Chalcogen Bonded Directly To The Metal Patents (Class 556/122)
  • Patent number: 8772523
    Abstract: The invention generally relates to chain shuttling agents (CSAs), a process of preparing the CSAs, a composition comprising a CSA and a catalyst, a process of preparing the composition, a processes of preparing polyolefins, end functional polyolefins, and telechelic polyolefins with the composition, and the polyolefins, end functional polyolefins, and telechelic polyolefins prepared by the processes.
    Type: Grant
    Filed: November 2, 2012
    Date of Patent: July 8, 2014
    Assignee: Dow Global Technologies LLC
    Inventors: Thomas P. Clark, Nahrain E. Kamber, Sara B. Klamo, Phillip D. Hustad, David R. Wilson
  • Publication number: 20120308823
    Abstract: A technique for bonding an organic group with the surface of fine particles such as nanoparticles through strong linkage is provided, whereas such fine particles are attracting attention as materials essential for development of high-tech products because of various unique excellent characteristics and functions thereof. Organically modified metal oxide fine particles can be obtained by adapting high-temperature, high-pressure water as a reaction field to bond an organic matter with the surface of metal oxide fine particles through strong linkage. The use of the same condition enables not only the formation of metal oxide fine particles but also the organic modification of the formed fine particles. The resulting organically modified metal oxide fine particles exhibit excellent properties, characteristics and functions.
    Type: Application
    Filed: June 27, 2012
    Publication date: December 6, 2012
    Inventor: Tadafumi Ajiri
  • Patent number: 6790972
    Abstract: The invention relates to new compounds having an element of group 12 and having a tridentate ligand, a process for their preparation and their use in particular as a polymerization catalyst.
    Type: Grant
    Filed: December 20, 2001
    Date of Patent: September 14, 2004
    Assignees: Societe de Conseils de Recherches et d'Applications Scientifiques (S.C.R.A.S.), Centre National de la Recherche Scientifique (C.N.R.S.)
    Inventors: Hanh Nguyen Ngoc, Heinz Gornitzka, Blanca Martin-Vaca, Didier Bourissou, Guy Bertrand, Jean-Bernard Cazaux
  • Patent number: 6781007
    Abstract: The invention relates to a process for preparing partial hydrolysates of organometallic compounds and to a process for preparing partial hydrolysates of organometallic compounds, in particular alkylaluminoxanes, or transition metal catalysts immobilized on inert support materials and also to the products prepared by this process.
    Type: Grant
    Filed: December 11, 2002
    Date of Patent: August 24, 2004
    Assignee: Crompton GmbH
    Inventors: Rainer Rieger, Ralf Alexander Wendt, Thomas Wanke
  • Patent number: 6770588
    Abstract: A reductive system including a silane, preferably PMHS, and an active zinc compound, which is monomeric and not a hydride, wherein a reduction of a carbonyl substrate to a corresponding alcohol is achievable.
    Type: Grant
    Filed: January 16, 2003
    Date of Patent: August 3, 2004
    Assignee: Firmenich SA
    Inventor: Hubert Mimoun
  • Publication number: 20030225223
    Abstract: It is an object of the present invention to provide a dimer diol derivative and a composition containing the dimer diol derivative which have an excellent water-holding property, an excellent pigment dispersion property and further a high level of safety.
    Type: Application
    Filed: March 28, 2003
    Publication date: December 4, 2003
    Applicant: Croda Japan KK
    Inventors: Takeshi Koresawa, Yasuhiro Shiren, Isamu Noda, Hiroyuki Tanabe, Mie Noda, Akio Otera
  • Patent number: 6448314
    Abstract: The subject of the present invention is the use of zinc ateylacetonate comprising at least 4.4% by weight of water as halogenated polymer stabilizer. Its subject is likewise a process for the preparation of zinc acetylacetonate monohydrate, in which a zinc oxide and/or hydroxide and acetylacetone are brought into contact, in the presence of a solvent; the said solvent being used with a quantity of between 20 and 200 parts by weight, per 100 parts by weight of acetylacetone.
