Abstract: Disclosed is an energetic reactive plasticizer for a plastic bonded explosive (PBX), and specifically an energetic reactive plasticizer for PBX which has high performance and insensitiveness without a plasticizer leak by being bonded with a polymer binder for a plastic bonded explosive.

Abstract: Disclosed is an energetic reactive plasticizer for a plastic bonded explosive (PBX), and specifically an energetic reactive plasticizer for PBX which has high performance and insensitiveness without a plasticizer leak by being bonded with a polymer binder for a plastic bonded explosive.

Abstract: The invention relates to a process for preparing ?-aminoacetals substantially in racemic form, comprising a step of oxidizing optically enriched ?-aminoacetals to the corresponding oximes, in the presence of a catalyst, and a step of reducing the oximes thus obtained.

Abstract: Bis(dinitroalkyl)acetals and formals having the formula (1) particularly bis(2,2-dinitropropyl)acetal and bis(2,2-dinitropropyl)formal are produced by oxidative nitration of compounds having the formula (2): preferably via a sodium or other alkali metal, or alkaline earth metal, salt of compounds of Formula (2). Certain of the compounds of formula (1) are novel. All of the intermediates of formula (2) are novel and form another aspect of this invention, as does a process for their production by reacting an aldehyde with a nitroalkanol. The process can readily produce a mixture of the dinitro compounds known as BDNPA and BDNPF (also known as A/F) using the non-explosive intermediates, BNPA and BNPF, both of which are novel.

Abstract: A process for the preparation of a fuel oil (diesel fuel or heating oil) composition which is a mixture of an alkanol tranesterified fatty acid ester triglyceride and an acetal of glycerol is described. The process preferably provides a prestep of the formation of at least some of the alkanol transesterified triglyceride containing the glycerol for use in the formation of the acetal of glycerol. The composition can also be formed from a reaction of 1,1-dimethoxy- or 1,1-diethoxyethane and glycerol to form the acetal in the alkanol transesterified triglyceride.

Abstract: Disclosed are novel compounds that can be used as an energetic binder used for improving the performance and the properties of a high explosive, and a preparation method thereof.

Abstract: The present invention provides a new process for the isolation of hydroxy citric acid in the form of a potassium salt from Garcinia fruit. The present invention also provides compositions containing the potassium hydroxy citrate for use as appetite suppressants.

Abstract: The present invention is directed to a new soluble double metal salt of group IA and IIA of (-) hydroxycitric acid of general formula I:where X is IA group metal: Li or Na or K or Rb or Cs or Frwhere Y is IIA group metal: Be or Mg or Ca or Sr or Ba or Rawhere the concentration of X in the salt varies from 1.5-51.0%,the concentration of Y in the salts varies from 2.0-50.9%,the concentration of HCA in the salt varies from 31.0-93.0% depending on the nature of X and Y.This invention more particularly relates to new soluble double metal salt of group IA and IIA of (-) hydroxycitric acid of general formula II.

Abstract: 2:2 mixed orthocarbonates of the formula ##STR1## wherein R.noteq.R' and wherein R and R' are --C(NO.sub.2).sub.3, --CF(NOb.2).sub.2, --CF.sub.2 (NO.sub.2), --C(NO.sub.2).sub.2 CH.sub.3, --CH(NO.sub.2)CH.sub.3, --CH(NO.sub.2)CH.sub.3, --CH.sub.2 (NO.sub.2), --CF.sub.3, or --CF.sub.2 CF.sub.3, and methods of preparation.Additionally, orthoformates of the formula ##STR2## wherein R is --C(NO.sub.2).sub.2 CH.sub.3, --CF.sub.2 (NO.sub.2), --CH(NO.sub.2)CH.sub.3, and --CH.sub.2 (NO.sub.2), and methods of preparation.

