Carboxylic Acid, Anhydride, Or Acid Halide Treating Agent Patents (Class 554/204)
  • Patent number: 11339349
    Abstract: An oil separation treatment composition providing a process stream mixture from a corn to ethanol process, and one or more polyglycerol esters of fatty acids (PGE) or mixture of PGE. A method for recovering oil in a corn to ethanol process wherein oil and solids are present in a process stream mixture, the method providing adding to the process stream mixture an oil separation treatment, the oil separation treatment comprises polyglycerol esters of fatty acids (PGE) or mixture of PGE.
    Type: Grant
    Filed: June 13, 2018
    Date of Patent: May 24, 2022
    Assignee: BL Technologies, Inc.
    Inventors: Umit Turunc, Michael Raab
  • Patent number: 9752097
    Abstract: Methods and composition are provided for recovering oil from an oil containing mixture or emulsion. The invention is particularly applicable for recovery of oil from corn in a corn to oil process. The process and compositions comprise a combination of two non-ionic surfactants i) and ii). The non-ionic surfactant i) is a non-ionic surfactant comprising a polyol derived from a sorbitol, a sorbitan, or isosorbide. The non-ionic surfactant ii) is an ester of a) polyethylene glycol and b) a fatty acid. In accordance with the methods, the combination of surfactants i) and ii) is brought into contact with a process stream mixture existing in a corn to ethanol process.
    Type: Grant
    Filed: October 15, 2013
    Date of Patent: September 5, 2017
    Assignee: General Electric Company
    Inventors: Umit Turunc, Michael James Aucutt, Charles Sinko
  • Patent number: 9410109
    Abstract: Processes and systems are provided for effectively degumming vegetable oils with the use of an acid and base pretreated mixture of vegetable oil. The pretreated mixture is subjected to compression and one or more intervals of explosive decompression of the compressed mixture to form a degummed vegetable oil. Also provided are compression and decompression rates and conditions that can be used to effectively degum vegetable oil to achieve reduced levels of phosphorus and metals such as iron, calcium and magnesium.
    Type: Grant
    Filed: April 15, 2016
    Date of Patent: August 9, 2016
    Assignee: ARISDYNE SYSTEMS, INC.
    Inventor: Oleg Kozyuk
  • Patent number: 9321983
    Abstract: Processes and systems are provided for effectively degumming vegetable oils with the use of an acid and base pretreated mixture of vegetable oil. The pretreated mixture is subjected to compression and one or more intervals of explosive decompression of the compressed mixture to form a degummed vegetable oil. Also provided are compression and decompression rates and conditions that can be used to effectively degum vegetable oil to achieve reduced levels of phosphorus and metals such as iron, calcium and magnesium.
    Type: Grant
    Filed: July 3, 2014
    Date of Patent: April 26, 2016
    Assignee: ARISDYNE SYSTEMS, INC.
    Inventor: Oleg Kozyuk
  • Patent number: 9006474
    Abstract: A method for manufacturing a refined fat or oil, including: carrying out a first steam treatment of bringing a fat or oil into contact with water vapor; and subsequently carrying out a second steam treatment of bringing the fat or oil having a temperature lower by 10° C. or more than a temperature of the fat or oil in the first steam treatment into contact with water vapor in the presence of an organic acid.
    Type: Grant
    Filed: February 25, 2011
    Date of Patent: April 14, 2015
    Assignee: Kao Corporation
    Inventors: Shinpei Fukuhara, Minoru Kase, Tetsuya Abe, Toshiteru Komatsu, Keiji Shibata
  • Patent number: 8987487
    Abstract: The present invention relates to a method for removing phosphorus-containing compounds from triglyceride-containing compositions.
    Type: Grant
    Filed: October 13, 2011
    Date of Patent: March 24, 2015
    Assignee: Süd—Chemie IP GmbH & Co. KG
    Inventors: Ulrich Sohling, Friedrich Ruf, Andrea Stege
  • Patent number: 8841469
    Abstract: A method is provided for the use of a chemical additive to improve the separation of oil from the process stream (whole stillage, thin stillage or syrup) generated as a byproduct in corn to ethanol production.
    Type: Grant
    Filed: February 10, 2012
    Date of Patent: September 23, 2014
    Assignee: Solenis Technologies, L.P.
