Plural Benzene Rings Bonded Directly To Each Other Patents (Class 568/642)
-
Publication number: 20150126779Abstract: This invention selectively synthesizes a cycloparaphenylene compound having 10, 11, or 13 benzene rings. The invention also synthesizes a cycloparaphenylene compound in which a functional group is introduced into a desired portion. By reacting specific raw materials using a specific reaction, a cyclic compound having 10, 11, or 13 bivalent aromatic hydrocarbon groups, bivalent heterocyclic groups, or derivative groups thereof can be selectively obtained as a pure substance.Type: ApplicationFiled: March 7, 2013Publication date: May 7, 2015Inventors: Kenichiro Itami, Yasutomo Segawa, Haruka Omachi, Sanae Matsuura, Yusuke Nakanishi, Yuuki Ishii
-
Publication number: 20150108402Abstract: The means concerns a liquid crystal composition that has negative dielectric anisotropy and that comprises a specific compound having a high stability to ultraviolet light as a first component, wherein the composition may comprise a specific compound having a high maximum temperature or a small viscosity as a second component, and a specific compound having a large negative dielectric anisotropy as a third component, and a specific compound having a polymerizable group as an additive component.Type: ApplicationFiled: October 21, 2014Publication date: April 23, 2015Inventors: ERIKO KURIHARA, MASAYUKI SAITO, YOSHIMASA FURUSATO
-
Patent number: 8999197Abstract: The invention provides a liquid crystal compound that has an excellent compatibility with other liquid crystal compounds and also has at least one of characteristics such as a high stability to heat, light or the like, a suitable refractive index anisotropy (?n), a low threshold voltage and a suitable dielectric anisotropy (??). A compound represented by formula (1) For example, R1 is alkyl having 1 to 10 carbons, R2 is halogen or alkenyl having 2 to 10 carbons; the ring A1, the ring A2 and the ring A3 are 1,4-cyclohexylene or 1,4-phenylene; Z1, Z2 and Z3 are a single bond or alkylene having 1 to 4 carbons; G is —CH2— or —O—; and m is 1, and n and p is 0 or 1.Type: GrantFiled: October 24, 2013Date of Patent: April 7, 2015Assignees: JNC Corporation, JNC Petrochemical CorporationInventors: Tokifumi Masukawa, Yasuyuki Goto, Tomohiro Yano
-
Publication number: 20150087847Abstract: There is provided a compound having a good miscibility with another liquid crystal compound and having a combination of a low viscosity (?), high storage stability, and high T?i even after being used to produce a liquid crystal composition. In particular, it is a compound having a 2-fluorophenyloxymethane structure is provided. Since the compound having a 2-fluorophenyloxymethane structure is highly miscible with another liquid crystal compound, using the compound having a 2-fluorophenyloxymethane structure as a component of a liquid crystal composition enables a production of a liquid crystal composition which exhibits a liquid crystal phase at low viscosity and in a wide temperature range and which has a high storage stability and enables production of a liquid crystal display device which responds fast and which has excellent display characteristics.Type: ApplicationFiled: March 24, 2013Publication date: March 26, 2015Applicant: DIC CORPORATIONInventors: Kenta Tojo, Tetsuo Kusumoto, Masashi Osawa, Masakazu Kaneoya, Kiyofumi Takeuchi
-
Patent number: 8987538Abstract: The present invention provides cycloparaphenylene compounds, their macrocyclic precursors, and methods for making the compounds. The cycloparaphenylene compounds can be used to prepare armchair carbon nanotubes.Type: GrantFiled: May 6, 2013Date of Patent: March 24, 2015Assignee: The Regents of the University of CaliforniaInventors: Ramesh Jasti, Carolyn Bertozzi
-
Patent number: 8956552Abstract: To provide a compound, when the compound has both a high clearing point and a low crystallization temperature, having a wide temperature range of a liquid crystal phase and also an excellent solubility in other liquid crystal compounds, and further having general physical properties necessary for the compound, namely, stability to heat, light and so forth, a suitable optical anisotropy and a suitable dielectric anisotropy. A compound is represented by formula (1): wherein, for example, Ra and Rb are alkyl having 1 to 10 carbons; A1, A2, A3 and A4 are 1,4-phenylene; Z1, Z2, Z3 and Z4 are a single bond or alkylene having 1 to 4 carbons; and m, n, q and r are independently 0, 1, or 2, and a sum of m, n, q and r is 1, 2, 3 or 4.Type: GrantFiled: June 17, 2013Date of Patent: February 17, 2015Assignees: JNC Corporation, JNC Petrochemical CorporationInventor: Yasuyuki Sasada
-
