Acyclic Carbon Chain Containing Carbon To Carbon Unsaturation Attached Directly To The Sulfonate Group By Nonionic Bonding Patents (Class 558/55)
-
Patent number: 9221750Abstract: The invention relates to a process for preparing an internal olefin sulfonate, comprising sulfonating an internal olefin, having an average carbon number that is equal to or greater than 20, in a sulfonation reactor into sulfonated internal olefin followed by contacting sulfonated internal olefin with a base containing solution, wherein the sulfonation reactor is cooled with a cooling means having a temperature which is greater than 35° C. Further, the invention relates to an internal olefin sulfonate obtainable by said process, and to use of internal olefin sulfonates obtainable or obtained by said process as a surfactant, suitably as a surfactant in chemical Enhanced Oil Recovery.Type: GrantFiled: February 22, 2013Date of Patent: December 29, 2015Assignee: Shell Oil CompanyInventors: Julian Richard Barnes, Hendrik Dirkzwager, Robert Moene
-
Patent number: 8993798Abstract: The present invention is directed to an isomerized alpha olefin sulfonate and a method of making the same wherein the isomerized alpha olefin sulfonate is derived from sulfonating an isomerized alpha olefin with sulfur trioxide in the presence of air thereby producing an isomerized alpha olefin sulfonic acid, wherein the isomerized alpha olefin is derived from the isomerization of C12-C20 normal alpha olefins; and neutralizing the isomerized alpha olefin sulfonic acid with a source of an alkali metal or ammonium or substituted ammonium ion.Type: GrantFiled: December 8, 2010Date of Patent: March 31, 2015Assignee: Chevron Oronite Company LLCInventors: Curtis Bay Campbell, Andrew J. Howes
-
Publication number: 20150073168Abstract: The invention relates to a process for preparing an internal olefin sulfonate, comprising sulfonating an internal olefin, having an average carbon number that is equal to or greater than 20, in a sulfonation reactor into sulfonated internal olefin followed by contacting sulfonated internal olefin with a base containing solution, wherein the sulfonation reactor is cooled with a cooling means having a temperature which is greater than 35° C. Further, the invention relates to an internal olefin sulfonate obtainable by said process, and to use of internal olefin sulfonates obtainable or obtained by said process as a surfactant, suitably as a surfactant in chemical Enhanced Oil Recovery.Type: ApplicationFiled: February 22, 2013Publication date: March 12, 2015Inventors: Julian Richard Barnes, Hendrik Dirkzwager, Robert Moene
-
Publication number: 20140087309Abstract: There are disclosed olefinic acid amplifier triggers and methods of using these compositions in, for example, photolithography.Type: ApplicationFiled: March 28, 2012Publication date: March 27, 2014Applicant: THE RESEARCH FOUNDATION OF STATE UNIVERSITY OF NEW YORKInventors: Brian Cardineau, Robert L. Brainard
-
Publication number: 20130296323Abstract: This invention relates to geranylgeranyl acetone (GGA) derivatives and the use of GGA, its isomers, and GGA derivatives in methods for inhibiting neural death, increasing neural activity, increasing axon growth and cell viability, and increasing the survival rate of subjects administered the GGA or GGA derivatives.Type: ApplicationFiled: February 27, 2013Publication date: November 7, 2013Applicant: COYOTE PHARMACEUTICALS, INC.Inventors: Hiroaki Serizawa, Ankush B. Argade, Akash Datwani, Natalie Spencer, Yonghua Pan, Florian Ermini
-
