Abstract: The process utilizes the adsorbent column system as a treatment after chemical refining or before physical refining rather than water or filtration, respectively, to remove soaps and other impurities entrained in a crude triacylglycerol. The CDTAG or ORTAG is contacted with an adsorbent packed into a column, or multiple columns in series, for a sufficient amount of time to remove impurities such as, but not limited to, soaps, metals, chlorophyll, and many of the other compounds that reduce the stability of the TAG. The resulting TAG exiting the column(s) is ready for the deodorization process. Once the adsorbent no longer removes the desired amount of impurities, it is regenerated for reuse. Such a continuous regenerable adsorbent refining process substantially reduces the amount of fresh water required and the amount of waste water generated to purify TAG and reduces the amount of solid waste produced.

Abstract: A method for producing biofuels along with valuable food and neutraceutical products is provided. A method of making biofuels includes dewatering substantially intact algal cells to make an algal biomass, extracting neutral lipids along with carotenoids and chlorophylls from the algal biomass, and separation of the carotenoids and chlorophylls using adsorption or membrane diafiltration or other methods. The remaining neutral lipids are esterified with a catalyst in the presence of an alcohol. The method also includes separating a water soluble fraction comprising glycerin from a water insoluble fraction comprising fuel esters and distilling the fuel esters under vacuum to obtain a C16 or shorter fuel esters fraction, a C16 or longer fuel ester fraction, and a residue comprising omega-3 fatty acids esters and remaining carotenoids.

Abstract: A quick, economical and environmentally friendly, “green”, process for the continuous purification of biodiesel (fatty acid alkyl esters (FAAE)) is described using a powdered, granulated or extruded adsorbent. The adsorbent is contained in a column system and is regenerated for reuse multiple times. The process employs an adsorbent such as, but not limited to, carbon, silica, clay, zeolite or a metal silicate contained in a column to remove the impurities from fatty acid alkyl esters (FAAE) or crude biodiesel in a continuous process. The process utilizes the adsorbent column system for the purification of biodiesel, rather than water or filtration, to remove soaps and other impurities entrained in a crude biodiesel.

Abstract: A process for the removal of impurities from fatty materials comprising the steps of providing a fatty material that may already have undergone some purification treatment, adding an aqueous suspension of liquid adsorbent to the fatty material and causing it to form a mixture with the fatty material, optionally adding some water to the mixture, and forming an aqueous phase separate from the fatty material and removing the aqueous phase from the fatty material.

Abstract: Method for improving the performance of a preparative batchwise Super Critical Fluid Chromatographic separation for the recovery of a target fatty acid or derivative thereof, or of a group of target fatty acids or of derivatives thereof from a mixture, characterized in that the said Super Critical Fluid Chromatographic separation employs a chromatographic column charged with a stationary phase chosen from the group consisting of aluminium oxide or aluminium oxides, titanium oxide or titanium oxides, silica gel or silica gels, amino propyl modified silica gels, diol modified silica gels, phenyl modified silica gels and “reversed phase” phases, the former in turn chosen from the group consisting of RP18, RP8 and RP3, and in that the said Super Critical Fluid Chromatographic Separation further employs a mobile phase chosen from the group consisting of ethylene, propane, ammonia, dinitrogen dioxide and CO2, wherein in the said method, during the run of the said mixture on the chromatographic column, a pressure an

Abstract: A method for producing biofuels along with valuable food and neutraceutical products is provided. A method of making biofuels includes dewatering substantially intact algal cells to make an algal biomass, extracting neutral lipids along with carotenoids and chlorophylls from the algal biomass, and separation of the carotenoids and chlorophylls using adsorption or membrane diafiltration or other methods. The remaining neutral lipids are esterified with a catalyst in the presence of an alcohol. The method also includes separating a water soluble fraction comprising glycerin from a water insoluble fraction comprising fuel esters and distilling the fuel esters under vacuum to obtain a C16 or shorter fuel esters fraction, a C16 or longer fuel ester fraction, and a residue comprising omega-3 fatty acids esters and remaining carotenoids.

