Abstract: A hydrocracking process for converting a petroleum feed to lower boiling products. The process comprises hydrotreating a petroleum feed in a pre-treating zone in the presence of hydrogen to produce a hydrotreated effluent stream comprising a liquid product. At least a portion of the hydrotreated effluent stream is then passed to an MMS catalyst zone, and then to a hydrocracking zone. In one embodiment, the MMS catalyst zone comprises a self-supported multi-metallic catalyst prepared from a precursor in the oxide or hydroxide form. The percentage work of the hydrotreating in the pre-treating zone is maintained at a level of at least 56%.

Abstract: A metal precursor and a method comprising decomposing a metal precursor on an integrated circuit device; and forming a metal from the metal precursor, wherein the metal precursor is selected from the group consisting of (i) a Co2(CO)6(R1C?CR2), wherein R1 and R2 are individually selected from a straight or branched monovalent hydrocarbon group have one to six carbon atoms that may be interrupted and substituted; (ii) a mononuclear cobalt carbonyl nitrosyl; (iii) a cobalt carbonyl bonded to one of a boron, indium, germanium and tin moiety; (iv) a cobalt carbonyl bonded to a mononuclear or binuclear allyl; and (v) a cobalt (II) complex comprising nitrogen-based supporting ligands.

Abstract: An activatable nanoprobe is provided having a core component and an active agent associated with the core component via a bond configured to be cleaved upon exposure to an endogenous compound.

Abstract: Preparation of semiconductor nanocrystals and their dispersions in solvents and other media is described. The nanocrystals described herein have small (1-10 nm) particle size with minimal aggregation and can be synthesized with high yield. The capping agents on the as-synthesized nanocrystals as well as nanocrystals which have undergone cap exchange reactions result in the formation of stable suspensions in polar and nonpolar solvents which may then result in the formation of high quality nanocomposite films.

Abstract: Preparation of semiconductor nanocrystals and their dispersions in solvents and other media is described. The nanocrystals described herein have small (1-10 nm) particle size with minimal aggregation and can be synthesized with high yield. The capping agents on the as-synthesized nanocrystals as well as nanocrystals which have undergone cap exchange reactions result in the formation of stable suspensions in polar and nonpolar solvents which may then result in the formation of high quality nanocomposite films.

Abstract: Embodiments of linkers for binding semiconductor quantum dots (QDs) to metal oxides are disclosed. The linkers have a general formula F1-A-(F2)z wherein F1 is —COOH, —COO?, —PO3H2, —PO3H?, —B(OH)2, —BO2H?, —SO3H, —SO3?, —NH2, —SH, or —S?; A is aryl, heteroaryl, aliphatic, or heteroaliphatic; and z?1 and each F2 independently is —PO3H2, —PO3H?, —B(OH)2, —BO2H?, —SO3H, —SO3?, or z?2 and each F2 independently is —COOH, —COO?, —PO3H2, —PO3H?, —B(OH)2, —BO2H?, —SO3H, or —SO3?, or z?2 and (F2)z collectively is an oxysilane moiety comprising z lower alkoxy groups bound to silicon. Methods of binding QDs to metal oxides with the disclosed linkers also are disclosed, as well as devices including the QD-functionalized metal oxides.

Abstract: The present invention relates to a paramagnetic polynuclear metal complex having enhanced self-relaxation rate and thermodynamic stability, and more particularly, to a synthetic method of a novel DTPA-bis-amide-histidine ligand and DTPA-bis-amide-aspartic acid ligand, a novel gadolinium complex ([Gd(L)H2O]) using the ligand, and a paramagnetic polynuclear metal complex using the gadolinium complex. The paramagnetic polynuclear metal complex is able to fix three or more metals (one gadolinium and two metal ions), thereby providing more excellent self-relaxation rate than the commercially available contrast agents. Thus, it can be widely applied to an MRI contrast agent because of meeting the high self-relaxation rate required as a contrast agent of magnetic resonance imaging (MRI).

Abstract: An activatable nanoprobe is provided having a core component and an active agent associated with the core component via a bond configured to be cleaved upon exposure to an endogenous compound.

