Metal Containing Contaminant Removal (e.g., Of Colloidal Elemental Metal Catalyst, Of Metal Ions, Etc.) Patents (Class 554/176)
  • Patent number: 11414622
    Abstract: The present disclosure is: a free polyunsaturated fatty acid-containing composition, which comprises at least one free polyunsaturated fatty acid having 20 or more carbon atoms, the content being at least 80.0% of the fatty acids in the composition, and satisfies at least one selected from a group consisting of conditions (1) and (2): (1) the content of conjugated unsaturated fatty acid is 1.0% or less of the fatty acids in the composition, and (2) the Gardner color is less than 3+; and a manufacturing method for the free polyunsaturated fatty acid-containing composition comprising the preparation of a raw material composition containing at least one polyunsaturated fatty acid having 20 or more carbon atoms, and hydrolysis of a reaction solution containing the prepared raw material composition, a lower alcohol, water and an alkali catalyst at a temperature of 10° C. or lower.
    Type: Grant
    Filed: December 17, 2020
    Date of Patent: August 16, 2022
    Assignee: NIPPON SUISAN KAISHA, LTD.
    Inventors: Yuhei Kosuge, Hideaki Yamaguchi, Nobushige Doisaki
  • Patent number: 11247964
    Abstract: The present invention provides methods of processing lipid materials such as soapstock, wet gums and dry gums. Enzymes are utilized to catalyze hydrolysis of the lipids materials to recover fatty acids. Addition of organic acids and/or polyols improved yield of fatty acids and reduced formation of emulsion. Lipid materials can be formulated with other agricultural products as new value-added animal feed products. Further, a process for concentrating nitrogenous compounds such as choline, inositol, ethanolamine and serine from phospholipid materials obtained as byproducts from vegetable oil refining is provided. The process involves performing hydrolysis of the gum based products in the presence of an alcoholic solvent and acid catalyst. Post hydrolysis, gums breakdown to oil and water phases which are further separated and concentrated. These concentrated products may be further fractionated to concentrate individual nitrogenous compounds.
    Type: Grant
    Filed: April 18, 2016
    Date of Patent: February 15, 2022
    Assignee: RRIP, LLC
    Inventors: Mohan Prasad A. Dasari, Abdullah A. Mahfuz, Shashank Ravi, Hugh Tallant Warren
  • Patent number: 11028336
    Abstract: The invention relates to a process for purification of oil by heat treatment in order to degrade phospholipids present in the non-purified oil.
    Type: Grant
    Filed: September 28, 2017
    Date of Patent: June 8, 2021
    Assignee: NESTE OYJ
    Inventors: Annika Malm, Mervi Waddilove
  • Patent number: 10626347
    Abstract: The present disclosure is: a free polyunsaturated fatty acid-containing composition, which comprises at least one free polyunsaturated fatty acid having 20 or more carbon atoms, the content being at least 80.0% of the fatty acids in the composition, and satisfies at least one selected from a group consisting of conditions (1) and (2): (1) the content of conjugated unsaturated fatty acid is 1.0% or less of the fatty acids in the composition, and (2) the Gardner color is less than 3+; and a manufacturing method for the free polyunsaturated fatty acid-containing composition comprising the preparation of a raw material composition containing at least one polyunsaturated fatty acid having 20 or more carbon atoms, and hydrolysis of a reaction solution containing the prepared raw material composition, a lower alcohol, water and an alkali catalyst at a temperature of 10° C. or lower.
    Type: Grant
    Filed: February 27, 2018
    Date of Patent: April 21, 2020
    Assignee: NIPPON SUISAN KAISHA, LTD.
    Inventors: Yuhei Kosuge, Hideaki Yamaguchi, Nobushige Doisaki
  • Patent number: 10597607
    Abstract: Provided is a method for producing a polyunsaturated fatty acid while preventing deterioration of a silver salt solution. A method for producing a composition comprising a polyunsaturated fatty acid, comprising: supplying an aqueous solution comprising a silver salt into a reaction vessel to contact the aqueous solution with a raw material solution comprising an alkyl ester of the polyunsaturated fatty acid; and collecting the aqueous solution comprising the silver salt which has been contacted with the raw material solution from the reaction vessel, wherein the supply of the aqueous solution comprising the silver salt into the reaction vessel and the collection of the aqueous solution comprising the silver salt from the reaction vessel are carried out concurrently with each other.
    Type: Grant
    Filed: May 1, 2017
    Date of Patent: March 24, 2020
    Assignee: NISSHIN PHARMA INC.
    Inventors: Masataka Harata, Shingo Nonaka, Hideki Kanai, Hiroyuki Ikemoto, Kenji Takemoto
  • Patent number: 10233405
    Abstract: This application provides an oil refining system and method, including a water circulation system with a chilled water circulation unit including chilled water equipment and a chilled water pipeline, a hot water circulation unit including hot water equipment and a hot water pipeline, and an ambient temperature water circulation unit including an ambient temperature water pipeline. The oil refining system further includes a deacidification system, deodorization system, and a decoloration system to implement a systematization and automation of oil refining.
