Increasing The Number Of Carbon Atoms In The Compound Patents (Class 570/237)
  • Patent number: 9382176
    Abstract: Processes for the production of chlorinated propenes are provided. The processes proceed through the production of cyclic intermediate that is thereafter readily converted to a desired chloropropane, e.g., via selective pyrolysis. The process may be conducted using starting materials that are readily commercially available and/or that may be reacted safely in standard laboratory equipment so that capital cost savings may be seen. The process does not require the use of catalysts and yet, process conditions less extreme than many conventional processes for the production of chlorinated propenes are suitable, so that raw material and utility cost savings are also possible.
    Type: Grant
    Filed: February 27, 2014
    Date of Patent: July 5, 2016
    Assignee: BLUE CUBE IP LLC
    Inventors: Matthew L. Grandbois, Brian Murdoch, Matthew M. Meyer
  • Patent number: 8936757
    Abstract: Apparatuses and processes are provided for stripping gaseous hydrocarbons from particulate material. One process comprises the step of contacting particles containing hydrocarbons with a stripping vapor in countercurrent flow to remove at least a portion of the hydrocarbons with the stripping vapor to form stripped particles. Contacting the particles includes advancing the particles down a sloping element of a structured packing toward a reinforcing rod that is disposed along a lower channel portion of the sloping element. The particles are advanced over the reinforcing rod. The particles are contacted with the stripping vapor that is rising up adjacent to the lower channel portion.
    Type: Grant
    Filed: December 28, 2011
    Date of Patent: January 20, 2015
    Assignee: UOP LLC
    Inventors: Erick D. Gamas-Castellanos, Mitchell John Kowalczyk
  • Patent number: 8927792
    Abstract: Processes for the production of chlorinated and/or fluonnated propenes provide good product yield with advantageous impurity profiles in the crude product. Advantageously, the processes may be conducted at lower temperatures than 600° C., or less than 500° C., so that energy savings are provided, and/or at higher pressures so that high throughputs may also be realized. The use of catalysts or initiators may provide additional enhancements to conversion rates and selectivity, as may adjustments to the molar ratio of the reactants.
    Type: Grant
    Filed: May 30, 2012
    Date of Patent: January 6, 2015
    Assignee: Dow AgroSciences, LLC
    Inventors: Max M. Tirtowidjojo, William J. Kruper, Jr., Kurt F. Hirsekorn, Debashis Chakraborty
  • Patent number: 8889924
    Abstract: The present invention provides a simple three step process for the production of 1,3,3,3-tetrafluoropropene (HFO-1234ze). In the first step, carbon tetrachloride is added to vinyl fluoride to afford the compound CCl3CH2CHClF (HCFC-241fb). HCFC-241fb is then fluorinated with anhydrous HF to afford CF3CH2CHClF (HCFC-244fa) in the second step. Dehydrochlorination of HCFC-244fa, in the third step, affords the desired product, CF3CH?CHF (HFO-1234ze). Following similar chemistry, vinyl chloride may be used in place of vinyl fluoride.
    Type: Grant
    Filed: February 4, 2013
    Date of Patent: November 18, 2014
    Assignee: Honeywell International Inc.
    Inventors: Haridasan K. Nair, Rajiv Ratna Singh, Andrew Joseph Poss, David Nalewajek
  • Patent number: 8835702
    Abstract: Disclosed is a process for the manufacture of haloalkane compounds, and more particularly, an improved process for the manufacture of the compound 1,1,1,3,3-penta-chloropropane (HCC-240fa), which mitigates the formation of by-products from vinyl chloride (CH2?CHCl). The present invention is also useful in the manufacture of other haloalkane compounds such as HCC-250 and HCC-360. One embodiment of the invention comprises a method for mitigating 1,1,3,3,5,5-hexachloropentane and 1,1,1,3,5,5-hexachloropentane formation in the HCC-240fa manufacturing process, in which FeCl3, is introduced to a reactor only after the start-up phase has ended and a continuous operation has started. In a preferred embodiment, “pre-chelated” FeCl3, which is concentrated in a catalyst recovery column, is introduced to reactor after the continuous operation has started.
    Type: Grant
    Filed: May 25, 2012
    Date of Patent: September 16, 2014
    Assignee: Honeywell International Inc.
