Abstract: Crystalline metal silicate compositions are prepared from a silica containing mixture which is substantially free of aluminum ions and which contains a chelating agent by digesting a reaction mixture comprising, a tetraalkylammonium compound, sodium hydroxide, a metal compound, an oxide of silicon, a chelating agent and water, with the reaction mixture containing less than about 100 ppm aluminum. Crystalline borosilicate compositions are of special interest. A method for activating the new crystalline compositions to enhance their usefulness for certain conversion processes is also disclosed.
Type:
Grant
Filed:
November 7, 1979
Date of Patent:
May 25, 1982
Assignee:
National Distillers & Chemical Corp.
Inventors:
James A. Hinnenkamp, Vernon V. Walatka, Jr.
Abstract: Hydraulic fluids containing novel compounds of the general formula ##STR1## wherein: (a) each R.sup.1 is a hydrocarbyl group, or a group of the formula: ##STR2## and each R.sup.1 may be the same as, or different from, any other group R.sup.1.(b) R.sup.2 is a group as defined for R.sup.1, or a group of the formula:--O(R.sup.5 O).sub.n Si(R.sup.1).sub.3 (iv)and each group R.sup.2 may be the same as, or different from, any other group R.sup.2.(c) each of R.sup.3 and R.sup.4 is independently a group of the formula: ##STR3## (d) R.sup.5 is an alkylene or an arylene group and each R.sup.5 may be the same as, or different from, any other group R.sup.5,(e) R.sup.6 is a hydrocarbyl group of hydrogens and each group R.sup.6 may be the same as, or different from, any other group R.sup.6,(f) n is zero or an integer and each n may be the same as, or different from, any other n.
Abstract: Novel compounds of the general formula: ##STR1## wherein: (a) each R.sup.1 is a hydrocarbyl group, or a group of the formula: ##STR2## and each R.sup.1 may be the same as, or different from, any other group R.sup.1.(b) R.sup.2 is a group as defined for R.sup.1, or a group of the formula:--O(R.sup.5 O).sub.n Si(R.sup.1).sub.3 (iv)and each group R.sup.2 may be the same as, or different from, any other group R.sup.2.(c) each of R.sup.3 and R.sup.4 is independently a group of the formula: ##STR3##--(R.sup.5 O).sub.n --R.sup.6 (vii)(d) R.sup.5 is an alkylene or an arylene group and each R.sup.5 may be the same as, or different from, any other group R.sup.5,(e) R.sup.6 is a hydrocarbyl group of hydrogen and each group R.sup.6 may be the same as, or different from, any other group R.sup.6,(f) n is zero or an integer and each n may be the same as, or different from, any other n.The compounds are useful as water scavengers, particularly for hydraulic fluids, as well as in paints, lubricating oils and electrical oils.
Abstract: A polyborodiphenylsiloxane having main repeating units of the formula, ##STR1## wherein X is a hydrogen atom or ##STR2## and a weight-average molecular weight of about 800 to about 5,000, and a method of preparing the same, which comprises polycondensing a borodiphenylsiloxanol of the formula, ##STR3## wherein n is zero or one, at a temperature of from about 140.degree. C. to about 400.degree. C. in the absence of a solvent.
Abstract: Dicarbonyl chelate salts of main group elements are provided having hexafluoro anions of an element selected from boron, arsenic and phosphorus. The dicarbonyl chelate salts are useful as curing catalysts when utilized with epoxy resins in the presence of moisture.