Ion Exchange Or Sorbent Material Utilized Patents (Class 568/872)
  • Patent number: 4846139
    Abstract: Process for the preparation of crystalline maltitol comprising successively:catalytic hydrogenation of a saccharified starch milk in a vessel 203,a step of chromatographic fractionation of the hydrogenated syrup in a vessel 204,crystallation and separation of the maltitol crystals in vessels 206 and 207 andrecycling through a pipe 309 emerging from the vessel 207 of the crystallization mother-liquors to the head of the chromatographic fractionation step.
    Type: Grant
    Filed: January 6, 1988
    Date of Patent: July 11, 1989
    Assignee: Roquette Freres
    Inventors: Francis Devos, Pierre-Antoine Gouy
  • Patent number: 4605783
    Abstract: An adsorptive method of separating alcohols and aldehydes or ketones and alcohols of monoterpenes is disclosed. The method uses an X-type zeolite containing sodium and potassium cations to selectively adsorb the alcohols thereby allowing recovery of an aldehyde or ketone raffinate stream and, after desorption, an alcohol extract stream. The method is suitable for feed mixtures containing individual or multiple monoterpenoid components.
    Type: Grant
    Filed: March 21, 1985
    Date of Patent: August 12, 1986
    Assignee: UOP Inc.
    Inventor: Hermann A. Zinnen
  • Patent number: 4588847
    Abstract: A process for liquid-phase separation of ethylene glycol from mixtures containing propylene glycol by selective adsorption on at least one aluminosilicate zeolite selected from the group consisting of X zeolite, Y zeolite, and A zeolite is disclosed.
    Type: Grant
    Filed: June 26, 1985
    Date of Patent: May 13, 1986
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Yu-Chia T. Chou
  • Patent number: 4571440
    Abstract: A continuous process for making alkylene glycols by the hydrolysis of alkylene oxides in the presence of selectivity-enhancing organometalate wherein the alkylene glycol-containing hydrolysis product contains organometalate comprises recovering organometalate by extraction with a water-immiscible solvent, separating the resulting organometalate-containing solvent into an organometalate-lean stream for reuse in the extraction and an organometalate-rich stream for reuse in the hydrolysis.
    Type: Grant
    Filed: October 23, 1984
    Date of Patent: February 18, 1986
    Assignee: Union Carbide Corporation
    Inventors: Brian T. Keen, John H. Robson
  • Patent number: 4560813
    Abstract: In processes for making alkylene glycols by the hydrolysis of alkylene oxides in the presence of selectivity-enhancing metalate anion-containing material, metalate anion can be recovered from the alkylene glycol-containing hydrolysis product by contact with a solid having electropositive complexing sites thereon such as anion exchange resins.
    Type: Grant
    Filed: March 28, 1984
    Date of Patent: December 24, 1985
    Assignee: Union Carbide Corporation
    Inventor: Joseph A. Collier
  • Patent number: 4544778
    Abstract: A process for the bulk separation of sorbitol from a solution of a carbohydrate mixture by selective adsorption on a zeolite molecular sieve having a faujasite type structure and having predominantly Ca.sup.++ cations in association with the AlO.sub.2.sup.- tetrahedra thereof.
    Type: Grant
    Filed: August 29, 1984
    Date of Patent: October 1, 1985
    Assignee: Union Carbide Corporation
    Inventors: Chien C. Chao, John D. Sherman
  • Patent number: 4518396
    Abstract: Disclosed is a method and associated apparatus by which glycols may be cleaned, particularly those which have been used to dehydrate natural gas. Glycol contaminated with water, hydrocarbons, salts such as sodium chloride, and other impurities is degassed and physically separated from immiscible liquid hydrocarbons prior to passing through a quantity of absorbent material to remove the bulk of any residual hydrocarbons and filter particulates. The glycol is then routed through strong acid cation and strong base anion exchange resins to remove salts. The net product of the deionization is water which may easily be removed in a reboiler, yielding a clean, reusable glycol. Glycol which is not contaminated by petroleum impurity may be cleaned by strong acid cation and strong base anion exchange means alone.
    Type: Grant
    Filed: March 1, 1983
    Date of Patent: May 21, 1985
    Assignee: Gas Conditioning Industries, Inc.
    Inventor: William E. Rawson
  • Patent number: 4482761
    Abstract: A process for the bulk separation of inositol and/or sorbitol is disclosed which comprises the selective adsorption of same on certain types of zeolitic molecular sieves. The process is especially useful for separating inositol from aqueous solutions containing same, using type X and type Y zeolite adsorbents whose cations are Na, Ca or Ba.
    Type: Grant
    Filed: January 12, 1983
    Date of Patent: November 13, 1984
    Assignee: Union Carbide Corporation
    Inventors: Chien C. Chao, John D. Sherman
  • Patent number: 4456774
    Abstract: Mannitol is separated from admixture with galactitol and/or from sorbitol by selective adsorption on cationic forms of zeolite X and zeolite Y.
    Type: Grant
    Filed: October 13, 1983
    Date of Patent: June 26, 1984
    Assignee: Union Carbide Corporation
    Inventors: John D. Sherman, Chien C. Chao
  • Patent number: 4398046
    Abstract: Standard activated carbons have been commonly employed in the purification of contaminated glycol scrubbing solutions used in a liquid-liquid extraction process for the manufacture of petrochemicals. These carbons are shown to cause a depression of pH within the glycol stream when a new carbon type is installed or when the exhausted carbon is replaced. The use of a magnesite containing activated carbon minimizes this pH drop to acceptable levels.
    Type: Grant
    Filed: April 7, 1982
    Date of Patent: August 9, 1983
    Assignee: Calgon Carbon Corporation
    Inventor: Michael R. Rosene
  • Patent number: 4260827
    Abstract: The invention is directed to a process for the purification of aqueous solutions of low molecular weight polyhydroxyl compounds containing calcium or lead compounds or mixtures thereof. Methanol and a precipitant for calcium and/or lead ions in a quantity equivalent to the ions to be removed are added to the solutions. The deposits thus formed are removed and the residual solutions are treated with a cation exchanger followed by distillation of the low-boiling fractions. The distillation sump which essentially contains the low molecular weight polyhydroxyl compounds is then treated with an anion exchanger.
    Type: Grant
    Filed: December 17, 1979
    Date of Patent: April 7, 1981
    Assignee: Bayer Aktiengesellschaft
    Inventors: Kurt Klinkmann, Raimund Wambach
  • Patent number: 4246431
    Abstract: A process for extracting xylitol from the end syrups of the xylitol crystallization by subjecting the end syrup to chromatographic separation, whereby it will be decomposed into two or more fractions, the first fraction containing mainly the polysaccharides and polysaccharide alcohols and the subsequent fractions containing essentially the pentitols and hexitols.
    Type: Grant
    Filed: June 12, 1979
    Date of Patent: January 20, 1981
    Assignee: Suddeutsche Zucker-Aktiengesellschaft
    Inventors: Mohammad Munir, Hubert Schiweck