Divalent Chalcogen, Bonded Directly To Two Carbons Or To Carbon And Hydrogen, Attached Indirectly To Phosphorus By Acyclic Nonionic Bonding (wherein The Hydrogen May Be Replaced By Substituted Or Unsubstituted Ammonium, Or By A Group Ia Or Iia Light Metal) Patents (Class 558/165)
  • Publication number: 20140251178
    Abstract: This invention provides a viscosity modifier for high concentration dispersion of inorganic fine particles which can reduce, by giving excellent viscosity modifying function to a high concentration dispersion of inorganic fine particles (e.g., printing ink composition, functional paste composition or paint composition, of high concentration dispersion of inorganic fine particles), the occurrence of inconvenience in a printing step or coating step for the manufacture of components or substrates, and also provides a high concentration dispersion of inorganic fine particles which contains said viscosity modifier.
    Type: Application
    Filed: February 24, 2014
    Publication date: September 11, 2014
    Applicant: KUSUMOTO CHEMICALS, LTD.
    Inventors: Daisuke SHIMIZU, Junpei SUETOU, Chihiro HAMAZAKI, Kenichi ASANO, Hideki SATAKE, Eiichi SATO
  • Publication number: 20130078194
    Abstract: The present invention refers to compositions for the treatment or prophylaxis of infectious or inflammatory processes in the oral cavity (cavitas oris) including dental hygiene, the composition comprising lipoteichoic acids and glycerophosphate derivatives, preferably added into a dental hygiene product like toothpastes, toothgels, creams or rinsing fluids, the use of glycerophosphate derivatives as prophylaxis against bacterial infections of the oral cavity like dental caries, or the use of polyglycerophosphates for the production of a medicament for the treatment of or prophylaxis against bacterial infections of the oral cavity, like dental caries.
    Type: Application
    Filed: March 31, 2011
    Publication date: March 28, 2013
    Applicant: LUNAMED AG
    Inventor: Peter Truog
  • Publication number: 20120058358
    Abstract: The present invention relates to timber materials rendered flame-retardant by using halogen-free organophosphorus compounds, to means and processes for producing these materials, and also to their use.
    Type: Application
    Filed: August 26, 2011
    Publication date: March 8, 2012
    Applicant: LANXESS DEUTSCHLAND GMBH
    Inventors: Jan-Gerd Hansel, Heiko Tebbe
  • Patent number: 6235689
    Abstract: The degree of bonding of a perfluoro polyether lubricant topcoat to a magnetic recording medium is improved by forming a polymeric phosphate derivative thereof. In an embodiment of the present invention, a perfluoro polyether phosphate polymer is formed with a molecular weight of about 1000 to about 5000, and applied to a magnetic recording medium to achieve a bonded lube ratio in excess of 0.9.
    Type: Grant
    Filed: October 5, 1998
    Date of Patent: May 22, 2001
    Assignee: Seagate Technology LLC
    Inventor: Samuel J. Falcone
  • Patent number: 6160153
    Abstract: The present invention provides crosslinking, conjugating and reducing agents which are functional with at least one phosphorothioate monoester group (--SPO.sub.3.sup.--2). Crosslinking and conjugation methods as well as solid phase reagents and conjugates which are useful in immunoassays are also provided.Crosslinking and conjugating agents of the invention generally comprise a compound corresponding to the formula (I), shown below, wherein n at least 1 and Q is a straight or branched monomer, polymer or oligomer having an average molecular weight between about 200 and about 1,000,000. Additionally, when n is 1, Q comprises at least 1 additional reactive functionality.Q--(S--PO.sub.3.sup.-2).sub.n (I)The reducing agents that are provided conform to a compound of the formula (Y), shown below, wherein (A) and (Z) can be independently selected from C.sub.1 -C.sub.5 alkyl and CONH(CH.sub.2).sub.p wherein p is an integer between 1 and 5.
    Type: Grant
    Filed: February 3, 2000
    Date of Patent: December 12, 2000
    Assignee: Abbott Laboratories
    Inventors: Christopher Bieniarz, Douglas F. Young, Michael J. Cornwell, Zbigniew Skrzypczynski
  • Patent number: 6121222
    Abstract: A novel class of anionic surfactants with improved surfact active properties is comprised of two hydrophilic and two hydrophobic groups represented by the formula: ##STR1## The surfactants exhibit unusually low critical micelle concentration (cmc) and pC-20 values in aqueous media.
    Type: Grant
    Filed: December 27, 1996
    Date of Patent: September 19, 2000
    Assignee: Rhodia Inc.