    Inventors: Paul W. Shepperd, McCord Pankonen, Jeffrey T. Gross
  • Patent number: 8802879
    Abstract: The invention describes process for demetallation of vegetable oils and animal fats to reduce metal content below 1 ppm to make them suitable for hydroprocessing feedstocks. The process comprises acid treatment with very low concentration of acids, utilizing synergistic effect of phosphoric acid and citric acid, followed by counter-current treatment with clay without intermediate step of water washing and treatment with ion exchange resin.
    Type: Grant
    Filed: July 4, 2011
    Date of Patent: August 12, 2014
    Assignee: Indian Oil Corporation Ltd.
    Inventors: Sarvesh Kumar, Ravi B. Kumar, Alok Sharma, Brijesh Kumar, Surbhi Semwal, Ajay Kumar Arora, Suresh Kumar Puri, Saeed Ahmed, Vivekanand Kagdiyal, Santanam Rajagopal, Ravinder Kumar Malhotra, Anand Kumar
  • Publication number: 20140171672
    Abstract: A method is for recovering lipids from algae, which comprises providing a biomass of a lipid-producing algae. The cell wall and/or cell membrane of said algae is ruptured by algal cytotoxin thereby releasing lipid from the cell, and recovering said lipid. An integrated system is for recovering lipids from lipid-producing algae cells.
    Type: Application
    Filed: April 2, 2012
    Publication date: June 19, 2014
    Applicant: NESTE OIL OYJ
    Inventors: Catherine LeGrand, Martin Olofsson
  • Publication number: 20140102157
    Abstract: A method for efficiently reducing water content of an object to be treated that contains water without requiring a high-temperature environment such as one exceeding the boiling point of water, and a method for efficiently extracting an oil-soluble substance from an object to be treated that contains water and the oil-soluble substance. A method for reducing water content of an object to be treated and/or extracting an oil-soluble substance in the object to be treated into oil is performed by mixing the object to be treated containing water or water and the oil-soluble substance with an oil at a temperature that is lower than the boiling point of water, at which temperature the oil is a liquid.
    Type: Application
    Filed: May 7, 2012
    Publication date: April 17, 2014
    Applicants: KIRISHIMA HIGHLAND BEER CO., LTD.
    Inventor: Masahiro Yamamoto
  • Publication number: 20140012025
    Abstract: The present invention relates to a method for removing phosphorus-containing compounds from triglyceride-containing compositions.
    Type: Application
    Filed: October 13, 2011
    Publication date: January 9, 2014
    Applicant: SUD -CHEMIE IP GmbH & CO.KG
    Inventors: Ulrich Sohling, Friedrich Ruf, Andrea Stege
  • Patent number: 8604228
    Abstract: A method for the continuous extraction of impurities, in particular saponification products, from a fatty acid alkyl ester phase produced by transesterification of vegetable or animal oils or fats with a great tendency to form saponification products, by means of an aqueous, acid glycerol phase containing a complexing agent.
    Type: Grant
    Filed: June 22, 2010
    Date of Patent: December 10, 2013
    Assignee: Lurgi GmbH
    Inventors: Rudolf Bönsch, Eckhard Seidel, Helmut Saft
  • Publication number: 20130302881
    Abstract: A method of producing a refined, bleached and deodorised vegetable oil comprises degumming a vegetable oil, bleaching the degummed oil and deodorising the bleached oil, wherein the degumming, bleaching and deodorising conditions are selected to reduce the content of 3-chloropropane-1,2-diol and esters thereof in the deodorised oil to less than 8 ppm.
    Type: Application
    Filed: October 12, 2011
    Publication date: November 14, 2013
    Applicant: LODER CROKLAAN B.V.
    Inventors: Krishnadath Bhaggan, Jeanine Luvelle Werleman
  • Publication number: 20130012734
    Abstract: A method for manufacturing a refined fat or oil, including: carrying out a first steam treatment of bringing a fat or oil into contact with water vapor; and subsequently carrying out a second steam treatment of bringing the fat or oil having a temperature lower by 10° C. or more than a temperature of the fat or oil in the first steam treatment into contact with water vapor in the presence of an organic acid.
