With Crystallization Or Precipitation (e.g., Separation According To Degree Of Saturation, Etc.) Patents (Class 554/208)
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Patent number: 12157780Abstract: Disclosed herein are process for removing color bodies from an organic solution comprising guayule resin. The processes include the use of activated carbon.Type: GrantFiled: December 19, 2019Date of Patent: December 3, 2024Assignee: Bridgestone CorporationInventors: Robert W. White, Michael R. Hartzell
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Patent number: 8957232Abstract: The invention relates to a method for the extraction of all unsaponifiable fraction contained in a vegetable oil, an oil originating from a micro-organism or a vegetable butter or in a co-product from the vegetable oil refining industry, such as deodorization discharge. The method includes at least: A) a step comprising the transformation of the aforementioned oils, butter or co-product from the vegetable oil refining industry or oils originating from micro-organisms into a hydro-alcoholic solution by means of, in particular, a step selected from saponification and esterification steps; B) a step comprising the extraction of the hydro-alcoholic solution in which the fatty fraction is separated from the unsaponifiable fraction by means of liquid/liquid extraction; and C) an optional step comprising the purification of the unsaponifiable fraction, selected from the group containing crystallization and liquid/liquid extraction steps.Type: GrantFiled: January 31, 2011Date of Patent: February 17, 2015Assignee: Laboratoires ExpanscienceInventors: Alex Saunois, Jacques Legrand, Eglantine Mercier
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Publication number: 20130261326Abstract: The invention relates to a procedure for stabilising polyunsaturated fatty acids with selective reducing agents. In particular, the invention relates to a process of preparation of polyunsaturated acids of the omega-3 series, as such or in the form of esters, which comprises treatment of fish oil or a mixture of acids with urea, and subsequent treatment with a metal hydride, preferably sodium borohydride. The polyunsaturated fatty acids of greatest interest present in fish oil are docosahexaenoic acid (DHA) and eicosapentaenoic acid (EPA).Type: ApplicationFiled: December 6, 2011Publication date: October 3, 2013Applicant: Prime European Therapeuticals S.p.A. in forma abbreviata EUTICALS S.p.A.Inventors: Giuseppe Guazzi, Lodovico Vezzoli
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Patent number: 8333811Abstract: This invention relates to a method for refining vegetable oils, in particular cottonseed oil or a possible mixture of it with others, as substitute of diesel fuel remarkable in that a sequence of treatment steps to be performed on crude vegetable oil, including: a) a pre-treatment thereof consisting of the removal of oil insoluble impurities from the crude oil, b) removal of oil soluble impurities therefrom, c) a free acid neutralization thereof, and d) a drying, bleaching and filtration thereof. This invention also relates to an Additive of organic basis, containing ether, ketone, toluene, hexane, turpentine, alcohols in specific concentrations.Type: GrantFiled: July 18, 2007Date of Patent: December 18, 2012Assignee: Aristotle University of Thessaloniki Research CommitteeInventor: Efstratios Hatziemmanouil
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Publication number: 20120269951Abstract: The present invention is based on the finding that stearin fats, obtainable by dry or solvent fractionation of sunflower high-stearic and high-oleic oils, optionally with seeding with tempered stearin crystals, have a high solid fat content at temperatures higher than 30° C., even higher than cocoa butter or other high saturated tropical fats with a similar disaturated triacylglycerol content due to the presence of disaturated triacylgiycerols rich in stearic acid, and improved melting point due to the presence of arachidic and behenic acids in these disaturated triacylgiycerols, being at the same time healthier that actual fats made from palm, palm kernel and coconut oils, or hydrogenated and trasesterified vegetable oils.Type: ApplicationFiled: October 21, 2010Publication date: October 25, 2012Applicant: Consejo Superior De Investigaciones Cientificas (CSIC)Inventors: Joaquín Jesús Salas Linan, Enrique Martinez Force, Miguel Angel Bootello García, Mónica Venegas Calerón, Rafael Garcés
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Patent number: 8246699Abstract: The processes of producing the low pour point palm diesel particularly but not exclusively via esterification of C18, C18:1 and C18:2 mixed fatty acids with methanol or ethanol, or fractional distillation of methyl or ethyl esters of palm oil, palm kernel oil and palm oil products, or fractional distillation of methyl or ethyl esters of palm oil, palm kernel oil and palm oil products, followed by crystallization, or crystallization of methyl or ethyl esters of palm oil, palm kernel oil and palm oil products, or crystallization of methyl or ethyl esters of palm oil, palm kernel oil and palm oil products, followed by fractional distillation.Type: GrantFiled: April 20, 2009Date of Patent: August 21, 2012Assignee: Malaysian Palm Oil BoardInventors: Choo Yuen May, Cheng Sit Foon, Yung Chee Liang, Harrison Lau Nik Nang, Ma Ah Ngan, Yusof Basiron