    Inventors: Ruoxin Li, David James Tracy, Jiang Yang, Manilal S. Dahanayake
  • Patent number: 6107507
    Abstract: An aryl group containing phosphite, such as triphenyl phosphite, can be added to a reaction mixture comprising an organophosphorus compound, phosphorus pentoxide and an alkylene oxide, optionally in the presence of a reagent for the incorporation of hydroxy functionality in the final product. The aryl group containing phosphite is employed to improve the color characteristics of the resulting oligomeric organophosphorus composition.
    Type: Grant
    Filed: September 10, 1999
    Date of Patent: August 22, 2000
    Assignee: Akzo Nobel NV
    Inventor: Jeffrey K. Stowell
  • Patent number: 6008398
    Abstract: A phosphorus ester oligomer having the structure: wherein A can be the same or different in each monomeric unit and each is independently selected from the group consisting of oxygen, sulfur, lower alkyl, substituted or unsubstituted alkylamino, substituted or unsubstituted arylamino and aminoalkyl; B.sub.1 and B.sub.2 can be the same or different and each is independently selected from hydrogen, lower alkyl, a labeling group, a protecting group, a phosphoramidate or a phosphomonoester; R.sub.1 can be the same or different in each monomeric unit, and in at least one of the non-nucleotide monomeric units, R.sub.
    Type: Grant
    Filed: February 1, 1996
    Date of Patent: December 28, 1999
    Assignee: Genzyme Corporation
    Inventors: Robert Gerard Gentles, Alan F. Cook, Morris Jonathan Rudolph, Reza Fathi
  • Patent number: 5944650
    Abstract: A surfactant composition represented by Formulas (I), (II) or (III); or optionally mixtures thereof ##STR1## wherein R.sup.1 is a hydrophobic moiety of alkyl or aryl, and wherein alkyl contains from about 4 to about 60 carbon atoms and aryl contains from about 6 to about 60 carbon atoms; R.sup.2 is selected from the group consisting of alkyl and aryl, wherein alkyl contains from 1 to about 60 carbon atoms and aryl contains from about 6 to about 60; R.sup.3 is hydrogen or alkyl of from 1 to about 10 carbon atoms; A is a hydrophilic polymer chain; m is the number of repeating segments of the hydrophilic polymer chain and is a number of from about 2 to about 500.
    Type: Grant
    Filed: October 29, 1997
    Date of Patent: August 31, 1999
    Assignee: Xerox Corporation
    Inventors: Nan-Xing Hu, Paul F. Smith, Beng S. Ong
  • Patent number: 5922897
    Abstract: A process for the preparation of surfactants is described comprising reacting a phosphorus acid ester of the following Formula (IV) ##STR1## wherein R.sup.t is aryl, R.sup.2 is alkyl or aryl, with a hydrophilic polyoxyalkylene of the following Formulas (VIII), or (IX) ##STR2## wherein R.sup.3 is alkyl and A is a hydrophilic polyoxyalkylene chain, and which reaction results in an intermediate compound Formulas (XI), (XII), or (XIII); ##STR3## reacting the intermediate compound selected from the group consisting of Formulas (XI) through (XIII), with a hydroxylic compound R.sup.1 -OH (X) to yield surfactant precursors comprised of Formulas (V), (VI), and (VII), respectively: ##STR4## and, oxidizing said phosphorus ester-linked surfactant precursors selected from the group consisting of Formulas (V), (VI) and (VII), with an oxidizing agent to produce the surfactants.
    Type: Grant
    Filed: May 29, 1998
    Date of Patent: July 13, 1999
    Assignee: Xerox Corporation
    Inventors: Nan-Xing Hu, H. Bruce Goodbrand
  • Patent number: 5824815
    Abstract: A composition that comprises a phosphatized alicyclic compound represented by the formulas (I), (II), (III), (VII) and (IX) as shown in the specification is described.
    Type: Grant
    Filed: September 23, 1997
    Date of Patent: October 20, 1998
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Takaaki Fujiwa, Terumasa Daito, Takashi Yamamoto, Takashi Matsufuji
  • Patent number: 5608100
    Abstract: The invention relates to mixtures of oligomeric phosphoric acid esters which carry hydroxyalkoxy groups, of the formula I ##STR1## in which R.sub.1 is a hydroxyl-containing radical of the formula IIa,R.sub.2 is a radical of the formula III ##STR2## R.sub.3 is a radical of the formula IIb, R.sub.4 is R.sub.1 or R.sub.3 ; R.sub.5, R.sub.6 and R.sub.7 are an H atom or an alkyl radical having 1 to 6 carbon atoms, m is 0 to 4, n is 1 to 4 q is 0 to 20 and q (the mean) is 0.5 to 10.The invention also relates to a process for the preparation of the mixtures and to their use as reactive flameproofing agents in polyurethane foams.