Publication number: 20150034870Abstract: A novel organic compound that can be used in a variety of liquid crystal devices or a liquid crystal composition containing the novel organic compound is provided. An organic compound represented by General Formula (G1) is provided. A novel liquid crystal composition containing the organic compound is provided. In General Formula (G1), Ar1 and Ar2 separately represent a substituted or unsubstituted arylene group having 6 to 12 carbon atoms, a substituted or unsubstituted cycloalkylene group having 3 to 12 carbon atoms, or a substituted or unsubstituted cycloalkenylene group having 3 to 12 carbon atoms. In addition, m and n separately represent 0 or 1. R1 and R2 separately represent a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 11 carbon atoms, or a substituted or unsubstituted alkoxy group having 1 to 11 carbon atoms.Type: ApplicationFiled: July 14, 2014Publication date: February 5, 2015Inventors: Momoko Kato, Yasuhiro Niikura, Makoto Ikenaga, Manabu Kobayashi, Tetsuji Ishitani
-
Patent number: 8916063Abstract: A liquid crystal composition and an AM liquid crystal display device are described. The liquid crystal composition has a negative dielectric anisotropy, contains a specific compound having a large negative dielectric anisotropy as a first component and a two-ring compound having a small viscosity as a second component, and may further contain a specific compound having a large negative dielectric anisotropy as a third component, a specific compound having a small viscosity as a fourth component and a specific compound having a large negative dielectric anisotropy as a fifth component. The AM liquid crystal display device includes the liquid crystal composition.Type: GrantFiled: February 8, 2013Date of Patent: December 23, 2014Assignees: JNC Corporation, JNC Petrochemical CorporationInventors: Yasuyuki Goto, Kazuhiko Saigusa, Norikatsu Hattori
-
Patent number: 8901031Abstract: Novel brominated poly(2,6-diphenyl-1,4-phenylene oxide) compounds are synthesized and found to have improved carbon dioxide separation properties, including improved carbon dioxide permeability and improved carbon dioxide/nitrogen selectivity.Type: GrantFiled: May 11, 2007Date of Patent: December 2, 2014Assignee: University of WyomingInventors: Maciej Radosz, Youqing Shen
-
Patent number: 8883037Abstract: Chiral liquid crystal compounds of the general formula (1): in which at least one of R1 and R2 is a chiral substituent, K may be a single bond or the same as K1-5 and K1-5 denote a six-membered ring system which rings may be at least partially unsaturated, wherein the number of atoms in these rings or ring systems between the two atoms forming a part of the link to the next ring, or to one of the substituents R1 and R2, does not differ by more than one if counted in the clockwise, and in the counter-clockwise sense, starting from the same atom in each case, X1-20 denote alkyl, or alkoxy, or fluorinated alkyl, or fluorinated alkoxy groups, or atom H, or halogen atoms, mixtures comprising such chiral liquid crystal compounds, and liquid crystal displays comprising such mixtures as active ingredients.Type: GrantFiled: April 15, 2013Date of Patent: November 11, 2014Assignee: Tetragon LC Chemie AGInventors: Wolfgang Haase, Artsiom Lapanik
-
Publication number: 20140275577Abstract: The present invention relates to a compound having a 2-fluorophenyloxymethane structure and useful for organic electronic materials and medical and agricultural chemicals, particularly materials for liquid crystal display elements. A problem to be solved by the invention is to provide a compound having relatively large ??, relatively high T?i, low viscosity (?), and high miscibility with other liquid crystal compounds, and also provide a liquid crystal composition containing the compound as a constituent component. The present invention provides a compound having a 2-fluorophenyloxymethane structure and also provides a liquid crystal composition containing the compound and a liquid crystal display device using the liquid crystal composition.Type: ApplicationFiled: May 22, 2012Publication date: September 18, 2014Applicant: DIC CORPORATIONInventors: Kenta Tojo, Kiyofumi Takeuchi, Masashi Osawa, Masakazu Kaneoya, Tetsuo Kusumoto
-
Publication number: 20140232977Abstract: The invention relates to bimesogenic compounds of formula I R1-MG1-Sp-MG2-R2??I wherein R1, R2, MG1, MG2 and Sp have the meaning given in claim 1, to the use of bimesogenic compounds of formula I in liquid crystal media and particular to flexoelectric liquid crystal devices comprising a liquid crystal medium according to the present invention. Furthermore the invention relates to bimesogenic compounds of formula I inducing a second nematic phase in nematic mixtures that do not show this additional phase without compounds of formula I.Type: ApplicationFiled: June 12, 2012Publication date: August 21, 2014Applicant: MERCK PATENT GMBHInventors: Kevin Adlem, David Wilkes, Patricia Eileen Saxton, Benjamin Snow, Rachel Tuffin, Owain Llyr Parri, Geoffrey Luckhurst
-
Publication number: 20140217325Abstract: The present invention relates to liquid-crystalline media and to high-frequency components comprising same, especially microwave components for high-frequency devices, such as devices for shifting the phase of microwaves, in particular for microwave phased-array antennas.Type: ApplicationFiled: August 7, 2012Publication date: August 7, 2014Applicant: MERCK PATENT GMBHInventors: Atsutaka Manabe, Dagmar Klass
