Abstract: A reactor for a mixture of fluids that can react with each other exothermically, the reactor combining the properties of heat transfer and porosity, and having a first chamber wherein reacted fluids are maintained above the reaction temperature threshold, a second chamber disposed adjacent to the first chamber, wherein unreacted fluids enter the second chamber at a temperature that is below a reaction temperature threshold that is necessary for reaction of the fluids to occur, the fluids flowing in a second direction, opposite the first direction and a porous wall disposed between the first chamber and a second chamber, allowing portions of the unreacted fluids from the second chamber to seep into the reacted fluids of the first chamber, thereby heating the seeped fluids, causing the seeped fluids to react, the reaction increasing the temperature of the reacted fluid.

Abstract: A method for making a lithium battery cathode composite is provided. A mixed solution including a solvent, an iron salt, and a phosphate is provided. An alkaline solution is added in the mixed solution until the mixed solution has a pH value in a range from about 1.5 to about 5. The mixed solution is stirred to react the iron salt with the phosphate to form a number of iron phosphate precursor particles. The iron phosphate precursor particles are heated. A lithium source solution, a reducing agent, and the iron phosphate precursor particles are mixed to form a lithium iron phosphate precursor slurry. Outer surfaces of the lithium vanadium phosphate particles are coated with the lithium iron phosphate precursor.

Abstract: A process for the production of olefins from at least one of an alcohol and ether, the process including: contacting at least one alcohol or ether with a hydrofluoric acid-treated amorphous synthetic alumina-silica catalyst under decomposition conditions to produce an olefin.

Abstract: Herein disclosed is a reactor comprising a housing; an inlet tube having a section with perforations along its length, wherein the inlet tube section is within the reactor housing; an outlet tube having a section with perforations along its length, wherein the outlet tube section is within the reactor housing; and at least one cylinder made of sintered metal contained within the reactor housing, wherein the sintered metal is catalytically active. In some cases, the sintered metal in the reactor comprises a porous metallic multifunctional (PMM) catalyst. Other reactor designs and the method of use are also described herein.

Abstract: A method for making a lithium battery cathode material is disclosed. A mixed solution including a solvent, an iron salt material, and a phosphate material is provided. An alkaline solution is added into the mixed solution until the mixed solution has a pH value ranging from about 1.5 to 5. The iron salt react with the phosphate material to form a plurality of iron phosphate precursor particles which are added in a mixture of a lithium source solution and a reducing agent to form a lithium iron phosphate precursor slurry. The lithium iron phosphate precursor slurry is heat-treated.

Abstract: A process for preparing ?-sulpho-fatty acid ester salt surfactant comprises: (1) sulphonating a fatty acid ester with SO3 to produce a crude sulphonic acid, (2) bleaching the crude sulphonic acid from step (1) with hydrogen peroxide; (3) secondarily esterifying the product from step (2) with alcohol; (4) neutralizing the product from step (3) with an alkali solution; and (5) drying the product from step (4) to powder.

Abstract: A process for preparing an ?-sulpho-fatty acid ester salt surfactant comprises: (1) sulphating a fatty acid ester with SO3 to produce a crude sulphonic acid, (2) bleaching the crude sulphonic acid from step (1) with hydrogen peroxide; (3) secondaryary esterifying the product from step (2) with alcohol; (4) neutralising the product from step (3) with an alkali solution; and (5) drying the product from step (4) to powder.

Abstract: A process for producing powder, flakes, or pellets containing ?-sulfo fatty acid alkylester salt in high concentrations, the process including: (1) a step of preparing a paste containing ?-sulfo fatty acid alkylester salt; (2) a step of aging the thus obtained paste; (3) a step of making the aged paste into flakes or pellets containing equal to or less than 10 wt % of water and then optionally crushing the resulting flakes or pellets into a powder having an average particle diameter of 100-1500 ?m; and (4) a step of aging The powder, flakes, or pellets.