Abstract: The molecular structures of metal-salen complexes which exerts pharmacological effects are clarified and the metal-salen complexes having such molecular structures and their derivatives are provided. A metal-salen complex compound is characterized in that a metal atom part in each of multiple molecules of the metal-salen complex or its derivative is multimerized via water.

Abstract: Claimed are a compound of the general formula (I) and pharmaceutically acceptable salts thereof, where M signifies metal atoms selected independently from the group comprising Pd, Fe, Mn, Co, Ni, Cu, Zn and Mo; R1 and R2, independently of each other, signify hydrogen, amino, hydroxy, oxy, carboxy, cyano, C1-12alkyl, C2-12alkenyl, C2-12alkynyl, C1-12alkoxy, C1-12alkylamino, C1-12alkoxycarbonyl, C1-12alkylamido, arylamido, wherein the alkylene groupings in the given substituents can in turn be substituted by one or more of the following groups: hydroxy, oxy, carboxy, amino or amido; R3-R10, independently of each other, signify hydrogen; or NHR3R4 and NHR5R6, taken together, and/or NHR7R8 and NHR9R10, taken together, are a ligand (or ligands) containing one or several donor aliphatic or aromatic atoms of nitrogen and being in cis position on the metal atoms (M).

Abstract: Hybrid particles that comprise a coating surrounding a chalcopyrite material, the coating comprising a metal, a semiconductive material, or a polymer; a core comprising a chalcopyrite material and a shell comprising a functionalized chalcopyrite material, the shell enveloping the core; or a reaction product of a chalcopyrite material and at least one of a reagent, heat, and radiation. Methods of forming the hybrid particles are also disclosed.

Abstract: The present invention refer to a innovative process for obtaining nanoparticulate magnetic ferrites, at low temperatures, simple or mixed, functionalized by organic molecules, for dispersion of these nanoparticles in polar or nonpolar media, and the same particles dispersed in a liquid medium, also known as ferrofluids. The present invention enables obtaining both simple ferrites (MFe2O4 or MFe12O19) and mixed ferrites (Nx M(1?x)Fe2O4 or N1?Y Mx+Y Fe(2?x)O4; as example) where M and N can be metals, such as Sm, La, Bi, Ba, Mo, Sr, Ni, Fe, Mn, Cr, etc., through the coprecipitation method, functionalized by organic molecules containing carboxylic groups, which are polymers, or long chain acids or short chain acids, containing mono, di or tricarboxylic groups and/or alcohols, whose dispersion in polar or nonpolar media is improved. The present invention enables also obtaining ferrofluids, through the mixture of the obtained magnetic particles with an appropriate liquid carrier.

Abstract: An iodine adsorbent of an embodiment includes: a carrier modified with a functional group represented by a formula (1); and a silver ion supported on the carrier, where R1 is a polyol group.

Abstract: A method is provided for producing separated substances, particularly metal compounds, the dopant element amounts of which have been controlled by the use of an apparatus that processes fluid between the processing surfaces of a processing member that can be made to approach/separate and which rotate relative to each other. The substance to be separated is separated by mixing a raw material solution, wherein the substance to be separated is solubilized in a solvent, with the solvent for separation and with the dopant element or dopant element-containing substance solubilized in at least one solvent selected from the solvent of said raw material solution, said solvent for separation or a solvent other than that of said raw material solution or said solution for separation. Separated substances with controlled dopant element amounts are obtained by controlling the solubility of the dopant element or dopant element-containing substance in the solvent for separation.

Abstract: An activatable nanoprobe is provided having a core component and an active agent associated with the core component via a bond configured to be cleaved upon exposure to an endogenous compound.

Abstract: An antibody-conserving method for linking a therapeutic platinum compound to nanoparticles comprising Au Like-Fe3O4, which is used for both drug delivery and tumor diagnosis.

Abstract: The present invention relates to a paramagnetic polynuclear metal complex having enhanced self-relaxation rate and thermodynamic stability, and more particularly, to a synthetic method of a novel DTPA-bis-amide-histidine ligand and DTPA-bis-amide-aspartic acid ligand, a novel gadolinium complex ([Gd(L)H2O]) using the ligand, and a paramagnetic polynuclear metal complex using the gadolinium complex. The paramagnetic polynuclear metal complex is able to fix three or more metals (one gadolinium and two metal ions), thereby providing more excellent self-relaxation rate than the commercially available contrast agents. Thus, it can be widely applied to an MRI contrast agent because of meeting the high self-relaxation rate required as a contrast agent of magnetic resonance imaging (MRI).