-
Publication number: 20140194620Abstract: The present invention relates to a precursor of positron emission tomography (PET) radioactive medical supplies, a preparation method thereof, and an application thereof, and more specifically, to a precursor having a tetravalent organic salt leaving group, a preparation method, and a method for preparing desired PET radioactive medical supplies in a high radiochemical yield within a short preparation time by introducing 18F using the same through a single step. The precursor having a tetravalent organic salt leaving group of the present invention can simplify the known complex multistep preparation of radioactive medical supplies into a single step, can save production costs because an excessive amount of a phase transfer catalyst is not required, facilitates separation of a compound after reaction, and enables rapid reaction velocity. The features are appropriate for the mass production of PET radioactive medical supplies by an automated synthesis system.Type: ApplicationFiled: May 11, 2012Publication date: July 10, 2014Applicant: FUTURECHEM CO., LTD.Inventors: Dae-Yoon Chi, Byoung-Se Lee, Chansoo Park, Min-Hyung Lee, Hyojin Cha, Woojin Cho, Heewon Kang, Kyunghun Kim
-
Publication number: 20140166931Abstract: A liquid crystal composition and an AM liquid crystal display device are described. The liquid crystal composition has a negative dielectric anisotropy, contains a specific compound having a large negative dielectric anisotropy as a first component and a two-ring compound having a small viscosity as a second component, and may further contain a specific compound having a large negative dielectric anisotropy as a third component, a specific compound having a small viscosity as a fourth component and a specific compound having a large negative dielectric anisotropy as a fifth component. The AM liquid crystal display device includes the liquid crystal composition.Type: ApplicationFiled: February 8, 2013Publication date: June 19, 2014Applicants: JNC PETROCHEMICAL CORPORATION, JNC CORPORATIONInventors: Yasuyuki Goto, Kazuhiko Saigusa, Norikatsu Hattori
-
Publication number: 20140138582Abstract: A liquid crystal compound having high stability to heat, light and so forth, a high clearing point, a low minimum temperature of a liquid crystal phase, small viscosity, suitable optical anisotropy, large negative dielectric anisotropy, a suitable elastic constant and excellent compatibility with other liquid crystal compounds, a liquid crystal composition containing the compound, and a liquid crystal display device including the composition. The compound is represented by formula (1-1): wherein, for example, R1 is alkyl having 1 to 10 carbons, alkoxy having 1 to 9 carbons or alkenyl having 2 to 10 carbons; R2 is alkyl having 1 to 10 carbons, alkoxy having 1 to 9 carbons or alkenyl having 3 to 10 carbons; ring A1 is 1,4-cyclohexylene or 1,4-phenylene; ring A2 is 1,4-cyclohexylene, 1,4-phenylene or 2,3-difluoro-1,4-phenylene; Z1 and Z2 are single bonds; L1 and L2 are fluorine; and 1 is 0, 1 or 2.Type: ApplicationFiled: November 15, 2013Publication date: May 22, 2014Applicants: JNC PETROCHEMICAL CORPORATION, JNC CORPORATIONInventors: Yasuyuki GOTOH, Masahide KOBAYASHI
-
Patent number: 8722942Abstract: A method produces a biphenyl derivative, with an industrially high yield and excellent productivity, by use of a raw material which is low in cost and toxicity. The method for producing the biphenyl derivative represented by Formula (1) is characterized in that a chlorine atom in a benzene derivative represented by Formula (2) reacts with magnesium metal to convert the benzene derivative into a Grignard reagent, and then the Grignard reagent is subjected to a coupling reaction in the presence of a catalyst and a dichloropropane: (wherein A represents at least one selected from alkyl groups, alkoxy groups, alkoxymethyl groups, a vinyl group, phenyl groups and chlorine, and n represents an integer of 1 to 4).Type: GrantFiled: October 12, 2007Date of Patent: May 13, 2014Assignee: Toray Fine Chemicals Co., Ltd.Inventors: Tamio Hayashi, Jiro Nakatani
-
Publication number: 20140118679Abstract: Disclosed is a liquid-crystal compound with negative dielectric anisotropy, having the chemical formula: wherein A1, A2, and A3 are independently selected from cyclohexyl group, cyclohexenyl group, or phenyl group; L1 and L2 are independently selected from H or F; R is selected from H, F, Cl, C1-10 alkyl group, C1-10 alkenyl group, C1-10 alkoxy group, or C1-10 ether group; Y is fluorinated methyl group; m and n are independently selected from an integer of 0-2; and 1?m+n?3.Type: ApplicationFiled: February 20, 2013Publication date: May 1, 2014Applicant: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTEInventors: Chao-Wu LIAW, Shih-Hsien LIU, Kung-Lung CHENG, Jian-Wen LIN, Kuo-Chang WANG
