Abstract: A chemical bond evaluation method capable of directly evaluating the presence or absence of a chemical bond between silica and a silane coupling agent includes performing multidimensional solid-state nuclear magnetic resonance (NMR) analysis on a rubber composition comprising a rubber component, a silica, and a silane coupling agent; and evaluating the presence or absence of a chemical bond between silica and the silane coupling agent in the rubber composition containing a rubber component, the silica, and the silane coupling agent.

Abstract: Anisotropic conductive films, each including an insulating adhesive layer and conductive particles insulating adhesive layer in a lattice-like manner. Among center distances between an arbitrary conductive particle and conductive particles adjacent to the conductive particle, the shortest distance to the conductive particle is a first center distance; the next shortest distance is a second center distance. These center distances are 1.5 to 5 times the conductive particles' diameter. The arbitrary conductive particle, conductive particle spaced apart from the conductive particle by the first center distance, conductive particle spaced apart from the conductive particle by first center distance or second center distance form an acute triangle. Regarding this acute triangle, an acute angle formed between a straight line orthogonal to a first array direction passing through the conductive particles and second array direction passing through conductive particles being 18 to 35°.

Abstract: The present invention aims to provide: a novel silicon-containing polymer that is alkali soluble or is soluble in an alkaline aqueous solution by using heat, etc.; a film-forming composition including the silicon-containing polymer; a method for forming a silicon-containing polymer coating using the film-forming composition; a method for forming a silica coating using the film-forming composition; and a production method for the silicon-containing polymer. The silicon-containing polymer including at least either a polysiloxane chain or oligosiloxane chain or a polysilane chain or oligosilane chain in the molecular chain thereof has a group that has e.g., a carboxy or carboxylic acid ester group and a sulfide group, introduced to the molecular chain as a result of an ene-thiol reaction.

Abstract: Binders to produce or promote cohesion in non-assembled or loosely assembled matter.

Abstract: A three-dimensional scaffold structure and a process for its manufacture. The scaffold structure has a polymer system obtainable by photostructuring a starting material containing precursor molecules or inorganic polymers thereof having an organically polymerizable radical with at least one C?C double bond, an inorganically polymerizable silane-based radical and a functional group or derivative thereof.

Abstract: Process for preparing polysulfane silanes of the formula I (R1O)3-mR2mSi—R3—Sx—R3—SiR2m(OR1)3-m??I, by reaction of silane of the formula II (R1O)3-mR2mSi—R3-Hal??II, with one or more metal sulfides of the formula III Me(SH)f and/or Me3-fSx-y??III, optionally in the presence of one or more salts of monohydric or polyhydric acids, with the optional addition of y mol of sulfur in aqueous R1—OH solution, wherein the water content of the aqueous R1—OH solution is 5% to 40% by weight, wherein a. the process stream from the reaction of silane of the formula II with one or more metal sulfides of the formula III, optionally in the presence of one or more salts and optionally with the addition of sulfur, in aqueous R1—OH solution, comprising polysulfane silanes of the formula I, silane of the formula II, metal sulfides of the formula III, solvent R1—OH, water and process salts, is combined with the wash solution from step d, comprising solvent R1—OH, water and polysulfane silanes of the formula I, b.

Abstract: A preparation method of functional silanes comprises: substance A and substance B are added in a three-necked bottle and a certain amount of solvent is added; the resultant mixture is stirred for 0.5-24 h in the presence of catalyst under an atmosphere of argon, resulting in the crude product; after removing the remaining solvent and catalyst, the residual product is purified by chromatographic column to obtain functional silanes; the substance A is an alkene-containing silane and the substance B is an alcohol; functional silanes with various structures can be prepared, and their structures can be controlled by regulating the ratio of substance A and substance B, thereby providing ideas for the preparation of different silanes and the structural design of silane coupling agents.

Abstract: The invention relates to silane mixtures comprising a silane of the formula I (R1)y(R2)3-ySi—R3—(S—R4)n—Sx—R5??(I) and a silane of the formula II (R1)y(R2)3-ySi—R3—Si(R1)y(R2)3-y??(II) where the molar ratio of silane of the formula I to silane of the formula II is 15:85-90:10. The silane mixture according to the invention can be prepared by mixing the silanes of the formula I and silanes of the formula II.