    Type: Grant
    Filed: November 17, 2000
    Date of Patent: September 10, 2002
    Assignee: Rhodia Chimie
    Inventor: Francoise Henrio
  • Patent number: 5977371
    Abstract: The instant invention provides a homologation process for making a zincate homoenolate from a carbon bound enolate zincate, by treating the carbon bound enolate zincate with an alkoxy lithium reagent. The homologation step can be coupled with a homoaldol reaction, as well as with other transmetallation reactions, in a one pot process. The zincate homoenolate is a useful intermediate in the preparation of a variety of different end-products, such as HIV protease inhibitors and renin inhibitors.
    Type: Grant
    Filed: November 12, 1997
    Date of Patent: November 2, 1999
    Assignee: Merck & Co., Inc.
    Inventors: Joseph D. Armstrong, III, J. Christopher McWilliams
  • Patent number: 5264243
    Abstract: This invention provides a process for deacidifying paper by contacting the paper one or more times with hydrocarbon or halocarbon solutions of certain magnesium and/or zinc alkoxyalkoxides which may have been treated with carbon dioxide to yield low viscosity solutions, drying the books and rehydrating the books.
    Type: Grant
    Filed: June 16, 1992
    Date of Patent: November 23, 1993
    Assignee: FMC Corporation
    Inventors: Robert S. Wedinger, Conrad W. Kamienski, Kent N. Smith, George R. Sandor, A. Revonda Porch, Sharon B. Smith
  • Patent number: 5157136
    Abstract: The present invention relates a precursor metal organic compound of the formula:(R.sub.3 --Si).sub.3 --Y--Q--M--A (I)wherein M is selected from the Group IIb elements of zinc, cadmium, or mercury;A is selected from amide, alkyl having from 1 to 10 carbon atoms, aryl, substituted aryl, or --Q'--Y'--(Si--R'.sub.3).sub.3 L.sub.2 wherein L is selected from nothing or a Lewis base ligand,Q and Q' are each independently selected from Group VIa elements of sulfur, selenium, or tellurium; andY and Y' are each independently selected from carbon, silicon, germanum and tin, andR and R' are each independently selected from alkyl having from 1 to 10 carbon atoms, aryl or substituted aryl.In a preferred embodiment, A is --Q'--Y'--(Si--R'.sub.3)L.sub.2 where L is nothing or a Lewis base ligand, especially wherein Q.dbd.Q', Y.dbd.Y' and R.dbd.R'. Methods of producing these compounds are also disclosed.
    Type: Grant
    Filed: April 9, 1991
    Date of Patent: October 20, 1992
    Assignee: Regents of the University of California
    Inventors: John Arnold, Phillip J. Bonasia
  • Patent number: 5091547
    Abstract: A pharmaceutical phenylacetic acid derivative of the following formula (I): ##STR1## with the process of obtention which includes reacting 2-(2,6-dichloroaniline)-phenylacetic acid with zinc oxide, zinc hydroxides, zinc carbonates or zinc salts or reacting an ammonium salt, an alkali metal salt or an alkaline earth metal salt of 2-(2,6-dichloroaniline)-phenylacetic acid with a zinc salt, e.g. zinc chloride, in a nonpolar solvent. The compound of formula I is novel and has improved pharmaceutical properties in anti-inflammatory preparations.
    Type: Grant
    Filed: May 17, 1990
    Date of Patent: February 25, 1992
    Assignee: Laboratorias Vinas, S.A.
    Inventor: Antonio Buxade
  • Patent number: 5028725
    Abstract: This invention relates to novel compounds which are precursors for di- and triarylmethane dye precursor compounds possessing a thiolactone, dithiolactone or thioether ring-closing moiety.