    Type: Grant
    Filed: September 1, 2015
    Date of Patent: March 19, 2019
    Inventor: Hanqing Chen
  • Patent number: 10221374
    Abstract: The present invention relates to a process for refining glyceride oil comprising the steps of: (i) contacting glyceride oil with a liquid comprising a basic quaternary ammonium salt to form a treated glyceride oil; wherein the quaternary ammonium salt comprises a basic anion selected from hydroxide, alkoxide, alkylcarbonate, hydrogen carbonate, carbonate, serinate, prolinate, histidinate, threoninate, valinate, asparaginate, taurinate and lysinate; and a quaternary ammonium cation; (ii) separating the treated glyceride oil from a salt comprising the quaternary ammonium cation; and (iii) subjecting the treated glyceride oil after the separation step to at least one further refining step; and to the use of contacting a glyceride oil with the basic quaternary ammonium salt for preventing or reducing the formation of fatty acid esters of chloropropanols and/or glycidol upon heating of the glyceride oil.
    Type: Grant
    Filed: May 27, 2016
    Date of Patent: March 5, 2019
    Assignee: Evonik Degussa GmbH
    Inventors: Gabriela Fedor, Martin Philip Atkins, Peter Goodrich, Christopher Klatt Hamer, Daniel Witthaut, Ulrich Boes
  • Patent number: 9803051
    Abstract: The invention relates to compositions of hydroxyl functional acrylic resins (acrylic polyols) comprising a mixture of ?,?-branched alkane carboxylic glycidyl esters derived from butene oligomers characterized in that the sum of the concentration of the blocked and of the highly branched isomers is at least 50%, preferably above 60% and most preferably above 75% on total composition.
    Type: Grant
    Filed: October 16, 2012
    Date of Patent: October 31, 2017
    Assignee: HEXION INC.
    Inventors: Denis Heymans, Christophe Steinbrecher, Cédric Le Fevere De Ten Hove
  • Patent number: 9738855
    Abstract: The disclosed apparatus, systems and methods relate to the conversion of high free fatty acid (“HFFA”) containing oils defined as oils containing 20-100% free fatty acids (“FFA”) and low free fatty acid (“LFFA”) containing oils defined as oils containing 1-20% free fatty acids (FFA) into oil with less than about 0.5-1% FFA. If the feedstock is HFFA oil, the process includes a combination of partial glycerolysis of HFFA oils to produce LFFA oils and subsequent stripping of LFFA oils to produce NFFA oils via steam distillation. If the feedstock is LFFA oil, the process includes stripping of LFFA oils to produce NFFA oils via steam distillation and subjecting FFA to partial glycerolysis to convert FFA to oil.
    Type: Grant
    Filed: February 5, 2016
    Date of Patent: August 22, 2017
    Assignee: Tehnochem
    Inventor: Sanjeev Agarwal
  • Patent number: 9481853
    Abstract: A method for degumming and/or refining crude oil containing impurities involving mixing the crude oil with degumming agents, i.e., water or acid, and subjecting the mixture to flow-through, hydrodynamic cavitation processing. The cavitational processing transfers impurities in the crude oil to a water phase for easier separation. The water phase may be separated from the oil phase by commonly available separation methods.
    Type: Grant
    Filed: November 3, 2014
    Date of Patent: November 1, 2016
    Assignee: Cavitation Technologies, Inc.
    Inventors: Roman Gordon, Igor Gorodnitsky, Varvara Grichko
  • Patent number: 9357790
    Abstract: A process for removing impurities from a crude vegetable oil. The process involves mixing the crude vegetable oil with removal reagents and pumping the mixture through a multi-stage, hydrodynamic cavitation device. The mixture is subjected to hydrodynamic cavitation processes, which result in the repeated generation and collapsing of vapor bubbles of volatile components in the process fluid, leading to the formation of an emulsion of vegetable oil and a water-phase from the process fluid into an emulsion. The water-phase contains the impurities. The vegetable oil and water-phase are then separated. Lecithin may be made from the phospholipids in the water-phase after appropriate drying processes.
    Type: Grant
    Filed: November 22, 2013
    Date of Patent: June 7, 2016
    Assignee: Cavitation Technologies, Inc.
    Inventors: Roman Gordon, Igor Gorodnitsky, Maxim A. Promtov
  • Patent number: 9085746
    Abstract: Processes for obtaining fatty acids with reduced content of by-products, wherein unrefined fats or oils are subjected to steam stripping in a counter-current column to produce a bottom fraction of de-acidified fats or oils, a first distillate consisting mainly of fatty acids and glycerides, and a second distillate comprising fatty acids and essentially all unwanted ketones, aldehydes and phenols, and the bottom fraction containing the de-acidified fats or oils is combined with the first distillate containing fatty acids and glycerides.
