Acyclic Carbon Chain Containing Carbon To Carbon Unsaturation Attached Directly To The Sulfonate Group By Nonionic Bonding Patents (Class 558/55)
  • Patent number: 9221750
    Abstract: The invention relates to a process for preparing an internal olefin sulfonate, comprising sulfonating an internal olefin, having an average carbon number that is equal to or greater than 20, in a sulfonation reactor into sulfonated internal olefin followed by contacting sulfonated internal olefin with a base containing solution, wherein the sulfonation reactor is cooled with a cooling means having a temperature which is greater than 35° C. Further, the invention relates to an internal olefin sulfonate obtainable by said process, and to use of internal olefin sulfonates obtainable or obtained by said process as a surfactant, suitably as a surfactant in chemical Enhanced Oil Recovery.
    Type: Grant
    Filed: February 22, 2013
    Date of Patent: December 29, 2015
    Assignee: Shell Oil Company
    Inventors: Julian Richard Barnes, Hendrik Dirkzwager, Robert Moene
  • Patent number: 8993798
    Abstract: The present invention is directed to an isomerized alpha olefin sulfonate and a method of making the same wherein the isomerized alpha olefin sulfonate is derived from sulfonating an isomerized alpha olefin with sulfur trioxide in the presence of air thereby producing an isomerized alpha olefin sulfonic acid, wherein the isomerized alpha olefin is derived from the isomerization of C12-C20 normal alpha olefins; and neutralizing the isomerized alpha olefin sulfonic acid with a source of an alkali metal or ammonium or substituted ammonium ion.
    Type: Grant
    Filed: December 8, 2010
    Date of Patent: March 31, 2015
    Assignee: Chevron Oronite Company LLC
    Inventors: Curtis Bay Campbell, Andrew J. Howes
  • Publication number: 20150073168
    Abstract: The invention relates to a process for preparing an internal olefin sulfonate, comprising sulfonating an internal olefin, having an average carbon number that is equal to or greater than 20, in a sulfonation reactor into sulfonated internal olefin followed by contacting sulfonated internal olefin with a base containing solution, wherein the sulfonation reactor is cooled with a cooling means having a temperature which is greater than 35° C. Further, the invention relates to an internal olefin sulfonate obtainable by said process, and to use of internal olefin sulfonates obtainable or obtained by said process as a surfactant, suitably as a surfactant in chemical Enhanced Oil Recovery.
    Type: Application
    Filed: February 22, 2013
    Publication date: March 12, 2015
    Inventors: Julian Richard Barnes, Hendrik Dirkzwager, Robert Moene
  • Publication number: 20140087309
    Abstract: There are disclosed olefinic acid amplifier triggers and methods of using these compositions in, for example, photolithography.
    Type: Application
    Filed: March 28, 2012
    Publication date: March 27, 2014
    Applicant: THE RESEARCH FOUNDATION OF STATE UNIVERSITY OF NEW YORK
    Inventors: Brian Cardineau, Robert L. Brainard
  • Publication number: 20130296323
    Abstract: This invention relates to geranylgeranyl acetone (GGA) derivatives and the use of GGA, its isomers, and GGA derivatives in methods for inhibiting neural death, increasing neural activity, increasing axon growth and cell viability, and increasing the survival rate of subjects administered the GGA or GGA derivatives.
    Type: Application
    Filed: February 27, 2013
    Publication date: November 7, 2013
    Applicant: COYOTE PHARMACEUTICALS, INC.
    Inventors: Hiroaki Serizawa, Ankush B. Argade, Akash Datwani, Natalie Spencer, Yonghua Pan, Florian Ermini
  • Publication number: 20130225408
    Abstract: Fatty amine compositions made from a metathesis-derived C10-C17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives are disclosed. In another aspect, fatty amidoamines made by reacting a metathesis-derived C10-C17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives with an aminoalkyl-substituted tertiary amine are disclosed. The fatty amines or amidoamines are advantageously sulfonated, sulfitated, oxidized, or reduced. In other aspects, the ester derivative is a modified triglyceride made by self-metathesis of a natural oil or an unsaturated triglyceride made by cross-metathesis of a natural oil with an olefin.