Abstract: The invention relates to silane mixtures comprising a silane of the formula I (R1)y(R2)3-ySi—R3—(S—R4)n—Sx—R5??(I) and a silane of the formula II (R1)y(R2)3-ySi—R3—S—R4—S—R3—Si(R1)y(R2)3-y??(II) where the molar ratio of silane of the formula I to silane of the formula II is 15:85-90:10. The silane mixture according to the invention can be prepared by mixing the silanes of the formula I and silanes of the formula II.

Abstract: The present invention provides a resist underlayer film-forming composition for lithography for forming a resist underlayer film that can be used as a hard mask with use of hydrolysis-condensation product of a hydrolyzable silane which also absorbs KrF laser. A resist underlayer film-forming composition for lithography comprising, as a silane, a hydrolyzable silane, a hydrolysis product thereof, or a hydrolysis-condensation product thereof, wherein the hydrolyzable silane includes a hydrolyzable silane of Formula (1): R1aR2bSi(R3)4?(a+b)??Formula (1) [where R1 is an organic group of Formula (2): and is bonded to a silicon atom through a Si—C bond; R3 is an alkoxy group, an acyloxy group, or a halogen group; a is an integer of 1; b is an integer of 0 to 2; and a+b is an integer of 1 to 3], and a ratio of sulfur atoms to silicon atoms is 7% by mole or more in the whole of the silane.

Abstract: Improved sparge compositions for froth flotation separation, methods of using them, and uses thereof are described. The compositions are suitably used in the froth flotation of particulate material containing ultrafine particles, and are well suited to the froth flotation separation of finely comminuted poor (low-grade) ores. The sparge compositions comprise functionalized silicone containing functionality that is tailored to the chemical nature of a beneficiary or a gangue in the ore. Sparging of the compositions effects improved recoveries and purities of beneficiaries. Sparge compositions and functionalized silicones suitable for the froth flotation of iron ores containing silica and/or silicate impurities are described. Sparge compositions and functionalized silicones suitable for the froth flotation of ores containing sulfur compounds such as sulfides are also disclosed.

Abstract: The invention relates to silane mixtures comprising a silane of the formula I (R1)y(R2)3-ySi—R3—(S—R4)n—Sx—(R4—S)n—R3—Si(R1)y(R2)3-y??(I) and a silane of the formula II (R1)y(R2)3-ySi—R3—(S—R4)z—S—R3—Si(R1)y(R2)3-y??(II) where the molar ratio of silane of the formula I to silane of the formula II is 19:81-81:19. The silane mixture according to the invention can be prepared by mixing the silanes of the formula I and silanes of the formula II.

Abstract: Disclosed herein are phosphino- and phosphate-silane functionalized polymers, methods of preparing a reactive polymer functionalized with an alkoxysilane having a phosphorous-containing group as a functionalizing reagent, the resulting polymer and vulcanizates thereof. The vulcanizates of the functionalized polymers can be used to produce vulcanized products, including tires.

Abstract: Novel polyfluoroalkylated alkenes and silicone compounds prepared therefrom are described.

Abstract: Novel fluoroalkysilanes of the following formula are described; Rf—O—CHFCF2—O—(CH2)n—Si(R)xX3?x, wherein Rf is a perfluoroalkyl group, optionally substituted by one or more in-chain -Q-, —S— or —NRf1-heteroatoms, where Rf1 is a -perfluoroalkyl; X is a hydrolysable group; R is a C1C4 alkyl group; n is at least 3; and x is 1 to 3.

Abstract: Novel polyfluoroalkylated alkenes and silane compounds prepared therefrom are described.

Abstract: Fluorinated cyclopentene moieties and fluorinated cyclopentene functionalized silica materials are provided. The fluorinated cyclopentene functionalized silica materials include a silica material having the fluorinated cyclopentene moiety covalently bonded thereto. Exemplary silica materials include a polysilsesquioxane, a nanosilica, a microsilica, a silica gel, a silica aerogel, or combinations thereof. The fluorinated cyclopentene moieties are based on a modification of perfluorocyclopentene (i.e., 1,2,3,3,4,4,5,5-octafluoro-1-cyclopentene) by nucleophilic substitution with an appropriate nucleophile having a reactive functional group. Methods for preparing fluorinated cyclopentene moieties and the corresponding fluorinated cyclopentene functionalized silica materials are also provided.

Abstract: The invention provides mercaptosilane-carbon black blends comprising at least 20 wt. % of mercaptosilanes of the general formula I and carbon black, the mercaptosilane-carbon black blend having an iron content of <9 ppm. They are produced by mixing the mercaptosilanes of the general formula I with the carbon black. They can be used in rubber mixtures.