    Type: Grant
    Filed: May 12, 2012
    Date of Patent: July 21, 2015
    Assignee: Cognis IP Management GmbH
    Inventors: Horst Josten, Ewelina Sobierska, Adrian Chan, Truc Tran Anh
  • Patent number: 9028697
    Abstract: The moisture absorption capacity of biofuels can be more or less 10 times that of fossil diesel oil, causing biofuels to form acids that induce metal corrosion and form deposits in the fuel tank and pipe lines. Methods for removing moisture from stored biofuels and plant oils are described wherein glycerol is used as a solvent to extract the moisture from the bioliquid or oil, comprising the steps of placing the biofuel or oil in fluid contact with glycerol, incubating for a time, and then removing the glycerol. A cellulous ester dialysis or other semi-permeable membrane may be used to prevent the glycerol from contaminating the biofuel while allowing moisture to pass. Crude glycerol produced as a byproduct of biodiesel production may be used in the method of the disclosed invention with good result. Preferred embodiments of apparatus that employ the method of the subject invention are described.
    Type: Grant
    Filed: January 25, 2012
    Date of Patent: May 12, 2015
    Inventor: Masatoshi Matsumura
  • Publication number: 20150094482
    Abstract: Methods for removing contaminants from algal oil are provided. In an embodiment, a method comprises the steps of combining a sulfuric acid-aqueous solution that has a pH of about 1 or less with a contaminant-containing algal oil at treatment conditions effective to form an effluent. The effluent comprises a treated algal oil phase and contaminants in an acidic aqueous phase. The contaminants comprise metals, phosphorus, or combinations thereof. The acidic aqueous phase is removed from the effluent to form a contaminant-depleted algal oil.
    Type: Application
    Filed: December 5, 2014
    Publication date: April 2, 2015
    Applicant: UOP LLC
    Inventor: Francis Stephen Lupton
  • Publication number: 20150057460
    Abstract: A method for degumming and/or refining crude oil containing impurities involving mixing the crude oil with degumming agents, i.e., water or acid, and subjecting the mixture to flow-through, hydrodynamic cavitation processing. The cavitational processing transfers impurities in the crude oil to a water phase for easier separation. The water phase may be separated from the oil phase by commonly available separation methods.
    Type: Application
    Filed: November 3, 2014
    Publication date: February 26, 2015
    Inventors: Roman Gordon, Igor Gorodnitsky, Varvara Grichko
  • Patent number: 8912351
    Abstract: A process for removing a metal from a tallow feed includes contacting the tallow feed comprising the metal with a tallow oil-immiscible ionic liquid to produce a tallow oil and TALLOW-immiscible ionic liquid mixture, and separating the mixture to produce a tallow oil effluent having a reduced metal content relative to the tallow feed. The metals removed include iron, aluminum, calcium, magnesium, sodium, zinc, and potassium.
    Type: Grant
    Filed: March 6, 2012
    Date of Patent: December 16, 2014
    Assignee: UOP LLC
    Inventors: Beckay J. Mezza, Alakananda Bhattacharyya, F. Stephen Lupton
  • Publication number: 20140148609
    Abstract: Crude algae oils are thermally-treated at temperature(s) in the range of 300-600° C., without catalyst and/or the addition of hydrogen, to produce a higher grade, cleaner algae oil with, for example, reduced oxygen, boiling range, viscosity and/or density, and acid number, in addition, because the thermal treatment reduces metals in the oil and produces carbonaceous solids, it is expected that catalyst deactivation by algae oil feedstocks will be greatly reduced if the crude algae oil or fractions thereof are thermally-treated prior to catalytic upgrading. Oxygen, fatty acids, metals, and metalloids are reduced/removed by the thermal treatment, so that RBI) processing of the crude bio-oil may be reduced or eliminated, and requirements for further deoxygenation and hydrotreating of the thermal products are reduced or eliminated.
    Type: Application
    Filed: July 2, 2012
    Publication date: May 29, 2014
    Inventors: Stilianos G. Roussis, Richard J. Cranford, Daniel J. Sajkowski
  • Patent number: 8629291
    Abstract: Process and steps for the production of biodiesel and/or glycerin from feedstock are provided.
    Type: Grant
    Filed: November 27, 2012
    Date of Patent: January 14, 2014
    Assignee: Menlo Energy Management, LLC
    Inventors: Gaurav Shah, Sunil Suri
  • Publication number: 20130197251
    Abstract: The invention describes process for demetallation of vegetable oils and animal fats to reduce metal content below 1 ppm to make them suitable for hydroprocessing feedstocks. The process comprises acid treatment with very low concentration of acids, utilizing synergistic effect of phosphoric acid and citric acid, followed by counter-current treatment with clay without intermediate step of water washing and treatment with ion exchange resin.