-
Publication number: 20140097383Abstract: A liquid crystal composition and an AM liquid crystal display device are described. The liquid crystal composition contains a specific compound having a small viscosity as a first component, may further contain a specific compound having a large negative dielectric anisotropy as a second component and a specific compound having a small viscosity as a third component, and has a negative dielectric anisotropy and a ratio of rotational viscosity to an elastic constant in the range of 4.2 GPa·s/N or lower. The liquid crystal display device includes the composition.Type: ApplicationFiled: February 8, 2013Publication date: April 10, 2014Applicants: JNC PETROCHEMICAL CORPORATION, JNC CORPORATIONInventors: Yoshimasa Furusato, Masayuki Saito
-
Publication number: 20140054499Abstract: The invention provides a liquid crystal compound that has an excellent compatibility with other liquid crystal compounds and also has at least one of characteristics such as a high stability to heat, light or the like, a suitable refractive index anisotropy (?n), a low threshold voltage and a suitable dielectric anisotropy (??). A compound represented by formula (1). For example, R1 is alkyl having 1 to 10 carbons, R2 is halogen or alkenyl having 2 to 10 carbons; the ring A1, the ring A2 and the ring A3 are 1,4-cyclohexylene or 1,4-phenylene; Z1, Z2 and Z3 are a single bond or alkylene having 1 to 4 carbons; G is —CH2— or —O—; and m is 1, and n and p is 0 or 1.Type: ApplicationFiled: October 24, 2013Publication date: February 27, 2014Applicants: JNC PETROCHEMICAL CORPORATION, JNC CORPORATIONInventors: Tokifumi MASUKAWA, Yasuyuki GOTO, Tomohiro YANO
-
Patent number: 8652353Abstract: A novel liquid crystalline carbonate and the mixture containing the same: wherein R3 is an alkyl (H2n+1Cn) or an alkenyl (H2n?1Cn) group, each of 1 to 12 carbon atoms, the ring A is laterally unsubstituted benzene or pyridine or pyrimidine or trans-substituted cyclohexane ring, symbol r is 0 to 2; the lateral substituents: X2, X3, X4 and X5 in the benzene rings represent independently hydrogen or fluorine or chlorine atoms, X1 is hydrogen or fluorine atom and simultaneously at least one of the substituents: X2, X3 and X4 is fluorine or chlorine atoms, Y is an alkyl or an alkyloxy or an alkenyl or an alkenyloxy group, each of 1 to 12 carbon atoms or hydrogen or fluorine or chlorine atom or NCS group are described.Type: GrantFiled: July 19, 2012Date of Patent: February 18, 2014Assignee: Wojskowa Akademia TechnicznaInventors: Roman Slawomir Dabrowski, Przemyslaw Kula, Artur Choluj, Jerzy Dziaduszek, Katarzyna Garbat
-
Publication number: 20140008573Abstract: The present invention relates to compounds containing at least one C—C triple bond within a chain of at least 3 ring systems which have positive dielectric anisotropy, to the use thereof for high-frequency components, to liquid-crystalline media comprising the compounds, and to high-frequency components, in particular antennae, especially for the gigahertz region, comprising these media. The liquid-crystalline media serve, for example, for the phase shifting of microwaves for tuneable ‘phased-array’ antennae.Type: ApplicationFiled: February 27, 2012Publication date: January 9, 2014Applicant: MERCK PATENT GMBHInventors: Christian Jasper, Constanze Brocke, Detlef Pauluth, Volker Reiffenrath, Atsutaka Manabe
-
Publication number: 20140012004Abstract: The invention relates to palladium(0) tris{tri-[3,5-bis(trifluoromethyl)-phenyl]-phosphine} complex of formula (I), as well as to its preparation and use. This compound is outstandingly stable, and can be used as catalyst with excellent results.Type: ApplicationFiled: December 13, 2011Publication date: January 9, 2014Applicant: H4SEP KFTInventors: Zoltán Daliczek, Tibor Soós, Zoltán Finta, Géza Timári, Gábor Vlád
-
Publication number: 20130337196Abstract: The present invention discloses a liquid crystal (LC) molecule having a five-membered ring structure and a mixture thereof. A traditional LC molecule is modified into the LC molecule having the five-membered ring structure. The rotational viscosity of the LC molecule within an LC panel is decreased by properties of the five-membered ring structure, so that the LC molecule having the five-membered ring structure has a fast off-time than that of the traditional LC molecule. The present invention can decrease the rotational viscosity of the LC molecule within the LC panel by modification of the five-membered ring structure of the LC molecule, and thus the problem of cross-talk effect produced from switching a two-dimensional mode to a three-dimensional mode in an LC display can be improved.Type: ApplicationFiled: July 2, 2012Publication date: December 19, 2013Applicant: Shenzhen China Star Optopelectronics Technology Co., Ltd.Inventor: Chung-Ching Hsieh
-