    Type: Application
    Filed: October 25, 2011
    Publication date: August 29, 2013
    Applicant: STEPAN COMPANY
    Inventors: Dave R. Allen, Marcos Alonso, Randal J. Bernhardt, Aaron Brown, Kelly Buchek, Gary Luebke, Renee Luka, Andrew D. Malec, Ronald A. Masters, Lawrence A. Munie, Dennis S. Murphy, Irene Shapiro, Patti Skelton, Brian Sook, Michael R. Terry, Laura Lee Whitlock, Michael Wiester, Patrick Shane Wolfe
  • Publication number: 20130224578
    Abstract: The present invention relates to a nonaqueous electrolyte solution comprising a lithium salt and a nonaqueous organic solvent, wherein the nonaqueous electrolyte solution comprises a specific sulfonic acid ester.
    Type: Application
    Filed: April 18, 2013
    Publication date: August 29, 2013
    Applicant: MITSUBISHI CHEMICAL CORPORATION
    Inventor: MITSUBISHI CHEMICAL CORPORATION
  • Publication number: 20130079261
    Abstract: A process for recovering oil from an oil-bearing formation comprises introducing into said formation an aqueous composition comprising at least one sulfonated derivative of one or more internal olefins, said internal olefins being characterized by having low amounts of tri-substitution on the olefin bond, said sulfonated derivative being obtained by sulfonating a composition comprising internal olefins of the formula: R1R2C?CR3R4 wherein R1, R2, R3 and R4 are the same or different and are hydrogen or straight- or branched-chain, saturated hydrocarbyl groups and the total number of carbon atoms of R1, R2, R3 and R4 is 6 to 44 with the proviso that at least about 96 mole percent of R1 and R3 are straight- or branched-chain, saturated hydrocarbyl groups and at least about 96 mole percent of R2 and R4 are hydrogen. Further provided are compositions for use in recovering oil from an oil bearing formation.
    Type: Application
    Filed: May 20, 2011
    Publication date: March 28, 2013
    Inventors: John C. Hutchison, Patrick Shane Wolfe
  • Publication number: 20120301797
    Abstract: The present invention provides an excellent nonaqueous electrolytic solution capable of improving low-temperature and high-temperature cycle properties and load characteristics after high-temperature charging storage, an electrochemical element using it, and an alkynyl compound used for it. The nonaqueous electrolytic solution of the present invention comprises containing at least one alkynyl compound represented by the following general formula (I) in an amount of from 0.01 to 10% by mass in the nonaqueous electrolytic solution. R1(O)n—X1—R2??(I) (In the formula, X1 represents a group —C(?O)—, a group —C(?O)—C(?O)—, a group —S(?O)2—, a group —P(?O) (—R3)—, or a group —X2—S(?O)2O—.
    Type: Application
    Filed: February 2, 2011
    Publication date: November 29, 2012
    Applicant: UBE Industries, Ltd.
    Inventors: Koji Abe, Kazuhiro Miyoshi, Masahide Kondo
  • Patent number: 8299289
    Abstract: The present invention is directed to an isomerized alpha olefin sulfonate and a method of making the same wherein the isomerized alpha olefin sulfonate is derived from sulfonating an isomerized alpha olefin with sulfur trioxide in the presence of air thereby producing an isomerized alpha olefin sulfonic acid, wherein the isomerized alpha olefin is derived from the isomerization of C12-C40 normal alpha olefins; and neutralizing the isomerized alpha olefin sulfonic acid with a source of a mono-valent cation.
    Type: Grant
    Filed: July 29, 2011
    Date of Patent: October 30, 2012
    Assignee: Chevron Oronite Company LLC
    Inventors: Curtis Bay Campbell, Theresa Ann Denslow
  • Patent number: 8097746
    Abstract: The present invention provides a method of producing 2-isopropenyl-5-methyl-4-hexen-1-yl 3-methyl-2-butenoate industrially advantageously in a high yield. More particularly, the present invention provides a method of producing 2-isopropenyl-5-methyl-4-hexen-1-yl 3-methyl-2-butenoate represented by the following formula (IV): which comprises reacting 2-isopropenyl-5-methyl-4-hexen-1-ol with an organic sulfonyl halide in the presence of a basic substance to give a sulfonate compound represented by the following formula (III): wherein R is a hydrocarbon group, and reacting the obtained sulfonate compound with senecionic acid in the presence of a basic substance.