    Type: Application
    Filed: July 4, 2011
    Publication date: August 1, 2013
    Applicant: INDIAN OIL CORPORATION LTD.
    Inventors: Sarvesh Kumar, Ravi B. Kumar, Alok Sharma, Brijesh Kumar, Surbhi Semwal, Ajay Kumar Arora, Suresh Kumar Puri, Saeed Ahmed, Vivekanand Kagdiyal, Santanam Rajagopal, Ravinder Kumar Malhotra, Anand Kumar
  • Publication number: 20130158279
    Abstract: A process for removing a metal from a tallow feed includes contacting the tallow feed comprising the metal with a tallow oil-immiscible ionic liquid to produce a tallow oil and TALLOW-immiscible ionic liquid mixture, and separating the mixture to produce a tallow oil effluent having a reduced metal content relative to the tallow feed. The metals removed include iron, aluminum, calcium, magnesium, sodium, zinc, and potassium.
    Type: Application
    Filed: March 6, 2012
    Publication date: June 20, 2013
    Applicant: UOP LLC
    Inventors: Beckay J. Mezza, Alakananda Bhattacharyya, F. Stephen Lupton
  • Publication number: 20130158278
    Abstract: Methods for removing contaminants from algal oil are provided. In an embodiment, a method comprises the steps of combining a sulfuric acid-aqueous solution that has a pH of about 1 or less with a contaminant-containing algal oil at treatment conditions effective to form an effluent. The effluent comprises a treated algal oil phase and contaminants in an acidic aqueous phase. The contaminants comprise metals, phosphorus, or combinations thereof The acidic aqueous phase is removed from the effluent to form a contaminant-depleted algal oil.
    Type: Application
    Filed: December 14, 2011
    Publication date: June 20, 2013
    Applicant: UOP LLC
    Inventor: Francis Stephen Lupton
  • Patent number: 8426622
    Abstract: The invention relates to a process for production of fatty acids directly from soapstock generated in the alkali refining process including the steps of (a) adding a lipase directly to the alkaline soapstock to facilitate hydrolysis of glycerides without prior neutralization, (b) neutralizing and splitting the soaps with strong acids, and (c) separating the fatty acid phase from the aqueous phase by settling and/or centrifugation. A second embodiment is a process in which the soapstock is first neutralized and split with strong acids, followed by adding a lipase to facilitate glyceride hydrolysis, and separating the fatty acid phase. The fatty acids so obtained can be esterified with C1-C6 alcohols using a lipase that is selective for fatty acids and does not transesterify the sterolesters, and the fatty acid esters and sterolesters are separated by distillation. The sterolesters are useful as supplements for food, as pharmaceutical agents for lowering cholesterol and as biofuel and biodiesel.
    Type: Grant
    Filed: June 27, 2007
    Date of Patent: April 23, 2013
    Assignee: Cognis IP Management GmbH
    Inventors: Peter Kempers, Ulrich Schörken, Thomas Wolf, Setsuo Sato, Wanderson Bueno de Almeida, Pablo Silva Bizzarri, Alexssander Shigueru Araujo
  • Patent number: 8314045
    Abstract: A porous solid acid catalyst having high concentration of acidic sites and a large surface area includes a porous silica support and a sulfonated carbon layer disposed within the pores of the silica support. The catalyst, in certain embodiments, has a concentration of —SO3H groups of at least about 0.5 mmol/g and a predominant pore size of at least about 300 ?. The catalyst is used to catalyze a variety of acid-catalyzed reactions, including but not limited to alkylation, acylation, etherification, olefin hydration and alcohol dehydration, dimerization of olefin and bicyclic compounds, esterification and transesterification. For example, the catalyst can be used to catalyze esterification of free fatty acids (FFAs) and, in certain embodiments, to catalyze transesterification of triglycerides in fats and oils.
    Type: Grant
    Filed: October 27, 2010
    Date of Patent: November 20, 2012
    Assignee: Entreprises Sinoncelli S.A.R.L.
    Inventors: Jacques Sinoncelli, Sergey V. Gurevich
  • Publication number: 20120219672
    Abstract: It is provided a process for producing a purified essential oil excellent in safety and quality with high productivity from an essential oil comprising a harmful contaminant such as an agricultural chemical by simply and smoothly removing the contaminant with high removal rate without causing poor balance of flavor which the essential oil originally has, decrease of flavor strength and the like. It relates to a process for producing a purified essential oil by treating an essential oil comprising a contaminant with an active carbon to remove the contaminant and the removal rate of the contaminant is further improved by using an active carbon activated with a chemical, particularly an active carbon activated with zinc chloride, in the treatment, or by conducting the treatment at a low temperature of room temperature or lower, particularly at ?25° C. to 5° C.