    Type: Application
    Filed: February 25, 2011
    Publication date: January 10, 2013
    Applicant: KAO CORPORATION
    Inventors: Shinpei Fukuhara, Minoru Kase, Tetsuya Abe, Toshiteru Komatsu, Keiji Shibata
  • Publication number: 20120245371
    Abstract: The present invention generally concerns a treatment process for crude alkaline glycerol obtained as a by-product of transesterification reaction of natural oils and fats with lower alcohols. The present invention particularly concerns the treatment of crude alkaline glycerol obtained as a by-product of the biodiesel production from vegetable oils and animal fats using organic alkyl carboxylic acids or their aqueous solution, comprising the steps of: (a) acidification of the crude alkaline glycerol stock to pH in the range of about 4 to about 6, particularly 4 to 5, with organic alkyl carboxylic acids, in the presence of water in the range from about 5% to about 50%, particularly 15 to 30%, in weight with respect to the weight of the crude alkaline glycerol stock; (b) separating the formed free fatty acids, for instance by flotation; (c) removing the alcohol present in the acidified crude glycerol stock, for instance by distillation; (d) separating the acidic glycerol.
    Type: Application
    Filed: September 29, 2010
    Publication date: September 27, 2012
    Applicant: RHODIA POLIAMIDA E ESPECIALIDADES LTDA
    Inventors: Célio Ferraz Wagner Lourenco, Richard Macret, José Eduardo Cielo
  • Publication number: 20120245370
    Abstract: A method is provided for the use of a chemical additive to improve the separation of oil from the process stream (whole stillage, thin stillage or syrup) generated as a byproduct in corn to ethanol production.
    Type: Application
    Filed: February 10, 2012
    Publication date: September 27, 2012
    Applicant: HERCULES INCORPORATED
    Inventors: Paul W. Sheppard, McCord Pankonen, Jeffrey T. Gross
  • Patent number: 8258330
    Abstract: Carrier fluid compositions and their use in processes for reducing the concentration of persistent organic pollutants, such as polychlorodibenzo-p-dioxins (PCDDs), polychlorodibenzo-p-furans (PCDDF), polychlorinated biphenyls (PCBs), polybrominated diphenyl ethers (PBDEs), polycyclic aromatic hydrocarbons (PAHs), and pesticides, such as chlorinated hydrocarbons, chlorinated toxaphenes and camphenes, in fish oil are disclosed. The process includes vacuum distillation of the fish oil in the presence of the carrier fluid compositions to provide a fish oil residue having a reduced concentration of persistent organic pollutants.
    Type: Grant
    Filed: January 4, 2012
    Date of Patent: September 4, 2012
    Assignee: Naturalis, S.A.
    Inventors: Thomas Francis Harting Glade, Miguel Angel Fuenzalida Diaz, Alejandro Markovits Rojas
  • Publication number: 20120203017
    Abstract: A method for the continuous extraction of impurities, in particular saponification products, from a fatty acid alkyl ester phase produced by transesterification of vegetable or animal oils or fats with a great tendency to form saponification products, by means of an aqueous, acid glycerol phase containing a complexing agent.
    Type: Application
    Filed: June 22, 2010
    Publication date: August 9, 2012
    Applicant: LURGI GMBH
    Inventors: Rudolf Bönsch, Eckhard Seidel, Helmut Saft
  • Patent number: 8034963
    Abstract: The present invention relates to a process for cooling fatty acid distillate from scrubbing section in a fats and oils refinery comprising cooling the fatty acid distillate by heat recovery in at least one heat-exchanging zone with refined oils having a temperature above about 50° C. heating the refined fats and oils to a temperature above about 70° C. The present invention relates further to a process for refining crude fats and oils, and refining plant for refining crude fats and oils.
    Type: Grant
    Filed: February 9, 2007
    Date of Patent: October 11, 2011
    Assignee: Alfa Laval Corporate AB
    Inventor: Daniel Ng
  • Publication number: 20090306419
    Abstract: A system and method of degumming a plant derived oil comprising mixing a feed stream under ultrahigh shear conditions to provide a mixed stream, passing the mixed stream through a retention tank, and separating the mixed stream into an aqueous stream and an oil stream is disclosed. The feed stream comprises water, optional added acid(s), and triglyceride oil, such as a plant derived oil, having a relatively high phosphorous content and may also include metal impurities such as calcium, magnesium and/or iron ions. The process can provide a triglyceride oil stream with a phosphorous content of no more than about 10 to 20 ppm and no more than about 0.5 wt. % free fatty acids. In many instances, the triglyceride oil stream has phosphorous content which is no more than about 3% of the phosphorous content of the feed stream. The process also provides a wet gum stream, which may have an AI of 75 or higher.