Abstract: A process for the production of alpha-sulfonated polyhydric esters (ASPA) is disclosed using starting materials derived from palm oil or palm kernel oil. The process involves reacting saturated alkyl carboxylic acids or, alkyl esters with sulfonating agent, such as gaseous SO3 followed by reaction with stoichiometric amount of polyhydric alcohols. The resultant product may be bleached with bleaching agent, such as H2O2 and neutralised with an aqueous base to produce water soluble alpha-sulfonated polyhydric alcohol ester salt (ASPA). The product is obtained with good color and yield. This process is more efficient as it requires only stoichiometric amounts of reagents, and can reduce the formation of undesirable by-product such as sodium sulfonated soaps.

Abstract: A method of producing fatty acid polyglycol ester sulfates of the general formula (I): R1COO(AO)nSO3M  (I) is disclosed, wherein R1CO represents a linear or branched, aliphatic, saturated and/or unsaturated acyl radical with 6 to 22 carbon atoms, AO represents CH2CH2O, CHCH3CH2O and/or CH2CHCH3, n represents a number from about 0.5 to about 5 and M represents a cation. The disclosed process comprises the sulfation of fatty acid polyglycol esters followed by neutralization, wherein the neutralization is carried out at a pH of from about 5 to about 9.

Abstract: Compositions of matter comprising fatty acid esters of hydroxyalkyl sulfonate salts, in particular sodium cocoyl isethionate (SCI) and process for preparing same. The esters are useful for personal care cleansing products, such as bar and liquid soaps, skin and hair care products.

Abstract: Process for the preparation of a tenside mixture, wherein a starting mixture containing an alkali metal salt of an alkyl sulfonic acid is treated with a concentrated sulfuric acid solution in an amount in excess of the amount needed for converting the salts to organic acids with stirring and cooling such that the temperature of the mixture does not exceed about 35.degree. C., the reaction mixture being allowed to separate into two layers, one layer containing the organic acids, wherein the one layer containing the organic acids is separated and neutralized with di- or triethanolamine in order to prepare di- or triethanolamine salts of the said acids.

Abstract: An process for forming a product which may be in a liquid phase is disclosed wherein a first reactant, preferably a liquid reactant, is directly fed into a reaction zone containing mixing elements and which comprises a first compartment of a reactor. A second reactant, which is maintained at a higher pressure, is fed into a second compartment of the reactor separated from the first compartment by a porous wall. The second reactant passes through this porous wall into the reaction zone to react with the first reactant. The process thereby controls rates of the reactions and the exothermic heats generated by the reactions. Pulsatile flow in one or both reaction compartments improves mixing. An evaporator for a portion of the product improves product quality and permits higher reaction temperatures in the reactor.

Abstract: An improved, no -bleach process for the production of sulfonated fatty acid alkyl ester surfactants containing sulfonated fatty acid alkyl esters and less than 10% of sulfonated fatty acid disalt, fatty acid salt (soap), and fatty acid alkyl ester impurities, said process comprising sulfonating fatty acid alkyl esters, reacting with a C.sub.1 to C.sub.8 alcohol, and continuously neutralizing with an alkoxide in a substantially anhydrous medium of a C.sub.1 to C.sub.

Abstract: A method of imparting low fogging characteristics to tanned leather, which includes the step of treating the leather in an aqueous emulsion including an effective quantity of an oil having less than 3 percent of fatty acid components of less than C-16, the oil having been first distilled to remove low molecular weight trace elements. The oil may be by way of example soybean oil, lard oil, safflower oil, or sunflower oil.

Abstract: A sulfonation process includes the process steps of air sulfonating a fatty acid alkyl ester feedstock, bleaching the crude product with co-addition of up to about 40 wt. % of an alcohol based upon the weight of the crude product. The bleaching/alcohol addition step of the process is performed in a nonmetallic or low-iron alloy system at temperatures above 90.degree. C. The resulting product is then neutralized with a liquid base or metal carbonate.