    Type: Grant
    Filed: March 29, 2006
    Date of Patent: January 17, 2012
    Assignee: Kuraray Co., Ltd.
    Inventors: Katsuji Ujita, Junko Sato, Takashi Fukumoto
  • Publication number: 20110053883
    Abstract: The present invention provides an agent that modulates physiological condition of pests, wherein the agent has an ability to modulate the activity of an insect c-Jun NH2-terminal kinase; a method for assaying pesticidal activity of a test substance, which comprises a step of measuring the activity of a c-Jun NH2-terminal kinase in a reaction system in which the c-Jun NH2-terminal kinase contacts with a test substance, and the like.
    Type: Application
    Filed: June 23, 2006
    Publication date: March 3, 2011
    Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Yasutaka Shimokawatoko, Mar Van De Craen, Irene Nooren, Sandra Turconi, Annelies Roobrouck, Wendy Maddelein
  • Publication number: 20100197950
    Abstract: The preparation of an intermediate, a process for the preparation thereof and the process of preparing [4-[3,3-Bis-(4-bromo-phenyl)-allyloxy]-2-methyl-phenoxy]-acetic acid using this intermediate are described.
    Type: Application
    Filed: June 6, 2007
    Publication date: August 5, 2010
    Inventors: Kaare Gyberg Rasmussen, Signe Maria Christensen, Rikke Eva Humble
  • Publication number: 20090112014
    Abstract: The present invention is directed to an isomerized alpha olefin sulfonate and a method of making the same wherein the isomerized alpha olefin sulfonate is derived from sulfonating an isomerized alpha olefin with sulfur trioxide in the presence of air thereby producing an isomerized alpha olefin sulfonic acid, wherein the isomerized alpha olefin is derived from the isomerization of C12-C40 normal alpha olefins; and neutralizing the isomerized alpha olefin sulfonic acid with a source of a mono-valent cation.
    Type: Application
    Filed: October 23, 2008
    Publication date: April 30, 2009
    Applicant: Chevron Oronite Company LLC
    Inventors: Curtis Bay Campbell, Theresa Anne Denslow
  • Publication number: 20090023941
    Abstract: The present invention provides a method of producing 2-isopropenyl-5-methyl-4-hexen-1-yl 3-methyl-2-butenoate industrially advantageously in a high yield. More particularly, the present invention provides a method of producing 2-isopropenyl-5-methyl-4-hexen-1-yl 3-methyl-2-butenoate represented by the following formula (IV): which comprises reacting 2-isopropenyl-5-methyl-4-hexen-1-ol with an organic sulfonyl halide in the presence of a basic substance to give a sulfonate compound represented by the following formula (III): wherein R is a hydrocarbon group, and reacting the obtained sulfonate compound with senecionic acid in the presence of a basic substance.
    Type: Application
    Filed: March 29, 2006
    Publication date: January 22, 2009
    Applicant: KURARAY CO., LTD.
    Inventors: Katsuji Ujita, Junko Sato, Takashi Fukumoto
  • Publication number: 20030100786
    Abstract: Provided is a bis(diphenylvinyl)arene compound having a reactive functional group on phenyl group, represented by below formula (1), 1
    Type: Application
    Filed: August 20, 2002
    Publication date: May 29, 2003
    Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Takahiro Ueoka, Hideyuki Ikehira, Yoshiaki Tsubata
  • Patent number: 6506539
    Abstract: A complex of a dye cation and an anionic TCNQ derivative of the formula (I): in which [Dye]+ is a dye cation, L1 is a linking group, R1 is a substituent group, p is an integer of 1-4, and r is an integer of 0-3 under the condition of 1<p+r<4, is favorably employable as a dye compound for preparing a recording layer of CD-R or DVD-R.