Abstract: A process for the removal of sterols, specifically cholesterol, from a triglyceride oil, preferably a marine triglyceride oil, said process comprising contacting an oil with an adsorbent, specifically TRIS YL™, clay or a mixture thereof, heating the mixture to 100° C. to 210° C., preferably 150° C. to 170° C., preferably for a time period of greater than one minute and optionally at a pressure less than 133 Pa, preferably less than 1.33 Pa.

Abstract: The present invention relates to a process for cooling fatty acid distillate from scrubbing section in a fats and oils refinery comprising cooling the fatty acid distillate by heat recovery in at least one heat-exchanging zone with refined oils having a temperature above about 50° C. heating the refined fats and oils to a temperature above about 70° C. The present invention relates further to a process for refining crude fats and oils, and refining plant for refining crude fats and oils.

Abstract: A method of obtaining a polyunsaturated fatty acid derivative comprises contacting a mixture of fatty acid derivatives with a silver salt aqueous solution, and adjusting the free fatty acid content in the silver salt aqueous solution to 0.2 meq or less per gram of silver when repeatedly using the silver salt aqueous solution. A polyunsaturated fatty acid derivative having high purity and excellent quality can thus be economically obtained.

Abstract: The present invention relates to devices and methods for selectively removing contaminants from a crude product mixture. In an embodiment the invention includes a method for removing organic acids from a crude product mixture including contacting the crude product mixture with a metal oxide substrate, wherein free organic acids in the crude product mixture bind to the metal oxide substrate, thereby removing free organic acids and forming a refined product mixture; separating the refined product mixture from the metal oxide substrate; and removing the organic acids bound to the metal oxide substrate by contacting the metal oxide substrate with an alkyl ester composition at a temperature of greater than about 100 degrees Celsius. Other embodiments are also described herein.

Abstract: The present invention relates to a continuous process of DHA enrichment of a solution of fatty acids or derivatives thereof comprising less than 50% of DHA relative to the total fatty acids of the solution or to derivatives thereof, wherein the process comprises the steps of (a) simultaneous countercurrent injection, into a fractionation column, of the flow of the solution of fatty acids or of derivatives thereof and of a flow of supercritical CO2 at a temperature of less than or equal to 70° C. and at a pressure of between 100×105 Pa and 160×105 Pa, wherein the level of supercritical CO2 is between 30 and 70, and (b) recovery of the residue comprising at least 50% of DHA relative to the total fatty acids of the residue or to derivatives thereof, wherein the DHA yield is greater than or equal to 60%.

Abstract: Use process chromatographic apparatus and process (for example, SMB chromatographic separation) to effect removal of at least a portion of components that contain neither a hydroxy moiety nor an aldehyde moiety from a feedstream that includes such components as well as components that contain one or more of a hydroxy moiety and an aldehyde moiety.

Abstract: A purification system suitable for use in fatty material processing is disclosed. A method of using a purification system to process fatty materials, such as oils, edible oils, fats, and similar materials, is also disclosed.

Abstract: The invention relates to a process for bleaching oils or fats. For this, a naturally active or non-naturally active bleaching earth is provided in a first vessel (10) and an organic acid in a second vessel (11). In a mixing vessel (8), the oil or fat which is to be bleached is admixed with bleaching earth and the organic acid, wherein the bleaching earth and the organic are added individually. Subsequently, the oil or fat which is to be bleached is bleached in a conventional manner.

Abstract: Disclosed are methods of removing and/or reducing compounds from oils (e.g., marine oils) and oils prepared by the disclosed methods. Methods of bleaching oils are also disclosed.

Abstract: The present invention relates to a method of producing a fatty acid ester, including treating a starting fatty acid ester with an adsorbent to adsorb sulfur contained in the starting fatty acid ester, the adsorbent containing at least one metal selected from Ni and Cu in an amount of 10 to 85 percent by weight as a metal oxide(s) thereof per all the adsorbent, having a pore volume having a pore diameter range from 20 to 200 nm within 0.15 to 1.0 mL/g and then a method of producing an alcohol, including hydrogenating a fatty acid ester obtained by the above shown method of producing a fatty acid ester.