    Type: Grant
    Filed: December 7, 1989
    Date of Patent: July 2, 1991
    Assignee: Polaroid Corporation
    Inventor: Patrick F. King
  • Patent number: 4931577
    Abstract: The novel antiseptic mercurial derivatives according to the invention have at least one benzene ring and comprise: a) at least one radical HgX in which X is selected from F,Cl,Br, I, OH, CH.sub.3 COO, CN, SCN, NO.sub.3, OB(OH).sub.2, b) and, bonded to a benzene ring, at least one group--OR or--COOR in which R is a functional group capable of intervening in a reaction of polymerization or of polyaddition. The preferred derivative is 2-chloromercuri 4-tertiobutyl phenol allyl-ether. They may intervene in grafting reactions for the protection of a polymeric support, or in reactions of copolymerization.
    Type: Grant
    Filed: October 7, 1988
    Date of Patent: June 5, 1990
    Assignee: Institut Textile de France
    Inventors: Michel Bourgeois, Roger Chatelin, Daniel Wattiez
  • Patent number: 4898955
    Abstract: Trans-.beta.-lactams are prepared in a nearly quantitative yield by a condensation reaction of a new intermediate metal enolate and an appropriate imine. Certain new metal enolates are provided as intermediates.
    Type: Grant
    Filed: December 12, 1988
    Date of Patent: February 6, 1990
    Assignee: Gist-Brocades N.V.
    Inventors: Gerard Van Koten, Frederick H. Van Der Steen, Johann T. B. H. Jastrzebski
  • Patent number: 4705875
    Abstract: The present invention relates to novel compounds, vitamin supplements, diet pills, and methods for making the same. The vitamin supplements include one or more phytosterol esters, such as esters of sitosterol or stigmasterol, and/or one or more novel substiuted fructose compounds. The diet pills within the scope of the invention include antitrypsin, and may be combined with the vitamin supplements to provide diet vitamin supplements.
    Type: Grant
    Filed: April 1, 1986
    Date of Patent: November 10, 1987
    Inventor: David C. Mitchell
  • Patent number: 4670573
    Abstract: There are disclosed improved methods for preparing metal alkoxides from metals and alcohols. The methods involve dry-grinding the metal in an inert atmosphere prior to the addition of the alcohol. When an activator is used, it is usually ballmilled with the metal. Higher yields are obtained, particularly when the metal and alcohol are not very reactive absent an activator. Typical metals are those from Groups 2A, 2B, 3A, and 3B, particularly aluminum, magnesium, and yttrium. Typical alcohols are those which contain up to 16 carbon atoms, particularly those containing 4 or more carbon atoms.
    Type: Grant
    Filed: December 17, 1984
    Date of Patent: June 2, 1987
    Assignee: Stauffer Chemical Company
    Inventors: Carl C. Greco, Kelly B. Triplett
  • Patent number: 4590288
    Abstract: A polydentate binucleating ligand having at least four donor sites selected from N, O and S, complexed with two atoms of the same metal, forms a coordination complex useful in homogeneous catalysis. Most preferably, all the metal cations are Cu cations and the ligand has a meta-xylyl functionality.
    Type: Grant
    Filed: June 29, 1983
    Date of Patent: May 20, 1986
    Assignee: Exxon Research and Engineering Co.
    Inventor: Lawrence P. Klemann
  • Patent number: 4588717
    Abstract: The present invention relates to novel compounds, vitamin supplements, diet pills, and methods for making the same. The vitamin supplements include one or more phytosterol esters, such as esters of sitosterol or stigmasterol, and/or one or more novel substituted fructose compounds. The diet pills within the scope of the invention include antitrypsin, and may be combined with the vitamin supplements to provide diet vitamin supplements.
    Type: Grant
    Filed: June 13, 1984
    Date of Patent: May 13, 1986
    Assignee: David C. Mitchell Medical Research Institute
    Inventor: David C. Mitchell