Abstract: A nonsolvent process of synthesizing bis(2,2-dinitropropyl)acetal (BDNPA) is disclosed. In the process, 2,2-dinitropropanol (DNPOH) is reacted at low temperature with an acetaldehyde source in the presence of an acid catalyst, such as a Lewis acid catalyst or protic acid catalyst. To inhibit by product formation, the reaction temperature is maintained from about -30.degree. C. to 30.degree. C. Upon completion of the reaction, the reaction solution is quenched with water and washed with an aqueous hydroxide solution. The hydroxide concentration should be sufficient to neutralize any acid formed during the quenching step and to solubilize unreacted 2,2-dinitropropanol as well as other aqueous soluble byproducts in the reaction solution. The BDNPA product is extracted with methyl tert-butyl ether (MTBE) or equivalent solvent. The organic solvent is evaporated to yield usable BDNPA product. The resulting yield is at least 50% based on the starting quantity of 2,2-dinitropropanol.

Abstract: A nonsolvent process of synthesizing bis(2,2-dinitropropyl)formal (BDNPF) is disclosed. In the process, 2,2-dinitropropanol (DNPOH) is reacted at low temperature with a formaldehyde source in the presence of a protic acid catalyst, such as H.sub.2 SO.sub.4, HCl, H.sub.3 PO.sub.4, or HBr. To inhibit byproduct formation, the reaction temperature is maintained from about -30.degree. C. to 30.degree. C. Upon completion of the reaction, the reaction solution is quenched with water and washed with an aqueous hydroxide ion solution. The hydroxide ion concentration should be sufficient to neutralize the protic acid catalyst during the quenching step and to solubilize unreacted 2,2-dinitropropanol as well as other aqueous soluble byproducts in the reaction solution. The BDNPF product is extracted with a low boiling temperature polar organic solvent, such as methyl tert-butyl ether (MTBE) or equivalent solvent. The organic solvent is evaporated to yield usable BDNPF product.

Abstract: A process for the preparation of vitamin A which preferably comprises bringing cyclogeranyl sulphone into contact with a C.sub.10 aldehyde acetal, halogenating the derivative obtained and then removing the halogen group and the sulphone, removing the acetal group and isomerizing the retinal obtained to the desired configuration. Also disclosed are compounds useful as intermediates in the synthesis of vitamin A and processes for preparation of these intermediate compounds.

Abstract: The present invention has an object of producing a polyoxyalkylene compound by ring-opening polymerization of an alkylene oxide to a certain specific highly hydrophobic initiator. The present invention provides a process for producing a polyoxyalkylene compound, characterized in that the polyoxyalkylene compound is produced by ring-opening polymerization of an alkylene oxide, in the presence of a plural metal cyanide complex catalyst, with an initiator selected from an organopolysiloxane compound having an active hydrogen-containing functional group to which an alkylene oxide is reactive, and a fluorine-containing compound having such an active hydrogen-containing functional group and a fluorinated hydrocarbon group.

Abstract: The invention relates to a process for preparing dialkyl malonates by ozonolysis of diketene, subsequent catalytic hydrogenation and esterification of the reaction products, the by-products being alkyl formates and dialkyl acetals.

Abstract: The invention relates to novel tri-acetal polyol compounds and to a crystalline polyolefin composition having dispersed therein a nucleating agent composed of one or more of said polyol acetals.

Abstract: A method of preparing difluoroformals of the formula(RCH.sub.2 O).sub.2 CF.sub.2,wherein R is --C(NO.sub.2).sub.3, --CF(NO.sub.2).sub.2, --CF.sub.2 (NO.su), --C(NO.sub.2).sub.2 CH.sub.3, or a fluoroalkyl group such as --CF.sub.3 or --CF.sub.2 CF.sub.3, by reacting the corresponding dichloroformals with hydrogen fluoride in pyridine. These difluoroformals are useful as energetic explosive and propellant ingredients.