    Type: Grant
    Filed: December 13, 1995
    Date of Patent: March 4, 1997
    Assignee: Hoechst Aktiengesellschaft
    Inventor: Martin Sicken
  • Patent number: 5476888
    Abstract: The diposphines have the formula (I) ##STR1## wherein: R.sup.2, R.sup.3 and R.sup.4 independently from each other represent a hydrocarbyl group which is substituted with one or more radicals selected from the group consisting of halogen, alkyl and alkoxy, andA is --C(O)--, --S(O).sub.2 --, --S(O)-- or certain divalent organic groups.The diphosphines are useful for stabilizing thermoplastic polymers, such as polycarbonates, against thermal discoloration.
    Type: Grant
    Filed: September 2, 1994
    Date of Patent: December 19, 1995
    Assignee: The Dow Chemical Company
    Inventors: Jurgen Eiffler, Gunter A. Juptner, David P. Flores
  • Patent number: 5312953
    Abstract: Polyether bis-phosphonic acid compounds are disclosed which have the formula (HO).sub.2 OP--R--(OR').sub.n --OR--PO(OH).sub.2 where R is selected from the group consisting of methylene and ethylene, R' is selected from the group consisting of ethylene and ethylene substituted with one or more methyl groups, and n is an integer from 1 to 4, water soluble salts thereof, and esters thereof with alkyl groups having from 1 to 6 carbon atoms. Also disclosed is a novel preparation of these compounds by reacting hydroxyalkylphosphonic acid dialkyl ester compounds with 2-benzyloxyalkyl organic sulfonates; reacting the intermediate formed therefrom with hydrogen or a hydrogen source; reacting the intermediate formed therefrom with a hydrogen ion acceptor and certain sulfonyl chlorides; and reacting the intermediate formed therefrom with hydroxyalkylphosphonic acid dialkyl ester compounds to form a polyether bis-phosphonic acid compound which may be hydrolyzed to form the polyether bis-phosphonic acid.
    Type: Grant
    Filed: August 17, 1993
    Date of Patent: May 17, 1994
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Charles G. Carter, Ranjit Kumar
  • Patent number: 5306436
    Abstract: Useful as additive for lubricating oils are novel phosphosulphur compounds in accordance with the general formula (I):(((R.sup.1 --S.sub.x --O.sub.y --A--).sub.r B.sub.v).sub.p P(X)--Y.sub.t --).sub.q Z.sub.min which e.g. R.sup.1 represents an alkyl or alkenyl group, A represents the group --(CH.sub.2).sub.n --O--, B represents the group --P(S)--S--CH.sub.2 --(CH.sub.3)--O--, X represents an oxygen atom or a sulphur atom, Y represents an oxygen atom, a sulphur atom or an oxygen or sulphur-containing hydrocarbon chain, Z represents a hydrogen, chlorine or sulphur atom, a polysulphide chain, a metal or an alkyl or alkenyl group, x=1,2 or 3, y=0, 1 or 2, v is 0 or 1, r is 1 (if v=0) or r=2 (if v=1), p=2 or 3, t=0 or 1, m=0,1 or 2, q=the valency of Z if Z is a metal or q=1 or 2 and n is an integer from 1 to 30.
    Type: Grant
    Filed: August 26, 1991
    Date of Patent: April 26, 1994
    Assignee: Institut Francais du Petrole
    Inventors: Maurice Born, Ourida Aberkane, Jean-Luc Mieloszynski, Daniel Paquer, Guy Parc
  • Patent number: 5266722
    Abstract: Polyether bis-phosphonic acid compounds are disclosed which have the formula (HO).sub.2 OP--R--(OR').sub.n --OR--PO(OH).sub.2 where R is selected from the group consisting of methylene and ethylene, R' is selected from the group consisting of ethylene and ethylene substituted with one or more methyl groups, and n is an integer from 1 to 4, water soluble salts thereof, and esters thereof with alkyl groups having from 1 to 6 carbon atoms.