Abstract: Vapochromic coordination polymers useful for analyte detection are provided. The vapochromism may be observed by visible color changes, changes in luminescence, and/or spectroscopic changes in the infrared (IR) signature. One or more of the above chromatic changes may be relied upon to identify a specific analyte, such as a volatile organic compound or a gas. The chromatic changes may be reversible to allow for successive analysis of different analytes. The polymer has the general formula MW[M?X(Z)Y]N wherein M and M? are the same or different metals capable of forming a coordinate complex with the Z moiety; Z is selected from the group consisting of halides, pseudohalides, thiolates, alkoxides and amides; W is between 1-6; X and Y are between 1-9; and N is between 1-5. One embodiment provides [Metal(CN)2]-based coordination polymers with vapochromic properties, such as Cu[Au(CN)2]2 and Zn[Au(CN)2]2 polymers.

Abstract: Preparation of semiconductor nanocrystals and their dispersions in solvents and other media is described. The nanocrystals described herein have small (1-10 nm) particle size with minimal aggregation and can be synthesized with high yield. The capping agents on the as-synthesized nanocrystals as well as nanocrystals which have undergone cap exchange reactions result in the formation of stable suspensions in polar and nonpolar solvents which may then result in the formation of high quality nanocomposite films.

Abstract: Bimetal chelates are prepared from a solution formed by adding to a solvent one or more polyfunctional acids with basic salts of two or more coordination elements listed in Groups IIIA to VIIIA, Groups IB to IIIB, of periods 4 and 5 and aluminum in Group IIIB, period 3 of The Periodic Table of the Elements and recovering the chelate. Such chelates can be used to formulate useful products.

Abstract: Disclosed is a clean method for preparing layered double hydroxides (LDHs), in which hydroxides of different metals are used as starting materials for production of LDHs by atom-economical reactions. The atom efficiency of the reaction is 100% in each case because all the atoms of the reactants are converted into the target product since only M2+(OH)2, M3+(OH)3, and CO2 or HnAn? are used, without any NaOH or other materials. Since there is no by-product, filtration or washing process is unnecessary. The consequent reduction in water consumption is also beneficial to the environment.

Abstract: This invention relates to processes for compounds, polymeric compounds, and compositions used to prepare semiconductor and optoelectronic materials and devices including thin film and band gap materials. This invention provides a range of compounds, polymeric compounds, compositions, materials and methods directed ultimately toward photovoltaic applications, transparent conductive materials, as well as devices and systems for energy conversion, including solar cells. In particular, this invention relates to polymeric precursor compounds and precursor materials for preparing photovoltaic layers. A compound may contain repeating units {MB(ER)(ER)} and {MA(ER)(ER)}, wherein MA is a combination of Cu and Ag, each MB is In or Ga, each E is S, Se, or Te, and each R is independently selected, for each occurrence, from alkyl, aryl, heteroaryl, alkenyl, amido, silyl, and inorganic and organic ligands.

Abstract: The present invention relates to conjugates of formula (I) having colloidal stability in a medium, wherein NP is a gold, silver or platinum nanoparticle; L is a linker selected from the group consisting of formula (II), formula (III), and a stereoisomer of any of the formulas (II) and (III), which is attached to the nanoparticle NP through sulfur atoms; wherein the meanings of X, n, p, Y and s are further specified in the description; and A is a platinum (II) biradical selected from the group consisting of formula (IV), formula (V) and formula (VI) including any of the stereoisomers of all of them, wherein the biradical is optionally in the form of a salt and is attached to the linker L through the single bonded oxygen atoms of the carboxyl groups. It also relates to a process for the preparation of the conjugates of formula (I) and to pharmaceutical compositions containing them. The conjugates of the invention are used for the treatment of cancer.

Abstract: Methods of forming bimetal complexes including reacting polyfunctional compounds with two or more coordination elements and recovering a bimetal complex.

