Of Ether Containing Compound Patents (Class 564/474)
  • Patent number: 4737592
    Abstract: A process is provided for producing dimethylamine, comprising reacting methanol and/or dimethylether and ammonia in amounts sufficient to provide a carbon/nitrogen (C/N) ratio from about 0.2 to about 1.5, at a temperature from about 250.degree. C. to about 450.degree. C., in the presence of a catalytic amount of an acidic zeolite catalyst selected from the group consisting of natural, H-exchanged, and M-exchanged chabazites, each having a geometric selectivity index greater than about 3, wherein M is one or more alkali metal ions selected from the group consisting of Na, K, Rb, and Cs.
    Type: Grant
    Filed: September 19, 1986
    Date of Patent: April 12, 1988
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Lloyd Abrams, Robert D. Shannon, George C. Sonnichsen
  • Patent number: 4683334
    Abstract: A process for producing dimethylamine is provided, comprising reacting methanol and/or dimethylether and ammonia, in amounts sufficient to provide a carbon/nitrogen (C/N) ratio from about 0.2 to about 1.5, and at a temperature from about 250.degree. C. to about 450.degree. C., in the presence of a catalytic amount of a modified acidic zeolite selected from the group consisting of chabazite, erionite, ZK-5, and rho, the zeolite having been modified by treatment with one or more compounds containing at least one element selected from the group consisting of silicon, aluminum, phosphorus, and boron, to deposit thereon at least 0.05 weight percent of the element.
    Type: Grant
    Filed: April 30, 1985
    Date of Patent: July 28, 1987
    Assignee: E. I. Du Pont de Nemours & Company
    Inventors: Horacio E. Bergna, David R. Corbin, George Sonnichsen
  • Patent number: 4665195
    Abstract: Disclosed is a process for producing di-amino-polyalkenyl ethers by reacting (a) one or more acyclic or heterocyclic amino compounds with (b) one or more polyalkenyl ether glycols or polyalkenyl amino ether alcohols, in the presence of a hydrogenation catalyst, at elevated temperatures and pressures.
    Type: Grant
    Filed: December 23, 1983
    Date of Patent: May 12, 1987
    Assignee: Exxon Research and Engineering Company
    Inventors: Eugene L. Stogryn, W.S. Winston Ho, Angelo A. Montagna
  • Patent number: 4602112
    Abstract: A process is provided for producing dimethylamine comprising reacting methanol and/or dimethylether and ammonia in amounts sufficient to provide a carbon/nitrogen (C/N) ratio from about 0.2 to about 1.5, at a temperature from about 250.degree. C. to about 450.degree. C., in the presence of a catalytic amount of an acidic H-ZK-5 zeolite catalyst.
    Type: Grant
    Filed: November 16, 1984
    Date of Patent: July 22, 1986
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Thurman E. Gier, Robert D. Shannon, George C. Sonnichsen
  • Patent number: 4582904
    Abstract: Synthesis of organic amines by condensation of organic hydroxy compound with ammonia or a primary or secondary amine in the presence of a rare earth metal hydrogen phosphate catalyst.
    Type: Grant
    Filed: January 6, 1984
    Date of Patent: April 15, 1986
    Assignee: Air Products and Chemicals, Inc.
    Inventors: James E. Wells, Victoria Eskinazi
  • Patent number: 4503252
    Abstract: A method for the synthesis of serinol and serinol derivatives substituted at the nitrogen atoms by reacting a lower 1,3-dialkoxy-isopropyl halide with ammonia or an amine to form a 1,3-dialkoxy-isopropylamine and then removing the ether groups by heating with a hydrogen halide acid. The method allows the production of serinol and serinol derivatives using inexpensive starting materials in a simple manner and obtaining a high purity product which is free of interfering isomers. Novel compounds obtained by the method which are useful as pharmaceutical intermediates, X-ray contrasting agents and cytostatic or psychopharmacological drugs are also disclosed.
    Type: Grant
    Filed: November 15, 1982
    Date of Patent: March 5, 1985
    Assignee: Eprova Aktiengesellschaft
    Inventors: Ernst Felder, Sergio Bianchi, Heinrich Bollinger
  • Patent number: 4487967
    Abstract: The present invention relates to a process for selectively preparing severely sterically hindered secondary aminoether alcohols by reacting a primary amino compound with a polyalkenyl ether glycol in the presence of a hydrogenation catalyst at elevated temperatures and pressures. The severely sterically hindered secondary aminoether alcohols are useful in acid gas scrubbing processes, particularly in the selective removal of H.sub.2 S from gaseous streams containing CO.sub.2 and H.sub.2 S.
    Type: Grant
    Filed: December 23, 1983
    Date of Patent: December 11, 1984
    Assignee: Exxon Research & Engineering Co.
    Inventors: Eugene L. Stogryn, W. S. Winston Ho, Angelo A. Montagna, Guido Sartori
  • Patent number: 4436938
    Abstract: A process for the manufacture of methylamines comprises reacting a feed comprising methanol and/or dimethylether and ammonia over a binderless zeolite A catalyst, preferably a binderless zeolite 5A catalyst. Use of binderless zeolite 5A makes the process attractively selective to dimethylamine in preference to mono- and tri-methylamine. In addition, if the catalyst is essentially free of alkali metal it is not only more active than similar catalysts containing alkali metal but also considerably more selective.
    Type: Grant
    Filed: August 31, 1982
    Date of Patent: March 13, 1984
    Assignee: Imperial Chemical Industries PLC
    Inventor: Alan J. Tompsett
  • Patent number: 4408075
    Abstract: A process of preparing tris-(ether-amines) of the formula:N--[A--O--(B--O).sub.n --R].sub.3in which R represents a hydrocarbon radical, A and B represent alkanediyl radicals, and n is a whole number between zero and 4, by ammonolysis of an alkylene glycol mono-ether of the formula:HO--A--O--(B--O).sub.n --Rin the presence of 10 to 40 percent by weight of a hydrogenation-dehydrogenation catalyst, based on weight of said alkylene glycol monoether.The tris-(ether-amines) produced, such as tris-(3,6-dioxa-octyl)amine, tris-(3,6,9-trioxaundecyl)amine, tris-(3,6-dioxaheptyl)amine, and tris-(3,6-dioxadecyl)amine.
    Type: Grant
    Filed: April 21, 1980
    Date of Patent: October 4, 1983
    Assignee: Rhone-Poulenc Industries
    Inventors: Gerard Soula, Louis Linguenheld
  • Patent number: 4374273
    Abstract: In the catalytic preparation of methylamines from methanol and ammonia using an aluminosilicate catalyst, the mono-, di- and trimethylamine content of the product mixture can be varied from the equilibrium mixture ordinarily produced by using an amorphous aluminosilicate catalyst containing varying amounts of sodium, potassium, lithium, barium or strontium atoms as a result of treating an amorphous aluminosilicate with a corresponding metal hydroxide.
    Type: Grant
    Filed: April 28, 1981
    Date of Patent: February 15, 1983
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: George E. Heinsohn
  • Patent number: 4370503
    Abstract: In the catalytic preparation of methylamines from methanol or dimethyl ether and ammonia using a silica-alumina catalyst, catalyst coking and byproduct formation are reduced and reaction speed and catalyst thermal stability are enhanced when a catalyst containing a high level of alumina is used.
    Type: Grant
    Filed: March 24, 1981
    Date of Patent: January 25, 1983
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Loren D. Brake