    Type: Grant
    Filed: April 6, 2001
    Date of Patent: January 14, 2003
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shinichi Morishima, Takashi Usami
  • Patent number: 6046351
    Abstract: The invention concerns a novel process for preparing racemic phenethylamines of formula (I) ##STR1## in which R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 have the meanings given in the description. According to this process: a) in a first step, optically active phenethylamines of formula (I*) ##STR2## are reacted with acetophenone derivatives of formula (II), ##STR3## the optically active phenethylamine used and the acetophenone derivative used each being substituted in an identical manner in the phenyl part, optionally in the presence of a diluting agent and optionally in the presence of a catalyst; b) in a second step, the resultant optically active Schiff bases of formula (III*) ##STR4## are reacted with metallic hydroxides containing between 0.1 and 50 wt. % water; and c) in a third step, the resultant racemic Schiff bases are reacted with acids in the presence of water.
    Type: Grant
    Filed: January 19, 1999
    Date of Patent: April 4, 2000
    Assignee: Bayer Aktiengesellschaft
    Inventor: Uwe Stelzer
  • Patent number: 6034127
    Abstract: Amidino and benzamidino compounds, including compounds of the formula: ##STR1## wherein R.sup.1 -R.sup.4, R.sup.6 -R.sup.9, Y, Z, n and m are set forth in the specification, as well as hydrates, solvates or pharmaceutically acceptable salts thereof, that inhibit a number of proteolytic enzymes are described. Also described are methods for preparing the compounds of Formula I.
    Type: Grant
    Filed: December 27, 1996
    Date of Patent: March 7, 2000
    Assignee: 3-Dimensional Pharmaceuticals, Inc.
    Inventors: Tianbao Lu, Bruce E. Tomczuk, Carl R. Illig, Richard M. Soll
  • Patent number: 5618965
    Abstract: Process for preparing a nitrile of the formula (I) ##STR1## in which R.sub.1, R.sub.2 and R.sub.3 are for example hydrogen, halogen, cyano, hydroxyl, carboxyl, alkyl, alkoxy, alkylthio, alkylamino, dialkylamino, aryl, aryloxy, arylthio or arylamino, or R.sub.2 and R.sub.3 together form a substituted or unsubstituted 4-membered carbon bridge,by reacting an aldehyde of the formula (II) ##STR2## with a hydroxylammonium salt followed by dehydration by heating to an elevated temperature, wherein the reaction takes place in the presence of an anhydrous inorganic sulfate and in the absence of diluents from the group consisting of carboxylic acids, strongly polar aprotic solvents, sulfur compounds and heteroaromatic basic nitrogen compounds.The nitriles obtainable by the process of the invention are valuable intermediates for, in particular, the preparation of diketopyrrolopyrrole pigments.
    Type: Grant
    Filed: March 4, 1996
    Date of Patent: April 8, 1997
    Assignee: CIBA-GEIGY Corporation
    Inventor: Martin Kudschus
  • Patent number: 5498491
    Abstract: This invention is directed to solid electrolytes containing a solid polymeric matrix derived from vinyl sulfonate polyalkylene oxides.
    Type: Grant
    Filed: February 4, 1994
    Date of Patent: March 12, 1996
    Inventor: Milton N. Golovin
  • Patent number: 5489491
    Abstract: Vinyl sulfonate-derivatized oligomers of poly(oxyalkylene)glycols or polyesters and isocyanate are urethane linked polymer precursors for the solid polymeric matrix of a solid electrolyte. The solid polymeric matrix is made by crosslinking the vinyl sulfonate-derivatized oligomer.
    Type: Grant
    Filed: April 20, 1994
    Date of Patent: February 6, 1996
    Inventor: Milton N. Golovin
  • Patent number: 5340837
    Abstract: Compounds of the formula ##STR1## wherein each of o and p, independently of the other, is 0, 1, 2, 3, 4 or 5, the radicals R.sub.1 being the same or different when o is greater than 1 and the radicals R.sub.2 being the same or different when p is greater than 1;each of R.sub.1 and R.sub.2, independently of the other, is C.sub.1 -C.sub.4 alkyl, halo-C.sub.1 -C.sub.4 alkyl, halogen, --NO.sub.2, --OH, C.sub.1 -C.sub.4 alkoxy, halo-C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylthio, halo-C.sub.1 -C.sub.4 alkylthio, --O--S(.dbd.O)--R.sub.6, --O--S(.dbd.O).sub.2 --R.sub.6, phenoxy or --N(R.sub.11)SO.sub.2 R.sub.12 and/or two substituents R.sub.1 and/or two substituents R.sub.2 are, independently of one another, together --Y--Z--Y--;R.sub.3 is hydrogen, C.sub.1 -C.sub.4 alkyl or halo-C.sub.1 -C.sub.4 alkyl;R.sub.4 is hydrogen, C.sub.1 -C.sub.4 alkyl, halo-C.sub.1 -C.sub.4 alkyl, unsubstituted phenyl or naphthyl or mono- or di-substituted phenyl or naphthyl;R.sub.5 is --S--R.sub.7, --S(.dbd.O)--R.sub.7, --S(.dbd.O).