Abstract: An economical and environmentally friendly, “green”, process for the continuous purification of triacylglycerol (TAG) is described using a powdered, granulated or extruded adsorbent, which can be used in either the chemical or physical refining of edible oils and fats, both of which are traditionally used to refine TAG. The adsorbent is contained in a column system and is regenerated for reuse multiple times. The process utilizes the adsorbent column system as a treatment after chemical refining or before physical refining rather than water or filtration, respectively, to remove soaps and other impurities entrained in a crude triacylglycerol. In the chemical refining process, the crude degummed triacylglycerol (CDTAG) is first refined to remove FFA, forming a once refined triacylglycerol (ORTAG), and then contacted with an adsorbent packed into column(s) prior to deodorization.

Abstract: A process for reducing the fluorosurfactant content of a stabilized fluorosurfactant-containing aqueous fluoropolymer dispersion by passing dispersion through a first fixed bed of anion exchange resin to reduce fluorosurfactant content. The first fixed bed has a working zone which moves though the column as the ion exchange resin is saturated. The process includes monitoring a property of the dispersion as the dispersion exits the fixed bed to determine break though of the working zone indicating saturation of the fixed bed. The property being monitored is selected from the group consisting of pH and conductivity.

Abstract: A process for reducing fluorosurfactant content of a stabilized fluorosurfactant-containing aqueous fluoropolymer dispersion. The process includes providing a fixed bed of anion exchange resin having anion exchange groups with counter ions. The anion exchange resin is treated to replace at least some the counter ions with counter ions of non-fluorinated anionic surfactant. The stabilized fluorosurfactant-containing aqueous fluoropolymer dispersion is passed through the treated fixed bed of anion exchange resin.

Abstract: A process for reducing fluorosurfactant content of a fluorosurfactant-containing aqueous fluoropolymer dispersion stabilized with nonionic surfactant. The process includes reducing the fluorosurfactant content of the stabilized fluorosurfactant-containing aqueous fluoropolymer dispersion to a predetermined level to provide a reduced surfactant dispersion, adding non-fluorinated anionic surfactant to the reduced fluorosurfactant dispersion, and concentrating the reduced fluorosurfactant dispersion. The non-fluorinated anionic surfactant is added in stages wherein a first portion is added to the dispersion prior to concentrating and a second portion of the non-fluorinated anionic surfactant is added to the dispersion after concentrating.

Abstract: A method of purifying a biodiesel fuel by contacting the biodiesel fuel with at least one adsorbent material, such as magnesium silicate. Such method removes impurities, such as soap, formed during the production of biodiesel fuels.

Abstract: A method for producing a fatty acid alkyl ester for diesel fuel oil starting with a fat/oil material such as an edible oil whereby the qualities required of diesel fuel oil can be satisfied and the wastes from the production process can be minimized. The method is characterized by including subjecting a fat/oil material to transesterification with an alcohol, washing with water the oily phase of the reaction mixture, eliminating water after washing via absorption by a high-water-absorptive resin, and then separating the high-water-absorptive resin gel to thereby provide a fatty acid alkyl ester suitable for diesel fuel oil.

Abstract: Methods, particles, and devices are disclosed for filtration of oil for use of the oil in the preparation of biodiesel. Disclosed particles may comprise a substantially inert porous particle with a coating comprising a polymer having amine, amino, and/or imine group(s).

Abstract: Disclosed are bleaching materials for processing oils, particularly edible oils, containing an acid activated clay having a specifically defined particle size distribution. Also disclosed are methods of making the bleaching materials, and systems and methods for purifying oils using the acid activated clay having the specifically defined particle size distribution.

Abstract: A quick, economical and environmentally friendly, “green”, process for the continuous purification of biodiesel (fatty acid alkyl esters (FAAE)) is described using a powdered, granulated or extruded adsorbent. The adsorbent is contained in a column system and is regenerated for reuse multiple times. The process employs an adsorbent such as, but not limited to, carbon, silica, clay, zeolite or a metal silicate contained in a column to remove the impurities from fatty acid alkyl esters (FAAE) or crude biodiesel in a continuous process. The process utilizes the adsorbent column system for the purification of biodiesel, rather than water or filtration, to remove soaps and other impurities entrained in a crude biodiesel.