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Patent number: 7544822Abstract: The present invention relates to an improved and integrated process for the extraction and purification of tocotrienols or tocopherols, carotenoids and sterols from vegetable and other edible oils. Fatty acids in the vegetable oils are subjected to alcoholic osterification to form ester-rich layer that includes fatty acid alkyl esters, carotenoids, tocotrienols or tocopherols, and sterols. The advantages of this process are that the tocotrienols or tocopherols, carotenoids and sterols are produced efficiently without any substantial decomposition or degradation of these phytonutrients.Type: GrantFiled: November 18, 2004Date of Patent: June 9, 2009Assignee: Carotech Bhd.Inventor: David Sue San Ho
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Patent number: 7439377Abstract: An easy and inexpensive process by which a concentrate of a given unsaturated fatty acid can be obtained from a mixture which has conventionally been difficult to concentrate.Type: GrantFiled: March 16, 2007Date of Patent: October 21, 2008Assignee: The Nisshin OilliO Group, Ltd.Inventors: Hidetaka Uehara, Tomomi Suganuma, Satoshi Negishi
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Patent number: 7423163Abstract: An easy and inexpensive process by which a concentrate of a given unsaturated fatty acid can be obtained from a mixture which has conventionally been difficult to concentrate. The process, which is for producing a concentrate of a desired isomer (a) from a conjugated fatty acid mixture (A), is characterized by comprising: a step in which the conjugated fatty acid mixture (A) is mixed with at least one unsaturated fatty acid (B) to obtain a mixture solution containing the isomer (a) dissolved therein; a crystallization step in which either crystals rich in the isomer (a) or crystals poor in the isomer (a) are precipitated from the mixture solution; and a solid-liquid separation step for obtaining the crystals rich in the isomer (a) or for obtaining a solution rich in the isomer (a) by removing the crystals poor in the isomer (a).Type: GrantFiled: September 20, 2007Date of Patent: September 9, 2008Assignee: The Nisshin Oillio Group, Ltd.Inventors: Hidetaka Uehara, Tomomi Suganuma, Satoshi Negishi, Toshihisa Suzuki
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Publication number: 20080034646Abstract: A method of making a feedstock for a biodiesel fuel from an animal fat or oil includes the steps of heating and maintaining the animal fat or oil in a reaction vessel at a temperature of between 90-100° F., reacting and mixing a first polymer material with the animal fat or oil to coagulate the unsaponifiable portion within the reaction vessel, reacting and mixing a second polymer material with the coagulated reaction contents in the presence of a non-polar solvent to flocculate the unsaponifiable portion within the reaction vessel, and separating the unsaponifiable portion from the reaction vessel to provide a biodiesel fuel feedstock.Type: ApplicationFiled: August 7, 2007Publication date: February 14, 2008Inventor: Eric A. Franzoi
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Patent number: 7214379Abstract: Marigold oleoresin having a low viscosity and a high lutein content which can be filled in soft capsules can be obtained according to the method of the present invention, which is characterized by combining a step of subjecting oleoresin to supercritical fluid extraction and a step of dissolving oleoresin in a ketone solvent, cooling the solution and removing the ingredient which precipitated in solution.Type: GrantFiled: September 22, 2003Date of Patent: May 8, 2007Assignee: Riken Vitamin Co., Ltd.Inventors: Shin Sadano, Kazuhiro Fujiwara, Koichi Harada
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Patent number: 6846942Abstract: Pure DHA and pure EPA can be obtained from a mixture of EPA and DHA in a solution by forming salts of DHA and EPA which have different solubilities in the solvent, cooling the solution until the salt of EPA is formed, filtering the solution to recover the salt of EPA, and acidifying the EPA salt and the DHA salt to obtain pure EPA and pure DHA.Type: GrantFiled: May 20, 2003Date of Patent: January 25, 2005Inventor: David Rubin
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Patent number: 6841692Abstract: The present invention provides a method for separating a saturated fatty acid and an unsaturated fatty acid from a mixture of fatty acids by a dry fractionation process with a superior efficiency. Namely, the present invention provides a method for producing a saturated fatty acid or an unsaturated fatty acid comprising a dry fractionation process to fractionate a saturated fatty acid and an unsaturated fatty acid in a raw fatty acids mixture by adding a polyglycerol ester of fatty acid to the raw fatty acids mixture, wherein the polyglycerol ester of fatty acid has a clear melting point (y) satisfying the following formula (1): 0.38x+13?y?0.54x+44??(1) wherein x is a ratio (% by mass) of saturated fatty acids (C12 to C22) in raw fatty acids, and y is a clear melting point (° C.) of a polyglycerol ester of fatty acid.Type: GrantFiled: June 5, 2003Date of Patent: January 11, 2005Assignee: Kao CorporationInventors: Minoru Kase, Eizo Maruyama, Hiroaki Yamaguchi