Patent number: 8603359Abstract: A liquid crystal compound having a high stability to heat, light or the like, a high clearing point, a low minimum temperature of a liquid crystal phase, a small viscosity, a suitable optical anisotropy, a large dielectric anisotropy, a suitable elastic constant and an excellent compatibility with other liquid crystal compounds, and a liquid crystal composition including this compound, and a liquid crystal display device containing this composition. A compound represented by formula (1): for example, R1 is alkyl having 1 to 10 carbons; ring A1, ring A2 and ring A3 are 1,4-cyclohexylene, 1,4-phenylene or 1,4-phenylene in which at least one of hydrogen has been replaced by fluorine; Z1 is a single bond, and Z2 and Z3 are —CF2O— or —OCF2—; X1 is fluorine; and L1 and L2 are fluorine.Type: GrantFiled: June 6, 2012Date of Patent: December 10, 2013Assignees: JNC Corporation, JNC Petrochemical CorporationInventors: Takahiro Kubo, Yasuyuki Goto
-
Publication number: 20130324745Abstract: A process is provided which allows the synthesis of a large number of styrene derivatives with formation of C—C bonds, with use being possible of economically advantageous substrates, readily available carbon nucleophiles, and both inexpensive and environmentally unproblematic catalyst systems, permitting reaction under mild conditions and a high compatibility with functional groups on the reactants involved.Type: ApplicationFiled: May 31, 2013Publication date: December 5, 2013Inventors: Matthias GOTTA, Bernd Wilhelm LEHNEMANN, Axel VON WANGELIN JACOBI, Samet GUELAK
-
Patent number: 8580146Abstract: A liquid crystal compound having a high stability to heat, light or the like, a wide temperature range of a nematic phase, a small viscosity, a suitable optical anisotropy, a large elastic constant K33, a large negative dielectric anisotropy and an excellent compatibility with other liquid crystal compounds. Also, a liquid crystal composition having characteristics similar to these of the compound. Additionally, a liquid crystal display device having a short response time, low electric power consumption, a low driving voltage, a large contrast and a wide temperature range in which the device can be used. The compound is a 2,3-difluorobenzene derivative (1) having a combination of a cyclohexane ring, a cyclohexene ring or a benzene ring phenyl and a butene bonding group. The liquid crystal composition includes this compound, and the liquid crystal display device contains this composition.Type: GrantFiled: January 27, 2012Date of Patent: November 12, 2013Assignees: JNC Corporation, JNC Petrochemical CorporationInventor: Masahide Kobayashi
-
Patent number: 8580142Abstract: The invention provides a liquid crystal compound having stability to heat, light and so forth, a wide temperature range of a nematic phase, a small viscosity, a suitable optical anisotropy, a suitable elastic constant K33, a suitable and negative dielectric anisotropy, and an excellent compatibility with other liquid crystal compounds. The invention provides a liquid crystal composition containing the compound described above and having stability to heat, light and so forth, a small viscosity, a suitable optical anisotropy, a suitable and negative dielectric anisotropy, a suitable elastic constant K33, a low threshold voltage, a high maximum temperature of a nematic phase, and a low minimum temperature of the nematic phase. The invention also provides a liquid crystal display device having a short response time, a small power consumption, a low driving voltage, and a large contrast, and containing the composition described above which can be used in a large temperature range.Type: GrantFiled: September 1, 2008Date of Patent: November 12, 2013Assignees: JNC Corporation, JNC Petrochemical CorporationInventors: Teru Shimada, Masahide Kobayashi
-
Publication number: 20130289316Abstract: A liquid crystal medium, which has a liquid crystal phase over a wide temperature range, a large refractive index anisotropy, and a large dielectric anisotropy, and exhibits an optically isotropic liquid crystal phase, is provided. The liquid crystal medium is characterized by containing a liquid crystal compound having four benzene rings and a difluoromethyleneoxy group, and a chiral reagent, and exhibiting an optically isotropic liquid crystal phase.Type: ApplicationFiled: June 26, 2013Publication date: October 31, 2013Inventors: YASUHIRO HASEBA, TAKAFUMI KUNINOBU
-
Publication number: 20130281700Abstract: The invention relates to palladium(0)-tris{tri-[3,5-bis(trifluoromethyl)-phenyl]-phosphine} complex of formula (I), as well as to its preparation and use. This compound is outstandingly stable, and can be used as catalyst with excellent results.Type: ApplicationFiled: June 14, 2013Publication date: October 24, 2013Applicants: CHINOIN GYOGYSZER-ES VEGYESZETI TER-MEKEK GYARA ZRT, H4SEP KFTInventors: Zoltán DALICZEK, Tibor SOÓS, Zoltán FINTA, Géza Timári, Gábor Vlád
-