Abstract: Provided is an ultrasonic cancer therapy accelerator comprising titanium oxide-metal complex particles showing a long-lasting antitumor effect imparted thereto while sustaining the dispersibility and catalytic activity thereof which are obtained by dispersing titanium oxide-metal complex particles in an aqueous solvent with the use of a water-soluble polymer and modifying the same with molecules containing a low-valent transition metal via linker molecules having been bound thereto without denaturing the water-soluble polymer. To the titanium oxide surface of titanium oxide-metal complex particles which have been dispersed in an aqueous solvent with the use of a water-soluble polymer, linker molecules are bound via at least one functional group selected from the group consisting of carboxyl, amino, diol, salicylate and phosphate groups followed by the modification with low-valent transition metal-containing molecules via the linker molecules.

Abstract: A catalyst precursor composition and methods for making such a catalyst precursor are disclosed. The catalyst precursor comprises at least a promoter metal selected from Group VIII, Group IIB, Group IIA, Group IVA and combinations thereof having an oxidation state of +2 or +4, at least one Group VIB metal having an oxidation state of +6, and at least one organic oxygen-containing ligand. Catalysts prepared from the sulfidation of such catalyst precursors are used in the hydroprocessing of hydrocarbon feeds.

Abstract: The invention provides methods and compounds for detecting protease activity in a sample solution comprising contacting the sample solution with a protease substrate labeled with an electrochemically active marker, providing conditions under which any protease which may be present in the sample may degrade the protease substrate and electrochemically determining information relating to the electrochemically active marker.

Abstract: A catalyst precursor composition and methods for making such catalyst precursor are disclosed. The catalyst precursor comprises at least a Promoter metal selected from Group VIII, Group IIB, Group IIA, Group IVA and combinations thereof, at least one Group VIB metal, at least one organic, oxygen-containing ligand, and a cellulose-containing material. The oxygen-containing ligand is an environmentally friendly/non-toxic material having an LD50 rate of >500 mg/Kg as single oral dose to rats. Catalysts prepared from the sulfidation of such catalyst precursors are used in the hydro processing of hydrocarbon feeds.

Abstract: A pigment having at least two layers according to the following structure (I), where C is an internal pigment core of formula [Mx(O)y(OH)z]; where MX=TiIV, ZnII, ZrIV, SnIV, FeII, FeIII, SnII, CrVI, or MnII; x=2, 3 or 4; and (y/2+z)=x; A is a plant polyphenol having an active-redox, radical scavanger behaviour and at least two chelating moieties and B is an outer hydrophobic layer consisting in an anionic surfactant, and where Ma and Mb denotes, each independently, Mq+=Ca2+, Zn2+, Ti4+, Si4+, Al3+, Sn4+, Mg2+, or Sr2+; and a=0 or 1; b=1; q=2, 3 or 4.

Abstract: Bimetal chelates are prepared from a solution formed by adding to a solvent one or more polyfunctional acids with basic salts of two or more coordination elements listed in Groups IIIA to VIIIA, Groups IB to IIIB, of periods 4 and 5 and aluminum in Group IIIB, period 3 of The Periodic Table of the Elements and recovering the chelate. Such chelates can be used to formulate useful products.

Abstract: Initiators for atom transfer radical polymerizations are described. The initiators have an azlactone or ring-opened azlactone moiety to provide telechelic (co)polymers.

Abstract: A catalyst precursor composition and methods for making such catalyst precursor are disclosed. The catalyst precursor comprises at least a Promoter metal selected from Group VIII, Group IIB, Group IIA, Group IVA and combinations thereof, at least one Group VIB metal, at least one organic, oxygen-containing ligand, and a cellulose-containing material. The oxygen-containing ligand is an environmentally friendly/non-toxic material having an LD50 rate of >500 mg/Kg as single oral dose to rats. Catalysts prepared from the sulfidation of such catalyst precursors are used in the hydroprocessing of hydrocarbon feeds.