    Type: Application
    Filed: February 23, 2007
    Publication date: December 10, 2009
    Applicant: CARGILL, INCORPORATED
    Inventors: K. Ko Myong, Kristopher T. Mortenson, Harapanahalli S. Muralidhara
  • Publication number: 20030050492
    Abstract: The present invention relates to improved methods for refining vegetable oils. Vegetable oil is combined with organic acid and subjected to high shear to finely disperse the acid solution in the oil. The resulting acid-and-oil mixture is mixed at low shear for a time sufficient to sequester contaminants into a hydrated impurities phase, producing a purified vegetable oil phase.
    Type: Application
    Filed: July 3, 2002
    Publication date: March 13, 2003
    Applicant: IP Holdings, L.L.C.
    Inventors: Dick Copeland, W. Maurice Belcher
  • Patent number: 6172248
    Abstract: The present invention relates to improved methods for refining vegetable oils and byproducts thereof. This invention also relates to an improved process for deodorizing lecithin. The invention additionally relates to deodorized lecithin and deodorized vegetable oil obtained by improved processes of the invention. In an organic acid refining process, vegetable oil is combined with a dilute aqueous organic acid solution and subjected to high shear to finely disperse the acid solution in the oil. The resulting acid-and-oil mixture is mixed at low shear for a time sufficient to sequester contaminants into a hydrated impurities phase, producing a purified vegetable oil phase. In a lecithin deodorizing process, a phosphatide concentrate is contacted with steam in a dryer operating at a pressure below 50 mm Hg and at a temperature of less than about 150° F. to form lecithin containing no more than about 0.5 percent by weight water.
    Type: Grant
    Filed: November 20, 1998
    Date of Patent: January 9, 2001
    Assignee: IP Holdings, L.L.C.
    Inventors: Dick Copeland, W. Maurice Belcher
  • Patent number: 6147237
    Abstract: Process for refining a triglyceride oil comprising stripping a triglyceride oil with an inert gas, characterized in that the refining process further comprises the preceding exposure of the triglyceride oil to an aqueous solution of ascorbic acid. Hydroperoxides are destroyed at a temperature <120.degree. C. and within one hour.
    Type: Grant
    Filed: March 2, 1998
    Date of Patent: November 14, 2000
    Assignee: Lipton, Inc.
    Inventors: Arend Zwanenburg, Marcho Stefanov Kouumdjiev, Jose Anibal Trujillo-Quijano
  • Patent number: 6103918
    Abstract: A process of producing glyceride oil having a very low content of non-hydratable phosphatides from fatty seeds and fruits is disclosed. In the process, the fatty material is instantaneously and for a very short time exposed to a high temperature at a controlled water content. The glyceride oil extracted from the thermally treated material has after water-degumming the same low contents of phosphorus, iron, calcium and magnesium as can be achieved by treatment with strong acid and alkali (superdegumming) of a conventionally produced glyceride oil.
    Type: Grant
    Filed: December 30, 1998
    Date of Patent: August 15, 2000
    Assignee: Karlshamns Crushing & Feed AB
    Inventor: Josef Dahlen
  • Patent number: 6015915
    Abstract: Process for degumming a fatty substance such as a crude or delecithinated, animal or vegetable oil or fat, including bringing this fatty substance into contact with an aqueous solution of a complexing agent and of a detergent and/or emulsifier making it possible to hydrate the phospholipids present in the latter, and fatty substance thus obtained.
    Type: Grant
    Filed: February 26, 1996
    Date of Patent: January 18, 2000
    Assignee: Fractionnement Tirtiaux S.A.