Publication number: 20130277612Abstract: To provide a compound, when the compound has both a high clearing point and a low crystallization temperature, having a wide temperature range of a liquid crystal phase and also an excellent solubility in other liquid crystal compounds, and further having general physical properties necessary for the compound, namely, stability to heat, light and so forth, a suitable optical anisotropy and a suitable dielectric anisotropy. A compound is represented by formula (1): wherein, for example, Ra and Rb are alkyl having 1 to 10 carbons; A1, A2, A3 and A4 are 1,4-phenylene; Z1, Z2, Z3 and Z4 are a single bond or alkylene having 1 to 4 carbons; and m, n, q and r are independently 0, 1, or 2, and a sum of m, n, q and r is 1, 2, 3 or 4.Type: ApplicationFiled: June 17, 2013Publication date: October 24, 2013Applicants: JNC CORPORATIONInventor: Yasuyuki SASADA
-
Publication number: 20130270480Abstract: To provide a compound, when the compound has both a high clearing point and a low crystallization temperature, having a wide temperature range of a liquid crystal phase and also an excellent solubility in other liquid crystal compounds, and further having general physical properties necessary for the compound, namely, stability to heat, light and so forth, a suitable optical anisotropy and a suitable dielectric anisotropy. A compound is represented by formula (1): wherein, for example, Ra and Rb are alkyl having 1 to 10 carbons; A1, A2, A3 and A4 are 1,4-phenylene; Z1, Z2, Z3 and Z4 are a single bond or alkylene having 1 to 4 carbons; and m, n, q and r are independently 0, 1, or 2, and a sum of m, n, q and r is 1, 2, 3 or 4.Type: ApplicationFiled: October 13, 2011Publication date: October 17, 2013Applicants: JNC PETROCHEMICAL CORPORATION, JNC CORPORATIONInventor: Yasuyuki Sasada
-
Patent number: 8551359Abstract: The present invention relates to liquid-crystalline compounds having two fluorinated biphenyl units, a terminal trifluoromethyl or trifluoromethoxy group and a —CF2O— bridge between the two fluorinated biphenyl units. The invention also relates to liquid-crystalline media prepared therewith and to liquid-crystal display devices (LC displays) containing these media.Type: GrantFiled: April 14, 2011Date of Patent: October 8, 2013Assignee: Merck Patent GmbHInventors: Axel Jansen, Helmut Haensel, Malgorzata Rillich
-
Patent number: 8530689Abstract: The invention concerns processes for the synthesis of a compound of the formula: wherein: R1 and R2 are each, independently, C1-C12 alkyl, CO2R3, OR4, R5(OR6), or C6-C18 aryl; R3-R6 are each, independently, C1-C12 alkyl or C6-C12 aryl; and n and m are each, independently, O or an integer from 1-5; said process comprising:—contacting a compound of the formula H0-R7-0H with BH3 and a compound of the formula in the presence of a nickel-containing catalyst to produce a first product, where R7 is a C2-C12 hydrocarbon group and X is a halogen, OMs or OTs;—contacting the first product in situ with a compound of the formula: in the presence of a nickel-containing catalyst to produce a compound of formula I, where Z is a halogen.Type: GrantFiled: April 30, 2009Date of Patent: September 10, 2013Assignee: The Trustees Of The University Of PennsylvaniaInventors: Virgil Percec, Brad Matthew Rosen, Daniela A. Wilson, Christopher J. Wilson
-
Publication number: 20130228720Abstract: Chiral liquid crystal compounds of the general formula (1): in which at least one of R1 and R2 is a chiral substituent, K may be a single bond or the same as K1-5 and K1-5 denote a six-membered ring system which rings may be at least partially unsaturated, wherein the number of atoms in these rings or ring systems between the two atoms forming a part of the link to the next ring, or to one of the substituents R1 and R2, does not differ by more than one if counted in the clockwise, and in the counter-clockwise sense, starting from the same atom in each case, X1-20 denote alkyl, or alkoxy, or fluorinated alkyl, or fluorinated alkoxy groups, or atom H, or halogen atoms, mixtures comprising such chiral liquid crystal compounds, and liquid crystal displays comprising such mixtures as active ingredientsType: ApplicationFiled: April 15, 2013Publication date: September 5, 2013Applicant: Tetragon LC Chemie AGInventors: Wolfgang Haase, Artsiom Lapanik
-
Publication number: 20130211106Abstract: Microwave irradiation is used to synthesize graphene and metallic nanocatalysts supported on graphene either by solid or solution phase. In solid phase methods, no solvents or additional reducing agents are required so the methods are “environmentally friendly” and economical, and the graphene and nanocatalysts are substantially free of residual contaminants. Recyclable, high efficiency Pd nanocatylysts are prepared by these methods.Type: ApplicationFiled: March 25, 2011Publication date: August 15, 2013Inventors: M. Samy El-Shall, Victor Abdelsayed, Hassan M.A. Hassan, Abd EI Rahman S. Khder, Khaled M. Abouzeid, Qilin Dai, Parichehr Afshani, Frank Gupton, Ali R. Siamaki, Zeid Abdullah M. Alothman, Hamad Zaid Alkhathlan
-