Publication number: 20130225408Abstract: Fatty amine compositions made from a metathesis-derived C10-C17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives are disclosed. In another aspect, fatty amidoamines made by reacting a metathesis-derived C10-C17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives with an aminoalkyl-substituted tertiary amine are disclosed. The fatty amines or amidoamines are advantageously sulfonated, sulfitated, oxidized, or reduced. In other aspects, the ester derivative is a modified triglyceride made by self-metathesis of a natural oil or an unsaturated triglyceride made by cross-metathesis of a natural oil with an olefin.Type: ApplicationFiled: October 25, 2011Publication date: August 29, 2013Applicant: STEPAN COMPANYInventors: Dave R. Allen, Marcos Alonso, Randal J. Bernhardt, Aaron Brown, Kelly Buchek, Gary Luebke, Renee Luka, Andrew D. Malec, Ronald A. Masters, Lawrence A. Munie, Dennis S. Murphy, Irene Shapiro, Patti Skelton, Brian Sook, Michael R. Terry, Laura Lee Whitlock, Michael Wiester, Patrick Shane Wolfe
-
Publication number: 20130224578Abstract: The present invention relates to a nonaqueous electrolyte solution comprising a lithium salt and a nonaqueous organic solvent, wherein the nonaqueous electrolyte solution comprises a specific sulfonic acid ester.Type: ApplicationFiled: April 18, 2013Publication date: August 29, 2013Applicant: MITSUBISHI CHEMICAL CORPORATIONInventor: MITSUBISHI CHEMICAL CORPORATION
-
Publication number: 20130079261Abstract: A process for recovering oil from an oil-bearing formation comprises introducing into said formation an aqueous composition comprising at least one sulfonated derivative of one or more internal olefins, said internal olefins being characterized by having low amounts of tri-substitution on the olefin bond, said sulfonated derivative being obtained by sulfonating a composition comprising internal olefins of the formula: R1R2C?CR3R4 wherein R1, R2, R3 and R4 are the same or different and are hydrogen or straight- or branched-chain, saturated hydrocarbyl groups and the total number of carbon atoms of R1, R2, R3 and R4 is 6 to 44 with the proviso that at least about 96 mole percent of R1 and R3 are straight- or branched-chain, saturated hydrocarbyl groups and at least about 96 mole percent of R2 and R4 are hydrogen. Further provided are compositions for use in recovering oil from an oil bearing formation.Type: ApplicationFiled: May 20, 2011Publication date: March 28, 2013Inventors: John C. Hutchison, Patrick Shane Wolfe
-
Publication number: 20120301797Abstract: The present invention provides an excellent nonaqueous electrolytic solution capable of improving low-temperature and high-temperature cycle properties and load characteristics after high-temperature charging storage, an electrochemical element using it, and an alkynyl compound used for it. The nonaqueous electrolytic solution of the present invention comprises containing at least one alkynyl compound represented by the following general formula (I) in an amount of from 0.01 to 10% by mass in the nonaqueous electrolytic solution. R1(O)n—X1—R2??(I) (In the formula, X1 represents a group —C(?O)—, a group —C(?O)—C(?O)—, a group —S(?O)2—, a group —P(?O) (—R3)—, or a group —X2—S(?O)2O—.Type: ApplicationFiled: February 2, 2011Publication date: November 29, 2012Applicant: UBE Industries, Ltd.Inventors: Koji Abe, Kazuhiro Miyoshi, Masahide Kondo
-
Patent number: 8299289Abstract: The present invention is directed to an isomerized alpha olefin sulfonate and a method of making the same wherein the isomerized alpha olefin sulfonate is derived from sulfonating an isomerized alpha olefin with sulfur trioxide in the presence of air thereby producing an isomerized alpha olefin sulfonic acid, wherein the isomerized alpha olefin is derived from the isomerization of C12-C40 normal alpha olefins; and neutralizing the isomerized alpha olefin sulfonic acid with a source of a mono-valent cation.Type: GrantFiled: July 29, 2011Date of Patent: October 30, 2012Assignee: Chevron Oronite Company LLCInventors: Curtis Bay Campbell, Theresa Ann Denslow
-