Abstract: An exothermic process for forming a product which may be in a liquid phase is disclosed wherein a first reactant, preferably a liquid reactant, is directly fed into a reaction zone containing mixing elements and which comprises a first compartment of a reactor. A second reactant, which is maintained at a higher pressure, is fed into a second compartment of the reactor separated from the first compartment by a porous wall. The second reactant passes through this porous wall into the reaction zone to react with the first reactant. The process thereby controls rates of the reactions and the exothermic heats generated by the reactions. Pulsatile flow in one or both reaction compartments improves mixing. An evaporator for a portion of the product improves product quality and permits higher reaction temperatures in the reactor.

Abstract: Chemical synthesis of amido acids, and their conversion to amido acid phenyl ester sulfates for use as bleach activators, starting from carboxylic acids and lactams.

Abstract: The invention is a process for hydrophilicizing a mixture of triglycerides and glycerol by ethoxylation of the mixture followed by sulfonation with sulfur trioxide and neutralization.

Abstract: A process for improving the color and purity of dark-colored potassium or magnesium alkyl ester sulfonate surfactant compositions, and particularly alpha-sulfo fatty acid methyl ester compositions, without the need for bleaching or other process steps. The process comprises the steps of (1) forming a mixture comprising (i) an alkyl ester sulfonate surfactant composition containing impurities including dark-colored impurities, organic and inorganic salts, and disalts, and (ii) water, and (2) separating the ester sulfonate surfactant from the mixture. The process may further comprise step (3) recovering the alkyl ester sulfonate surfactant. Methyl ester sulfonate surfactant compositions are most preferred. After processing in accordance with the invention, the alkyl ester sulfonate surfactant composition has improved color, purity, and odor properties.

Abstract: In the production of light-colored pastes of .alpha.-sulfofatty acid alkyl ester alkali metal salts by reaction of fatty acid alkyl esters with gaseous SO.sub.3, subsequent after-reaction in liquid phase, neutralization with aqueous alkali metal hydroxide solutions and bleaching, effective bleaching can be obtained without any reduction in the washing-active substance content by addition of the hydrogen peroxide during neutralization of the .alpha.-sulfofatty acid alkyl ester and subjecting the neutralization product obtained to a temperature-controlled after-reaction.

Abstract: In the production of highly concentrated pastes of .alpha.-sulfofatty acid alkyl ester alkali metal salts by reaction of fatty acid alkyl esters with gaseous SO.sub.3, subsequent after-reaction in liquid phase and neutralization with aqueous alkali hydroxide solutions, the sulfonation product and aqueous alkali metal hydroxide solution are introduced during neutralization into an aqueous phase initially containing 0 to 55% by weight washing-active substance at a pH value in the range from 2 to 8 and washing-active substance contents of 60 to 70% by weight are established.

Abstract: The present invention relates to derivatives of natural fats and oils that are liquid or flowable, respectively, and to a process for the production of said derivatives, in which oxalkylation is carried out at elevated temperatures in the presence of basic catalysts with at least one compound containing an epoxide group, and sulfation is carried out in a manner known per se, in which a starting material containingA) at least one C.sub.8 -C.sub.24 -fatty acid ester of an aliphatic C.sub.1 -C.sub.5 -monoalcoholThe present invention furthermore relates to the use of said derivatives, optionally in combination with other greasing substances and anionic and/or non-ionic emulsifiers, for the fatliquoring and greasing of leather.

Abstract: Light-colored ester sulfonates can be obtained by sulfonation of fatty acid lower alkyl esters and subsequent working up providing fatty acid esters having a low content of oxo compounds and unsaturated compounds are used in the sulfonation stage.