Patent number: 8507724Abstract: The present invention concerns compounds derived from the anaethetic propofol. The compounds may be useful in the treatment of pain, particularly, but not exclusively, chronic pain and central pain sensitisation.Type: GrantFiled: December 9, 2009Date of Patent: August 13, 2013Assignee: The University of DundeeInventors: Martin Leuwer, Paul O'Neill, Neil Berry, Gertrud Haeseler
-
Publication number: 20130182202Abstract: The present invention relates to liquid-crystalline media (LC media) having negative or positive dielectric anisotropy comprising self-aligning mesogens (SAMs) which effect homeotropic (vertical) alignment of the LC media at a surface or the cell walls of a liquid-crystal display (LC display). The invention therefore also encompasses LC displays having homeotropic alignment of the liquid-crystalline medium (LC medium) without conventional imide alignment layers. The LC media may be supplemented by a polymerisable or polymerised component, which serves for stabilisation of the alignment, for adjustment of the tilt angle and/or as passivation layer.Type: ApplicationFiled: August 29, 2011Publication date: July 18, 2013Applicant: MERCK PATENT GESELLSCHAFT MIT BESCHRANKTER HAFTUNGInventors: Archetti Graziano, Andreas Taugerbeck
-
Publication number: 20130181135Abstract: A material according to one embodiment exhibits an optical response signature for neutrons that is different than an optical response signature for gamma rays, said material exhibiting performance comparable to or superior to stilbene in terms of distinguishing neutrons from gamma rays, wherein the material is not stilbene, the material comprising a molecule selected from a group consisting of: two or more benzene rings, one or more benzene rings with a carboxylic acid group, one or more benzene rings with at least one double bound adjacent to said benzene ring, and one or more benzene rings for which at least one atom in the benzene ring is not carbon.Type: ApplicationFiled: January 8, 2013Publication date: July 18, 2013Applicant: LAWRENCE LIVERMORE NATIONAL SECURITY, LLCInventor: Lawrence Livermore National Security, LLC
-
Publication number: 20130165660Abstract: A complex of formula (1), wherein, M is palladium or nickel, R1 and R2 are independently organic groups having 1-20 carbon atoms, or R1 and R2 are linked to form a ring structure with the phosphorus atom, R3 is selected from the group consisting of substituted and unsubstituted aryl, substituted and unsubstituted heteroaryl, and substituted and unsubstituted metallocenyl, R4 is an organic group having 1-20 carbon atoms, n is 0, 1, 2, 3, 4 or 5, X is an anionic ligand. A process for the preparation of the complex, and its use in carbon-carbon or carbon-nitrogen coupling reactions is also provided.Type: ApplicationFiled: June 22, 2011Publication date: June 27, 2013Applicant: JOHNSON MATTHEY PUBLIC LIMITED COMPANYInventors: Thomas John Colacot, Carin Johansson Seechurn, Sebastien Laurent Parisel
-
Publication number: 20130131337Abstract: An optically active bisbenzyl compound or a racemic bisbenzyl compound represented by formula (2) that has axial chirality. An optically active azepine derivative or a racemic azepine derivative represented by formula (3). Methods of producing an optically active quaternary ammonium salt compound represented by formula (8).Type: ApplicationFiled: December 5, 2012Publication date: May 23, 2013Applicant: NIPPON SODA CO., LTD.Inventor: NIPPON SODA CO., LTD.
-
Publication number: 20130100369Abstract: A liquid crystal compound with branched alkyl or branched alkenyl as represented by formula (1), a liquid crystal medium (a liquid crystal composition or a polymer/liquid crystal composite material) containing the liquid crystal compound, and an optical element containing the liquid crystal medium are described. In formula (1), R1 is branched alkyl of C3-20 or branched alkenyl of C3-20. The ring A1, A2, A3, A4 or A5 is 1,4-phenylene or 1,3-dioxane-2,5-diyl, for example. Z1, Z2, Z3 and Z4 are independently a single bond or C1-4 alkylene, for example. Y1 is fluorine, for example, m, n and p are independently 0 or 1, and 1?m+n+p?3.Type: ApplicationFiled: June 15, 2011Publication date: April 25, 2013Applicants: JNC PETROCHEMICAL CORPORATION, JNC CORPORATIONInventors: Kouki Sagou, Yasuhiro Haseba
-
Patent number: 8415504Abstract: The disclosure provides a catalyst carrier, including a nano carbon material; and a polymer grafted on the nano carbon material, wherein the polymer has a repetitive unit comprising a phosphorous atom. The disclosure further provides a catalyst deposited on the catalyst carrier of the disclosure. The catalyst of the disclosure has high reactivity, and is easy to be recovered in C—C coupling reactions such as a Suzuki-Miyaura coupling reaction.Type: GrantFiled: December 27, 2010Date of Patent: April 9, 2013Assignee: Industrial Technology Research InstituteInventors: Mao-Lin Hsueh, Cheng-Wei Yeh, Kuo-Chen Shih, Hsiao-Chun Yeh, Yi-Zhen Chen
-