Patent number: 8097746Abstract: The present invention provides a method of producing 2-isopropenyl-5-methyl-4-hexen-1-yl 3-methyl-2-butenoate industrially advantageously in a high yield. More particularly, the present invention provides a method of producing 2-isopropenyl-5-methyl-4-hexen-1-yl 3-methyl-2-butenoate represented by the following formula (IV): which comprises reacting 2-isopropenyl-5-methyl-4-hexen-1-ol with an organic sulfonyl halide in the presence of a basic substance to give a sulfonate compound represented by the following formula (III): wherein R is a hydrocarbon group, and reacting the obtained sulfonate compound with senecionic acid in the presence of a basic substance.Type: GrantFiled: March 29, 2006Date of Patent: January 17, 2012Assignee: Kuraray Co., Ltd.Inventors: Katsuji Ujita, Junko Sato, Takashi Fukumoto
-
Publication number: 20110053883Abstract: The present invention provides an agent that modulates physiological condition of pests, wherein the agent has an ability to modulate the activity of an insect c-Jun NH2-terminal kinase; a method for assaying pesticidal activity of a test substance, which comprises a step of measuring the activity of a c-Jun NH2-terminal kinase in a reaction system in which the c-Jun NH2-terminal kinase contacts with a test substance, and the like.Type: ApplicationFiled: June 23, 2006Publication date: March 3, 2011Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Yasutaka Shimokawatoko, Mar Van De Craen, Irene Nooren, Sandra Turconi, Annelies Roobrouck, Wendy Maddelein
-
Publication number: 20100197950Abstract: The preparation of an intermediate, a process for the preparation thereof and the process of preparing [4-[3,3-Bis-(4-bromo-phenyl)-allyloxy]-2-methyl-phenoxy]-acetic acid using this intermediate are described.Type: ApplicationFiled: June 6, 2007Publication date: August 5, 2010Inventors: Kaare Gyberg Rasmussen, Signe Maria Christensen, Rikke Eva Humble
-
Publication number: 20090112014Abstract: The present invention is directed to an isomerized alpha olefin sulfonate and a method of making the same wherein the isomerized alpha olefin sulfonate is derived from sulfonating an isomerized alpha olefin with sulfur trioxide in the presence of air thereby producing an isomerized alpha olefin sulfonic acid, wherein the isomerized alpha olefin is derived from the isomerization of C12-C40 normal alpha olefins; and neutralizing the isomerized alpha olefin sulfonic acid with a source of a mono-valent cation.Type: ApplicationFiled: October 23, 2008Publication date: April 30, 2009Applicant: Chevron Oronite Company LLCInventors: Curtis Bay Campbell, Theresa Anne Denslow
-
Publication number: 20090023941Abstract: The present invention provides a method of producing 2-isopropenyl-5-methyl-4-hexen-1-yl 3-methyl-2-butenoate industrially advantageously in a high yield. More particularly, the present invention provides a method of producing 2-isopropenyl-5-methyl-4-hexen-1-yl 3-methyl-2-butenoate represented by the following formula (IV): which comprises reacting 2-isopropenyl-5-methyl-4-hexen-1-ol with an organic sulfonyl halide in the presence of a basic substance to give a sulfonate compound represented by the following formula (III): wherein R is a hydrocarbon group, and reacting the obtained sulfonate compound with senecionic acid in the presence of a basic substance.Type: ApplicationFiled: March 29, 2006Publication date: January 22, 2009Applicant: KURARAY CO., LTD.Inventors: Katsuji Ujita, Junko Sato, Takashi Fukumoto
-
Publication number: 20030100786Abstract: Provided is a bis(diphenylvinyl)arene compound having a reactive functional group on phenyl group, represented by below formula (1), 1Type: ApplicationFiled: August 20, 2002Publication date: May 29, 2003Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Takahiro Ueoka, Hideyuki Ikehira, Yoshiaki Tsubata
-
Patent number: 6506539Abstract: A complex of a dye cation and an anionic TCNQ derivative of the formula (I): in which [Dye]+ is a dye cation, L1 is a linking group, R1 is a substituent group, p is an integer of 1-4, and r is an integer of 0-3 under the condition of 1<p+r<4, is favorably employable as a dye compound for preparing a recording layer of CD-R or DVD-R.Type: GrantFiled: April 6, 2001Date of Patent: January 14, 2003Assignee: Fuji Photo Film Co., Ltd.Inventors: Shinichi Morishima, Takashi Usami
