Chalcogen Containing Preservative Or Stabilizer Patents (Class 556/5)
  • Patent number: 7312251
    Abstract: Stable rare earth tris (organophosphate) solutions comprise a rare earth tris (organophosphate) and a hydrocarbon solvent. From about 2% to about 10% rare earth element, preferably from about 3% to about 8%, is present in the solutions. The rare earth tris (organophosphate) solutions are stable from precipitation of the rare earth tris (organophosphate) for at least about fifteen (15) days, preferably for at least about twenty (20) days and most preferably at least about thirty (30) days. A process for preparing these solutions is described herein. A stabilizing additive, acid, glycol or mixtures thereof, is utilized to inhibit precipitation. The molar ratios of free acid, glycol and/or water to the rare earth element are controlled to inhibit precipitation.
    Type: Grant
    Filed: April 7, 2004
    Date of Patent: December 25, 2007
    Assignee: Rhodia Rare Earths, Inc.
    Inventors: Kenan Yunlu, Min He
  • Patent number: 7067165
    Abstract: A mineral fortified food matrix can comprise a dimetalhydroxy malate composition and a food matrix fortified with the dimetalhydroxy malate composition. Additionally, a method of administering a mineral in a bioavailable form to a warm-blooded animal can comprise steps of fortifying a food matrix with a dimetalhydroxy malate composition and orally administering the food matrix to a warm-blooded animal. In one embodiment, the mineral can be calcium and the method of administering calcium in a bioavailable form can comprise fortifying a food matrix with a dicalciumhydroxy malate composition.
    Type: Grant
    Filed: January 21, 2004
    Date of Patent: June 27, 2006
    Assignee: Albion International, Inc.
    Inventors: Jennifer Hartle, Stephen D. Ashmead, Robert Kreitlow, Earl Christiansen
  • Patent number: 6927264
    Abstract: A metal complex useful as a component of a catalyst composition for addition polymerizations comprising an anionic, polycyclic, fused ring ligand system containing at least 4 fused rings, at least one such ring comprising at least one heteroatom, said ligand being bonded to M by means of delocalized ?-electrons and an addition polymerization process using the same.
    Type: Grant
    Filed: May 27, 2004
    Date of Patent: August 9, 2005
    Assignee: Dow Global Technologies Inc.
    Inventors: Shaoguang Feng, Ravi B. Shankar, Francis J. Timmers
  • Patent number: 6767927
    Abstract: Stable rare earth tris (organophosphate) solutions comprise a rare earth tris (organophosphate) and a hydrocarbon solvent. From about 2% to about 10% rare earth element, preferably from about 3% to about 8%, is present in the solutions. The rare earth tris (organophosphate) solutions are stable from precipitation of the rare earth tris (organophosphate) for at least about fifteen (15) days, preferably for at least about twenty (20) days and most preferably at least about thirty (30) days. A process for preparing these solutions is described herein. A stabilizing additive, acid, glycol or mixtures thereof, is utilized to inhibit precipitation. The molar ratios of free acid, glycol and/or water to the rare earth element are controlled to inhibit precipitation.
    Type: Grant
    Filed: April 25, 2000
    Date of Patent: July 27, 2004
    Assignee: Rhodia Rare Earths Inc.
    Inventors: Kenan Yunlu, Min He
  • Patent number: 6706904
    Abstract: Dimetalhydroxy malate compositions as well as methods of administering and making such bioavailable compositions are provided. The metal used can be any nutritionally relevant divalent metal such as calcium, magnesium, zinc, copper, manganese, and iron. The composition can be prepared by reacting malic acid with a divalent metal oxide or hydroxide at a 1:2 molar ratio. The composition can be administered to a warm-blooded animal by any of a number of known delivery routes, including oral delivery.
    Type: Grant
    Filed: December 4, 2002
    Date of Patent: March 16, 2004
    Assignee: Albion International, Inc.
    Inventors: Jennifer Hartle, Stephen D. Ashmead, Robert Kreitlow
  • Patent number: 6087515
    Abstract: A metallocene corresponding to the formula ##STR1## wherein M is a group 4 transition metal, each Y is, independently, selected from the group of halogen, hydrocarbyl and hydrocarbyloxy,R.sup.1, R.sup.4 are, independently, selected from the group of hydrogen, hydrocarbyl, hydrocarbyloxy,R.sup.2, R.sup.3, R.sup.5, R.sup.6, R.sup.7, R.sup.8 are, independently, selected from the group of hydrogen, hydrocarbyl, hydrocarbyloxy, with the provision that, respectively, R.sup.2 and R.sup.3, R.sup.5 and R.sup.6, R.sup.7 and R.sup.8 can be linked to each other.A process for the preparation of metallocenes comprising the following steps:(a) contacting, in a solvent, a transition metal halide of formula MX.sub.4 with an organometallic compound of formula M'R.sub.