Abstract: Disclosed are methods of removing and/or reducing compounds from oils (e.g., marine oils) and oils prepared by the disclosed methods. Methods of bleaching oils are also disclosed.

Abstract: An aqueous dispersion of polytetrafluoroethylene (PTFE) comprising from 55 to 70 mass % of PTFE fine particles having an average particle diameter of from 0.1 to 0.5 ?m, from 0.0001 to 0.02 mass %, based on PTFE, of a specific C8 fluorine-containing carboxylic acid salt (APFO) such as ammonium perfluorooctanoate, from 1 to 20 mass %, based on PTFE, of a specific nonionic surfactant and from 0.01 to 0.3 mass %, based on PTFE, of a specific C5-7 fluorine-containing carboxylic acid salt such as ammonium perfluorohexanoate. The aqueous dispersion of PTFE has excellent properties which can form crack-resistant coatings which do not undergo coloration during baking or form problematic ionic impurities by improving the friction stability of aqueous PTFE dispersions even at APFO concentrations without viscosity increase.

Abstract: To obtain a high concentration aqueous PTFE dispersion containing PTFE at a concentration of from 60 to 75 mass % by dissolving from 0.001 to 0.1 mass %, based on the mass of PTFE, of a specific carboxylic acid salt such as ammonium laurate in a low concentration aqueous dispersion of polytetrafluoroethylene (PTFE) comprising from 1 to 40 mass % of PTFE fine particles, from 0.0001 to 0.02 mass %, based on the mass of PTFE, of a specific fluorine-containing carboxylic acid type emulsifier (for example, ammonium perfluorooctanoate), and from 1 to 20 mass %, based on the mass of PTFE, of a specific nonionic surfactant, and then concentrating the low concentration aqueous dispersion of PTFE.

Abstract: Methods of producing lubricity additives and lubricity additives are disclosed. The methods of producing lubricity additives include removing sulfur from a tall oil fatty acid to a level of about 25 ppm or less and fractionally crystallizing the tall oil fatty acid to produce a lubricity additive which does not form crystals at temperatures as low as about ?20° F. The sulfur may be removed prior to or after fractionally crystallizing the tall oil fatty acid. Methods of improving the lubricity of a fuel are also disclosed.

Abstract: The present invention provides a method of purifying an aqueous fluoropolymer emulsion by which fluorine-containing surfactants can be removed without lowering the dispersibility of the aqueous fluoropolymer dispersions. The present invention provides a method of purifying an aqueous fluoropolymer emulsion comprising; purifying an aqueous fluoropolymer emulsion by a specific technique of concentration wherein the aqueous fluoropolymer emulsion comprises a fluoropolymer and a fluorine-containing surfactant, said specific technique of concentration comprises concentration by phase separation, electric concentration and/or ion exchange concentration, and said concentration by phase separation, electric concentration and/or ion exchange concentration is carried out for removing the fluorine-containing surfactant.

Abstract: A process for reducing the odor of an oil. The oil being treated is first distilled by a carrier vapor or carrier gas distillation to form a distilled oil. The distilled oil is then contacted with a polymeric adsorbent; whereby the odor of the oil is reduced. The polymeric adsorbent is regenerated. The polymeric adsorbent can be a cross-linked polymer with an internal surface area of from 900 to 1500 m2/gram.

Abstract: A process for producing an aqueous dispersion of purified polytetrafluoroethylene (PTFE), comprising passing a crude aqueous dispersion of PTFE comprising from 10 to 50 mass % of PTFE fine particles having an average particle diameter of from 0.1 to 0.5 ?m, from 0.05 to 1.0 mass %, based on PTFE, of a fluorine-containing carboxylic acid salt (APFO) and from 2 to 20 mass %, based on PTFE, of a nonionic surfactant through a column packed with a weak basic AER upward at a linear velocity of 0.1 to 2 mm/sec with a contact time of 0.2 to 4 hours to reduce the APFO concentration. The process can increase the absorption of APFO by the anion exchange resin, prevents agglomeration of PTFE during passage and makes it easy to elute the absorbed APFO.