-
Patent number: 6046351Abstract: The invention concerns a novel process for preparing racemic phenethylamines of formula (I) ##STR1## in which R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 have the meanings given in the description. According to this process: a) in a first step, optically active phenethylamines of formula (I*) ##STR2## are reacted with acetophenone derivatives of formula (II), ##STR3## the optically active phenethylamine used and the acetophenone derivative used each being substituted in an identical manner in the phenyl part, optionally in the presence of a diluting agent and optionally in the presence of a catalyst; b) in a second step, the resultant optically active Schiff bases of formula (III*) ##STR4## are reacted with metallic hydroxides containing between 0.1 and 50 wt. % water; and c) in a third step, the resultant racemic Schiff bases are reacted with acids in the presence of water.Type: GrantFiled: January 19, 1999Date of Patent: April 4, 2000Assignee: Bayer AktiengesellschaftInventor: Uwe Stelzer
-
Patent number: 6034127Abstract: Amidino and benzamidino compounds, including compounds of the formula: ##STR1## wherein R.sup.1 -R.sup.4, R.sup.6 -R.sup.9, Y, Z, n and m are set forth in the specification, as well as hydrates, solvates or pharmaceutically acceptable salts thereof, that inhibit a number of proteolytic enzymes are described. Also described are methods for preparing the compounds of Formula I.Type: GrantFiled: December 27, 1996Date of Patent: March 7, 2000Assignee: 3-Dimensional Pharmaceuticals, Inc.Inventors: Tianbao Lu, Bruce E. Tomczuk, Carl R. Illig, Richard M. Soll
-
Patent number: 5618965Abstract: Process for preparing a nitrile of the formula (I) ##STR1## in which R.sub.1, R.sub.2 and R.sub.3 are for example hydrogen, halogen, cyano, hydroxyl, carboxyl, alkyl, alkoxy, alkylthio, alkylamino, dialkylamino, aryl, aryloxy, arylthio or arylamino, or R.sub.2 and R.sub.3 together form a substituted or unsubstituted 4-membered carbon bridge,by reacting an aldehyde of the formula (II) ##STR2## with a hydroxylammonium salt followed by dehydration by heating to an elevated temperature, wherein the reaction takes place in the presence of an anhydrous inorganic sulfate and in the absence of diluents from the group consisting of carboxylic acids, strongly polar aprotic solvents, sulfur compounds and heteroaromatic basic nitrogen compounds.The nitriles obtainable by the process of the invention are valuable intermediates for, in particular, the preparation of diketopyrrolopyrrole pigments.Type: GrantFiled: March 4, 1996Date of Patent: April 8, 1997Assignee: CIBA-GEIGY CorporationInventor: Martin Kudschus
-
Patent number: 5498491Abstract: This invention is directed to solid electrolytes containing a solid polymeric matrix derived from vinyl sulfonate polyalkylene oxides.Type: GrantFiled: February 4, 1994Date of Patent: March 12, 1996Inventor: Milton N. Golovin
-
Patent number: 5489491Abstract: Vinyl sulfonate-derivatized oligomers of poly(oxyalkylene)glycols or polyesters and isocyanate are urethane linked polymer precursors for the solid polymeric matrix of a solid electrolyte. The solid polymeric matrix is made by crosslinking the vinyl sulfonate-derivatized oligomer.Type: GrantFiled: April 20, 1994Date of Patent: February 6, 1996Inventor: Milton N. Golovin
-