Abstract: A method of preparing dichloroformals of the formula(RCH.sub.2 O).sub.2 CCl.sub.2by reaction of one mole of a thionocarbonate of the formula(RCH.sub.2 O).sub.2 C.dbd.Swith two moles of benzenesulfenyl chloride, chlorobenzenesulfenyl chloride, r methanesulfenyl chloride wherein R is --C(NO.sub.2).sub.3, --CF(NO.sub.2).sub.2, --CF.sub.2 (NO.sub.2), --CCl(NO.sub.2).sub.2, --C(NO.sub.2).sub.2 CH.sub.3, --CCl.sub.3, --CF.sub.3, or --CF.sub.2 CF.sub.3. These energetic dichloroformals are useful as explosive and propellant ingredients and as intermediates in the synthesis of other energetic explosive and propellant ingredients.

Abstract: The present invention relates to a process for preparing halo acetals of ethylenic aldehydes by reaction of a halogen cation with enamine followed by a hydrolysis and reaction with an alcohol, a glycol or an orthoformate. These halo acetals are used as intermediate for the synthesis of vitamins A and E.It also relates to a new compound of formula (IV), ##STR1## to a process for preparing it from halo acetals of ethylenic aldehydes by reaction with triethyl phosphate, and to its use for the preparation of retinal by reaction with .beta.-ionylideneacetaldehyde.

Abstract: A tert-amine which contains an acid-activated color body precursor is treated to prevent it or a derivative thereof, e.g., an amine oxide, betaine, or quaternary ammonium compound, from turning pink when exposed to acidic conditions by contacting it with a dialkylacetal.

Abstract: A new compound 2,2-dinitrobutyl 2,2-dinitropropyl formal (DNBPF),CH.sub.3 C(NO.sub.2).sub.2 CH.sub.2 CH.sub.2 OCH.sub.2 OCH.sub.2 C(NO.sub.sub.2 CH.sub.3,and a energetic plasticizer which is a 1:1 eutectic mixture of DNBPF and bis(2,2-dinitropropyl) formal.

Abstract: 4-Monoacetals of (E)-2-methylbut-2-ene-1,4-dial of the general formula I ##STR1## where R.sup.1 and R.sup.2 are each an aliphatic hydrocarbon radical of 1 to 12 carbon atoms, cycloalkyl of 5 to 7 carbon atoms or benzyl, or R.sup.1 and R.sup.2 together form an ethylene or propylene radical which may furthermore be substituted by lower alkyl, are prepared by a process in which a compound of the general formula II ##STR2## where either R.sup.3 and R.sup.4 are both one of the groups ##STR3## where R.sup.1 and R.sup.2 have the above meanings, or R.sup.3 is one of the groups ##STR4## and R.sup.4 is formyl ##STR5## is reacted, at from 20.degree. to 200.degree. C., in the presence of an acidic compound, with the compound of the formula IIIR.sup.5 --OH (III)where R.sup.5 is hydrogen, alkyl of 1 to 12 carbon atoms or hydroxyalkyl of 2 to 5 carbon atoms, and, where R.sup.3 and R.sup.4 are each ##STR6## R.sup.5 is alkyl, and where R.sup.3 and R.sup.4 are each ##STR7## R.sup.5 is hydrogen, and where R.sup.

Abstract: Bis(2-fluoro-2,2-dinitroethoxy)(1-fluoro-1,1-dinitro-2-propoxy)methane wh is useful as an energetic coplasticizer with bis(2-fluoro-2,2-dinitroethyl)formal in plastic-bonded explosives.