    Inventors: Joshua Close, Haiyou Wang, Hsueh Sung Tung
  • Patent number: 8829254
    Abstract: The present invention describes a process for making CF3CH?CHF (HFO-1234ze). The process involves the addition of carbon tetrachloride (CCl4) to 1,2-dichloroethylene to form CCl3CHClCHCl2. The compound CCl3CHClCHCl2 thus can then either be treated with HF to produce CF3CHClCHClF as the main product, or it can be converted to CCl2?CHCHCl2 (1230za) by dechlorination. CCl2?CHCHCl2 can be treated with HF such that the main product obtained is CF3CHClCHClF. CF3CH?CHCl may be produced as a by-product, but upon treatment with HF, it affords the compound CF3CHClCHClF. The desired compound, CF3CH?CHF (HFO-1234ze), is obtained as a trans/cis mixture by dehydrochlorination of CF3CH2CHClF or by dechlorination of CF3CHClCHClF.
    Type: Grant
    Filed: February 4, 2013
    Date of Patent: September 9, 2014
    Assignee: Honeywell International Inc.
    Inventors: Haridasan K. Nair, Rajiv Ratna Singh, David Nalewajek, Andrew Joseph Poss
  • Publication number: 20140088329
    Abstract: Processes for the production of chlorinated and/or fluonnated propenes provide good product yield with advantageous impurity profiles in the crude product. Advantageously, the processes may be conducted at lower temperatures than 600° C., or less than 500° C., so that energy savings are provided, and/or at higher pressures so that high throughputs may also be realized. The use of catalysts or initiators may provide additional enhancements to conversion rates and selectivity, as may adjustments to the molar ratio of the reactants.
    Type: Application
    Filed: May 30, 2012
    Publication date: March 27, 2014
    Inventors: Max Tirtowidjojo, William J. Kruper, JR., Kurt F. Hirsekorn, Debashis Chakraborty
  • Patent number: 8558041
    Abstract: The present invention provides isothermal multitube reactors suitable for the production of chlorinated and/or fluorinated propene and higher alkenes from the reaction of chlorinated and/or fluorinated alkanes and chlorinated and/or fluorinated alkenes. The reactors utilize a feed mixture inlet temperature at least 20° C. different from a desired reaction temperature.
    Type: Grant
    Filed: October 8, 2010
    Date of Patent: October 15, 2013
    Assignee: Dow Global Technologies, LLC
    Inventors: Max M. Tirtowidjojo, Hua Bai, Debashis Chakraborty, Juergen Eiffler, Heinz Groenewald, Kurt F. Hirsekorn, Manfred Kokott, William J. Kruper, Jr., Thomas U. Luebbe, Avani M. Patel, Shirley S. Sexton, Peter Wenzel, Marcus Wobser
  • Patent number: 8258354
    Abstract: An improved process for producing perfluoroalkyl iodides of formula (I) F(CF2CF2)n—I??(I) wherein n is an integer from 2 to 3, wherein the improvement comprises contacting at least one perfluoroalkyl iodide of formula (II) and at least one perfluoroalkyl iodide of formula (III) F(CF2CF2)m—I??(II) F(CF2CF2)p—I??(III) wherein m is an integer greater than or equal to 3, and p is an integer equal to or lower than 2, at a) a molar ratio of formula (III) to formula (II) of from about 1:1 to about 6:1, b) a residence time of from about 1 to about 9 seconds, and c) a temperature of from about 450° C. to about 495° C.
    Type: Grant
    Filed: June 8, 2010
    Date of Patent: September 4, 2012
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Stephen Ernest Jacobson, Sourav Kumar Sengupta, John Joseph Hagedorn, Liza Lopez
  • Publication number: 20110201840
    Abstract: Disclosed is a process for preparing terminal 1,1-disubstituted alkenes and is to compounds prepared therewith.
    Type: Application
    Filed: February 16, 2010
    Publication date: August 18, 2011
    Applicant: THE CHINESE UNIVERSITY OF HONG KONG
    Inventor: Chun Yu HO
  • Publication number: 20110178343
    Abstract: The present invention provides one-step processes for the production of chlorinated and/or fluorinated propenes. The processes provide good product yield with low, e.g., less than about 20%, or even less than 10%, concentrations of residues/by-products. Advantageously, the processes may be conducted at low temperatures relative to conventional processes, so that energy savings are provided, and/or at higher pressures so that high throughputs may also be realized. The use of catalysts may provide enhancements to conversion rates and selectivity over those seen in conventional processes, as may adjustments to the molar ratio of the reactants.
    Type: Application
    Filed: April 20, 2010
    Publication date: July 21, 2011
    Applicant: DOW GLOBAL TECHNOLOGIES, INC.