Abstract: A novel silicon compound capable of initiating radical polymerization is provided. The silicon compound is represented by the following general formula (1) A-Z1—S—Z2—Si(OR1)n(R2)3-n??(1) wherein A is a group capable of initiating radical polymerization, Z1 and Z2 are each independently a bivalent group that has at least a carbon atom, R1 and R2 are each independently an alkyl group having from 1 to 3 carbon atoms, and n is an integer of 1 to 3. A radical polymerization initiator comprising the silicon compound, and a polymer obtained by radical polymerization of a monomer with the radical polymerization initiator are also provided. Also provided is a complex having a polymer graft chain formed on a solid substance surface with the use of the silicon compound.

Abstract: A polymeric coating for a glass substrate includes a hexafluoropropylene oxide derived silane polymer. The hexafluoropropylene oxide derived silane polymer has a molecular weight of greater than about 5500, a thickness of between about 2 and about 15 nanometers and a coefficient of friction constant of less than about 0.35. A water contact angle of the polymeric hexafluoropropylene oxide derived silane coating decreases by less than about 27% after being subjected to 10000 abrasion cycles.

Abstract: The present invention relates to a process for a chain extension of radicals bonded to silicon via carbon in silanes or siloxanes while maintaining or increasing the number of functional groups on the respective Si—C-bonded radicals, wherein a silane or siloxane with a radical bonded to a silicon atom by a carbon atom, which bears at least two functional groups, wherein a first group of the functional groups is an unsaturated, organically polymerizable group and a second group of the functional groups is selected from among (a) additional unsaturated, organically polymerizable groups, (b) COOR8 or —(O)bP(O)(R5)2 and (c) —OH, with R8 equal to R4 or M1/xx+ wherein Mx+ is a hydrogen or an x-fold positively charged metal cation, and b=0 or 1, is converted in a first reaction with a compound of a formula (I) X—W—(Z)a??(I) wherein X is SH, NH2 or NHR4, Z is OH, the carboxylic acid radical —COOH or a salt or an ester of this radical or a silyl radical, W is a substituted or non-substituted hydrocarbon, the chain

Abstract: The invention relates to a radical-initiated thiol-ene or thiol-yne “click” reaction that provides a simple and efficient route to diverse trialkoxysilanes. Trialkoxysilanes made in this way are obtained in quantitative to near-quantitative yields with high purity without any or minimal purification. A wide range of functional groups is tolerated in this approach, and even complex alkenes click with the silane precursors. The modular nature of these radical-based thiol-ene or thiol-yne “click” reactions allows a wide variety of pendant groups to be coupled to silane compounds that can then be coupled to a wide variety surfaces in order to modify their material properties. Consequently, such radical initiated thiol-ene and thiol-yne reactions provide facile and efficient methods for preparing an enormous number of surface-active functional trialkoxysilanes.

Abstract: A method of producing sulfur modified organosilane compounds that can be used in asphalt binders which method involves: combining together an organosilane or mixtures of organosilanes, a sulfide, a halogen acceptor and solvent to form a reaction mixture; and allowing the organosilane to react with the sulfide in the presence of a halogen acceptor to produce a sulfur modified organosilane compound. The sulfur modified organosilane compound can be introduced into a polymer modified or unmodified asphalt binder in which the sulfur modified organosilane compound reacts with components in the asphalt mixture to form a modified asphalt. The organosilanes used to produce the sulfur modified organosilanes can be from a source of waste products (such as Direct Product Residue) in which case the waste products can be reused in asphalt binders.

Abstract: An isocyanurate compound for forming an organic anti-reflective coating layer, which has superior stability and etch rate at a high temperature, and which has a high refractive index, is represented by following Formula 1. In Formula 1, R is independently a hydrogen atom or a methyl group, R1 is independently a chain type or ring type saturated or unsaturated hydrocarbyl group of 1 to 15 carbon atoms containing 0 to 6 of hetero atoms, and R2 independently a chain type or ring type saturated or unsaturated hydrocarbyl group of 1 to 15 carbon atoms containing 0 to 15 of hetero atoms, wherein, R1 can have at least two bonding parts, and in the case that R1 has at least two bonding parts, the rest parts except R1 of the compounds represented by Formula 1 can connect to the R1 to form a polymer structure.