Patent number: 5340837Abstract: Compounds of the formula ##STR1## wherein each of o and p, independently of the other, is 0, 1, 2, 3, 4 or 5, the radicals R.sub.1 being the same or different when o is greater than 1 and the radicals R.sub.2 being the same or different when p is greater than 1;each of R.sub.1 and R.sub.2, independently of the other, is C.sub.1 -C.sub.4 alkyl, halo-C.sub.1 -C.sub.4 alkyl, halogen, --NO.sub.2, --OH, C.sub.1 -C.sub.4 alkoxy, halo-C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylthio, halo-C.sub.1 -C.sub.4 alkylthio, --O--S(.dbd.O)--R.sub.6, --O--S(.dbd.O).sub.2 --R.sub.6, phenoxy or --N(R.sub.11)SO.sub.2 R.sub.12 and/or two substituents R.sub.1 and/or two substituents R.sub.2 are, independently of one another, together --Y--Z--Y--;R.sub.3 is hydrogen, C.sub.1 -C.sub.4 alkyl or halo-C.sub.1 -C.sub.4 alkyl;R.sub.4 is hydrogen, C.sub.1 -C.sub.4 alkyl, halo-C.sub.1 -C.sub.4 alkyl, unsubstituted phenyl or naphthyl or mono- or di-substituted phenyl or naphthyl;R.sub.5 is --S--R.sub.7, --S(.dbd.O)--R.sub.7, --S(.dbd.O).Type: GrantFiled: June 25, 1993Date of Patent: August 23, 1994Assignee: Ciba-Geigy CorporationInventors: Roger G. Hall, Alfons Pascual, Odd Kristiansen
-
Patent number: 5262253Abstract: This invention is directed to solid electrolytes containing a solid polymeric matrix derived from vinyl sulfonate polyalkylene oxides.Type: GrantFiled: July 22, 1992Date of Patent: November 16, 1993Assignee: Valence Technology, Inc.Inventor: Milton N. Golovin
-
Patent number: 5166373Abstract: The present invention provides novel acyclic terpenes of the formula: ##STR1## which are useful as intermediates for the industrially advantageous production of sarcophytol A.Type: GrantFiled: December 30, 1991Date of Patent: November 24, 1992Assignee: Mitsubishi Kasei CorporationInventors: Hisao Takayanagi, Yasunori Kitano, Yasuhiro Morinaka
-
Patent number: 5086338Abstract: A color television camera for converting an image formed by an objective lens into video signals is contructed with inclusion of a prism for splitting light having passed through the objective lens into a plurality of color components, and a lens unit arranged in between the prism and at least one of a plurality of solid-state image pickup means and having such an optical power that the sizes of the images of all the color components are made coincident with one another.Type: GrantFiled: November 9, 1989Date of Patent: February 4, 1992Assignee: Canon Kabushiki KaishaInventor: Fumiaki Usui
-
Patent number: 4871868Abstract: A method of producing substituted acetylenic compounds which comprises: reacting an organic compound having the general formula ofA--X (I)wherein A represents a saturated or unsaturated aliphatic hydrocarbon residue of 1-20 carbon atoms which may have one or more substituents inactive in the reaction, and X represents a halogen atom or an arylsulfonyloxy group, with a metal acetylide having the general formula ofM--C.tbd.C--B (II)wherein M represents an alkali metal, and B represents (a) a hydrogen, (b) a saturated or unsaturated hydrocarbon residue which may have one or more substituents inactive in the reaction, or (c) a saturated or unsaturated hydrocarbon residue which has a substituent having the general formula of--C.tbd.C--M (III)wherein M represents an alkali metal, in the presence of an alkyl-2-imidazolidinone having the general formula of ##STR1## wherein R.sup.1 and R.sup.2 independently represent a lower alkyl, and R.sup.3 represents a hydrogen or a lower alkyl.Type: GrantFiled: March 3, 1988Date of Patent: October 3, 1989Assignee: Takeda Chemical Industries, Ltd.Inventors: Yuzuru Saito, Kokichi Yoshida
-
Patent number: 4736055Abstract: Oxime sulfonates of formula I ##STR1## wherein Y is a polymerizable unsaturated group or epoxide group or an --OH, --NHR.sup.5, --COOH, COOR.sup.6, --COCl, --CH.sub.2 Hal, --SO.sub.2 Cl or --NCO group, Z is an (x+y)-valent connecting member, R.sup.1 and R.sup.2 are monovalent organic radicals, m is 0 or 1, x is 1 or 2 and y is 1 or 2, can be converted into polymers which can be thermally or photochemically dissociated to form free sulfonic acid groups. Said polymers can therefore be used as photoresists which can be developed with aqueous alkalis.Type: GrantFiled: April 11, 1986Date of Patent: April 5, 1988Assignee: Ciba-Geigy CorporationInventors: Kurt Dietliker, Werner Rutsch, Godwin Berner, Max Hunziker, Christopher G. Demmer