    Inventors: William J. Kruper, JR., Max M. Tirtowidjojo, Kurt F. Hirsekorn, Debashis Chakraborty, Juergen Eiffler
  • Publication number: 20110087055
    Abstract: The present invention provides continuous, gas phase, free radical processes for the production of chlorinated and/or fluorinated propenes or higher alkenes from the reaction of chlorinated and/or fluorinated alkanes and chlorinated and/or fluorinated alkenes, wherein wherein at least a portion of any intermediate boiler by-products generated by the process are removed from the process
    Type: Application
    Filed: October 8, 2010
    Publication date: April 14, 2011
    Applicant: DOW GLOBAL TECHNOLOGIES
    Inventors: Max M. Tirtowidjojo, Patrick H. Au-Yeung, Debashis Chakraborty, Juergen Eiffler, Heinz Groenewald, Kurt F. Hirsekorn, Manfred Kokott, William J. Kruper, JR., Thomas U. Luebbe, Holger Meeman, Shirley S. Sexton, Peter Wenzel, Marcus Wobser
  • Publication number: 20110083955
    Abstract: The present invention provides one-step processes for the production of chlorinated and/or fluorinated propenes. The processes provide good product yield with low, e.g., less than about 20%, or even less than 10%, concentrations of residues/by-products. Advantageously, the processes may be conducted at low temperatures than 500° C. so that energy savings are provided, and/or at higher pressures so that high throughputs may also be realized. The use of catalysts or initiators may provide additional enhancements to conversion rates and selectivity, as may adjustments to the molar ratio of the reactants.
    Type: Application
    Filed: October 8, 2010
    Publication date: April 14, 2011
    Applicant: DOW GLOBAL TECHNOLOGIES, INC
    Inventors: Max M. Tirtowidjojo, Debashis Chakraborty, Juergen Eiffler, Kurt F. Hirsekorn, William J. Kruper, JR.
  • Publication number: 20110087054
    Abstract: The present invention provides isothermal multitube reactors suitable for the production of chlorinated and/or fluorinated propene and higher alkenes from the reaction of chlorinated and/or fluorinated alkanes and chlorinated and/or fluorinated alkenes. The reactors utilize a feed mixture inlet temperature at least 20° C. different from a desired reaction temperature.
    Type: Application
    Filed: October 8, 2010
    Publication date: April 14, 2011
    Applicant: DOW GLOBAL TECHNOLOGIES
    Inventors: Max M. Tirtowidjojo, Hua Bai, Debashis Chakraborty, Juergen Eiffler, Heinz Groenewald, Kurt F. Hirsekorn, Manfred Kokott, William J. Kruper, JR., Thomas U. Luebbe, Avani M. Patel, Shirley S. Sexton, Peter Wenzel, Marcus Wobser
  • Patent number: 7786332
    Abstract: In a process for the preparation of ring compounds via a combinatorial synthesis, the reaction procedure is based on a Suzuki coupling, subsequent halo-demetallation and finally a further Suzuki coupling. The Suzuki couplings are each carried out with a boronic acid or a boronic acid ester. The reaction procedure uses provides novel ring compounds and uses novel synthesis units used for this purpose. The novel ring compounds are suitable for use as constituents in liquid-crystalline mixtures.
    Type: Grant
    Filed: August 8, 2008
    Date of Patent: August 31, 2010
    Assignee: Merck Patent GmbH
    Inventors: Detlef Pauluth, Peer Kirsch, Peter Baeuerle, Oliver Deeg
  • Patent number: 7411100
    Abstract: In a process for the preparation of ring compounds via a combinatorial synthesis, the reaction procedure is based on a Suzuki coupling, subsequent halo-demetallation and finally a further Suzuki coupling. The Suzuki couplings are each carried out with a boronic acid or a boronic acid ester. The reaction procedure uses provides novel ring compounds and uses novel synthesis units used for this purpose. The novel ring compounds are suitable for use as constituents in liquid-crystalline mixtures.
    Type: Grant
    Filed: May 22, 2006
    Date of Patent: August 12, 2008
    Assignee: Merck GmbH
    Inventors: Detlef Pauluth, Peer Kirsch, Peter Baeuerle, Oliver Deeg
  • Patent number: 7312350
    Abstract: The invention relates to a process for preparing arylvinyl halides and sulphonates and arylalkynes by reacting haloaromatics or aryl sulphonates with vinyl halides or sulphonates in the presence of a palladium catalyst and a base and, if appropriate, subsequent elimination.