Abstract: As a substitute for distillation of crude feedstock in the production of oleo-chemicals, the crude feedstock is bleached to remove color and odor. The crude feedstock can include fatty acids and/or glycerin, and the bleached product can be incorporated into a commercial product, such as liquid laundry detergent, bar soap, anti-freeze, paper de-inking cleaners, lubricants, dark rubber and plastics.

Abstract: A solid bed adsorptive process for separating a seed oil into two substantially pure triglyceride fractions. The process involves contacting a seed oil, such as castor oil, preferably as a concentrate, with an adsorbent in a bed, the adsorbent having a particle size greater than about 40 microns, and thereafter contacting the adsorbent with a desorbent material, preferably under minimal flow conditions, to obtain a raffinate output stream containing predominantly a second triglyceride and an extract output stream containing predominantly a first triglyceride. Purified fatty acid triglyceride esters obtainable from castor, vernonia, and lesquerella plant oils provide renewable, non-petroleum-based sources of chemical feedstocks.

Abstract: The invention relates to a process for purifying lipoic acid, which comprises adding to a solution of lipoic acid at least 0.1 times the amount of an adsorbent, based on the mass of lipoic acid to be purified, and subsequently removing the adsorbent. It is possible in this way to provide racemic or nonracemic lipoic acid with an oligomer content below 1% by weight, for example from 0.1 to 1% by weight.

Abstract: The present invention provides a method of treating fats and oils containing low concentrations of aromatic halogen compounds and other contaminants by contacting the fats or oils with an adsorbing agent. The adsorbing agent contains a porous body and a non-protonic polar solvent held in the interiors of fine pores in the porous body to adsorb the contaminants. In one embodiment, the porous body also carries noble metal fine particles. In another embodiment, the adsorbing body comprises a solid acid for adsorbing the contaminants and there is a step of contacting the adsorbing body with an organic solvent to extract the adsorbed contaminants into the organic solvent.

Abstract: There is provided a process wherein a lower alkyl ester of a fatty acid derived from natural fats and oils and a lower alcohol containing 1 to 4 carbon atoms is produced in a lower sulfur content at lower costs without causing a reduction in yield and a deterioration in selectivity, as well as a process for producing an alcohol without reducing the activity of a catalyst. The process comprises the step of adsorption treatment of an ester with at least one adsorbent selected from clay and activated carbon. Further are provided a process for producing an ester which further comprises adsorption treatment with a hydrogenating decomposition-type adsorbent containing Ni and/or Cu, in hydrogen or a mixed gas atmosphere of hydrogen and an inert gas, and a process for producing an alcohol which comprises hydrogenation reaction with an ester produced by any one of these processes as the starting material.

Abstract: The invention relates to a novel extraction method for obtaining at least one unsaturated, optionally derivatised compound, from mixtures of said compounds with other less saturated constituents, e.g. for obtaining polyunsaturated fatty acids or the derivatives thereof from mixtures with saturated and/or less unsaturated, optionally derivatised fatty acids, by means of selective complexation with a cation exchanger which is partially or fully charged with silver ions, and subsequent decomplexation.

Abstract: Fluorinated carboxylic acid, used as a surfactant in fluoropolymerization in aqueous media, can be recovered by scrubbing from the exhaust gas of the dryer during polymer drying and, after concentration and treatment with alumina, directly reused in fluoropolymerization in aqueous media.

Abstract: There is provided a process wherein a lower alkyl ester of a fatty acid derived from natural fats and oils and a lower alcohol containing 1 to 4 carbon atoms is produced in a lower sulfur content at lower costs without causing a reduction in yield and a deterioration in selectivity, as well as a process for producing an alcohol without reducing the activity of a catalyst. The process comprises the step of adsorption treatment of an ester with at least one adsorbent selected from clay and activated carbon. Further are provided a process for producing an ester which further comprises adsorption treatment with a hydrogenating decomposition-type adsorbent containing Ni and/or Cu, in hydrogen or a mixed gas atmosphere of hydrogen and an inert gas, and a process for producing an alcohol which comprises hydrogenation reaction with an ester produced by any one of these processes as the starting material.