    Inventors: Said Jamil, Jean-Pierre Ghislain Dufour, Etienne Marie Joseph Deffense
  • Patent number: 5859270
    Abstract: A method of preparing a purified monoester composition is provided. The method generally involves a step of adding triglycerides to the crude monoester composition, with a follow up step of extracting into an alcohol/water phase, of the monoester to be purified. The process can be utilized to isolate and purify monoglycerides and propylene glycol monoesters, to advantage. The invention also concerns equipment for conduct of the processes, provision of preferred food additives, and provision of preferred food industry compositions.
    Type: Grant
    Filed: March 13, 1996
    Date of Patent: January 12, 1999
    Assignee: Cargill, Incorporated
    Inventors: Jeffrey John Kolstad, Richard D. Benson, Scott D. Bloomer, Paris Tsobanakis
  • Patent number: 5844111
    Abstract: A process for purifying an inert gas stream from a transesterification reaction wherein a lower alkyl alcohol is released during the reaction is claimed. A second use of the process is to make a lower alkyl, e.g., methyl, esters of fatty acids through a transesterification reaction using gaseous alcohols as a source of the lower alkyl alcohols. The alcohol is diluted with nitrogen or other inert gas carrier and reacted with a fatty acid ester, preferably a triglyceride, to form the corresponding methyl or lower alkyl fatty acid ester.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: December 1, 1998
    Assignee: The Procter & Gamble Company
    Inventors: Eric Paul Granberg, Richard Gerard Schafermeyer, James Anthony Letton
  • Patent number: 5362893
    Abstract: The present invention relates to a process for refining glyceride oil comprising a neutralization treatment in which alkali is mixed into crude or water degummed glyceride oil and a separation treatment in which the soapstock formed is separated from the glyceride oil by subjecting the oil to two centrifugal separators in series, in which at least 1 wt. % of the oil passes through both separators twice.
    Type: Grant
    Filed: March 4, 1993
    Date of Patent: November 8, 1994
    Assignee: N.V. Vandemoortele International
    Inventors: Joose R. L. Muylle, Albert J. Dijkstra, Pieter J. A. Maes, Martin Van Opstal
  • Patent number: 5278325
    Abstract: A vegetable oil process and assembly is disclosed for extracting oil from an oil bearing material such as soybean, corn and the like. The process comprises adding at least one reagent to the oil bearing material to form a slurry mixture. The slurry is heated at a preselected temperature for a preselected period of time preferably under a partial vacuum. This processing reduces the phospholipid and trace metal content in the oil extracted from the oil heating material. The oil product produced is light in color, shows no turbidity and exhibits minimal amount of phosphorus, calcium, magnesium and iron. The oil is ready for physical refining.
    Type: Grant
    Filed: July 30, 1990
    Date of Patent: January 11, 1994
    Inventors: Hans R. Strop, Richard R. Perry
  • Patent number: 5264599
    Abstract: A process is provided for treating an edible animal fat to reduce the content of components having free hydroxyl groups. The process comprises forming a reaction mixture from the fat and a cyclic anhydride such as succinic or glutaric anhydride, heating the mixture to a temperature promoting conversion of these components to hemisuccinates or hemiglutarates, and subjecting the reacted fat to alkali-refining to remove the converted components as water-soluble soaps. The process is particularly useful for reducing the cholesterol content of the animal fats.
    Type: Grant
    Filed: November 8, 1991
    Date of Patent: November 23, 1993
    Assignee: Iowa State University Research Foundation
    Inventors: Earl G. Hammond, Ying Chen
  • Patent number: 5239096
    Abstract: A method of removing gums which cannot be removed by simple water degumming from plant oils having the following steps:(a) adding to a plant oil containing gum substances not hydratable with water and wax substances, substantially 0.01 to 0.08% of a food acid or an acid anhydride of a food acid in a 5 to 15% solution thereof at a temperature of 20.degree. to 70.degree. C., intimately mixing the oil and the solution and causing the oil and the solution to remain in contact for a contact time in excess of 5 minutes with slow stirring;(b) to a mixture formed in step (a) adding a 1 to 5% solution of a base at a temperature of 10.degree. to 40.degree. C.
    Type: Grant
    Filed: August 22, 1991
    Date of Patent: August 24, 1993
    Assignee: Krupp Maschinentechnik GmbH
    Inventors: Herbert L. Rohdenburg, Karoly Csernitzky, Bela Chikany, Jozsef Peredi, Attila Borodi, Anna F. Ruzics