 4, 2012Applicant: EPOLIN, INC.Inventor: MURRAY S. COHEN
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Publication number: 20120251831Abstract: An object of the present invention is to provide a near infrared absorbent dye capable of providing a near infrared shielding filter with excellent transparency as well as high heat resistance and hygrothermal resistance. The near infrared absorbent dye is characterized in that it is made of the amorphous form of diimmonium salt represented by formula (1).Type: ApplicationFiled: December 16, 2010Publication date: October 4, 2012Applicant: JAPAN CARLIT CO., LTDInventors: Akinori Okayasu, Masaaki Tamura
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Patent number: 8080626Abstract: This invention provides chain extender compositions. These compositions comprise (i) an aromatic primary diamine, and (ii) a component selected from the group consisting of: (a) an aliphatic secondary diamine; (b) an aliphatic primary diamine; (c) an aliphatic secondary diamine and an aliphatic primary diamine; (d) a diimine; and (e) a combination of any two or more of (a) through (d). When (ii) is (a), (a) has amino hydrocarbyl groups which are secondary or tertiary hydrocarbyl groups; when (ii) is (d), and (d) is an aromatic diimine, each imino hydrocarbylidene group has at least two carbon atoms. Processes for producing polyurethanes, polyureas, and polyurea-urethanes are also provided.Type: GrantFiled: February 16, 2011Date of Patent: December 20, 2011Assignee: Albemarle CorporationInventors: Paul L. Wiggins, John Y. Lee, Judit Orgad
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Patent number: 7964695Abstract: This invention provides chain extender compositions. These compositions comprise (i) an aromatic primary diamine, and (ii) a component selected from the group consisting of: (a) an aliphatic secondary diamine; (b) an aliphatic primary diamine; (c) an aliphatic secondary diamine and an aliphatic primary diamine; (d) a diimine; and (e) a combination of any two or more of (a) through (d). When (ii) is (a), (a) has amino hydrocarbyl groups which are secondary or tertiary hydrocarbyl groups; when (ii) is (d), and (d) is an aromatic diimine, each imino hydrocarbylidene group has at least two carbon atoms. Processes for producing polyurethanes, polyureas, and polyurea-urethanes are also provided.Type: GrantFiled: September 25, 2006Date of Patent: June 21, 2011Assignee: Albemarle CorporationInventors: John Y. Lee, Paul L. Wiggins, Judit Orgad, Mahmood Sabahi, Vernon O. Brandt
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Patent number: 7759504Abstract: A triarylamine derivative is represented by the following Formula (I). In Formula (I): R111, R112, R121 and R122 each independently represent a hydrogen atom, an aliphatic group or an aromatic group, R113, R114, R115, R116, R123, R124, R125 and R126 each independently represent a hydrogen atom or a substituent, provided that at least one pair among R111 and R121, R112 and R122, R113 and R123, R114 and R124, R115 and R125 and R116 and R126 includes two different groups; at least one ring may be formed by mutual bonding in at least one pair among R111 and R112, R111 and R114, R113 and R114, R113 and R123, R123 and R124, R121 and R124, R121 and R122, and two R116s which are respectively bound to different phenyl groups; Xm? represents an m-valent anion; m and n represent 1 or 2; and a product of in and n is 2.Type: GrantFiled: April 10, 2008Date of Patent: July 20, 2010Assignee: Fujifilm CorporationInventors: Tomohito Masaki, Keizo Kimura, Osamu Uchida
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Patent number: 6828450Abstract: This invention provides analogs of triptycene which are useful as anticancer drugs, as well as for other uses. The potency of these compounds is in a similar magnitude as daunomycin, a currently used anticancer drug. Each compound of the invention produces one or more desired effects (blocking nucleoside transport, inhibiting nucleic acid or protein syntheses, decreasing the proliferation and viability of cancer cells, inducing DNA fragmentation or retaining their effectiveness against multidrug-resistant tumor cells).Type: GrantFiled: October 9, 2001Date of Patent: December 7, 2004Assignee: Kansas State University Research FoundationInventors: Duy Hua, Jean-Pierre Perchellet