    Type: Grant
    Filed: January 5, 2004
    Date of Patent: December 25, 2007
    Assignee: LANXESS Deutschland GmbH
    Inventors: Wolfgang Ebenbeck, Florian Rampf
  • Patent number: 7253328
    Abstract: A method is provided for producing vinyl chloride monomer from methyl chloride and methylene chloride. In the method, methyl chloride is reacted with methylene chloride in the vapor phase in the presence of a catalyst to produce vinyl chloride and hydrogen chloride. The reaction temperature is in the range of from about 300° C. to 500° C. The catalyst is selected from the group alumina gel, gamma-alumina, zinc chloride on active alumina, silica-alumina, zeolite, and silicon-aluminum-phosphorus oxide.
    Type: Grant
    Filed: January 24, 2005
    Date of Patent: August 7, 2007
    Inventor: John Stauffer
  • Patent number: 6806396
    Abstract: The present invention relates to the co-pyrolysis of fluoroform and chlorodifluoromethane to form a mixture of useful fluoroolefin and saturated HFCs, notably, tetrafluoroethylene and hexafluoropropylene and CF3CHF2 and CF3CHFCF3, respectively.
    Type: Grant
    Filed: December 16, 2002
    Date of Patent: October 19, 2004
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Peter Gideon Gelblum, Velliyur Nott Mallikarjuna Rao, Charles Joseph Noelke, Norman Herron
  • Publication number: 20040192952
    Abstract: The invention relates to a process for preparing arylvinyl halides and sulphonates and arylalkynes by reacting haloaromatics or aryl sulphonates with vinyl halides or sulphonates in the presence of a palladium catalyst and a base and, if appropriate, subsequent elimination.
    Type: Application
    Filed: January 5, 2004
    Publication date: September 30, 2004
    Inventors: Wolfgang Ebenbeck, Florian Rampf
  • Publication number: 20040186328
    Abstract: This invention has as its object a process for preparation of vinyl aryl derivatives by an electrochemical path.
    Type: Application
    Filed: December 23, 2003
    Publication date: September 23, 2004
    Inventors: Jacques Perichon, Corinne Gosmini, Mylene Bastienne, Paulo Gomes
  • Publication number: 20030149272
    Abstract: The invention concerns a method for preparing a polyaromatic compound comprising at least a chain formation of two aromatic cycles. The method for preparing a polycyclic aromatic compound comprising at least a chain formation of two aromatic cycles is characterised in that it consists in reacting an aromatic compound bearing a leaving group and an alkaline organometallic compound, in the presence of an efficient amount of a nickel catalyst, said element being optionally complexed with at least a co-ordination agent or ligand.
    Type: Application
    Filed: November 4, 2002
    Publication date: August 7, 2003
    Inventors: Henri-Jean Cristau, Corinne Bouchitte, Marc Taillefer, Jean-Francis Spindler, Thierry Schlama
  • Patent number: 6060630
    Abstract: The present invention relates to a process for the production of perchloroethylene by non-catalytic thermal chlorination of hydrocarbons, of partially chlorinated hydrocarbons and/or of mixtures thereof, combined with the conversion into perchloroethylene of CCl.sub.4 obtained from external sources.
    Type: Grant
    Filed: December 15, 1998
    Date of Patent: May 9, 2000
    Assignee: Solvay (Societe Anonyme)
    Inventors: Michel Monzain, Eric Bouilhot
  • Patent number: 5446203
    Abstract: Alternative methods for synthesizing haloenones and haloakenes and their use as starting materials for synthesis of substituted or unsubstituted alkyl and aryl substituted enones and alkenes, including tamoxifen and tamoxifen analogs, using such haloenones and haloalkenes.
    Type: Grant
    Filed: July 29, 1993
    Date of Patent: August 29, 1995
    Assignee: New York University
    Inventor: Edward McNelis
  • Patent number: 5426256
    Abstract: Perchloroethylene and hydrogen chloride are made by thermal noncatalytic chlorination of hydrocarbons and/or their partially chlorinated derivatives using carbon tetrachloride as a reactive diluent under conditions which maximize consumption of carbon tetrachloride and minimize the production of heavy ends, such as hexachlorobenzene and other tarry products.