Publication number: 20130085306Abstract: A liquid crystal compound and a liquid crystal medium are described. The liquid crystal compound is stable to heat and light and has a large dielectric anisotropy and a large optical anisotropy. The liquid crystal medium has a wide temperature range of liquid crystal phase, a large optical anisotropy and a large dielectric anisotropy, and exhibits an optically isotropic liquid crystal phase. The liquid crystal compound has 4 or 5 benzene rings, one of which is a chlorofluorobenzene ring. The liquid crystal medium is characterized in containing the liquid crystal compound and a chiral dopant and exhibiting an optically isotropic liquid crystal phase.Type: ApplicationFiled: November 30, 2012Publication date: April 4, 2013Inventor: YASUHIRO HASEBA
-
Patent number: 8372975Abstract: The invention provides a liquid crystal compound having general physical properties necessary for the compound, namely stability to heat, light and so forth, a wide temperature range of a liquid crystal phase, a high clearing point, a good compatibility with other compounds, a large optical anisotropy and a large dielectric anisotropy; a compound represented by formula (1): wherein, for example, R1 is alkyl having 1 to 20 carbons; ring A1 and ring A4 each are 1,4-cyclohexylene, 1,4-phenylene, or 1,4-phenylene in which arbitrary hydrogen is replaced by halogen; Z1 and Z4 each are a single bond; L1, L2, L3 and L4 each are hydrogen or fluorine; and X1 is fluorine, chlorine, —CF3 or —OCF3.Type: GrantFiled: March 15, 2010Date of Patent: February 12, 2013Assignees: JNC Corporation, JNC Petrochemical CorporationInventor: Hiroyuki Tanaka
-
Publication number: 20130020532Abstract: A novel liquid crystalline carbonate and the mixture containing the same: wherein R3 is an alkyl (H2n+1Cn) or an alkenyl (H2n?1Cn) group, each of 1 to 12 carbon atoms, the ring A is laterally unsubstituted benzene or pyridine or pyrimidine or trans-substituted cyclohexane ring, symbol r is 0 to 2; the lateral substituents: X2, X3, X4 and X5 in the benzene rings represent independently hydrogen or fluorine or chlorine atoms, X1 is hydrogen or fluorine atom and simultaneously at least one of the substituents: X2, X3 and X4 is fluorine or chlorine atoms, Y is an alkyl or an alkyloxy or an alkenyl or an aikenyloxy group, each of 1 to 12 carbon atoms or hydrogen or fluorine or chlorine atom or NCS group are described.Type: ApplicationFiled: July 19, 2012Publication date: January 24, 2013Inventors: Roman Slawomir Dabrowski, Przemyslaw Kula, Artur Choluj, Jerzy Dziaduszek, Katarzyna Garbat
-
Publication number: 20120314146Abstract: The invention relates to a liquid-crystalline medium comprising one or more compounds of the formula (I), in which R0 has the meanings indicated in Claim 1, and to the use thereof in electro-optical liquid-crystal displays.Type: ApplicationFiled: January 25, 2011Publication date: December 13, 2012Applicant: MERCK PATENT GESELLSCHAFT MIT BESCHRANKTER HAFTUNGInventors: Michael Wittek, Brigitte Schuler, Lars Lietzau
-
Publication number: 20120271055Abstract: The present invention relates to a compound as a peroxisome proliferator activated receptor (PPAR) activator and a hydrate, a solvate, a stereoisomer and a pharmaceutically acceptable salt thereof, and a pharmaceutical composition, a cosmetic composition, a muscle strengthening agent, a memory improving agent, a therapeutic agent for dementia and Parkinson's disease, a functional food and a feed composition containing the same.Type: ApplicationFiled: December 1, 2007Publication date: October 25, 2012Applicant: SEOUL NATIONAL UNIVERSITY INDUSTRY FOUNDATIONInventors: Heonjoong Kang, Jungwook Chin, Jaehwan Lee
-
Publication number: 20120248374Abstract: The present invention relates to a liquid-crystalline medium based on a mixture of polar compounds having negative dielectric anisotropy (??), which is distinguished by the fact that it has a value for the ratio ?1/?n2 in the range 6-45 with a clearing point of >60° C. and a ?? of ??2.3. Media of this type are particularly suitable for electro-optical displays having active-matrix addressing based on the ECB, PA LCD, FFS or IPS effect.Type: ApplicationFiled: June 15, 2012Publication date: October 4, 2012Applicant: Merck Patent GmbHInventors: Melanie KLASEN-MEMMER, Sabine SCHOEN
-
Publication number: 20120232310Abstract: Disclosed are: a novel palladium catalyst which does not undergo leakage, can be recycled, does not require the use of any phosphorus-containing ligand, and has a high catalytic activity; and a process for producing a novel bisaryl compound using the palladium catalyst. In the production of a bisaryl compound by reacting an aromatic halide with an aromatic boronic acid in the presence of a palladium catalyst and a base, the palladium catalyst comprises a dendrimer containing a silica particle as a core and a palladium compound dissolved in an ionic liquid and supported on the dendrimer.Type: ApplicationFiled: November 11, 2010Publication date: September 13, 2012Applicant: Niigata UniversityInventors: Hisahiro Hagiwara, Norio Tsubokawa