    Type: Grant
    Filed: November 9, 1988
    Date of Patent: November 30, 1993
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Charles G. Carter, Ranjit Kumar
  • Patent number: 5162405
    Abstract: The present invention comprises novel single-functional and mixtures of multi-functional oligomeric performance additive compounds having one or more components of Structure A R1 ? ? ##STR1## (The definitions of R, Z1, Z2, Z3, A1, A2, A3 and y are given in the Summary Section), their uses and polymeric compounds and compositions containing them which have enhanced oxidative stabilities, enhanced ultraviolet (UV) and light stabilites and/or enhanced flame retardance. An example is the bis sulfonic acid bispotassium salt reaction product from an oligomeric caprolactone diol (TONE.RTM. 260), 2-sulfobenzoic acid anhydride and potassium carbonate, and use of this product, at levels up to about 3.0%, in a general purpose bisphenol A polycarbonate resin, to enhance the fire resistance or flame retardance of the polycarbonate resin.
    Type: Grant
    Filed: March 22, 1991
    Date of Patent: November 10, 1992
    Assignee: ELF Atochem North America, Inc.
    Inventors: Ronald E. MacLeay, Jose Sanchez, Daryl L. Stein
  • Patent number: 5117033
    Abstract: There are disclosed multiphosphorus-containing compounds comprising phosphonate-containing or phosphate-containing phosphate esters. The compounds can be prepared by: (a) reacting a phosphonate-containing or phosphate-containing alcohol with phosphorus pentoxide following by reaction with an epoxide, (b) reacting a phosphonate-containing or phosphate-containing alcohol with a phosphorus oxyhalide, hydrolyzing any phosphorus halogen bonds and then reacting with the resulting phosphoric acid derivative with an epoxide, (c) transesterifying a phosphonate-containing or phosphate-containing alcohol with a dialkyl phosphite, oxidizing the resulting compound to yield a phosphoric acid derivative and reacting the phosphoric acid derivative with an epoxide. The compounds are useful as flame retardant additives for polyurethanes and textiles.
    Type: Grant
    Filed: October 31, 1990
    Date of Patent: May 26, 1992
    Assignee: Akzo America Inc.
    Inventors: Thomas A. Hardy, Edward N. Walsh
  • Patent number: 5091550
    Abstract: 5,5-Bis(perfluoroalkylheteromethyl)-2-hydroxy-2-oxo-1,3,2-dioxaphosphorinan es, derived acyclic phosphorus and phosphoric acids obtained by ring-opening, and salts or esters thereof are prepared from heteroatom containing perfluoroalkyl terminated neopentyl glycols of the formula: HO[CH.sub.2 C(CH.sub.2 --X--E.sub.n --R.sub.f).sub.2 CH.sub.2 O]H by cyclization with appropriate phosphorus containing esters or acids, or hydrolysis. These compositions provide improved thermal stability, and useful low surface energy oil and water repellent coatings for textiles, glass, paper, leather and other materials.Another aspect of this invention relates to the use of the phosphite group containing products as polymer stabilizers.
    Type: Grant
    Filed: April 20, 1990
    Date of Patent: February 25, 1992
    Assignee: Ciba-Geigy Corporation
    Inventors: Robert A. Falk, Kirtland P. Clark
  • Patent number: 5013777
    Abstract: The present invention comprises novel single-functional and mixtures of multi-functional oligomeric performance additive compounds having one or more components of Structure A ##STR1## (The definitions of R, Z1, Z2, Z3, A1, A2, A3 and y are given in the Summary Section), their uses and polymeric compounds and compositions containing them which have enhanced oxidative stabilities, enhanced ultraviolet (UV) and light stabilities and/or enhanced flame retardance. An example is the bis sulfonic acid bispotassium salt reaction product from an oligomeric caprolactone diol (TONE.RTM. 260), 2-sulfobenzoic acid anhydride and potassium carbonate, and use of this product, at levels up to about 3.0%, in a general purpose bisphenol A polycarbonate resin, to enhance the fire resistance or flame retardance of the polycarbonate resin.
    Type: Grant
    Filed: December 24, 1987
    Date of Patent: May 7, 1991
    Assignee: Atochem North America, Inc.