    Type: Grant
    Filed: June 1, 1994
    Date of Patent: June 20, 1995
    Assignee: Vulcan Materials Company
    Inventor: Jimmie T. Petrosky
  • Patent number: 5399797
    Abstract: Perchloroethylene and hydrogen chloride are made by noncatalytic thermal chlorination of hydrocarbons and/or their partially chlorinated derivatives by reacting them with chlorine in the presence of hydrogen and carbon tetrachloride as a reactive diluent, under conditions which maximize consumption of carbon tetrachloride and minimize the production of heavy ends, such as hexachlorobenzene and other tarry products.
    Type: Grant
    Filed: February 22, 1994
    Date of Patent: March 21, 1995
    Assignee: Vulcan Materials Company
    Inventors: Jimmie T. Petrosky, Steven R. Hieger, Evert E. Gannaway, Charles R. Cupit
  • Patent number: 5315050
    Abstract: Perchloroethylene and hydrogen chloride are made by thermal noncatalytic pyrolysis of carbon tetrachloride in the presence of elemental hydrogen and chlorine under conditions which maximize consumption of carbon tetrachloride while minimizing the production of heavy ends.
    Type: Grant
    Filed: February 11, 1993
    Date of Patent: May 24, 1994
    Assignee: Vulcan Materials Company
    Inventor: Jimmie T. Petrosky
  • Patent number: 5212248
    Abstract: Hydrocarbons and polymers thereof, of the structure (I)R--C(CH.sub.3).sub.2 --CH.sub.2 --C(CH.sub.3).sub.2 --CH.sub.2 --CH.dbd.CH--CH.sub.2 --Cl (I)where R is a hydrocarbon radical, are prepared by reacting corresponding starting materials which contain chlorine bonded to tertiary carbon, of the structureR--C(CH.sub.3).sub.2 --CH.sub.2 --C(CH.sub.3).sub.2 --Cl (II)with from 1 to 10 moles of butadiene in the presence of a Friedel-Crafts catalyst in a solvent which is inert to the catalyst, and the hydrocarbons or polymers thereof can be reacted in a further step of the process with a compound from the group comprising ammonia, primary or secondary amine or polyamine, amino alcohol, amino ether, hydrazine or hydrazine which is substituted up to three times.
    Type: Grant
    Filed: August 14, 1991
    Date of Patent: May 18, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Konrad Knoll, Klaus Bronstert, Dietmar Bender
  • Patent number: 5208393
    Abstract: A process for the manufacture of chloroform by catalytic hydrogenolysis of carbon tetrachloride in liquid phase, wherein liquid phase carbon tetrachloride is reacted with hydrogen gas or a gas containing molecular hydrogen, at a pressure below 8,000 kPa and at a temperature below 250.degree. C., in the presence of a catalyst formed by a metal selected from the group consisting of palladium, rhodium, ruthenium and platinum, deposited on a substrate and held in suspension in the liquid.
    Type: Grant
    Filed: August 2, 1991
    Date of Patent: May 4, 1993
    Assignee: Ercros, S.A.
    Inventors: Emilio Tijer Miquel, Jose M. Sule Gimenez, Antonio Cortes Arroyo, Xose L. Seoane Gomez, Adolfo Arcoya Martin
  • Patent number: 4818442
    Abstract: A process for the disproportionation of olefins comprising contacting said olefins under suitable reaction conditions with a neutral-carbene complex catalyst and then using anhydrous ammonia to effect separation of the catalyst and the organic products.
    Type: Grant
    Filed: October 9, 1984
    Date of Patent: April 4, 1989
    Assignee: Phillips Petroleum Company
    Inventors: John W. Vanderveen, Dennis S. Banasiak
  • Patent number: 4571438
    Abstract: A process for the preparation of olefinic aldehydes and intermediates is disclosed. The condensation of an .alpha.,.omega.-dihalide with a metal acetylide gives an acetylenic halide which can be reduced to give an olefinic halide, then oxidized to give the desired olefinic aldehyde or the acetylenic halide can be oxidized first to give an acetylenic aldehyde and then reduced to give the desired olefinic aldehyde.
    Type: Grant
    Filed: March 21, 1985
    Date of Patent: February 18, 1986
    Assignee: Phillips Petroleum Company
    Inventors: Jim D. Byers, Dennis S. Banasiak
  • Patent number: 4556741
    Abstract: This invention relates to a process for dismuting functionalized olefins using a catalyst which has rhenium heptoxide on phosphated alumina and a metal hydrocarbon compound such as an alkyl tin. The olefins that may be dismuted are those which have a hetero atom such as oxygen, nitrogen or halide in the chain. Specific examples are olefinic compounds which have an ester, ether or a ketone group. The products of the reaction are useful chemical intermediates.
