Polyhydroxy Nitro Containing Patents (Class 568/712)
  • Patent number: 4415487
    Abstract: Bis-betaines of the formula ##STR1## in which R denotes a saturated or an olefinically unsaturated hydrocarbon radical which has 1 to 3 double bonds and 8 to 22 carbon atoms,n.sup.1 and n.sup.2 represent an integer from 2 to 3, and n.sup.1 and n.sup.2 can be identical or different,m.sup.1 and m.sup.2 represent an integer from 1 to 4, and m.sup.1 and m.sup.2 can be identical or different, anda, b, c and d, which are identical or different, each is a number from 1 to 5, but the sum (a+b+c+d) should be at most 10.The compounds are prepared from primary amines of the formula RNH.sub.2, by dicyanoalkylation, hydrogenation, ethoxylation and reaction with alkali metal salts of .omega.-halogenocarboxylic acids. They are suitable for formluating cosmetic and industrial cleaning agents.
    Type: Grant
    Filed: November 8, 1982
    Date of Patent: November 15, 1983
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Gunter Blaschke, Alwin Reng, Jochen M. Quack
  • Patent number: 4324925
    Abstract: An improved process for the preparation of a polyhydric phenol by hydroxylation of a phenol with a peroxidic hydroxylating agent, is disclosed. The improvement resides in that before the hydroxylation, all or some of the mixture to be hydroxylated is treated with a cation exchanger.
    Type: Grant
    Filed: June 30, 1980
    Date of Patent: April 13, 1982
    Assignee: Bayer Aktiengesellschaft
    Inventors: Christoph Jupe, Helmut Waldmann, Hermann Seifert
  • Patent number: 4233245
    Abstract: Tris(hydroxymethyl)aminomethane, an intermediate of organic synthesis, in ystalline form is made by formylation followed by hydrogenation. Nitromethane and formaldehyde in a molar ratio on the order of 1:3 are reacted in a concentrated alcohol medium made up of a 2 to 5% mixture of methylene chloride in methanol, in the presence of 1 to 10 milliequivalents per mole of nitromethane of a solid base catalyst selected from sodium or potassium, with agitation for a period between 3 and 36 hours at a temperature below 50.degree. C.
    Type: Grant
    Filed: January 25, 1979
    Date of Patent: November 11, 1980
    Assignee: Societe Chimique de La Grande Paroisse, Azote et Produits Chimiques
    Inventors: Jean Bourguignon, Marcel-Xavier Sion, Michel Moreau
  • Patent number: 4215228
    Abstract: A novel process for preparing 2-fluoro-2-nitro-3-propanediol by reacting diethyl fluoronitromalonate with formaldehyde in the presence of an alkali metal hydroxide.
    Type: Grant
    Filed: August 14, 1978
    Date of Patent: July 29, 1980
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Kurt Baum, Philip T. Berkowitz
  • Patent number: 4123615
    Abstract: The invention relates to a novel process for producing the threo- and erythro-isomers of 1-phenyl-2-nitro-1,3-propanediol through the aldol-type alkaline condensation of benzaldehyde and nitroethanol, wherein the reaction mixture is acidified and, if desired, the isomers are separated from the obtained isomer mixture and the obtained isomers are transformed into each other through epimerization, characterized in that the condensation and, if desired, also the epimerization are carried out in the presence of catalytical amounts of an alkaline hydroxide.The process according to the invention makes it possible to produce 1-phenyl-2-nitro-1,3-propanediol, an intermediate of the antibiotic chloramphenicol, in high yields, and in an extremely advantageous way which can be carried out simply and economically even on an industrial scale.
    Type: Grant
    Filed: February 23, 1977
    Date of Patent: October 31, 1978
    Assignee: Egyt Gyogyszervegyeszeti Gyar
    Inventors: Laszlo Levai, Gyula Mikite