Abstract: Mixtures of silicon-containing coupling reagents comprising (mercaptoorganyl)alkylpolyethersilanes containing silanol groups and (mercaptoorganyl)alkylpolyethersilanes free of silanol groups in a weight ratio of from 5:95 to 95:5. The mixtures can be prepared by transesterification and hydrolysis. The mixtures can be used in rubber mixtures.

Abstract: The invention provide a silica nanoparticle comprising a non-porous matrix of silicon-oxygen bonds, wherein the matrix comprises organic agents conjugated to silicon or oxygen atoms in the matrix, the organic agents are conjugated to the matrix through linker L groups, wherein the linker L comprises, for example, an ester, urea, thiourea, or thio ether group, and wherein the diameter of the nanoparticle is about 15 nm to about 200 nm. The invention also provides novel methods of making and using the silica nanoparticles described herein.

Abstract: This invention relates to hydrolysable silanes useful in the modification of elastomers, and as coupling agents for diene elastomer compositions containing a filler. In particular the invention relates to novel hydrolysable silanes containing a piperazine ring and an ether or thioether linkage.

Abstract: An organosilane of general formula I below: (HO)2R1Si—Z—Sm—R2 in which: R1, which are identical or different, each represent a monovalent hydrocarbon-based group chosen from alkyls, which are linear or branched, cycloalkyls or aryls, having from 1 to 18 carbon atoms; R2 represents a monovalent hydrocarbon-based group chosen from alkyls, which are linear or branched, cycloalkyls or aryls, having from 1 to 30 carbon atoms; Z represents a divalent bonding group comprising from 1 to 18 carbon atoms; and m is a number greater than or equal to 2.

Abstract: A compound represented by the following General Formula (1): where R1 represents a protective group for a hydroxyl group or a hydrogen atom, and R2 represents a methyl group or an ethyl group.

Abstract: A novel silicon compound capable of initiating radical polymerization is provided. The silicon compound is represented by the following general formula (1) A-Z1—S—Z2—Si(OR1)n(R2)3-n??(1) wherein A is a group capable of initiating radical polymerization, Z1 and Z2 are each independently a bivalent group that has at least a carbon atom, R1 and R2 are each independently an alkyl group having from 1 to 3 carbon atoms, and n is an integer of 1 to 3. A radical polymerization initiator comprising the silicon compound, and a polymer obtained by radical polymerization of a monomer with the radical polymerization initiator are also provided. Also provided is a complex having a polymer graft chain formed on a solid substance surface with the use of the silicon compound.

Abstract: A method for blending functionalized silica with styrene butadiene rubber or ethylene propylene diene monomer rubber can include silica and an organosilane chemically and covalently bound to a surface of the silica. The organosilane can be derived from an organic silane with a functional group. A silica rubber masterbatch for complexing with an emulsion styrene butadiene rubber latex, a synthetic polymer, a natural polymer, or combinations thereof can include the functionalized silica with the organosilane or a blend of organosilanes chemically and covalently bound to a surface of the silica. Each organosilane can have an average tetrameric structure having a T3/T2 ratio of 0.3 to 0.9 or greater as measured by 29Si silicon cross polarization magic angle spinning nuclear magnetic resonance.

Abstract: The present invention discloses functionalized nanoparticles comprising on the surface a covalently bound radical of the formula (I) wherein the nanoparticles are SiO2, Al2O3 or mixed SiO2 and Al2O3 nanoparticles, and wherein the general symbols are as defined in claim 1. These functionalized nanoparticles are for example useful as stabilizers and/or compatibilizers in organic materials, or as photoinitiators in pre-polymeric or pre-crosslinking formulations, or as reinforcer of coatings and improver of scratch resistance in coating compositions for surfaces.

Abstract: A compound represented by the following General Formula (1): where R1 represents a protective group for a hydroxyl group or a hydrogen atom, and R2 represents a methyl group or an ethyl group.

Abstract: This invention provides aqueous-compatible, polar-embedded reversed-phase stationary phase compositions, devices and systems comprising the stationary phases as well as methods of producing these compositions using epoxide ring-opening reactions. Also provided are methods of using the stationary phases of the invention in separations.

Abstract: This invention provides mixed-mode stationary phase compositions, devices and systems comprising the stationary phases as well as methods of producing these compositions using epoxide ring-opening reactions. Also provided are methods of using the stationary phases of the invention in separations.