    Type: Application
    Filed: May 8, 2012
    Publication date: August 30, 2012
    Applicant: TAKASAGO INTERNATIONAL CORPORATION
    Inventors: Ryo TAKEUCHI, Shigemasa Oshikubo
  • Patent number: 8252949
    Abstract: The present invention relates to a process for producing fatty acid alkyl esters from fats/oils and a C1 to C5 lower alcohol as reaction starting materials with a solid catalyst, wherein the starting materials and reaction products in a reaction system where the degree of conversion of fats/oils is 50 mol % or more are reacted in such a state as to be in one-liquid phase, or the starting materials and reaction products in a reaction system at a stage with the highest degree of conversion of fats/oils are reacted in such a state as to be in one-liquid phase.
    Type: Grant
    Filed: June 11, 2008
    Date of Patent: August 28, 2012
    Assignee: Kao Corporation
    Inventors: Yuichiro Seki, Takanobu Katayama, Katsutoshi Yamamoto
  • Patent number: 8097049
    Abstract: A quick, economical and environmentally friendly, “green”, process for the continuous purification of biodiesel (fatty acid alkyl esters (FAAE)) is described using a powdered, granulated or extruded adsorbent. The adsorbent is contained in a column system and is regenerated for reuse multiple times. The process employs an adsorbent such as, but not limited to, carbon, silica, clay, zeolite or a metal silicate contained in a column to remove the impurities from fatty acid alkyl esters (FAAE) or crude biodiesel in a continuous process. The process utilizes the adsorbent column system for the purification of biodiesel, rather than water or filtration, to remove soaps and other impurities entrained in a crude biodiesel.
    Type: Grant
    Filed: February 5, 2009
    Date of Patent: January 17, 2012
    Assignee: The Dallas Group of America, Inc.
    Inventors: James R. Munson, Brian S. Cooke, Bryan L. Bertram
  • Publication number: 20090199460
    Abstract: A quick, economical and environmentally friendly, “green”, process for the continuous purification of biodiesel (fatty acid alkyl esters (FAAE)) is described using a powdered, granulated or extruded adsorbent. The adsorbent is contained in a column system and is regenerated for reuse multiple times. The process employs an adsorbent such as, but not limited to, carbon, silica, clay, zeolite or a metal silicate contained in a column to remove the impurities from fatty acid alkyl esters (FAAE) or crude biodiesel in a continuous process. The process utilizes the adsorbent column system for the purification of biodiesel, rather than water or filtration, to remove soaps and other impurities entrained in a crude biodiesel.
    Type: Application
    Filed: February 5, 2009
    Publication date: August 13, 2009
    Inventors: James R. Munson, Brian S. Cooke, Bryan L. Bertram
  • Publication number: 20080119664
    Abstract: A method for making alkyl esters, such as methyl ester, for use as a biodiesel fuel from various oil sources. A steady state reaction with a single phase solution created from multi phase constituents can be achieved without the use of co-solvents that cannot or should not be present in the final fuel and must therefore be removed.
    Type: Application
    Filed: October 30, 2007
    Publication date: May 22, 2008
    Inventors: Jacques Sinoncelli, David R. Wallace
  • Publication number: 20040259947
    Abstract: It is an object of the present invention to provide a glycerin fatty acid ester having an effect of mitigating the symptoms associated with the premenstrual syndromes (hereunder referred to as PMS) and excellent in the immediate effect as well as a drug for mitigating the symptoms associated with the PMS, a food or drink for mitigating the symptoms associated with the PMS, an edible fats and oils-containing composition for mitigating the symptoms associated with the PMS or the like, which comprise the glycerin fatty acid ester.
    Type: Application
    Filed: June 23, 2004
    Publication date: December 23, 2004
    Inventors: Shinji Seki, Yuuko Hirasawa, Miho Sakurada, Yuri Arai, Seiichi Shirasawa, Satoshi Negishi
  • Publication number: 20040254387
    Abstract: A method for making biodiesel from a vegetable oil source is described. The method involves simultaneously reacting the free fatty acids and glycerides of the vegetable oil source with methanol, under pressure up to 250 psig, into fatty acid alkyl esters for use as biodiesel. The conversion is catalyzed by an acid at temperatures between about 80° C. to about 200° C.
    Type: Application
    Filed: April 21, 2004
    Publication date: December 16, 2004
    Applicant: Stepan Company
    Inventors: Franz J. Luxem, William M. Troy
  • Publication number: 20040242910
    Abstract: A solvent-free process for making a polyol fatty acid polyester composition useful for preparation of polyurethanes is described. These compositions are preferably made by reaction of a natural oil (from plant or animal) with a multi-functional hydroxyl compound derived from a natural source, such as sorbitol, in presence of an alkali metal salt or base such as potassium hydroxide as a catalyst which also acts to saponify the reaction mixture. The hydroxyl content of the prepared composition depends on the amount of the multi-functional hydroxyl compound used in the preparation. In another embodiment, the hydroxyl groups of these compositions are reacted with an isocyanate, such as the polymeric diphenylmethane diisocyanate (also known as 4,4′-diphenyl methane diisocyanate, or MDI) to form polyurethanes in a conventional manner.