Abstract: 1:3 "mixed" orthocarbonates of the formula[CF(NO.sub.2).sub.2 CH.sub.2 O].sub.3 C--ORwherein R is--CH.sub.2 C(NO.sub.2).sub.3,--CH.sub.2 C(NO.sub.2).sub.2 CH.sub.3,--CH.sub.2 CH.sub.2 NO.sub.2,--CH.sub.2 C(NO.sub.2).sub.2 CH.sub.2 OH,--CH.sub.2 C(NO.sub.2).sub.2 CH.sub.2 OC[OCH.sub.2 CF(NO.sub.2).sub.2 ].s3,--CH.sub.2 C(NO.sub.2).sub.2 CH.sub.2 OCH.sub.2 OCH.sub.2 C(NO.sub.2).sub.2 CH.sub.2 OH,--CH.sub.2 C(NO.sub.2).sub.2 CH.sub.2 OCH.sub.2 OCH.sub.2 C(NO.sub.2).sub.2 CH.sub.2 OC[OCH.sub.2 CF(NO.sub.2).sub.2 ].sub.3,--CH.sub.2 CF.sub.3,--CH.sub.2 CH.sub.3, and ##STR1## and a method of preparation.

Abstract: Polysaccharide aldehydes having the formula Sacch--O--CH.sub.2 --CH.dbd.CH--CHO, ##STR1## such as starch, cellulose, and gum aldehydes, are useful for imparting wet, dry, or temporary wet strength to paper. They are prepared by a non-oxidative method which involves reacting the polysaccharide base, in the presence of alkali, with a derivatizing acetal reagent having the general structure ##STR2## and then hydrolyzing the acetal by adjusting the pH to less than 7, preferably 2-4. In the formulas, n is 1-3; R.sup.11 and R.sup.12 are independently an alkyl, aryl, aralkyl, or alkaryl group when n is 1, R.sup.11 or R.sup.12 is one of the groups when n is 2, or R.sup.11 and R.sup.12 are not present when n is 3; R.sup.13 is an alkyl group, optionally containing an ether linkage, or an aralkyl group; R.sup.14 and R.sup.15 are individually a hydrogen or a methyl group; R.sup.16, R.sup.17, and R.sup.

Abstract: Energetic orthoformates of the formula ##STR1## wherein R and R' vary independently and R is --CH.sub.2 C(NO.sub.2).sub.2 H.sub.3,--CH.sub.2 C(NO.sub.2).sub.3,--CH.sub.2 CF(NO.sub.2).sub.2,--CH.sub.2 CF.sub.2 (NO.sub.2), or--CH.sub.2 CF.sub.3,R' is--CH.sub.2 CF(NO.sub.2).sub.2,--CH.sub.2 F.sub.2 (NO.sub.2), or--CH.sub.2 CF.sub.3,and Y is --F, --N.sub.3, --C.tbd.N, ##STR2## and methods of preparation.

Abstract: 2,2-dinitropropyl 2-fluoro-2,2-dinitroethyl formal which is prepared by the ollowing processes: ##STR1##

Abstract: A 1:1:2 mixed orthocarbonate of the formula ##STR1## wherein R and R" are each one of the following groups--CH.sub.2 C(NO.sub.2).sub.2 CH.sub.3,--CH.sub.2 C(NO.sub.2).sub.3,--CH.sub.2 CF(NO.sub.2).sub.2,--CH.sub.2 CF.sub.2 (NO.sub.2), and--CH.sub.2 CF.sub.3, andR' is one of the followingCH.sub.2 CF(NO.sub.2).sub.2,CH.sub.2 CF.sub.2 (NO.sub.2), andCH.sub.2 CF.sub.3,provided that R.noteq.R', R.noteq.R", and R'.noteq.R". These 1:1:2 orthoconates are produced by the following reaction sequence: ##STR2## wherein R, R', and R" are as defined above. By choosing R and R" to be the same and either --CH.sub.2 (NO.sub.2).sub.2 CH.sub.3 or --CH.sub.2 C(NO.sub.2).sub.3 in the above reaction, 1:3 mixed orthocarbonates of the formula ##STR3## wherein R.noteq.R', R".noteq.R', R=R", and R and R" are each CH.sub.2 C(NO.sub.2).sub.2 CH.sub.3,CH.sub.2 C(NO.sub.2).sub.3,CH.sub.2 CF.sub.2 (NO.sub.2), orCH.sub.2 CF.sub.3,and R' is CH.sub.2 CF(NO.sub.2).sub.2, CH.sub.2 CF.sub.2 (NO.sub.2) or CH.sub.2 CF.sub.3 may be prepared.