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Patent number: 6825368Abstract: The present invention provides a method for producing a saturated fatty acid and an unsaturated fatty acid, which comprises adding and mixing a polyglycerol ester of a fatty acid to a raw fatty acids mixture, cooling the resultant mixture to deposit crystals, and fractionating the saturated fatty acid and the unsaturated fatty acid, wherein a cooling procedure is performed at a cooling rate of 4° C./h or less when a supersaturation ratio is 60% or more and said cooling rate is varied during the cooling, and a glycerides mixture obtained from the fractionated unsaturated fatty acids. According to the present invention, a saturated fatty acid and an unsaturated fatty acid in a raw fatty acids mixture can be separated easily and efficiently by a dry fractionation process.Type: GrantFiled: July 9, 2003Date of Patent: November 30, 2004Assignee: Kao CorporationInventors: Minoru Kase, Keiji Shibata, Eizo Maruyama
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Patent number: 6759543Abstract: The invention concerns a method for extracting usaponifiable matters from a vegetable oil comprising at least a saponification step whereby the oil is transformed into a hydro alcoholic solution, a step for extracting the hydro alcoholic solution with a organic solvent such as chloro-1-butane, preferably the treated vegetable oil is avocado or soya oil.Type: GrantFiled: July 12, 2002Date of Patent: July 6, 2004Assignee: Laboratoires ExpanscienceInventors: Sandrine Bardet, Jacques Legrand, Antoine Piccirilli
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Patent number: 6552208Abstract: The invention refers to a process for fractionating a vegetable oil giving one or more solid fractions suitable for confectionary applications as well as a liquid fraction rich in unsaponifiable biologically active components. The liquid fractions of shea butter and rapeseed oil having a high content of phytosterols and tocoferols, respectively, are useful for cosmetical and pharmaceutical preparations.Type: GrantFiled: January 18, 2001Date of Patent: April 22, 2003Assignee: Karlshamns ABInventors: Jari Alander, Ann-Charlotte Andersson, Håkan Malmros, Jörgen Nilsson
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Patent number: 6369251Abstract: A method for purification of a polyprenyl compound, which comprises the step of recrystallizing a polyprenyl compound, preferably (2E, 4E, 6E, 10E)-3,7,11,15-tetramethyl-2,4,6,10,14-hexadecapentaenoic acid by using a solvent comprising an alcohol.Type: GrantFiled: April 21, 2000Date of Patent: April 9, 2002Assignee: Nikken Chemicals Co., Ltd.Inventors: Michika Takano, Noriaka Gomi
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Publication number: 20020035284Abstract: A process for the purification and isolation of a chemical compound, by extractive solution crystallization. The process comprises combining in any order a first solvent, a second solvent, and a mixture comprising a chemical compound with at least one impurity. The second solvent phase extracts impurities out of the first solvent, and keeps the impurities dissolved to avoid their co-crystallization with the phenyl ester salt. Once the chemical compound has crystallized out of solution, it is collected, washed and/or dried. The second solvent may be added after the mixture containing at least one chemical compound is dissolved in a first solvent, as long as the second solvent phase is added prior to the end of crystallization. Advantageously, this invention combines the previously distinct steps of extraction and crystallization in one unit operation.Type: ApplicationFiled: June 1, 2001Publication date: March 21, 2002Inventor: Kevin J. Fontenot
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Patent number: 6265595Abstract: A method of solvent fractionation of a fat by which a high fat concentration, a rise in refrigerant temperature, and a reduction in operation time, etc. can be attained and fractions are efficiently produced at a low cost, characterized by rapidly cooling a feedstock fat dissolved in a solvent to a temperature higher by 1 to 20° C. than the crystallization temperature used in a crystallizer in the step prior to introduction of the feedstock fat into the crystallizer.Type: GrantFiled: March 30, 2000Date of Patent: July 24, 2001Assignee: Fuji Oil Company, LimitedInventors: Atsushi Taniguchi, Shin Yoneda, Yuji Kuwabara, Tokisane Kajiyama