    Type: Grant
    Filed: June 25, 1993
    Date of Patent: August 23, 1994
    Assignee: Ciba-Geigy Corporation
    Inventors: Roger G. Hall, Alfons Pascual, Odd Kristiansen
  • Patent number: 5262253
    Abstract: This invention is directed to solid electrolytes containing a solid polymeric matrix derived from vinyl sulfonate polyalkylene oxides.
    Type: Grant
    Filed: July 22, 1992
    Date of Patent: November 16, 1993
    Assignee: Valence Technology, Inc.
    Inventor: Milton N. Golovin
  • Patent number: 5166373
    Abstract: The present invention provides novel acyclic terpenes of the formula: ##STR1## which are useful as intermediates for the industrially advantageous production of sarcophytol A.
    Type: Grant
    Filed: December 30, 1991
    Date of Patent: November 24, 1992
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Hisao Takayanagi, Yasunori Kitano, Yasuhiro Morinaka
  • Patent number: 5086338
    Abstract: A color television camera for converting an image formed by an objective lens into video signals is contructed with inclusion of a prism for splitting light having passed through the objective lens into a plurality of color components, and a lens unit arranged in between the prism and at least one of a plurality of solid-state image pickup means and having such an optical power that the sizes of the images of all the color components are made coincident with one another.
    Type: Grant
    Filed: November 9, 1989
    Date of Patent: February 4, 1992
    Assignee: Canon Kabushiki Kaisha
    Inventor: Fumiaki Usui
  • Patent number: 4871868
    Abstract: A method of producing substituted acetylenic compounds which comprises: reacting an organic compound having the general formula ofA--X (I)wherein A represents a saturated or unsaturated aliphatic hydrocarbon residue of 1-20 carbon atoms which may have one or more substituents inactive in the reaction, and X represents a halogen atom or an arylsulfonyloxy group, with a metal acetylide having the general formula ofM--C.tbd.C--B (II)wherein M represents an alkali metal, and B represents (a) a hydrogen, (b) a saturated or unsaturated hydrocarbon residue which may have one or more substituents inactive in the reaction, or (c) a saturated or unsaturated hydrocarbon residue which has a substituent having the general formula of--C.tbd.C--M (III)wherein M represents an alkali metal, in the presence of an alkyl-2-imidazolidinone having the general formula of ##STR1## wherein R.sup.1 and R.sup.2 independently represent a lower alkyl, and R.sup.3 represents a hydrogen or a lower alkyl.
    Type: Grant
    Filed: March 3, 1988
    Date of Patent: October 3, 1989
    Assignee: Takeda Chemical Industries, Ltd.
    Inventors: Yuzuru Saito, Kokichi Yoshida
  • Patent number: 4736055
    Abstract: Oxime sulfonates of formula I ##STR1## wherein Y is a polymerizable unsaturated group or epoxide group or an --OH, --NHR.sup.5, --COOH, COOR.sup.6, --COCl, --CH.sub.2 Hal, --SO.sub.2 Cl or --NCO group, Z is an (x+y)-valent connecting member, R.sup.1 and R.sup.2 are monovalent organic radicals, m is 0 or 1, x is 1 or 2 and y is 1 or 2, can be converted into polymers which can be thermally or photochemically dissociated to form free sulfonic acid groups. Said polymers can therefore be used as photoresists which can be developed with aqueous alkalis.
    Type: Grant
    Filed: April 11, 1986
    Date of Patent: April 5, 1988
    Assignee: Ciba-Geigy Corporation
    Inventors: Kurt Dietliker, Werner Rutsch, Godwin Berner, Max Hunziker, Christopher G. Demmer