Abstract: Vinyl ethers are prepared by reacting divinyl ether with a primary alcohol in the presence of a catalytic amount of red mercuric oxide and trifluoroacetic acid. The vinyl ethers so produced are particularly useful as monomers which can be polymerized into energetic macromolecular binder materials with excellent mechanical, physical and energetic properties.

Abstract: The present invention relates to the novel compound acetaldehyde ethyl 6-dihydrolinalyl acetal, useful as a fragrance material. The invention also provides a method of preparing this compound from 6-dihydrolinalool, and fragrance compositions which include the compound.

Abstract: A process for synthesizing energetic ethers, esters and acetals is disclosed that comprises reacting certain alcohols with certain alkenes or alkynes in the presence of mercuric or mercurous sulfate. The products obtained are particularly useful as plasticizers, monomers or prepolymers for propellant binder systems.

Abstract: Nitropolyformals of the formula H--OCH.sub.2 C(NO.sub.2).sub.2 ZC(NO.sub.sub.2 CH.sub.2 OCH.sub.2 --OCH.sub.2 C(NO.sub.2).sub.2 ZC(NO.sub.2).sub.2 CH.sub.2 OH wherein Z is --CH.sub.2 --, --CH.sub.2 CH.sub.2 --, --CH.sub.2 CH.sub.2 CH.sub.2 --, --CH.sub.2 OCH.sub.2 --, or --CH.sub.2 NHCH.sub.2 -- and wherein the average molecular weight of the nitropolyformal molecules is from about 1,000 to about 50,000. The nitropolyformals are prepared by reacting a diol of the formula HOCH.sub.2 C(NO.sub.2).sub.2 ZC(NO.sub.2).sub.2 CH.sub.2 OH, wherein Z is defined as above, with formaldehyde in the presence of concentrated sulfuric acid. These polymers are useful as energetic binders in explosives and propellants.

Abstract: 2,2,2-trifluoroethoxy bis(2-fluoro-2,2-dinitroethoxy)methane, CF.sub.3 CHb.2 OCH[OCH.sub.2 CF(NO.sub.2).sub.2 ].sub.2, is an energetic plasticizer useful in plastic-bonded explosives. Of particular importance is its miscibility with fluoropolymers.

Abstract: An energetic plasticizer which is a mixture of bis(2,2,2-trinitroethyl)fol, bis(2,2-dinitropropyl)formal, and a new compound 2,2-dinitropropyl 2,2,2-trinitroethyl formal.

Abstract: 4,4,10,10-tetranitro-6,8-dioxatridecane-1,13-diol polyformal, HO(CH.sub.2ub.3 C(NO.sub.2).sub.2 CH.sub.2 OCH.sub.2 OCH.sub.2 C(NO.sub.2).sub.2 (CH.sub.2).sub.3 O[CH.sub.2 O(CH.sub.2).sub.3 C(NO.sub.2).sub.2 CH.sub.2 OCH.sub.2 OCH.sub.2 C(NO.sub.2).sub.2 (CH.sub.2).sub.3 O].sub.n H, which has high energy, high thermal stability, and which is useful as a prepolymer for plastic-bonded explosive compositions.

Abstract: Bis(2-fluoro-2,2-dinitroethoxy) 2,2,3,3,4,4,4-heptafluorobutoxymethane, (F), CF.sub.3 CF.sub.2 CF.sub.2 CH.sub.2 OCH[OCH.sub.2 CF(NO.sub.2).sub.2 ].sub.2, is an energetic plasticizer with a melting point of -18.degree. C. and thermal stability up to 150.degree. C. HFBF is miscible with polyfluoro- and polynitropolymers and useful as a plasticizer in plastic-bonded explosives.