Abstract: A method is for removing coumafos (O,O′-diethyl-O″-(3-chloro-4-methyl-7-coumarinyl)thiophosphate) from beeswax by melting the beeswax, adding activated charcoal to the melted beeswax to form a suspension of the activated charcoal in the melted beeswax, and adsorbing coumafos from the melted beeswax onto the activated charcoal, and then pressure filtering.

Abstract: The present invention relates to a process for the preparation of refined hard sugarcane wax having improved qualities from press mud which comprises digesting press mud with a non polar solvent in the presence of activated charcoal and separating the sugarcane wax from the residue.

Abstract: The invention relates to a process for the recovery of minor components and refining of vegetable oils and fats from crude vegetable oils and fats.

Abstract: Eicosapentaenoic acid or its ester is separated and purified from a mixture containing a highly unsaturated fatty acid or its ester effectively at low cost by a process, which comprises developing the mixture by a mixed solvent of an ether solvent and a hydrocarbon solvent, using a column filled with a silica gel having a particle diameter of 1-100 micrometers.

Abstract: A method for providing a purified conjugated fatty acid is disclosed. The purified conjugated fatty acid is formed by separating by liquid chromatography a conjugated fatty acid formed by a novel synthesis of reacting an ester of a fatty acid having a four carbon chain such that carbon one bears one hydrogen and one hydroxyl group, carbon two bears two hydrogen atoms, and a double bond is positioned between carbon three and carbon four, with a tosyl chloride or a mesyl chloride to form a tosylate or mesylate of said ester, and reacting the tosylate or mesylate of said ester with diazabicyclo-undecene.

Abstract: The present invention relates to a process for the isolation of oryzanols from rice bran oil soap stock by (a) saponifying the oil present in soap stock with an alkali followed by neutralisation of the excess alkali, (b) converting the soap stock into anhydrous, porous soap noodles, (c) extracting the soap noodles with an organic solvent, (d) crystallising the crude unsaponifiable matter to remove impurities, (e) subjecting the residue to column chromatography to obtain an oryzanol rich fraction, and (f) recrystallising the oryzanol rich fraction using an organic solvent to obtain pure oryzanol.

Abstract: This invention is directed to a process for separating a first triglyceride comprising a docosahexaenoic acid residue from a second triglyceride. The process comprises introducing a feed mixture comprising the first triglyceride and the second triglyceride into a chromatographic separation zone, and then isolating a fraction of the feed mixture in the separation zone that has a mass ratio of the first triglyceride to the second triglyceride that is greater than in the feed mixture. The separation zone comprises a stationary phase which comprises metal ions that are capable of coordinating with a double bond of a fatty acid residue of the first triglyceride to form a metal complex with the fatty acid residue.

Abstract: A method separating tocotrienols from tocopherols and the isomers thereof on a large-scale or commercially feasible basis. Separation is accomplished using reverse phase partition liquid chromatography. The chromatography column is prepared using a stationary phase comprising a hydrophobic or aromatic reverse phase chromatography media. The mobile phase consists of a solvent which is capable of solubilizing the crude stock, tocotrienols and tocopherols. The chromatography column containing the stationary and mobile phases is loaded with a crude feed stock and the tocotrienols, tocopherols and/or isomers thereof are eluted at a predetermined linear velocity.

Abstract: A process for purifying a non-ionic surfactant or solvent capable of dispersing and solubilizing a pharmaceutical compound. In the process, a solution of solvent and alcohol is contacted with an activated carbon column and an ion exchange resin column. The process is particularly adapted to the purification of polyethoxylated castor oils. The purified solvent is useful in the preparation of pharmaceutic compositions having enhance shelf life, such as for use with paclitaxel.

Abstract: A single-step acid degumming/decolorizing process removes chlorophyll-type compounds from vegetable oils from seeds, especially frost damaged seeds which have large amounts of chlorophyll-type compounds. A mixture of aqueous sulfuric and phosphoric acids is blended with the oil to remove chlorophyll-type compounds from the oil. The purified oil has less than about 5 ppm chlorophyll-type compounds, less than about 50 ppm phosphorus and less than about 1.0 weight percent free fatty acids.