    Type: Application
    Filed: April 29, 2004
    Publication date: December 2, 2004
    Applicant: Board of Trustees of Michigan State University
    Inventors: Jean-Pierre L. Dwan ' Isa, Lawrence T. Drzal, Amar K. Mohanty, Manjusri Misra
  • Publication number: 20040186307
    Abstract: The present invention is directed to a method of producing fuel from vegetable or animal fat having a free fatty acid content by means of catalytic esterification reactions. The method includes esterification of free fatty acids at a higher temperature in a vacuum with one or more multivalent alcohols accompanied by solid neutral catalysts, which are present in a packing bed inside a reactor, whereby the fat travels from top to bottom in the reactor with the alcohol(s) running counter current and a mixture containing alcohol and water being removed from an upper part of the reactor by means of a vacuum effect. The present invention is also directed to the apparatus for implementing the methods disclosed.
    Type: Application
    Filed: February 9, 2004
    Publication date: September 23, 2004
    Applicant: GMK-GESELLSCHAFT FUR MOTOREN
    Inventors: Aldo Piacentini, Rene Niesner
  • Publication number: 20040170658
    Abstract: This invention proposes a lanolin substitute, capable of absorbing up to at least twice its weight of water or aqueous solution or aqueous suspension. It forms true emulsions, stable over time with a capacity for water absorption superior to that of lanolin.
    Type: Application
    Filed: January 2, 2004
    Publication date: September 2, 2004
    Inventors: Pierre Charlier De Chily, Mikaele Raynard
  • Publication number: 20040167343
    Abstract: The invention provides reaction mixtures comprising polyols, triglycerides, base initiators and phase-transfer catalysts for performing transesterification reactions. The reaction product comprises a mixture of polyol monoesters, polyol diesters, triglycerides and glycerol.
    Type: Application
    Filed: February 24, 2004
    Publication date: August 26, 2004
    Applicant: PTC Organics, Inc.
    Inventors: Marc E. Halpern, Darrell Crick
  • Publication number: 20040166571
    Abstract: The present invention is an enzymatic method of interesterification of fats and oils characterized in that the fats and oils to be used as a reaction substrate comprises a fat or oil (triglycerides), a fatty acid and a fatty ester, and the acid value of the reaction substrate is 8 to 30. The formation of undesirable by-products are suppressed and the desired triglycerides of high quality can be obtained constantly.
    Type: Application
    Filed: November 17, 2003
    Publication date: August 26, 2004
    Inventors: Nobuo Sagi, Tadayuki Okada, Masayuki Fukazawa
  • Publication number: 20040159537
    Abstract: There is provided a method for producing fatty acid alcohol ester useful as a substitute fuel for light oil in which an ester interchange reaction between fats or oils and alcohol is carried out in a reactor 1 by applying ultrasonic irradiation at a frequency of 15 to 100 kHz and irradiation intensity of 0.5 to 20 W/cm2 in the presence of a catalyst, followed by an application of ultrasonic irradiation at a frequency of 200 to 3,000 kHz and irradiation intensity of 0.5 to 20 W/cm2 to the reaction product in a separation tank 4 to separate fatty acid alcohol ester and glycerol. Such ultrasonic irradiation in the separation tank 4 may be applied to an interface between fatty acid alcohol ester and glycerol.
    Type: Application
    Filed: October 6, 2003
    Publication date: August 19, 2004
    Inventors: Yasuaki Maeda, Mircea Vinatoru, Carmen Eugenia Stavarache, Kunio Iwai, Hideki Oshige
  • Publication number: 20040158083
    Abstract: A process for the separation and recovery of minor components from vegetable oil such as palm oil. Esterified palm oil is subjected to molecular distillation giving a concentrate rich in minor components. The concentrate is then adsorbed to adsorbents such as normal phase silica gel, reversed phase (particularly C18) silica gel or neutral alumina as well as polymer absorbents such as polyethylene glycol and polyacrylate polyalcohol. Minor components such as squalene, carotenes, tocols and sterols are then selectively desorbed, separated and recovered using solvents operating at isocratic conditions. The desorption of the said minor components are sped up by applying pressure of between 0.2 to 50 bar. By the same method, individual tocols isomers from palm oil can also be separated and recovered.
