Abstract: Reactive dyes of the formula ##STR1## in which D is the radical of an organic dye of the monoazo, polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan, azomethine, dioxazine, phenazine, stilbene, triphenylmethane, xanthene, thioxanthone, nitroaryl, naphthoquinone, pyrenequinone or perylenetetracarbimide series, R is hydrogen or substituted or unsubstituted C.sub.1-4 -alkyl, A is a polymethylene radical having 2 to 6 C atoms (or its branched isomers) which can be substituted by chlorine, bromine, fluorine, hydroxyl, sulfato, acyloxy having 1 to 4 C atoms, cyano, carboxyl, alkoxycarbonyl having 1 to 5 C atoms or carbamoyl, or an alkyleneoxalkylene radical having 1 to 6 C atoms in each alkylene member, independently of each other; Y is a radical --CH.dbd.CH.sub.2 or --CH.sub.2 CH.sub.
Type:
Grant
Filed:
August 10, 1987
Date of Patent:
June 20, 1989
Inventors:
Peter Aeschlimann, Hansrudolf Schwander
Abstract: Metabolically-acceptable, surgical adhesives are prepared from polyisocyanates having the structral formula: ##STR1## wherein R is a polyvalent aliphatic radical of about 1 to 10 carbon atoms or a polyvalent aromatic radical of 6 to about 24 carbon atoms;A is C, S or P;Z is O or S;Y is 1 when A is C or P, and 2 when A is S;n is 1 or 2;p is at least 1;q is 0 or 1, with the proviso that when A is carbon or sulfur, q is 0;r is 0 or 1, with the proviso that when A is carbon or sulfur, r is 0;X is a residue of an organic compound having active hydrogen-containing groups; andX' is a residue of an organic compound having at least 1 active hydrogen-containing group.
Type:
Grant
Filed:
July 17, 1987
Date of Patent:
May 9, 1989
Assignee:
Bioresearch, Inc.
Inventors:
William D. Fuller, Robert K. Blair, Murray Goodman
Abstract: This invention relates to a class of alkenylated toluenediisocyanates having at least one alkenyl group ortho to an isocyanate group. More particularly the toluendiisocyanates are represented by the formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 are hydrogen, C.sub.1-3 aliphatic, phenyl, halogen or alkoxy radicals, or R.sub.2 and R.sub.4 or R.sub.5 are bridged via an alkylene radical --(CH.sub.2).sub.y --wherein y=2 to 5, and x is one or two provided that in said formula at least one of R.sub.1, R.sub.2, R.sub.3, R.sub.4 or R.sub.5 is C.sub.1 or greater.The above described alkenylated toluenediisocyanates have been found to be well suited for preparing crosslinkable condensation polymers by providing pendant unsaturation for post curing and polymerization. They are also well suited for preparing polyurethane and polyurea elastomer systems.
Type:
Grant
Filed:
July 21, 1986
Date of Patent:
December 27, 1988
Assignee:
Air Products and Chemicals, Inc.
Inventors:
William F. Burgoyne, Jr., Dale D. Dixon
Abstract: Compounds containing from 0.15 to 20.3 wt. % aromatic amino groups are produced by hydrolyzing an isocyanate compound mixed with water and a solvent or solvent mixture at -20.degree. to 185.degree. C. The isocyanate starting material must contain at least two aromatically bound isocyanate groups and an isocyanate content of from 0.5 to 40 wt. %. The water must be used in at least a stoichiometric amount but is preferably used in excess. The solvent or solvent mixture must contain 50-100 wt. % solvent containing ether and/or thioether bonds. A partly water-soluble solvent may be used in an amount no greater than 50 wt. % total solvent. No acidic or basic catalysts are present during the hydrolysis. The product amine may be isolated by phase separation, filtration or extraction. The amines thus-produced are particularly useful in the production of polyurethane(urea)s.