Organic Or Inorganic Acid Or Anhydride Treating Agent (e.g., Carbon Dioxide, Sulfur Dioxide, Etc.) Patents (Class 554/179)
  • Patent number: 9657319
    Abstract: Provided here is an enzymatic process for production of low saturate oil, in one embodiment, low palmitic oils from triacylglycerol sources. The enzymes used in the processes herein are saturase enzymes, including palmitase enzymes. The oils produced by the processes herein are used in food products.
    Type: Grant
    Filed: June 13, 2013
    Date of Patent: May 23, 2017
    Assignee: BUNGE GLOBAL INNOVATION LLC
    Inventor: Christopher L. G. Dayton
  • Patent number: 9315764
    Abstract: The present invention provides methods of processing lipid materials such as soapstock, wet gums and dry gums. Enzymes are utilized to catalyze hydrolysis of the lipids materials to recover fatty acids. Addition of organic acids and/or polyols improved yield of fatty acids and reduced formation of emulsion. Lipid materials can be formulated with other agricultural products as new value-added animal fee products.
    Type: Grant
    Filed: April 30, 2010
    Date of Patent: April 19, 2016
    Assignee: RRIP, LLC
    Inventors: Mohan Prasad A. Dasari, Abdullah A. Mahfuz
  • Publication number: 20140024847
    Abstract: Separate collection and conversion method and plant for the reuse of used oils and greases for energy purposes, which method provides one or more of the following steps: producing and separating the waste from other substances or compounds, collecting the waste gathering/storing the waste in at least a collection and/or regeneration facility, regenerating or treating the waste, reusing the collected or regenerated or treated waste, an oil or a grease or a mixture containing at least a natural and/or synthetic ester-based oil and/or grease being considered as waste, which oil or grease or which mixture is the by-product or waste of industrial processes.
    Type: Application
    Filed: March 30, 2012
    Publication date: January 23, 2014
    Applicant: A. & A. Fratelli Parodi S.p.A.
    Inventors: Augusto Parodi, Leandro Marini
  • Patent number: 7652156
    Abstract: A method allowing, from natural fat or oils, vegetable or animal, or from other glyceride mixtures, to obtain in a quasi-quantitative way fatty acid ethyl esters that can be used as gas oil substitutes, comprises the succession of stages as follows: a stage (a) wherein the oil, the fat or the glyceride mixture is transesterified by ethanol using a soluble catalyst or a catalyst that becomes soluble during the reaction, a stage (b) wherein the glycerin formed is decanted and removed, without requiring an excess ethanol evaporation operation, a stage (c) wherein a second transesterification reaction is carried out so as to obtain a product whose ester content is at least 97% by mass, a stage (d) wherein controlled neutralization of the catalyst is carried out, a stage (e) wherein the excess ethanol is removed by distillation, a stage (f) wherein the ester undergoes purification by means of water wash sequences, and a stage (g) wherein the ester mixture is dried under reduced pressure.
    Type: Grant
    Filed: September 20, 2006
    Date of Patent: January 26, 2010
    Assignee: Institut Francais du Petrole
    Inventors: GĂ©rard Hillion, Bruno Delfort
  • Patent number: 6426423
    Abstract: This invention relates to improved methods for treating phosphatide-containing mixtures. More particularly, this invention relates to methods for recovering purified vegetable oil, aqueous organic acid, and organic acid-treated phosphatide from a phosphatide-containing mixture comprising an acid-and-oil mixture obtained from organic acid refining of vegetable oil.
    Type: Grant
    Filed: February 2, 2001
    Date of Patent: July 30, 2002
    Assignee: I.P. Holdings
    Inventors: Dick Copeland, W. Maurice Belcher
  • Patent number: 6399802
    Abstract: Methods for acidification of soapstock and recovery of acidulated fatty acids are disclosed. Further methods of conversion of the acidulated fatty acids to esters are also disclosed. Further methods of crystallizing the acidulated fatty acids from the extraction solvent at low temperatures and fractionating the acidulated fatty acids from the extraction solvent using urea are also disclosed. The novel method of adding both a monohydric alcohol to the soapstock to lower viscosity and a strong acid to hydrolyse the soaps prevents the formation of emulsions of soaps and oils. The preferred embodiment uses a soapstock such as soybean soapstock, sulphuric acid and isopropanol. The novel process allows the quantitative recovery of fatty acids and glyceride from the soapstock by removal of the alcohol by evaporation. Alternatively the fatty acids and glyceride may be converted to esters of monohydric alcohols.