    Inventors: Ronald E. MacLeay, Jose Sanchez, Daryl L. Stein
  • Patent number: 5013465
    Abstract: Metal dithiophosphates obtainable by reacting a basic zinc or copper compound or a molybdenum compound with a dithiophosphoric acid, said dithiophosphoric acid being obtainable by reacting phosphorus pentasulphide with a mixture of alcohols ROH and R.sup.1 (OH).sub.m where m is 1 or 2, the group R is an aliphatic hydrogen- and carbon-containing group having at least 4 carbon atoms, e.g. a C.sub.4 to C.sub.10 alkyl group, or is an alkaryl group, R.sup.1 is a hydrogen- and carbon-containing group containing at least 12 carbon atoms and either (a) a ##STR1## group or (b) the group--(C.sub.n H.sub.2n-p R.sub.p.sup.2 O).sub.q --, R.sup.2 being an alkyl group, n begin an integer of from 2 to 5, p being zero or an integer of from 1 to 5 and q being an integer of 2 or more or R.sup.1 (OH.sub.m is a glyceryl derivative having the formula ##STR2## where R.sup.3 is an aliphatic hydrogen- and carbon-containing group containing at least 9 carbon atoms and R.sup.4, R.sup.5, R.sup.6 and R.sup.7 are hydrogen or alkyl groups.
    Type: Grant
    Filed: December 22, 1988
    Date of Patent: May 7, 1991
    Assignee: Exxon Chemical Patents, Inc.
    Inventor: Terence Colclough
  • Patent number: 4959441
    Abstract: Alkenylphosphonic and -phosphinic acid esters of 1,1,1-tris(hydroxymethyl)alkanes and of 2,2-bis-hydroxymethyl-1,3-propanediol are useful as cross-linking agents in polymeric hydrogels.
    Type: Grant
    Filed: May 8, 1989
    Date of Patent: September 25, 1990
    Assignee: Cassella Aktiengesellschaft
    Inventors: Friedrich Engelhardt, Ulrich Riegel, Joachim Gersdorf, Hans-Jerg Kleiner
  • Patent number: 4853455
    Abstract: The present invention relates to hardenable mixtures containing:(i) a polyglycidyl ether or ester based on an aliphatic, cycloaliphatic or aromatic alcohol or a corresponding carboxylic acid and(ii) a hardener obtainable by reaction of:(A) a mixture of 2-4 mol of a monohydric, aliphatic alcohol and 1 mol of phosphorus pentoxide in an inert organic solvent, or of 2 mol of a dialkyl phosphate or of 2 mol of phosphoric acid, if appropriate in combination with 1-2 mol of a monohydric, aliphatic alcohol, with(B) 0.5-1.5 mol of a diglycidyl ether based on a cycloaliphatic or aromatic diol,with the proviso that the said diglycidyl ether used for the preparation of the hardener has an average molecular weight (number-average) of not more than 2,500 and the said hardener is essentially free from 1,2-epoxide groups.The hardenably mixtures are suitable in particular for the production of coatings.
    Type: Grant
    Filed: May 6, 1988
    Date of Patent: August 1, 1989
    Assignee: Ciba-Geigy Corporation
    Inventors: Wolfgang Schneider, Kurt Amsler
  • Patent number: 4766228
    Abstract: The invention relates to compounds of the metal dihydrocarbyl-dithiophosphyl-dithiophosphate type, their manufacture and use. These compounds can be represented by the general formula: ##STR1## wherein R is a monovalent substantially hydrocarbon-containing radical of 1 to 30 carbon atoms, X and Y are each a hydrogen atom or a monovalent substantially hydrocarbon-containing radical of 1 to 30 carbon atoms, M is a metal selected from zinc, cadmium, lead and antimony or an oxygen- and/or sulfur-containing molybdenum complex, and n is the valence of said metal M. The compounds according to the invention can be used as additives for lubricants wherein they act as a very efficient wear preventive.
    Type: Grant
    Filed: September 4, 1986
    Date of Patent: August 23, 1988
    Assignee: Institut Francais du Petrole
    Inventors: Maurice Born, Jacques Lallement, Pierre Marchand, Guy Parc, Nicole Thevenin
  • Patent number: 4697029
    Abstract: Phosphobrominated polyetherpolyols which contain in their molecule oxyalkylene radicals bound to phosphorus atoms in the phosphate or phosphonate state and 1,4-dioxy-2,3-dibromo-2-butylene radicals in which the ratio of the total number of oxyalkylene radicals to the total number of phosphorus atoms is equal to at least 7.These polyetherpolyols can be used as flame-retarding reactive additives in the manufacture of flame-retardant flexible polyurethane foams involving polyetherpolyols, the foams possessing good comfort-conferring properties.
    Type: Grant
    Filed: January 17, 1986
    Date of Patent: September 29, 1987
    Assignee: Solvay & Cie. (Societe Anonyme)
    Inventors: Andre Collin, Henri Wautier