Abstract: The present invention relates to silicic acid (hetero) polycondensates comprising structural units of a following formula (1) wherein radicals, indices, and bonding symbols have the following meaning: R1 refers to a group that is accessible to a thiol-ene polyaddition when a thiol is added and can also be polymerized by a ROMP (ring opening metathesis polymerization), R2 is selected from (a) organically polymerizable groups that are available to a thiol-ene polyaddition when a thiol is added, but not to a ROMP, (b) —COOR8 with R8 equal to R4 or M1/xx+, (c) —OH or COOH, and (d) —(O)bP(O)(R5)2, wherein b is equal to 0 or 1, —SO3M1/xx+, NR72 or NR7+3, wherein Mx+ is an x-fold positively charged metal cation, R4 is a non-substituted or substituted hydrocarbon radical, the radicals R5 independently represent a non-substituted or substituted hydrocarbon radical or OR6 and R6 is hydrogen or a non-substituted or substituted hydrocarbon radical, R7 has either the same meaning as R4 or two radicals R7 together repr

Abstract: The present invention relates to a process for a chain extension of radicals bonded to silicon via carbon in silanes or siloxanes while maintaining or increasing the number of functional groups on the respective Si—C-bonded radicals, wherein a silane or siloxane with a radical bonded to a silicon atom by a carbon atom, which bears at least two functional groups, wherein a first group of the functional groups is an unsaturated, organically polymerizable group and a second group of the functional groups is selected from among (a) additional unsaturated, organically polymerizable groups, (b) COOR8 or —(O)bP(O)(R5)2 and (c) —OH, with R8 equal to R4 or M1/xx+ wherein Mx+ is a hydrogen or an x-fold positively charged metal cation, and b=0 or 1, is converted in a first reaction with a compound of a formula (I) X—W—(Z)a??(I) wherein X is SH, NH2 or NHR4, Z is OH, the carboxylic acid radical —COOH or a salt or an ester of this radical or a silyl radical, W is a substituted or non-substituted hydrocarbon, the c

Abstract: The present invention provides a novel 11-step enantioselective approach to the natural product hyperforin, which enables access to a wide variety of hyperforin analogs. The present invention also provides pharmaceutical compositions comprising inventive hyperforin analogs. Hyperforin analogs synthesized using the present synthetic method are envisioned useful in the treatment of various conditions, including, but not limited to, depression and conditions characterized by depression, inflammatory skin conditions, diabetes, asthma, chronic obstructive pulmonary disease (COPD), kidney disorders, and ischemic brain damage.

Abstract: Organopolysiloxanes containing a sulfide-containing organic group, a long-chain alkyl group, and a hydrolyzable group are novel. The organopolysiloxanes are effective for improving the shelf stability of epoxy resin compositions.

Abstract: The invention provides a process for preparing organosilanes of the general formula (I) wherein a) (haloorganyl)alkoxysilane of the formula (II) is reacted with a sulphurising reagent selected from the group of alkali metal hydrogensulphide, metal sulphide M2S, metal polysulphide M2Sg and any desired combinations thereof and optionally additionally with sulphur and/or with H2S in an organic solvent, b1) subsequently, the organic solvent is removed from the suspension which forms, and the liquid phase comprising the organosilane of the formula (I), and the solid phase comprising MX and residual organosilane of the formula (I), are separated from the remaining suspension, or b2) subsequently, the liquid phase comprising the organosilane of the formula (I) and the organic solvent, and the solid phase comprising MX and residual organosilane of the formula (I), are separated from the suspension which forms, and the organic solvent is removed from the liquid phase, c) the solid phase comprising MX and residual orga

Abstract: The invention relates to a radical-initiated thiol-ene or thiol-yne “click” reaction that provides a simple and efficient route to diverse trialkoxysilanes. Trialkoxysilanes made in this way are obtained in quantitative to near-quantitative yields with high purity without any or minimal purification. A wide range of functional groups is tolerated in this approach, and even complex alkenes click with the silane precursors. The modular nature of these radical-based thiol-ene or thiol-yne “click” reactions allows a wide variety of pendant groups to be coupled to silane compounds that can then be coupled to a wide variety surfaces in order to modify their material properties. Consequently, such radical initiated thiol-ene and thiol-yne reactions provide facile and efficient methods for preparing an enormous number of surface-active functional trialkoxysilanes.

Abstract: The present invention discloses functionalized nanoparticles comprising on the surface a covalently bound radical of the formula (I) wherein the nanoparticles are SiO2, Al2O3 or mixed SiO2 and Al2O3 nanoparticles, and wherein the general symbols are as defined in claim 1. These functionalized nanoparticles are for example useful as stabilizers and/or compatibilizers in organic materials, or as photoinitiators in pre-polymeric or pre-crosslinking formulations, or as reinforcer of coatings and improver of scratch resistance in coating compositions for surfaces.