    Type: Grant
    Filed: March 21, 2001
    Date of Patent: June 4, 2002
    Assignee: KRU Feed Energy Company
    Inventor: Martin J. T. Reaney
  • Patent number: 5696278
    Abstract: The present invention relates to a process for the preparation of degummed glyceride oils, which comprises applying an acid degumming treatment to a crude glyceride oil which has not substantially been exposed to enzymatic activity. Preferably such crude glyceride oil has been obtained by heating and pressing glyceride oil containing vegetable material, optionally preceded by a cold pressing step, where the heating comprises an exposure of the vegetable material to a temperature of 30.degree.-80.degree. C. for 0.1-20 minutes, preferably for 0.1-15 minutes, more preferably 0.1-5 minutes, and then to a temperature of 80.degree.-140.degree. C., preferably 90.degree.-110.degree. C. for 1-60 minutes, preferably 15-20 minutes. Residual phosphorus levels of <7 ppm and even <2 ppm can be easily and consistently attained.
    Type: Grant
    Filed: December 13, 1995
    Date of Patent: December 9, 1997
    Assignee: Unilever Patent Holdings B.V.
    Inventor: Jacobus Cornelis Segers
  • Patent number: 5565590
    Abstract: This invention relates to a process for recycling waste material selected from amino-carboxylic acid oligomers or polymers and amido-carboxylic acid oligomers or polymers into amido-carboxylic acids. A mixture containing water, an oligomeric or polymeric waste material, and a carboxylic acid is heated. The mixture is cooled to obtain a two phase system containing an aqueous phase and an organic phase which are separated. Carboxylic acids, unreacted starting materials, and the monomeric amido-carboxylic acid product are distilled from the organic phase. The remaining solid residue composed of high boiling oligomeric amino-carboxylic acids is recycled into Step (A).
    Type: Grant
    Filed: November 7, 1994
    Date of Patent: October 15, 1996
    Assignee: Eastman Chemical Company
    Inventors: George C. Zima, Gary P. Lutz, Gary W. McChesney, T. Hugh Williams
  • Patent number: 5424466
    Abstract: A description is given of an improved process for the production of esters from fatty substances having a natural origin (animal and vegetable oils) and low molecular weight alcohols, in which the soaps and oily compounds entrained in the alkaline phases are recycled by treating them, following acidification and separation, with a fraction of the glycerol phase produced, in the presence of an alkaline catalyst and for forming preferably a triglyceride or a partly substituted glyceride.This process makes it possible to quantitatively obtain methyl, ethyl, propyl or butyl esters usable as a substitute for gas oil.
    Type: Grant
    Filed: September 24, 1993
    Date of Patent: June 13, 1995
    Assignee: Institut Francais du Petrole
    Inventors: Robert Stern, Gerard Hillion, Jean-Jacques Rouxel
  • Patent number: 5239096
    Abstract: A method of removing gums which cannot be removed by simple water degumming from plant oils having the following steps:(a) adding to a plant oil containing gum substances not hydratable with water and wax substances, substantially 0.01 to 0.08% of a food acid or an acid anhydride of a food acid in a 5 to 15% solution thereof at a temperature of 20.degree. to 70.degree. C., intimately mixing the oil and the solution and causing the oil and the solution to remain in contact for a contact time in excess of 5 minutes with slow stirring;(b) to a mixture formed in step (a) adding a 1 to 5% solution of a base at a temperature of 10.degree. to 40.degree. C.
    Type: Grant
    Filed: August 22, 1991
    Date of Patent: August 24, 1993
    Assignee: Krupp Maschinentechnik GmbH
    Inventors: Herbert L. Rohdenburg, Karoly Csernitzky, Bela Chikany, Jozsef Peredi, Attila Borodi, Anna F. Ruzics
  • Patent number: 5210240
    Abstract: A process for the extraction of oils from oil-containing solid vegetable material by means of compressed gases, wherein said vegetable material is extracted with a mixture consisting of a supercritical gas and a subcritical entraining agent selected from the group consisting of propane, butane, pentane, ethanol, ethyl acetate, formaldehydedimethylacetal, CHF.sub.
    Type: Grant
    Filed: August 20, 1992
    Date of Patent: May 11, 1993
    Inventors: Siegfried Peter, Gerd Brunner
  • Patent number: 5156879
    Abstract: The present invention is directed to a method for treatment of soapstock obtained by alkali refining of fats to provide a fluid, uniform, pumpable animal feed product. In the method, a raw soapstock is provided. The soapstock is pretreated by adding a strong, soluble base to the soapstock. Propionic acid is then added to the pretreated soapstock and the pH is adjusted to provide an acidified soapstock. With soapstocks having low gum levels, a fluid, uniform, pumpable product is provided without further treatment. At higher gum levels, the pretreated soapstock and/or the acidified soapstock is heated to a predetermined temperature to provide the fluid, uniform, pumpable product.
    Type: Grant
    Filed: July 25, 1991
    Date of Patent: October 20, 1992
    Assignee: Cargill, Incorporated
    Inventor: Jeffrey C. Evans