Abstract: In the production of .alpha.-sulfofatty acid alkyl ester alkali metal salt pastes by reaction of fatty acid alkyl esters with gaseous SO.sub.3, subsequent after-reaction in liquid phase and neutralization with aqueous alkali metal hydroxide solutions, the crude sulfonation product is fed to an at least two-stage cascade of stirred tanks equipped with heating and cooling systems in which it is subjected with mechanical agitation to a temperature-controlled after-reaction until a degree of sulfonation of at least 90% is reached, after which the aged sulfonation product is further processed in known manner to .alpha.-sulfofatty acid alkyl ester alkali metal salt pastes.

Abstract: In the production of highly concentrated pastes of .alpha.-sulfofatty acid alkyl ester alkali metal salts by reaction of fatty acid alkyl esters with gaseous SO.sub.3, subsequent after-reaction in liquid phase and neutralization with aqueous alkali hydroxide solutions, the sulfonation product and aqueous alkali metal hydroxide solution are introduced during neutralization into an aqueous phase initially containing at least 55% by weight washing-active substance at a pH value in the range from 2 to 8 and washing-active substance contents of 60 to 70% by weight are established.

Abstract: The invention relates to a process for the production of concentrated mono- and/or disalt dispersions of .alpha.-sulfofatty acids by sulfonation of saturated fatty acids and/or fatty acid mixtures with sulfur trioxide, surfactants being added during the neutralization stage to improve the flowability of the dispersions.

Abstract: Process for the production of aqueous solutions of alkali metal, alkaline earth metal, ammonium and/or amine salts of sulfonated fatty acid glycerides by sulfonation of unsaturated fatty acid glycerol esters with gaseous sulfur trioxide, neutralization with aqueous bases and subsequent heating with phase separation, and to the aqueous solutions produced thereby.

Abstract: Polyhydroxy fatty acid amide nonionic surfactants are converted in high yields to their sulfated analog surfactants using an SO.sub.3 /pyridine complex as a sulfating agent. Thus, C.sub.12 -C.sub.18 N-methyl glucamide is sulfated in methylene chloride or pyridine solvent to form the corresponding sulfated glucamide in yields of 80% or higher.

Abstract: To obtain highly sulfated fatty acids, hydroxy fatty acids or oxalkylated hydroxy fatty acids, the reaction mixture obtained from the sulfatation of unsaturated fatty acid esters and/or saturated hydroxy fatty acid ester and/or oxalkylated hydroxy fatty acid esters is neutralized, optionally separated from the brine, diluted with water and hydrolyzed at a temperature between 20.degree. C. and 160.degree. C. after addition of lye the amount of which at maximum is equivalent to the organically bonded sulfuric acid content. After phase separation from the non-sulfated starting products, the highly sulfated fatty acids are isolated from the aqueous phase.

Abstract: Silica-aluminas having a sodium content less than about 0.1 weight percent show increased stability when used as a catalyst for the alkylation of aromatic compounds. Where such silica-aluminas are used as the catalyst in detergent alkylation their increased stability permits continuous alkylation to be performed at lower temperatures, as a result of which the detergent alkylate product shows an incrementally higher linearity. Fluorided silica-aluminas having a sodium content of under 0.05 weight percent are particularly advantageous.

Abstract: A process for the preparation of light-colored oleic acid sulfonates by continuous sulfonation of an industrial oleic acid having an oleic acid content of 65 to 85% by weight and a linoleic acid content of up to 13% by weight with gaseous sulfur trioxide in a molar ratio of industrial oleic acid to sulfur trioxide of 1 : 0.8 to 1 : 1.0, neutralization and hydrolysis of the acid sulfonation product with aqueous bases and bleaching of the neutralized and hydrolyzed sulfonation product give oleic acid sulfonates having Klett color numbers of not more than 100.

Abstract: An improved process for preparing alkanoyloxyacetyloxybenzenesulfonate salts in which phenyl esters of alkanoyloxyacetic acids (alkanoyloxyacetyloxybenzenes) are sulfonated to yield novel alkanoyloxyacetyloxybenzenesulfonic acids which, on neutralization, yield the corresponding alkanoyloxyacetyloxybenzenesulfonate salts.