    Type: Grant
    Filed: November 28, 1983
    Date of Patent: December 3, 1985
    Assignee: BP Chemicals Limited
    Inventor: Malcolm J. Lawrenson
  • Patent number: 4540826
    Abstract: A process for the preparation of olefinic aldehydes and intermediates is disclosed. The condensation of an .alpha.,.omega.-dihalide with a metal acetylide gives an acetylenic halide which can be reduced to give an olefinic halide, then oxidized to give the desired olefinic aldehyde or the acetylenic halide can be oxidized first to give an acetylenic aldehyde and then reduced to give the desired olefinic aldehyde.
    Type: Grant
    Filed: August 12, 1983
    Date of Patent: September 10, 1985
    Assignee: Phillips Petroleum Company
    Inventors: Dennis S. Banasiak, Jim D. Byers
  • Patent number: 4471096
    Abstract: Vinyl chloride polymers are prepared by polymerizing a monomer component that comprises vinyl chloride in an aqueous medium in the presence of a free radical-generating polymerization initiator and 0.01% to 2% by weight, based on the weight of the monomer component, of a chain-transfer agent that is a mercapto organic compound having at least one beta-ether linkage. The process can be used to produce low molecular weight vinyl chloride polymers.
    Type: Grant
    Filed: August 3, 1982
    Date of Patent: September 11, 1984
    Assignee: Tenneco Polymers, Incorporated
    Inventors: Zaev Sharaby, Donald Goodman
  • Patent number: 4342704
    Abstract: A process for the preparation of a 1,1-dichloroalkene of the formula ##STR1## in which R.sup.1 is hydrogen or an optionally substituted alkyl, alkenyl, alkynyl, aralkyl or aryl radical, andR.sup.2 is an optionally substituted alkyl, alkenyl, alkynyl, aralkyl, aralkenyl or aryl radical, or cycloalkyl which is optionally substituted by halogen, alkyl, alkanoyl, carbamoyl, cyano or phenyl, orR.sup.1 and R.sup.2 together form a hydrocarbon chain which is optionally branched and/or optionally contains a fused benzene ring,comprising reacting an aldehyde or ketone of the formula ##STR2## with a dichloromethane-phosphonic acid ester of the formula ##STR3## in which R.sup.3 each independently is alkyl or phenyl or the two radicals R.sup.3 together are alkanediyl,in the presence of a base at a temperature between about -50.degree. and +50.degree. C.
    Type: Grant
    Filed: July 2, 1980
    Date of Patent: August 3, 1982
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hellmut Hoffmann, Fritz Maurer, Uwe Priesnitz, Hans-Jochem Riebel
  • Patent number: 4271080
    Abstract: Tetrahydrofuran is prepared by reacting a 1,4-dihalobutane with water in the vapor phase in the presence of a catalytically effective amount of at least one solid acidic elemental oxide and/or solid acidic mixed elemental oxide, or acidic ion exchange resin which is stable under reaction conditions.
    Type: Grant
    Filed: June 16, 1980
    Date of Patent: June 2, 1981
    Assignee: National Distillers and Chemical Corp.
    Inventor: Jawad H. Murib
  • Patent number: 4233230
    Abstract: A process for preparing esters and halides is disclosed comprising the step of reacting a cyclic olefin having the formula I ##STR1## wherein R.sub.1 and R.sub.4 are the same or different from each other and each represents hydrogen, methyl, or ethyl;R.sub.2 and R.sub.3 are the same or different from each other and each represents hydrogen or alkyl containing 1 to 5 carbon atoms; andn represents a whole number from 2 to 12, with an acyclic olefin having the formula II ##STR2## wherein R.sub.5 represents hydrogen, methyl, ethyl or the group ##STR3## wherein R.sub.12 and R.sub.13 are the same or different from each other and each represents hydrogen or alkyl containing 1 to 5 carbon atoms;Y represents halogen; an acyloxy group R.sub.14 --CO--O wherein R.sub.14 represents alkyl containing 1-12 carbon atoms, phenyl or phenyl alkyl containing 7-12 carbon atoms, or an oxycarbonyl group R.sub.15 --O--CO wherein R.sub.
    Type: Grant
    Filed: May 4, 1978
    Date of Patent: November 11, 1980
    Assignee: Rhone-Poulenc Industries
    Inventor: Jean Otton