    Type: Application
    Filed: November 25, 2003
    Publication date: August 12, 2004
    Inventors: Yuen May Choo, Mei Han Ng, Ah Ngan Ma, Yusof Basiron
  • Publication number: 20040152908
    Abstract: A process for producing a processed glyceride having a satisfactory color tone and having high purity without the need of a fractionation step, by mitigating the deterioration in a color tone caused by the processing and recycling of a fatty acid ester recovered after an interesterification reaction. The process comprises subjecting a glyceride fat and a fatty acid ester and/or a free fatty acid to interesterification, distilling the reaction product to recover a part or all of fatty acid esters and/or free fatty acids therein, subjecting the distillation fraction recovered to hydrogenation, and to re-distillation or mixing with the fresh fatty acid ester and/or fresh free fatty acid in any order, re-reacting the resultant fraction or mixture with the distillation residue, and separating a fat fraction from the final reaction product, and is characterized in that the content of components other than the fatty acid ester and/or free fatty acid is controlled to 3.0 wt. % or lower.
    Type: Application
    Filed: December 9, 2003
    Publication date: August 5, 2004
    Inventors: Tadayuki Okada, Kotaro Yamaguchi
  • Publication number: 20040106813
    Abstract: The method for the esterification of a fatty acid F is carried out in a column with a packing. In addition to functioning as a catalytic reactor, the packing functions as a stripping section. A heteregenous catalysis of a fatty acid is carried out with an alcohol used in the same molar ratio or in excess. A gaseous alcohol-rich counter-flow is produced in a sump of the column by vaporisation. Water is removed from the reaction zone by means of the counter-flow acting as a stripping gas. The loaded stripping gas is at least partially liquefied at the head of the column. The head product is separated into a water-rich fraction as well as an alcohol-rich fraction. The alcohol-rich fraction is returned to the process as a starting material for the esterification and for the production of the stripping gas.
    Type: Application
    Filed: November 12, 2003
    Publication date: June 3, 2004
    Inventors: Peter Moritz, Peter Faessler, Claudia von Scala, Oliver Bailer
  • Publication number: 20040059143
    Abstract: This invention relates to a process for obtaining fatty acid esters from triacylglycerides by means of alcoholysis. In particular, the invention relates to a process for the transesterification of fat and/or oil by alcoholysis wherein, in order to accelerate the process, in the initial stage at least one alkanol fatty acid ester is added in a quantity such that the reaction mixture produced thereby consists of one phase. A high reaction rate can thereby be maintained in the process from the beginning.
    Type: Application
    Filed: September 24, 2003
    Publication date: March 25, 2004
    Inventors: Siegfried Peter, Eckhard Weidner
  • Patent number: 6635775
    Abstract: An improved process for preparing reduced-odor or odorless esters, preferably benzoate esters, octanoate esters, aliphatic emollient esters and glycol dibenzoate esters. The improved process comprises, in part, removing the esterification catalyst from the crude ester after the esterification reaction is substantially complete, before neutralization of acidity. The resultant ester compositions are odorless or have substantially reduced odor as compared to commercially available esters.
    Type: Grant
    Filed: February 4, 2000
    Date of Patent: October 21, 2003
    Assignee: Finetex, Inc.
    Inventors: Ismail Walele, Samad A. Syed
  • Publication number: 20030120095
    Abstract: Disclosed are processes for separating valuable products, including unsaponifiable materials, from any given matrix of raw materials that is mainly composed of saponifiable components and unsaponifiable components. Preferred methods include converting sodium or potassium soaps obtained from the saponification of a starting material into metallic soaps which have a lower melting point, and when melted, have viscosity sufficiently low to enable processing such as by distillation/evaporation processes. Preferred raw materials include animal or vegetable products, as well as by-products, residues, and waste products from the processing of animal or vegetable products, such as from food processing, cellulose processing and the like. Valuable products which may be obtained by the disclosed processes include sterols, vitamins, flavonoids, and tocopherols.
    Type: Application
    Filed: February 20, 2002
    Publication date: June 26, 2003
    Inventors: Rodolfo Rohr, Raul Rohr
  • Publication number: 20030050491
    Abstract: A process for purifying a fatty acid containing unwanted unsaponifiable materials involving: (a) providing a C4-C26 fatty acid starting material containing unsaponifiable materials; (b) reacting the fatty acid starting material with a zinc oxide component to form a zinc soap; (d) heating the zinc soap; (e) distilling the unsaponifiable materials from the zinc soap; (f) cooling the purified zinc soap; (g) adding a neutralizing acid component to the purified zinc soap to form a mixture containing a zinc salt and an organic layer containing clean fatty acid; and (h) distilling the purified fatty acid from the organic layer.
    Type: Application
    Filed: September 12, 2001
    Publication date: March 13, 2003
    Inventors: Michael D. Sublett, Christopher G. Ciolino
  • Patent number: 5925776
    Abstract: Polyethoxylated castor oil with a low cation content are claimed, along with particular methods for achieving such low cation content polyethoxylated castor oil. One method of production of such a low cationic content polyethoxylated castor oil according to the invention is to pre-treat the polyethoxylated castor oil with a strong cationic exchange resin to remove a substantial portion of the cations present in an untreated polyethoxylated castor oil. The low cationic content polyethoxylated castor oil of the invention can then be utilized to prepare formulations of various agents which are found to be sensitive to the previously commercially available polyethoxylated castor oil (CREMOPHOR EL.RTM.).