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Publication number: 20020128499Abstract: The invention comprises a process for preparing a compound having the formula comprising: 1Type: ApplicationFiled: December 5, 2001Publication date: September 12, 2002Inventors: Otto William Maender, Charles John Rostek, Alan Roy Katritzky, Herman Howard Odens, Michael Victor Voronkov
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Patent number: 6384249Abstract: Inhibitor compounds containing a moiety according to this invention are used to inhibit air oxidation and thermal polymerization of furfural or furfural derivatives. A process is provided for use of the inhibitors in the solvent refining of lubricating oils where furfural is used to extract impurities including polycyclic aromatic and oxygen-containing compounds from the lubricating oils. The process provides for combination of the inhibitor with a continuously recirculating furfural stream in the extraction process.Type: GrantFiled: October 17, 2000Date of Patent: May 7, 2002Assignee: Hercules, Inc.Inventors: James G. Edmondson, Grace B. Arhancet
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Patent number: 6187937Abstract: A hydroxydiphenylamine compound can be converted to an N-phenylquinoneimine by reacting the hydroxydiphenylamine with oxygen or an oxygen containing gas in the presence of a modified activated carbon catalyst, the catalyst having had surface oxides removed therefrom.Type: GrantFiled: December 23, 1998Date of Patent: February 13, 2001Assignee: Flexsys America L.P.Inventors: Donald L. Fields, Jr., Michael K. Stern, Jayant Shivji Lodaya
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Patent number: 6147239Abstract: The invention relates to a process for preparing N,N'-disubstituted p-quinonediimines of general formula I ##STR1## wherein a corresponding N,N'-disubstituted p-phenylenediamine is oxidized in alkaline/alcoholic solution, and also their use. The invention further provides organosilanes containing methacryloxy or acryloxy groups and having general formula II ##STR2## where R.sup.3 is a hydrogen atom or a methyl group and R.sup.4 and R.sup.5 are identical or different alkyl groups having from 1 to 4 carbon atoms and m is equal to 0 or 1 or 2, which organosilanes contain N,N'-disubstituted p-quinonediimines. Processes for preparing and stabilizing organosilanes of general formula II are described.Type: GrantFiled: September 15, 1998Date of Patent: November 14, 2000Assignee: Huels AktiengesellschaftInventors: Guenther Bernhardt, Klaus-Dieter Steffen, Margret Haas, Heinz Kragl
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Patent number: 6114554Abstract: A phenylenediamine compound can be converted, with high selectivity, into its corresponding quinonediimine by reacting the phenylenediamine with a hypochlorite oxidation reactant.Type: GrantFiled: June 3, 1998Date of Patent: September 5, 2000Assignee: Flexsys America L.P.Inventors: Jayant Shivji Lodaya, Raymond Anton Lohr, Jr., Donald Lee Fields, Jr.
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Patent number: 6071908Abstract: A method of treating neoplastic disease wherein a patient in need of such treatment is administered an effective amount of a radiation-activated cytotoxin prodrug (RACP) which has low toxicity, which is reducible by reducing agents generated by the radiolysis of water and which, upon reduction, releases a sufficient amount of a cytotoxic effector of sufficient cytotoxic potency to kill tumor cells. The tumor cells are irradiated with ionizing radiation to reduce the prodrug which is present at the locus of the tumor cells to release the cytotoxic effector.Type: GrantFiled: May 7, 1998Date of Patent: June 6, 2000Assignee: Auckland Uniservices LimitedInventors: William A. Denny, Moena Tercel, William R. Wilson
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Patent number: 6025508Abstract: A phenylenediamine compound can be converted, with high selectivity, into its corresponding quinonediimine by reacting the phenylenediamine with oxygen and a metal catalyst or a salt thereof.Type: GrantFiled: May 28, 1999Date of Patent: February 15, 2000Assignee: Flexsys America L.P.Inventors: Jayant S. Lodaya, Raymond A. Lohr, Jr., Donald L. Fields, Jr.
