Preparing Directly By Condensing A Haloamine Patents (Class 564/466)
  • Patent number: 7683217
    Abstract: The present invention relates to a process for preparing monomethylhydrazine by methylating hydrazine or hydrazinium hydrochloride or hydrazinium dihydrochloride with methyl chloride and/or a methano/HCl mixture, characterized in that the reaction mixture formed in the methylation is reacted with an organic base from the group of the alkylamines or alkanolamines and monomethylhydrazine is removed by distillation from the reaction mixture in a low boiler fraction and the low boiler fraction is optionally subjected to a further distillation.
    Type: Grant
    Filed: September 18, 2008
    Date of Patent: March 23, 2010
    Assignee: Saltigo GmbH
    Inventors: Uwe Boger, Ulrich Notheis, Mathias Siekmann
  • Patent number: 7390929
    Abstract: The invention relates to a method for the continuous synthesis of monoalkyl-hydrazines with a functionalized alkyl group. The inventive method is characterized in that it comprises a step consisting in demixing a solution containing the synthesized monoalkyl-hydrazine, by reacting an anhydrous amine with monochloramine, in an organic phase and an aqueous phase with the addition of anhydrous sodium hydroxide. The invention can be used to obtain perfect selectivity in relation to monoalkyl-hydrazine without the presence of the di- and tri-substituted forms thereof. According to the invention, the staffing amine which has not reacted is collected and reused directly without any additional treatment.
    Type: Grant
    Filed: December 17, 2004
    Date of Patent: June 24, 2008
    Assignees: Isochem, Centre National de la Recherche Scientifique (CNRS), Universite Claude Bernard Lyon 1
    Inventors: Henri Delalu, Cécile Colas-Duriche, Jacques Berthet, Philippe Leurent
  • Publication number: 20020062044
    Abstract: The present invention provides processes for the synthesis of novel cationic amphiphiles capable of facilitating transport of biologically active molecules into cells wherein the said amphiphiles contain N-hydroxyalkyl group and have at least one hydroxyalkyl group containing 1-3 carbon atoms directly linked to the positively charged nitrogen atom
    Type: Application
    Filed: December 4, 2001
    Publication date: May 23, 2002
    Applicant: Council of Scientific & Industrial Research
    Inventors: Rajkumar Banerjee, Prasanta Kumar Das, Gollapudi Venkata Srilakshmi, Nalam Madhusudhana Rao, Arabinda Chaudhuri
  • Patent number: 4588823
    Abstract: Novel compounds of the following general formula: ##STR1##
    Type: Grant
    Filed: September 27, 1984
    Date of Patent: May 13, 1986
    Assignee: The Upjohn Company
    Inventor: Paul A. Aristoff
  • Patent number: 4508695
    Abstract: Anhydrous hydrazine and hydrocarbyl-substituted hydrazines are efficiently prepared according to a three-step procedure, comprising a first step wherein ammonia, a primary or secondary amine, an alkali metal amide, an alkaline earth metal amide, a hydrocarbyl-substituted alkali metal amide or a hydrocarbyl-substituted alkaline earth metal amide is reacted with a chlorinating agent to produce the corresponding chloramine without co-production of an amine hydrochloride salt; a second step wherein the chloramine is reacted with a tertiary amine to produce a tertiary hydrazinium chloride; and a final step wherein the tertiary hydrazinium chloride is reacted with an alkali metal amide or an alkaline earth metal amide under anhydrous conditions to produce the desired product.
    Type: Grant
    Filed: April 22, 1982
    Date of Patent: April 2, 1985
    Inventor: Hans Osborg
  • Patent number: 4490555
    Abstract: Novel compounds of the following general formula: ##STR1##
    Type: Grant
    Filed: March 19, 1982
    Date of Patent: December 25, 1984
    Assignee: The Upjohn Company
    Inventor: John C. Sih
  • Patent number: 4487961
    Abstract: Novel compounds of the following general formula: ##STR1##
    Type: Grant
    Filed: February 16, 1982
    Date of Patent: December 11, 1984
    Assignee: The Upjohn Company
    Inventor: Paul A. Aristoff