    Type: Grant
    Filed: December 24, 1997
    Date of Patent: July 20, 1999
    Assignee: Schein Pharmacetical, Inc.
    Inventors: Aleksandr Nikolayev, Fakrul Sayeed, Rupa Iyer, Mitchell Garber, Robert C. Butterhof, Todd M. Hoyer, Marvin Samson
  • Patent number: 5696278
    Abstract: The present invention relates to a process for the preparation of degummed glyceride oils, which comprises applying an acid degumming treatment to a crude glyceride oil which has not substantially been exposed to enzymatic activity. Preferably such crude glyceride oil has been obtained by heating and pressing glyceride oil containing vegetable material, optionally preceded by a cold pressing step, where the heating comprises an exposure of the vegetable material to a temperature of 30.degree.-80.degree. C. for 0.1-20 minutes, preferably for 0.1-15 minutes, more preferably 0.1-5 minutes, and then to a temperature of 80.degree.-140.degree. C., preferably 90.degree.-110.degree. C. for 1-60 minutes, preferably 15-20 minutes. Residual phosphorus levels of <7 ppm and even <2 ppm can be easily and consistently attained.
    Type: Grant
    Filed: December 13, 1995
    Date of Patent: December 9, 1997
    Assignee: Unilever Patent Holdings B.V.
    Inventor: Jacobus Cornelis Segers
  • Patent number: 5599376
    Abstract: A process for recovering edible oil and bleaching clay from an edible oil-bleaching clay waste stream and for recovering edible oil and nickel catalyst from a hydrogenated edible oil-nickel catalyst-filter aid waste stream; the recovered bleaching clay may be reused directly and the recovered nickel catalyst and filter aid mixture is pelletized for metallurgical nickel recovery.
    Type: Grant
    Filed: November 27, 1995
    Date of Patent: February 4, 1997
    Inventor: John D. Camp
  • Patent number: 5550264
    Abstract: A process for purifying crude ester containing residual metallic catalyst is described. The process comprises (a) adding to a crude ester product an amorphous silicon dioxide adsorbent capable of adsorbing dissolved metallic catalyst; (b) heating the combination at a temperature of between about 80.degree. C. and about 130.degree. C.; and (c) separating the ester from the adsorbent by filtration, such that residual metallic catalyst is retained on the adsorbent.
    Type: Grant
    Filed: July 13, 1994
    Date of Patent: August 27, 1996
    Assignee: Henkel Corporation
    Inventor: A. Fred Elsasser
  • Patent number: 5278325
    Abstract: A vegetable oil process and assembly is disclosed for extracting oil from an oil bearing material such as soybean, corn and the like. The process comprises adding at least one reagent to the oil bearing material to form a slurry mixture. The slurry is heated at a preselected temperature for a preselected period of time preferably under a partial vacuum. This processing reduces the phospholipid and trace metal content in the oil extracted from the oil heating material. The oil product produced is light in color, shows no turbidity and exhibits minimal amount of phosphorus, calcium, magnesium and iron. The oil is ready for physical refining.
    Type: Grant
    Filed: July 30, 1990
    Date of Patent: January 11, 1994
    Inventors: Hans R. Strop, Richard R. Perry
  • Patent number: 5239096
    Abstract: A method of removing gums which cannot be removed by simple water degumming from plant oils having the following steps:(a) adding to a plant oil containing gum substances not hydratable with water and wax substances, substantially 0.01 to 0.08% of a food acid or an acid anhydride of a food acid in a 5 to 15% solution thereof at a temperature of 20.degree. to 70.degree. C., intimately mixing the oil and the solution and causing the oil and the solution to remain in contact for a contact time in excess of 5 minutes with slow stirring;(b) to a mixture formed in step (a) adding a 1 to 5% solution of a base at a temperature of 10.degree. to 40.degree. C.
    Type: Grant
    Filed: August 22, 1991
    Date of Patent: August 24, 1993
    Assignee: Krupp Maschinentechnik GmbH
    Inventors: Herbert L. Rohdenburg, Karoly Csernitzky, Bela Chikany, Jozsef Peredi, Attila Borodi, Anna F. Ruzics
  • Patent number: 5225049
    Abstract: A process for refining organic-solvent containing crude polyol fatty-acid polyester reaction product, including the steps of distilling the crude reaction product to substantially remove the organic solvent, and subsequently subjecting the distilled reaction product to a bleaching treatment. The process allows an economic use of bleaching agents while achieving good color and color stability of the refined product.
    Type: Grant
    Filed: December 13, 1990
    Date of Patent: July 6, 1993
    Assignee: Van den Bergh Foods Co., Division of Conopco, Inc.
    Inventors: Bart Barmentlo, Jan Van Buuren, Alexander M. Hulstaert