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Patent number: 5952518Abstract: A method for efficiently removing saturated fatty acids from a fatty acid mixture is provided by adding an emulsifying agent to a feedstock fatty acid mixture, mixing and then cooling the mixture, and removing the crystallized portion by dry fractionation, and the use of the obtained reduced saturated fatty acid level mixture to produce fatty acid esters resistant to crystallization at low temperatures.Type: GrantFiled: April 30, 1998Date of Patent: September 14, 1999Assignee: Kao CorporationInventors: Masakatsu Sugiura, Minoru Kase
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Patent number: 5849940Abstract: The invention concerns a fractionation process for the production of triglycerides with at least 12 wt % SSU (S=saturated fatty acids; U=unsaturated fatty acids) by subjecting a fat with at least 5 wt % SSU to a fractionation, achieving an enrichment factor fo the SSU enrichment of at least 1.Type: GrantFiled: September 10, 1997Date of Patent: December 15, 1998Assignee: Loders-Croklaan B.V.Inventors: John Bernard Harris, Stephen Raymond Moore, Christopher Rawlings
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Patent number: 5602265Abstract: Process for triglyceride oil fractionation using a crystallisation modifying substance which isi. a copolymer having subunits A and B of which subunit A is derived from maleic acid or itaconic acid and subunit B is derived from vinyl alcohol, alkyl substituted vinyl alcohol, acrylic acid or styrene, A and B being present in a ratio of 10:1 to 1:10, where 5-100% of the the maleic acid or itaconic acid subunits are connected to unbranched (C8-C24)-alkyl chains and where 0-100% of the vinyl alcohol or alkyl substituted vinyl alcohol or acrylic acid subunits are connected to unbranched (C1-C8)-alkyl chains and whereii. inulin or phlein of which 5-100% of the hydroxyl groups on the fructose subunits are connected to (C8-C24) unbranched alkyl chains and 0-95% of the hydroxyl groups have been esterified with a (C1-C8)-alkyl containing fatty acid, preferably acetic acid.Type: GrantFiled: July 19, 1994Date of Patent: February 11, 1997Assignee: Van den Bergh Foods Co., Division of Conopco, Inc.Inventors: Marcelle van den Kommer, Paul R. Smith, Adrianus Visser, Cornelis Winkel, Deryck Cebula
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Patent number: 5556972Abstract: The invention relates to a method for dry fractionation of fatty substances by a counter current dry fractionation operation, comprising at least two dry fractional crystallization treatments;a first dry fractional crystallization treatment comprising the steps of:1a) dry fractionating by crystallization the fatty substances into a higher melting first stearin fraction and a lower melting first olein fraction;1b) separating the first stearin fraction from the first olein fraction by membrane filter pressing; and1c) feeding the separated first olein fraction to a second dry fractional recrystallization treatment; anda second dry fractional crystallization treatment comprising the steps of:2a) dry fractionating by crystallization the first olein fraction into a higher melting second stearin fraction and a lower melting second olein fraction;2b) separating the second stearin fraction from the second olein fraction by membrane filter pressing; and2c) feeding the separated second stearin fraction to the first dryType: GrantFiled: June 6, 1995Date of Patent: September 17, 1996Assignee: Van den Bergh Foods Co., Division of Conopco, Inc.Inventors: Cornelis N. M. Keulemans, Christiaan E. Van den Oever
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Patent number: 5399730Abstract: This invention relates to a purified wool fat essentially free from low molecular weight volatile acids, water soluble aliphatic alcohols and water. This purified wool fat is produced by effecting the esterification of free alcohols and fatty acid contained in the wool fat followed by solvent extraction and chromatographical purification of the extracted solvent. The purified wool fat can be used as a lubricant enhancer in lubricating oils.Type: GrantFiled: August 1, 1991Date of Patent: March 21, 1995Assignee: Development Products, Inc.Inventors: Boris I. Koupchinov, Viktor P. Parkalov, Vladimir G. Rodnenkov, Sergey F. Ermakov, Vitaly G. Tischenco, Lenoid A. Sarkisov, Feliks E. Gulijaev, Vladimir N. Kestelman, Anatoly I. Sviridenok
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Patent number: 5210241Abstract: This invention relates to a process of preparing Cocoa Butter Equivalent (CBE) from Chinese Vegetable Tallow (CVT) and to the product prepared. Crude CVT is first subjected to a semi-refining process comprising an alkali treatment, a water wash and an adsorption step. The semi-refined CVT is subjected to a single step fractional crystallization under controlled conditions. After removal of the solvent from the crude CBE found in the mother liquor after filtration, the crude CBE is subjected to a steam distillation process, addition of antioxidants and a final filtration. The resulting product meets all of the criteria necessary for Cocoa Butter Equivalent.Type: GrantFiled: January 3, 1992Date of Patent: May 11, 1993Inventor: Yitian Lin