Abstract: A process for making a catalyst precursor is disclosed. In one embodiment, the process comprises co-precipitating at reaction conditions forming a precipitate or cogel: at least a promoter metal compounds selected from Group VIII, Group IIB, Group IIA, Group IVA and combinations thereof, at least one of Group VIB metal compounds, at least an organic oxygen-containing ligand L. The precursor is represented by the formula Av[(MP)(OH)x(L)ny]z(MVIBO4), wherein A comprises an alkali metal cation, an ammonium, an organic ammonium or a phosphonium cation, MP is at least one of Group VIII, Group IIB, Group IIA, Group IVA and combinations thereof, L is the organic, oxygen-containing co-ordinating ligand, MVIB is at least one of Group VIB metals, and the atomic ratio of MP:MVIB is between 100:1 and 1:100.

Abstract: A catalyst precursor composition and methods for making such a catalyst precursor are disclosed. The catalyst precursor comprises at least a promoter metal selected from Group VIII, Group IIB, Group IIA, Group IVA and combinations thereof having an oxidation state of +2 or +4, at least one Group VIB metal having an oxidation state of +6, and at least one organic oxygen-containing ligand. Catalysts prepared from the sulfidation of such catalyst precursors are used in the hydroprocessing of hydrocarbon feeds.

Abstract: The invention relates to a method for polymerising ethylenically unsaturated monomers, wherein ethylenically unsaturated monomers are polymerised in the presence of a solvent-stable transition metal complex having slightly co-ordinating anions as polymer catalysts. The invention also relates to specific solvent-stable transition metal complexes having slightly co-ordinating anions. The invention also relates to highly reactive copolymers which are made of monomers comprising isobutene and at least one vinylaromatic compound which can be obtained according to said inventive method.

Abstract: A single source precursor for depositing ternary I-III-VI2 chalcopyrite materials useful as semiconductors. The single source precursor has the I-III-VI2 stoichiometry “built into” a single precursor molecular structure which degrades on heating or pyrolysis to yield the desired I-III-VI2 ternary chalcopyrite. The single source precursors effectively degrade to yield the ternary chalcopyrite at low temperature, e.g. below 500° C., and are useful to deposit thin film ternary chalcopyrite layers via a spray CVD technique. The ternary single source precursors according to the invention can be used to provide nanocrystallite structures useful as quantum dots. A method of making the ternary single source precursors is also provided.

Abstract: Synthetic hydrotalcites of the general formula [M2+1?xM3+x(OH)2]x+[An?x/n.mH2O]x? where M2+ is a divalent cation, M3+ is a trivalent cation and An? is an organic anion selected from straight chain carboxylates of C16-C18 acids, carboxylates of aromatic acids, carboxylates of acrylic acid, unsaturated carboxylates of methacrylic acid and unsaturated carboxylates of vinylacetic acid are disclosed, along with methods of synthesis and uses.

Abstract: Chemical vapor deposition processes utilize as precursors volatile metal complexes with ligands containing metalloid elements silicon, germanium, tin or lead.

Abstract: Volatile metal complexes with &agr;-sila-&bgr;-diketonate ligands containing haloalkyl, and particularly, perfluoroalkyl, substitutents are useful as metal precursors for chemical vapor deposition processes and as nanostructured materials containing fluorous domains.

Abstract: A novel Group IV elements-bridged metallocene complex is disclosed which is represented by the following formula (I): wherein R and R1 are different and are independently selected from the group consisting of &eegr;5-cyclopentadienyl group, substituted &eegr;5-cyclopentadienyl group, indenyl group, and fluorenyl group; R2 is selected from the group consisting of —N(CH3)2, —N(C2H5)2, halogen, alkoxy, —(C═O)NH2, and C6-12 hydrocarbyl group; M is a Group IVA element; and M1 is a Group IVB metal. When employing the metallocene complex to prepare olefin polymers, since it is bridged by a Group IV element, there are two catalytic sites in the single metallocene complex catalyst. Therefore, the olefin monomers can be polymerized to a bimodal olefin polymer by a single catalyst in a single reactor, resulting in lowered capital costs.

Abstract: Chemical vapor deposition processes utilize as precursors volatile metal complexes with ligands containing metalloid elements silicon, germanium, tin or lead.

Abstract: The present invention is directed to a zinc-molybdenum-based dithiocarbamate derivative which is a complex salt having the metallic components of zinc and molybdenum in the same molecule. When used as a lubricant additive, it imparts a notable friction-reducing effect to the lubricant composition in which it is incorporated, reducing its friction coefficient and improving its stability of friction coefficient at both low and high temperature, particularly at high temperature. In particular, it improves friction-related characteristics much more notably than a combination of a molybdenum and zinc compound.

