Abstract: An improved process for producing perfluoroalkyl iodides of formula (I) F(CF2CF2)n—I??(I) wherein n is an integer from 2 to 3, wherein the improvement comprises contacting at least one perfluoroalkyl iodide of formula (II) and at least one perfluoroalkyl iodide of formula (III) F(CF2CF2)m—I??(II) F(CF2CF2)p—I??(III) wherein m is an integer greater than or equal to 3, and p is an integer equal to or lower than 2, at a) a molar ratio of formula (III) to formula (II) of from about 1:1 to about 6:1, b) a residence time of from about 1 to about 9 seconds, and c) a temperature of from about 450° C. to about 495° C.
Type:
Application
Filed:
June 8, 2010
Publication date:
December 8, 2011
Applicant:
E. I. DU PONT DE NEMOURS AND COMPANY
Inventors:
Stephen Ernest Jacobson, Sourav Kumar Sengupta, John Joseph Hagedorn, Liza Lopez
Abstract: Halogenated aromatics are prepared by heating halogenoformic acid esters to 80.degree. to 280.degree. C. in the presence of hydrogen fluoride or a catalytic amount of one or more Lewis acids from the group comprising aluminium halides, iron halides and antimony halides, and in the liquid phase.
Type:
Grant
Filed:
July 28, 1993
Date of Patent:
April 26, 1994
Assignee:
Bayer Aktiengesellschaft
Inventors:
Norbert Lui, Dietmar Bielefeldt, Albrecht Marhold
Abstract: The present invention relates to new perfluoroalkyl halides and to their preparation by a process based on the thermodecomposition of perfluorocarbides in the presence of Cl.sub.2, Br.sub.2 and I.sub.2.
Abstract: The present invention relates to new perfluoroalkyl halides and to their preparation by a process based on the thermodecomposition of perfluorocarbides in the presence of Cl.sub.2, Br.sub.2 and I.sub.2.
Abstract: A method of manufacturing CF.sub.4 and/or C.sub.2 F.sub.6 characterized by employing a mixed gas of tetrafluoroethylene and carbon dioxide at a mol ratio of less than 4:1 and heating it to a temperature exceeding 900.degree. C.