    Type: Grant
    Filed: October 7, 1998
    Date of Patent: July 11, 2000
    Assignee: Solvay Polyolefins Europe-Belgium (Societe Anonyme)
    Inventors: John J. Eisch, Yun Qian, Jurgen Weber, Nicola Zandona, Fabian Siberdt
  • Patent number: 5030741
    Abstract: The invention relates to cyclic organometallic compounds which are intramolecularly stabilized and also to their use to produce thin films and epitaxial layers by gas-phase deposition.
    Type: Grant
    Filed: May 18, 1989
    Date of Patent: July 9, 1991
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventors: Dietrich Erdmann, Ludwig Pohl, Martin Hostalek, Matthias Lokai
  • Patent number: 4861500
    Abstract: A crosslinker composition that can produce delayed crosslinking of an aqueous solution of a crosslinkable organic polymer. The composition comprises an organic titanium complex. The composition further contains an organic hydroxycarboxylic acid, preferably hydroxyacetic acid. The pH of the composition is preferably less than 5. The pH of the composition is further preferably such that when sufficient amount of composition is added to an aqueous polymer solution to result in delayed crosslinking of the polymer, the composition produces a pH in the resulting gel solution, preferably of between about 3 to about 4.5. Gel solutions produced using the composition are particularly useful in fracturing subterranean formations, and in particular in fracturing subterranean formations penetrated by an oil well in which fracturing process carbon dioxide and a proppant are added to the fracturing fluid.
    Type: Grant
    Filed: November 17, 1986
    Date of Patent: August 29, 1989
    Assignee: Dowell Schlumberger Incorporated
    Inventor: Richard M. Hodge
  • Patent number: 4812333
    Abstract: A metal sulfide thin film, such as a zinc sulfide thin film, is formed by thermal decomposition of a metal mercaptide or other suitable metallo-organic compound having a metal-to-sulfur bond. To produce the film, the metallo-organic compound is applied to a substrate in a solution that also contains a sulfur to facilitate dissolution of the compound and enhance stability of the solution. It is also found that sulfur addition reduces carbon contamination of the product sulfide thin film.
    Type: Grant
    Filed: May 2, 1988
    Date of Patent: March 14, 1989
    Assignee: General Motors Corporation
    Inventor: Adolph L. Micheli
  • Patent number: 4659847
    Abstract: The present invention provides chemically stable colloidal antimony oxide which has been treated with a particular organosilicon compound in the ratio of from 0.5 to 25 weight % based on the antimony and whose pH has been regulated to within the range of from 2 to 12.
    Type: Grant
    Filed: March 29, 1985
    Date of Patent: April 21, 1987
    Assignee: Japan Exlan Company, Ltd.
    Inventors: Toshiyuki Kobashi, Hideo Naka
  • Patent number: 4644073
    Abstract: A sulfate-free clear green solution of chromium(III) propionate is prepared by mixing aqueous propionic acid containing up to 55 weight percent propionic acid with a chromium(VI) oxidant, such as a dichromate or chromate, and a sulfur-containing reductant, such as a bisulfite, which on reacting yields two phases: a lower sulfate-containing phase for discard or recycle and an upper phase solution of sulfate-free clear green propionate-sequestered chromium(III), the latter phase being stabilized with additional acid. The upper phase solution is useful for crosslinking polymeric viscosifiers such as partially hydrolyzed acrylamide-based polymers and the like in permeability contrast corrections in enhanced oil recovery operations.
    Type: Grant
    Filed: March 11, 1985
    Date of Patent: February 17, 1987
    Assignee: Phillips Petroleum Company
    Inventors: Naim A. Mumallah, Tod K. Shioyama
  • Patent number: 4636572
    Abstract: A process for preparing clear green chromium(III) propionate solutions which comprises admixing such as propionic acid with water, a chromium(VI) source such as dichromate, adding thereto a nitrite, such as sodium nitrite, to reduce the chromium(VI) to chromium(III), in the presence of excess acid, preferably propionic acid, optionally combined with additional acid such as muriatic acid, to produce a stable solution useful with polymers, such as partially hydrolyzed acrylamide-based polymers, in permeability contrast correction procedures for high permeability streaks in oil field treatments.
    Type: Grant
    Filed: March 11, 1985
    Date of Patent: January 13, 1987
    Assignee: Phillips Petroleum Company
    Inventors: Paul S. Hudson, Tod K. Shioyama