Abstract: The present invention relates to a new bimetallic complex catalyst system having the empirical formula of M.sup.1.sub.a M.sup.2.sub.b X.sub.m (L.sub.1).sub.n, wherein M.sup.1 is Rh or Ru, M.sup.2 is Ru or a lanthanide, when M.sup.1 is Rh, M.sup.2 is Ru or a lanthanide; when M.sup.1 is Ru, M.sup.2 is a lanthanide; X is H, Cl, Br or the combinations thereof; L.sub.1 is the ligand to the metal salt; 1.ltoreq.a.ltoreq.4; 1.ltoreq.b.ltoreq.2; 3.ltoreq.m.ltoreq.6; 6.ltoreq.n.ltoreq.15. The present invention also relates to a corresponding improved process for the hydrogenation of unsaturated copolymers, particularly NBR type rubber, wherein the above mentioned new bimetallic complex catalyst system is used.

Abstract: An x-ray contrast medium containing a multinuclear complex of the formula (M.sub.6 (.mu..sub.3 B).sub.8 A.sub.v).sub.x L.sub.w, wherein M is Mo, W, Re Tc, V, Nb, Ta, Ru, or Fe; .mu..sub.3 B represent a tridentate bridging atom; A is a non-bridging atom; L is a ligand coordinately bonded to at least one M atom; x is a positive integer; and v and w are independently zero or positive integers.

Abstract: Pre-blended combinations and reaction products of at least one metallic dithiocarbamate and at least one metallic dithiophosphate provide the synergism of antiwear properties with friction-reducing properties for lubricants and greases.

Abstract: A method of forming a layered-perovskite bismuth-strontium-tantalum oxide (SBT) ferroelectric material is performed by dissolving a bismuth compound in a first solvent to form a first solution, mixing a strontium compound and a tantalum compound to form a binary mixture, dissolving the binary mixture in a second solvent to form a second solution, mixing the first solution with the second solution to form a SBT precursor solution, evaporating the first and second solvents to form a SBT precursor material and subsequently sintering said SBT precursor material in the presence of oxygen.

Abstract: The present invention relates to novel reaction products of azlactones and organometallic nucleophiles and the method of making these reaction products. The invention also relates to methods of using such reaction products to prevent or eliminate microbial and fungal growth on substrates. Reaction products can be provided that show improved antifouling and antimicrobial action.

Abstract: A higher alcohol synthesis catalyst precursor comprises a homogeneous, highly crystalline, hydroxycarbonate compound containing copper, zinc and at least one element selected from the group consisting of aluminium, manganese and chromium. It also comprises at least one element from at least one of the followng groups of the Periodic Table of Elements: Group IIIA, Group IIIB, Group IVB and Group VIIB.

Abstract: Metals are reacted in a first solvent, such as 2-methoxyethanol, to form an initial precursor comprising metal-oxide compounds dissolved in the first solvent. A second solvent, such as xylene, that does not react with the metal is added to the solution and the solution heated to distill away the first solvent and form a final precursor. The final precursor is spin-coated on an integrated circuit substrate then dried and annealed to form a thin film of a metal oxide. For metal oxides including bismuth, the bismuth precursor is added to a cold initial precursor and the final precursor is not heated after the bismuth precursor is added. The second solvent wets the substrate better than the first solvent and has a better viscosity for spin-coating, thus resulting in a denser thin film with fewer imperfections.

Abstract: Novel salts are prepared wherein the cation of the salt is a divalent or trivalent cation which is an essential trace element comprising a 1:1 ratio of a complex ion formed between a trace mineral and methionine and any suitable anion, either inorganic or organic. The novel salts have the generic formula: ##STR1## Wherein R.sub.1 is methyl or ethyl, R.sub.2 is hydrogen, methyl or ethyl, R.sub.3 is hydrogen or methyl, M is a covalent or trivalent trace mineral cation, X is an anion and w is an integer to balance the anionic charge of X. These novel compounds are useful nutritional supplements, both for animals and humans, in that they provide a readily available source of a highly water soluble methionine which is an essential amino acid.