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Patent number: 5959126Abstract: A phenylenediamine compound can be converted, with high selectivity, into its corresponding quinonediimine by reacting the phenylenediamine with oxygen in the presence of a modified activated carbon catalyst in an aqueous system.Type: GrantFiled: February 12, 1998Date of Patent: September 28, 1999Assignee: Flexsys America L. P.Inventors: Raymond Anton Lohr, Jr., Otto William Maender, Donald Lee Fields, Jr.
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Patent number: 5919846Abstract: A novel colorant compound is provided which is the addition product of an organic chromophore having at least one reactive hydroxyl or amine substituent, a polyisocyanate, and a carboxylic acid, sulfonic acid, or salt of either thereof. The polyisocyanate, added in a molar excess relative to the number of such reactive substituents, reacts with the reactive hydroxyl or amine groups to provide terminal isocyanate groups. Subsequently, the carboxylic acid or salt thereof, also added in an amount excessive in relation to the number of terminal isocyanate groups, reacts therewith to from urethane moieties on the colorant. Such a compound provides excellent ink compositions upon dilution and are very soluble within all the standard ink diluents. Furthermore, such colorants provide good jettability, waterfastness, washfastness, and the like, within ink-jet applications on various types of printing substrates.Type: GrantFiled: February 19, 1998Date of Patent: July 6, 1999Assignee: Milliken Research CorporationInventors: Raj Batlaw, John W. Miley
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Patent number: 5847171Abstract: The invention is drawn to organic compounds of the general formulae L--A--Z or L--A'--L' as defined in the specification. The compounds are readily crystallizable and can be used for their ferromagnetic properties.Type: GrantFiled: September 16, 1997Date of Patent: December 8, 1998Assignee: Alcatel Alsthom Compagnie Generale D'ElectriciteInventors: Stanislas Galaj, Alain Le Mehaute
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Patent number: 5840935Abstract: Polymeric compositions having inherent electroconductive properties and unsaturated electron-donor and electron-receptor polymerizable monomers for producing such compositions in the form of blends of homopolymers of such monomers or as copolymers of such monomers.Type: GrantFiled: April 10, 1997Date of Patent: November 24, 1998Assignee: Northrop Grumman CorporationInventor: Nicholas T. Castellucci
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Patent number: 5714622Abstract: The invention is drawn to organic compounds of the general formulae L--A--Z or L--A'--L' as defined in the specification. The compounds are readily crystallizable and can be used for their ferromagnetic properties.Type: GrantFiled: April 12, 1996Date of Patent: February 3, 1998Assignee: Alcatel Alsthom Compagnie Generale D'ElectriciteInventors: Stanislas Galaj, Alain Le Mehaute
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Patent number: 5053540Abstract: The present invention relates to a process for the preparation of a p-aminodiphenylamine comprising reacting N-phenylquinoneimine of the formula: ##STR1## with ammonia, ammonium hydroxide or mixtures thereof, wherein the molar ratio of N-phenylquinoneimine to NH.sub.3 in the reaction mixture ranges from about 1:1 to 1:80.Type: GrantFiled: March 8, 1990Date of Patent: October 1, 1991Assignee: The Goodyear Tire & Rubber CompanyInventor: Kirkwood S. Cottman
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Patent number: 4999441Abstract: Tetrakis(dialkylamino)aromatics Ia to Ic ##STR1## where the radicals A may be identical or different and are n-C.sub.1 -C.sub.6 -alkyl and the radicals R may be identical or different and are hydrogen or C.sub.1 -C.sub.6 -alkyl, and their charge transfer complexes with electron acceptors, and the preparation of Ia to Ic from the corresponding N-unsubstituted amines by alkylation with A'--CHO (where A'.dbd.H or N-C.sub.1 -C.sub.5 -alkyl) and reduction with NaBH.sub.3 CN.The charge transfer complexes of Ia and Ic are used to prepare electrically conductive polymers.Type: GrantFiled: April 17, 1989Date of Patent: March 12, 1991Assignee: Max-Planck-Gesellschaft zur Foerderung der Wissenschaften e.V.Inventors: Heinz A. Staab, Karin Elbl