Abstract: A polymer and a method of forming a polymer are provided. The polymer has the general structure (I): wherein M is a main group element, a transition metal element, or an organic moiety; X is a main group element selected from S, P, As, Se, Te, and Sb; R1 is a direct bond between M and the ethylene group depicted between M and X or a hydrocarbyl linking moiety having between 1 and about 9 carbon atoms; R2 is a hydrocarbyl moiety; R3 is an organic linking group; Y has a value of 0, 1, 2, 3, or 4; Z has a value of 0, 1, 2, 3, or 4; YY has a value of 0, 1 or 2; and Y, YY, and Z are such that the total number of moieties bonded to M is 3, 4, 5, or 6.

Abstract: The invention provide a silica nanoparticle comprising a non-porous matrix of silicon-oxygen bonds, wherein the matrix comprises organic agents conjugated to silicon or oxygen atoms in the matrix, the organic agents are conjugated to the matrix through linker L groups, wherein the linker L comprises, for example, an ester, urea, thiourea, or thio ether group, and wherein the diameter of the nanoparticle is about 15 nm to about 200 nm. The invention also provides novel methods of making and using the silica nanoparticles described herein.

Abstract: A coating composition comprising a Photocatalyst Composition comprising a photocatalyst and a pendent silyl ester group, wherein the photocatalyst produces singlet oxygen in the presence of light and ambient air. In certain embodiments, the coating composition further comprises a singlet oxygen scavenger.

Abstract: The present invention provides an anisotropic conductive material in which lower continuity resistance and higher adhesive strength are obtained, and a method for manufacturing the same. When a glass substrate and a metal wiring material are thermally compressed and bonded, in an interface between the glass substrate and an anisotropic conductive material, Si on a surface of the glass substrate reacts on an alkoxyl group (OR) at an end of disulfide silane modified by hydrophobic silica, and chemically binds thereto. Furthermore, at an interface between the metal wiring material and the anisotropic conductive material, a part of S—S bonds (disulfide bonds) in disulfide silane dissociates due to the heat at the time of thermocompression bonding, and the dissociated sulfide silane chemically binds to metal Me.

Abstract: This invention relates to organometallic precursor compounds represented by the formula (H)mM(R)n wherein M is a metal or metalloid, R is the same or different and is a substituted or unsubstituted, saturated or unsaturated, heterocyclic radical containing at least one nitrogen atom, m is from 0 to a value less than the oxidation state of M, n is from 1 to a value equal to the oxidation state of M, and m+n is a value equal to the oxidation state of M, a process for producing the organometallic precursor compounds, and a method for producing a film or coating from the organometallic precursor compounds.

Abstract: An asymmetric organomodified disiloxane surfactant having the formula: MM? wherein M comprises branched hydrocarbon substituents and M? comprises a cationic, anionic or zwitterionic substituent and a polyether substituent that may be combined as one moiety, wherein the disiloxane surfactant has an enhanced resistance to hydrolysis between a pH of about 3 to about 12.

Abstract: A rubber composition and a tire using the rubber composition utilizing a functionalized silica dry precipitated silica with a specific surface area in the range of 100 to 300 m2/gm treated with a plurality of silanes coupling agents to form a wet polymer silica masterbatch, then blending the masterbatch with a latex rubber component that includes a styrene-butadiene copolymer rubber or a blend of the styrene-butadiene copolymer rubber and another conjugated diene base rubber using a plurality of coupling agents simultaneously.

Abstract: Disclosed is a method of storing a fluorine-containing disilanol compound represented by the following formula (3) in the presence of a tertiary amine in such an amount that a molar ratio of the tertiary amine to a silanol group of the fluorine-containing disilanol compound ranges from 0.001 to 20, HO—Z—R1—Rf—R1—Z—OH??(3) wherein Rf is a divalent fluorinated hydrocarbon group or a divalent fluorinated polyether group, R1 may be the same with or different from each other and is a substituted or unsubstituted divalent hydrocarbon group which may have at least one atom selected from the group consisting of oxygen, nitrogen, silicon, and sulfur atoms, and Z is a group represented by the following formula (2) —SiR2R3—??(2) wherein R2 and R3 may be the same with or different from each other and are monovalent organic groups.